EP0774468A3 - Catalyseurs de polymérisation par addition à geométrie restreinte, procédés pour leur préparation, précurseurs, procédés d'utilisation et polymères obtenus. - Google Patents

Catalyseurs de polymérisation par addition à geométrie restreinte, procédés pour leur préparation, précurseurs, procédés d'utilisation et polymères obtenus. Download PDF

Info

Publication number: EP0774468A3
Authority: EP; European Patent Office
Prior art keywords: processes; preparation; methods; novel polymers; addition polymerization
Prior art date: 1989-08-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP96119530A

Other languages

German (de)

English (en)

Other versions

EP0774468B1 (fr

EP0774468A2 (fr

Inventor

James C. Stevens

Peter N. Nickias

Francis J. Timmers

Robert K. Rosen

David R. Wilson

George W. Knight

Gregory F. Schmidt

Shih-Yaw Lai

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-08-31

Filing date

1990-08-30

Publication date

1998-02-11

1990-08-30 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1997-05-21 Publication of EP0774468A2 publication Critical patent/EP0774468A2/fr

1998-02-11 Publication of EP0774468A3 publication Critical patent/EP0774468A3/fr

2002-09-18 Application granted granted Critical

2002-09-18 Publication of EP0774468B1 publication Critical patent/EP0774468B1/fr

2010-08-30 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0838—Copolymers of ethene with aromatic monomers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerization Catalysts (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Catalysts (AREA)
Compositions Of Macromolecular Compounds (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Polyamides (AREA)
Graft Or Block Polymers (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Peptides Or Proteins (AREA)
Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)

EP96119530A 1989-08-31 1990-08-30 Catalyseurs de polymérisation par addition, procédés pour leur préparation, précurseurs et procédés d'utilisation Expired - Lifetime EP0774468B1 (fr)

Applications Claiming Priority (15)

Application Number	Priority Date	Filing Date	Title
US40134589A	1989-08-31	1989-08-31
US40134489A	1989-08-31	1989-08-31
US401345		1989-08-31
US401344		1989-08-31
US42808289A	1989-10-27	1989-10-27
US42827689A	1989-10-27	1989-10-27
US42828389A	1989-10-27	1989-10-27
US428082		1989-10-27
US428283		1989-10-27
US428276		1989-10-27
US43652489A	1989-11-14	1989-11-14
US436524		1989-11-14
US54540390A	1990-07-03	1990-07-03
US545403		1990-07-03
EP90309496A EP0416815B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus

Related Parent Applications (2)

Application Number	Title	Priority Date	Filing Date
EP90309496.9 Division		1990-08-30
EP90309496A Division EP0416815B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus

Publications (3)

Publication Number	Publication Date
EP0774468A2 EP0774468A2 (fr)	1997-05-21
EP0774468A3 true EP0774468A3 (fr)	1998-02-11
EP0774468B1 EP0774468B1 (fr)	2002-09-18

Family

ID=27569750

Family Applications (6)

Application Number	Title	Priority Date	Filing Date
EP96119603A Expired - Lifetime EP0765888B1 (fr)	1989-08-31	1990-08-30	Un polymere pseudo-aléatoire de alpha-olefine et un monomere vinylidene polymerisable
EP96119530A Expired - Lifetime EP0774468B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation par addition, procédés pour leur préparation, précurseurs et procédés d'utilisation
EP96119394A Withdrawn EP0764654A3 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymerisation par réaction d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
EP90309496A Expired - Lifetime EP0416815B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
EP96119258A Expired - Lifetime EP0764653B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation, leur procédé de préparation, les précurseurs et procédé d'utilisation
EP96119354A Withdrawn EP0764664A3 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation par réaction d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus

Family Applications Before (1)

Application Number	Title	Priority Date	Filing Date
EP96119603A Expired - Lifetime EP0765888B1 (fr)	1989-08-31	1990-08-30	Un polymere pseudo-aléatoire de alpha-olefine et un monomere vinylidene polymerisable

Family Applications After (4)

Application Number	Title	Priority Date	Filing Date
EP96119394A Withdrawn EP0764654A3 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymerisation par réaction d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
EP90309496A Expired - Lifetime EP0416815B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
EP96119258A Expired - Lifetime EP0764653B1 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation, leur procédé de préparation, les précurseurs et procédé d'utilisation
EP96119354A Withdrawn EP0764664A3 (fr)	1989-08-31	1990-08-30	Catalyseurs de polymérisation par réaction d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus

Country Status (16)

Country	Link
US (6)	US5703187A (fr)
EP (6)	EP0765888B1 (fr)
JP (3)	JP2535249B2 (fr)
KR (3)	KR100191380B1 (fr)
AT (4)	ATE224399T1 (fr)
CA (1)	CA2024333C (fr)
DE (5)	DE69034005T2 (fr)
ES (4)	ES2179148T3 (fr)
FI (1)	FI109422B (fr)
HK (1)	HK1001918A1 (fr)
HU (1)	HU209316B (fr)
IL (1)	IL95542A0 (fr)
MY (1)	MY110234A (fr)
NO (1)	NO176964C (fr)
NZ (1)	NZ235032A (fr)
PL (1)	PL166689B1 (fr)

Families Citing this family (797)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5264405A (en) *	1989-09-13	1993-11-23	Exxon Chemical Patents Inc.	Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5621126A (en) *	1987-01-30	1997-04-15	Exxon Chemical Patents Inc.	Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
USRE37788E1 (en) *	1987-01-30	2002-07-09	Exxon Chemical Patents, Inc.	Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5055438A (en) *	1989-09-13	1991-10-08	Exxon Chemical Patents, Inc.	Olefin polymerization catalysts
GB8914703D0 (en) *	1989-06-27	1989-08-16	Dow Europ Sa	Bioriented film
US5763547A (en) *	1992-10-02	1998-06-09	The Dow Chemical Company	Supported catalyst complexes for olefin in polymerization
US6087447A (en) *	1989-08-31	2000-07-11	The Dow Chemical Company	Blends of substantially random interpolymers with vinyl or vinylidene aromatic polymers
TW408155B (en) *	1989-08-31	2000-10-11	Dow Chemical Co	Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers
NZ235032A (en)	1989-08-31	1993-04-28	Dow Chemical Co	Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) *	1989-09-13	1991-06-25	Exxon Chemical Patents Inc.	Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5420217A (en) *	1989-09-13	1995-05-30	Exxon Chemical Patents Inc.	Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US6265338B1 (en) *	1989-09-13	2001-07-24	Exxon Chemical Patents, Inc.	Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts
US5547675A (en) *	1989-09-13	1996-08-20	Exxon Chemical Patents Inc.	Modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins
CA2024830A1 (fr) *	1989-09-29	1991-03-30	Richard E. Campbell, Jr.	Procede de preparation de polymeres syndiotactiques de vinyl aromatique
US6294625B1 (en)	1990-03-20	2001-09-25	Exxonmobil Chemical Patents Inc.	Catalyst system of enhanced productivity and its use in polymerization process
EP0670334A3 (fr) †	1990-06-22	1995-09-13	Exxon Chemical Patents Inc.	Catalyseurs à base de métallocène monocyclopentadienylique dépourvus d'aluminium destinées à la polymérisation d'oléfines
US5272236A (en) *	1991-10-15	1993-12-21	The Dow Chemical Company	Elastic substantially linear olefin polymers
US6538080B1 (en)	1990-07-03	2003-03-25	Bp Chemicals Limited	Gas phase polymerization of olefins
CA2060019A1 (fr) *	1991-03-04	1992-09-05	Phil Marvin Stricklen	Procede d'obtention de polyolefines a distribution bimodale des pm
JP2927566B2 (ja) *	1991-03-28	1999-07-28	出光興産株式会社	スチレン系共重合体の製造方法
JP3275211B2 (ja) *	1991-05-20	2002-04-15	ザダウケミカルカンパニー	付加重合触媒の製造方法
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- 1990-08-31 JP JP2228538A patent/JP2535249B2/ja not_active Expired - Lifetime
1994
- 1994-03-14 JP JP6079125A patent/JP2684154B2/ja not_active Expired - Lifetime
- 1994-03-14 JP JP6079126A patent/JP2623070B2/ja not_active Expired - Lifetime
1995
- 1995-06-06 US US08/469,828 patent/US5703187A/en not_active Expired - Lifetime
- 1995-08-30 KR KR1019950028873A patent/KR100191226B1/ko not_active IP Right Cessation
- 1995-08-30 KR KR1019950028874A patent/KR0181710B1/ko not_active IP Right Cessation
1996
- 1996-08-26 US US08/703,264 patent/US6013819A/en not_active Expired - Fee Related
1998
- 1998-02-06 HK HK98100901A patent/HK1001918A1/xx not_active IP Right Cessation
- 1998-04-13 US US09/059,095 patent/US6858557B1/en not_active Expired - Fee Related
- 1998-04-13 US US09/059,636 patent/US6884857B1/en not_active Expired - Fee Related
2000
- 2000-05-18 US US09/573,414 patent/US6670432B1/en not_active Expired - Fee Related
2001
- 2001-11-06 US US10/037,335 patent/US6806326B2/en not_active Expired - Fee Related

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Title
No relevant documents disclosed *

Also Published As

Publication number	Publication date
AU6203990A (en)	1991-03-07
JP2535249B2 (ja)	1996-09-18
US6858557B1 (en)	2005-02-22
EP0774468B1 (fr)	2002-09-18
DE69031255T2 (de)	1998-03-05
HUT59423A (en)	1992-05-28
DE69034004T2 (de)	2003-06-05
KR100191380B1 (ko)	1999-06-15
EP0765888B1 (fr)	2007-08-29
NZ235032A (en)	1993-04-28
FI904276A0 (fi)	1990-08-30
DE69034250D1 (de)	2007-10-11
DE774468T1 (de)	1999-06-02
EP0416815A3 (en)	1992-03-11
CA2024333A1 (fr)	1991-03-01
ES2106020T3 (es)	1997-11-01
FI109422B (fi)	2002-07-31
US6013819A (en)	2000-01-11
ES2289748T3 (es)	2008-02-01
EP0764653A2 (fr)	1997-03-26
KR100191226B1 (en)	1999-06-15
EP0764653A3 (fr)	1998-02-11
ATE156827T1 (de)	1997-08-15
ES2179148T3 (es)	2003-01-16
JPH0770223A (ja)	1995-03-14
PL166689B1 (pl)	1995-06-30
DE69031255D1 (de)	1997-09-18
JPH03163088A (ja)	1991-07-15
EP0764653B1 (fr)	2002-09-18
NO176964B (no)	1995-03-20
HK1001918A1 (en)	1998-07-17
EP0764654A3 (fr)	1998-02-11
DE69034005T2 (de)	2003-06-05
ATE371676T1 (de)	2007-09-15
HU905704D0 (en)	1991-03-28
KR910004676A (ko)	1991-03-29
US5703187A (en)	1997-12-30
JPH0753618A (ja)	1995-02-28
JP2684154B2 (ja)	1997-12-03
EP0764654A2 (fr)	1997-03-26
KR0181710B1 (ko)	1999-05-15
EP0764664A2 (fr)	1997-03-26
EP0416815B1 (fr)	1997-08-13
US6670432B1 (en)	2003-12-30
US6884857B1 (en)	2005-04-26
US20020128403A1 (en)	2002-09-12
NO176964C (no)	1995-06-28
MY110234A (en)	1998-03-31
EP0765888A2 (fr)	1997-04-02
US6806326B2 (en)	2004-10-19
DE69034005D1 (de)	2002-10-24
DE69034250T2 (de)	2008-05-21
KR960003536A (ko)	1996-01-26
EP0774468A2 (fr)	1997-05-21
ATE224400T1 (de)	2002-10-15
EP0764664A3 (fr)	1998-02-11
JP2623070B2 (ja)	1997-06-25
EP0416815A2 (fr)	1991-03-13
IL95542A0 (en)	1991-06-30
NO903797D0 (no)	1990-08-30
DE69034004D1 (de)	2002-10-24
ATE224399T1 (de)	2002-10-15
NO903797L (no)	1991-03-01
CA2024333C (fr)	2001-01-16
HU209316B (en)	1994-04-28
PL286684A1 (en)	1992-06-26
ES2179145T3 (es)	2003-01-16
AU645519B2 (en)	1994-01-20
EP0765888A3 (fr)	1998-02-11

Publication	Publication Date	Title
EP0764664A3 (fr)	1998-02-11	Catalyseurs de polymérisation par réaction d'addition à géométrie restreinte, leur procédé de préparation, les précurseurs, procédés d'utilisation et polymères obtenus
EP0812862A3 (fr)	1998-04-29	Procédé de polymérisation d'oléfines
MY121287A (en)	2006-01-28	Cyclopentaphenanthrenyl titanium complexes and polymerization process
MY108939A (en)	1996-11-30	Catalyst compositions and process for preparing polyolefins
EP0241560A4 (fr)	1988-01-28	Catalyseur de polymerisation d'olefines et procede de preparation d'un polymere d'olefines en utilisant ledit catalyseur.
CA2019256A1 (fr)	1990-12-26	Copolymere alternant des groupes ethylene et vinyliques aromatiques, et procede pour sa production
MY107310A (en)	1995-11-30	Syndiotactic polymers from arylcyclobutene functional monomers, process for preparation and crosslinked derivatives thereof.
MY110241A (en)	1998-03-31	Olefin polymerization process.
ES2118265T3 (es)	1998-09-16	Copolimerizacion de tetrahidrofuranos y anhidridos ciclicos.
TW372979B (en)	1999-11-01	Hydrogenated asymmetric radial copolymer
JPS5330686A (en)	1978-03-23	Preparation of ethylene-propylene block copolymers
MY132469A (en)	2007-10-31	Improved syndiotactic vinylidenearomatic polymerization process
DE69411381D1 (de)	1998-08-06	Verfahren zur Herstellung von geträgertem Katalysator und seine Verwendung bei der Polymerisation oder Copolymerisation von Ethylen
JPS649206A (en)	1989-01-12	Polymerization of olefin
FI970960A (fi)	1997-03-06	Menetelmä olefiinien polymeroimiseksi ja näin saadut polymeerit ja kopolymeerit

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