ZA200503105B - Amphoteric fluorescent whitening agents - Google Patents
Amphoteric fluorescent whitening agents Download PDFInfo
- Publication number
- ZA200503105B ZA200503105B ZA200503105A ZA200503105A ZA200503105B ZA 200503105 B ZA200503105 B ZA 200503105B ZA 200503105 A ZA200503105 A ZA 200503105A ZA 200503105 A ZA200503105 A ZA 200503105A ZA 200503105 B ZA200503105 B ZA 200503105B
- Authority
- ZA
- South Africa
- Prior art keywords
- formula
- compound
- compounds
- som
- formulae
- Prior art date
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- 239000006081 fluorescent whitening agent Substances 0.000 title claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 86
- -1 sulphonamido Chemical group 0.000 claims description 68
- 239000001257 hydrogen Substances 0.000 claims description 61
- 229910052739 hydrogen Inorganic materials 0.000 claims description 61
- 239000000203 mixture Substances 0.000 claims description 48
- 150000002431 hydrogen Chemical class 0.000 claims description 40
- 229910052757 nitrogen Inorganic materials 0.000 claims description 31
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 19
- REJHVSOVQBJEBF-UHFFFAOYSA-N 5-azaniumyl-2-[2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 230000002087 whitening effect Effects 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 150000002440 hydroxy compounds Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 12
- 239000011734 sodium Chemical group 0.000 description 12
- 229910052708 sodium Chemical group 0.000 description 12
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 150000002367 halogens Chemical group 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 239000011591 potassium Chemical group 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 5
- 125000004430 oxygen atom Chemical group O* 0.000 description 5
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- RWFZHFYWPYSEOZ-UHFFFAOYSA-N 1,2-diphenyl-N,N'-bis(triazin-4-yl)ethene-1,2-diamine Chemical compound N1=NN=C(C=C1)NC(=C(C1=CC=CC=C1)NC1=NN=NC=C1)C1=CC=CC=C1 RWFZHFYWPYSEOZ-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 125000006239 protecting group Chemical group 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- 125000004809 1-methylpropylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000004810 2-methylpropylene group Chemical group [H]C([H])([H])C([H])(C([H])([H])[*:2])C([H])([H])[*:1] 0.000 description 1
- YTZWQUYIRHGHMJ-UHFFFAOYSA-N 3-(1,2-diamino-2-phenylethenyl)benzene-1,2-disulfonic acid Chemical group NC(=C(C1=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)N)C1=CC=CC=C1 YTZWQUYIRHGHMJ-UHFFFAOYSA-N 0.000 description 1
- GHBWBMDGBCKAQU-OWOJBTEDSA-N 5-amino-2-[(e)-2-(4-nitro-2-sulfophenyl)ethenyl]benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C([N+]([O-])=O)C=C1S(O)(=O)=O GHBWBMDGBCKAQU-OWOJBTEDSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- ZNSMQAWUTCXMJI-UHFFFAOYSA-N ethane-1,2-diamine;2-methyloxirane;oxirane Chemical class C1CO1.CC1CO1.NCCN ZNSMQAWUTCXMJI-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LJJVZJSGXHJIPP-UHFFFAOYSA-N ethylpentyl Chemical group [CH2+]CCC[CH]C[CH2-] LJJVZJSGXHJIPP-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3955—Organic bleaching agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Detergent Compositions (AREA)
- Plural Heterocyclic Compounds (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405998 | 2002-11-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200503105B true ZA200503105B (en) | 2006-07-26 |
Family
ID=32319718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200503105A ZA200503105B (en) | 2002-11-19 | 2005-04-18 | Amphoteric fluorescent whitening agents |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US7247174B2 (fr) |
| EP (2) | EP1674616B1 (fr) |
| JP (1) | JP2006506492A (fr) |
| KR (1) | KR20050085044A (fr) |
| CN (2) | CN100522951C (fr) |
| AU (1) | AU2003288033B2 (fr) |
| BR (1) | BR0316400A (fr) |
| CA (1) | CA2504256A1 (fr) |
| MX (2) | MXPA05005347A (fr) |
| PL (1) | PL377038A1 (fr) |
| RU (1) | RU2356898C2 (fr) |
| WO (1) | WO2004046293A2 (fr) |
| ZA (1) | ZA200503105B (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7863236B2 (en) * | 2003-03-24 | 2011-01-04 | Ciba Specialty Chemicals Corp. | Detergent compositions |
| JP4385885B2 (ja) * | 2004-07-27 | 2009-12-16 | パナソニック電工株式会社 | 半導体封止用エポキシ樹脂組成物とそれを用いた半導体装置 |
| JP2008517129A (ja) * | 2004-10-20 | 2008-05-22 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 紙用蛍光増白剤としての両性の４−４’−ビス（トリアジニルアミノ）スチルベン−２，２’−ジスルホン酸誘導体 |
| JP4917274B2 (ja) * | 2005-03-22 | 2012-04-18 | 日本製紙株式会社 | 水剥離性塗工紙及びその製造方法 |
| CN101198686B (zh) * | 2005-06-15 | 2012-04-18 | 西巴特殊化学制品控股公司 | 用于增白合成织物的洗烫方法 |
| IT1395341B1 (it) * | 2009-04-10 | 2012-09-14 | 3V Sigma Spa | Composizioni per la patinatura della carta |
| SI2302132T1 (sl) * | 2009-09-17 | 2012-12-31 | Blankophor Gmbh Co. Kg | Fluorescentna belilna sredstva disulfo-tipa |
| JP5698348B2 (ja) * | 2010-05-18 | 2015-04-08 | ミリケン・アンド・カンパニーＭｉｌｌｉｋｅｎ ＆ Ｃｏｍｐａｎｙ | 蛍光増白剤およびそれを含む組成物 |
| JP5612198B2 (ja) | 2010-05-18 | 2014-10-22 | ミリケン・アンド・カンパニーＭｉｌｌｉｋｅｎ ＆ Ｃｏｍｐａｎｙ | 光学的増白剤及びそれを含んだ組成物 |
| EP2518058B1 (fr) * | 2011-04-27 | 2014-10-29 | Clariant International Ltd. | Nouveaux dérivés de bis-(triazinylamino)-stilbène |
| CN102320779B (zh) * | 2011-06-21 | 2012-12-05 | 云浮市新富云岗石有限公司 | 一种凯撒米黄人造岗石及其制备方法 |
| PT2781648E (pt) | 2013-03-21 | 2016-03-07 | Clariant Int Ltd | Agentes de branqueamento ótico para impressão a jato de tinta de alta qualidade |
| CN104650684B (zh) * | 2013-11-15 | 2019-04-23 | 罗门哈斯公司 | 冻融稳定的漆制剂 |
| CN109504369A (zh) * | 2018-11-28 | 2019-03-22 | 贺州学院 | 一种磺酰胺基二苯乙烯二磺酸类色差改良剂 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL252972A (fr) | 1959-06-24 | |||
| DE1495645C3 (de) | 1961-05-26 | 1974-11-07 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung stabiler, wäßriger Emulsionen bzw. Dispersionen von Äthylen-Mischpolymerisaten |
| FR1479540A (fr) * | 1966-03-23 | 1967-05-05 | Prod Chim Et De Synthese Soc D | Nouveaux dérivés stilbéniques, azurants optiques pour fibres naturelles et synthétiques |
| US3546218A (en) * | 1966-06-29 | 1970-12-08 | Geigy Chem Corp | Substituted bis-triazinylamino stilbene compounds and compositions thereof |
| DE1595680A1 (de) | 1966-09-16 | 1970-04-23 | Bayer Ag | Sulfonsaeuregruppen enthaltende Polymerisate |
| DE1720593A1 (de) | 1967-01-02 | 1971-06-24 | Bayer Ag | Filmbildende Emulsionen aus Copolymerisaten |
| CH610312A5 (fr) * | 1973-09-21 | 1979-04-12 | Hoechst Ag | |
| DE2850382A1 (de) * | 1978-11-21 | 1980-06-04 | Hoechst Ag | Farbstabile waschmittelaufheller |
| DE3922494A1 (de) * | 1989-07-08 | 1991-01-17 | Bayer Ag | Fluessigwaschmittel |
| GB9412756D0 (en) * | 1994-06-24 | 1994-08-17 | Hickson & Welch Ltd | Chemical compounds |
| PT835906E (pt) | 1996-10-10 | 2004-03-31 | Ciba Sc Holding Ag | Dispersoes de abrilhantadores opticos |
| GB9626851D0 (en) * | 1996-12-24 | 1997-02-12 | Ciba Geigy Ag | Compounds |
| EP1054873B1 (fr) * | 1998-02-20 | 2004-09-22 | Ciba SC Holding AG | Procede de preparation de composes de stilbene |
| US6165973A (en) * | 1999-02-05 | 2000-12-26 | Ciba Specialty Chemicals Corporation | Fluorescent whitening agent, its preparation and use |
| DE19920784A1 (de) * | 1999-05-05 | 2000-11-09 | Bayer Ag | Stilbenaufheller |
| GB0100610D0 (en) | 2001-01-10 | 2001-02-21 | Clariant Int Ltd | Improvements in or relating to organic compounds |
| US6960699B2 (en) * | 2002-03-15 | 2005-11-01 | Oxeno Olefinchemie Gmbh | Method for the hydroformylation of olefins |
-
2003
- 2003-11-11 BR BRPI0316400-4A patent/BR0316400A/pt not_active IP Right Cessation
- 2003-11-11 PL PL377038A patent/PL377038A1/pl unknown
- 2003-11-11 RU RU2005119634/04A patent/RU2356898C2/ru not_active IP Right Cessation
- 2003-11-11 MX MXPA05005347A patent/MXPA05005347A/es active IP Right Grant
- 2003-11-11 CA CA002504256A patent/CA2504256A1/fr not_active Abandoned
- 2003-11-11 AU AU2003288033A patent/AU2003288033B2/en not_active Ceased
- 2003-11-11 CN CNB2003801035296A patent/CN100522951C/zh not_active Expired - Fee Related
- 2003-11-11 EP EP06111552A patent/EP1674616B1/fr not_active Expired - Lifetime
- 2003-11-11 JP JP2004552569A patent/JP2006506492A/ja active Pending
- 2003-11-11 EP EP03779887A patent/EP1563049A2/fr not_active Ceased
- 2003-11-11 WO PCT/EP2003/012583 patent/WO2004046293A2/fr active Application Filing
- 2003-11-11 KR KR1020057008936A patent/KR20050085044A/ko not_active Application Discontinuation
- 2003-11-11 MX MX2009000820A patent/MX2009000820A/es unknown
- 2003-11-11 CN CN200810183708XA patent/CN101575828B/zh not_active Expired - Fee Related
- 2003-11-11 US US10/534,315 patent/US7247174B2/en not_active Expired - Fee Related
-
2005
- 2005-04-18 ZA ZA200503105A patent/ZA200503105B/en unknown
-
2007
- 2007-06-11 US US11/811,469 patent/US7566349B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006506492A (ja) | 2006-02-23 |
| CN1711348A (zh) | 2005-12-21 |
| US7566349B2 (en) | 2009-07-28 |
| US7247174B2 (en) | 2007-07-24 |
| WO2004046293A8 (fr) | 2004-08-26 |
| WO2004046293A3 (fr) | 2004-10-14 |
| EP1563049A2 (fr) | 2005-08-17 |
| WO2004046293A2 (fr) | 2004-06-03 |
| AU2003288033A1 (en) | 2004-06-15 |
| EP1674616A2 (fr) | 2006-06-28 |
| RU2005119634A (ru) | 2006-01-27 |
| CN101575828A (zh) | 2009-11-11 |
| CA2504256A1 (fr) | 2004-06-03 |
| KR20050085044A (ko) | 2005-08-29 |
| US20070260060A1 (en) | 2007-11-08 |
| PL377038A1 (pl) | 2006-01-23 |
| BR0316400A (pt) | 2006-02-21 |
| AU2003288033B2 (en) | 2009-11-19 |
| CN101575828B (zh) | 2011-12-14 |
| EP1674616A3 (fr) | 2010-02-03 |
| US20060155124A1 (en) | 2006-07-13 |
| MXPA05005347A (es) | 2005-08-03 |
| MX2009000820A (es) | 2009-04-15 |
| CN100522951C (zh) | 2009-08-05 |
| RU2356898C2 (ru) | 2009-05-27 |
| EP1674616B1 (fr) | 2012-09-19 |
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