CN104829267A - High wear resistance in-glaze decoration ceramic brick and preparation method thereof - Google Patents
High wear resistance in-glaze decoration ceramic brick and preparation method thereof Download PDFInfo
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Abstract
The present invention relates to a high wear resistance in-glaze decoration ceramic brick and a preparation method thereof. The high wear resistance in-glaze decoration ceramic brick comprises a billet body with printed patterns and a transparent glaze layer obtained by firing on the billet body with the printed patterns, wherein the transparent glaze layer comprises a transparent base glaze and high wear resistance transparent frit particles wrapped by the transparent base glaze, the fineness of the high wear resistance transparent frit particles is 130-180 mesh, and the high wear resistance transparent frit particles comprise 52-58 wt% SiO2, 25-30 wt% of Al2O3, 8-15 wt% of CaO, 0.2-0.5 wt% of MgO, 1-3 wt% of K2O, 0.5-2 wt% of Na2O, and 1-5 wt% of ZnO.
Description
Technical field
The present invention relates to a kind of in-glaze decoration ceramic tile and preparation method thereof, particularly a kind of high abrasion in-glaze decoration ceramic product and preparation method thereof.
Background technology
Along with developing rapidly of domestic and international architectural ceramic industry, the shortage increasingly of the energy, country also advocates gradually and defines energy-saving and cost-reducing, environmental protection.This improves threshold to building ceramic enterprises undoubtedly, makes it face potential crisis of survival.In recent years, assortment get more and more, product innovation, novel process continues to bring out, and appreciation level and the requirement of people are also more and more higher, and raising product specification has become the target that Production of Ceramics person urgently pursues, developing low-cost, high-grade ceramic product obtains the attention of each producer day by day, at present pottery ooze flower process by the painted reason of oozing spent ion, assortment are dull; Glomerocryst micro mist technique is by the impact of cloth system, and assortment are greatly affected; Microlite is not wear-resisting again.In ceramic glaze, flower process absorbs the advantage of three kinds of techniques, avoids weakness, will become a kind of novel process of architectural pottery.
Throwing glazed brick is the very fast a kind of building decorative product of development in recent years, and its decorative pattern enriches, and color desktop, surface gloss high is very popular, becomes the main product on market gradually.Current throwing glaze process for producing bricks is all carry out printing ornament again, then last layer transparent after the glaze of adobe surface spraying bottom surface, obtains the finished product through burning till, after polishing edging.Although the product prepared by this technique also belongs to in-glaze decoration, pattern is subject to the protection of surface transparent glaze layer; because transparent glassy phase is too many, itself belongs to porcelain tendre, and its hardness, fastness to rubbing are all poor; be easy to wearing and tearing, be not suitable for the large place of flow of the people and use.
Therefore, how further those skilled in the art are devoted to raising always and throw the wear resisting property of glazed brick and keep its transparency, thus the use range of glazed brick is thrown in expansion.
Summary of the invention
The present invention is intended to overcome the existing wear resisting property comprising the in-glaze decoration ceramic product throwing glazed brick, the invention provides a kind of high abrasion in-glaze decoration ceramic product and preparation method thereof.
The invention provides a kind of high abrasion in-glaze decoration ceramic tile, described high abrasion in-glaze decoration ceramic tile comprises the figuratum base substrate of printing and the transparent layer through being fired on the figuratum base substrate of printing, wherein, transparent layer composition comprises transparent base glaze and by the coated high abrasion clear frit particle of transparent base glaze, the fineness of high abrasion clear frit particle is 130 order ~ 180 orders, and composition comprises 52 ~ 58wt%SiO
2, 25 ~ 30wt%Al
2o
3, 8 ~ 15wt%CaO, 0.2 ~ 0.5wt%MgO, 1 ~ 3wt%K
2o, 0.5 ~ 2wt%Na
2o, 1 ~ 5wt%ZnO.
Adopt in the present invention and add high abrasion clear frit particle in transparent layer, to increase the wear resistance of transparent layer, thus in-glaze decoration ceramic tile can be applicable to wider scope.High abrasion clear frit particle fineness: 130 order ~ 180 orders.In too thick production process, slurry easily precipitates, and not easily peels off with base glaze bonding force and affect performance.Too carefully easily be fused to transparent, affect abrasion resistant effect.
Preferably, the composition of transparent base glaze comprises 55 ~ 65wt%SiO
2, 16 ~ 20wt%Al
2o
3, 8 ~ 15wt%CaO, 1 ~ 3wt%MgO, 1 ~ 4wt%K
2o, 3 ~ 5wt%Na
2o, 0 ~ 5wt%ZnO.
Preferably, transparent layer thickness 0.2 ~ 0.8mm.
Preferably, transparent layer is containing 10-60wt% high abrasion clear frit particle.
Preferably, described transparent layer also comprises the buffer layer between transparent base glaze and high abrasion clear frit particle, and described buffer layer is interpenetrated by the component of base glaze transparent in described sintering process and high abrasion clear frit particle and formed.When high temperature burns till, transparent base glaze is filled between high temperature high abrasion clear frit particle hole as glassy phase, and reaction is formed in conjunction with good buffer layer with it, and therefore, high abrasion clear frit particle can not peel off in polishing process.Due to pyroreaction, transparent base glaze part can melt temperature resistant transparent frit particle surface layer, phase mutual diffusion, infiltration, and composition should be between transparent base glaze and high abrasion clear frit particle.Such as near the component of the buffer layer of temperature resistant transparent frit particle close to the composition of temperature resistant transparent frit particle, near the component of the buffer layer of transparent base glaze then near the composition of transparent base glaze.
Again, present invention also offers a kind of preparation method of above-mentioned high abrasion in-glaze decoration ceramic tile, comprising:
To print after figuratum base substrate sprays transparent layer slurry, burn till at 1150-1230 DEG C, described high abrasion in-glaze decoration ceramic tile is obtained again after polishing, wherein, transparent layer slurry comprises the high abrasion clear frit particle of 10-60wt%, the transparent base glaze of 30-50wt% and 10-15wt% suspension agent.
Preferably, the powder fineness of transparent base glaze was 325 mesh screen residues 0.4 ~ 0.8%
Preferably, suspension agent adopts Xylo-Mucine, ethylene glycol and/or polyoxyethylene glycol.
Preferably, straight line slip shower is adopted to be applied to by transparent layer slurry on the figuratum base substrate of printing.
Preferably, glaze slip specific gravity control is 1.70 ~ 1.85, and flow rate control is at 20 ~ 40s, and glaze volume is 460-500 grams/m.
Preferably, firing time is 60-80 minute.
The present invention compared with prior art, its beneficial effect is: because high abrasion frit particle temperature is higher than base glaze, and size ratio base glaze is thick, glaze layer good permeability in production process, be easy to dry, can not because of moisture excessive enter kiln cause fried brick, widened product firing range, glaze volume is large simultaneously, transparent thickness, product fastness to rubbing is high, and penetrating sense, stereoscopic sensation are good, and class is apparently higher than common throwing glazed brick.
Accompanying drawing explanation
Fig. 1 shows transparent Rotating fields schematic diagram in the in-glaze decoration ceramic tile prepared in one embodiment of the present invention.
Embodiment
Further illustrate the present invention below in conjunction with accompanying drawing and following embodiment, should be understood that accompanying drawing and following embodiment are only for illustration of the present invention, and unrestricted the present invention.
In order to solve the poor defect of existing throwing glazed brick wear resistance, the invention provides a kind of high abrasion in-glaze decoration ceramic tile preparation method provided.
Adopt following technical scheme to realize above-mentioned purpose:
The invention provides a kind of high abrasion in-glaze decoration ceramic tile preparation method, described method comprises:
After carrying out spray ink Printing or roller printing decoration by existing Antique Imitation Tiles technique, recycling bell jar or straight line slip shower drench the transparent of one deck containing 10 ~ 60% high abrasion clear frit particles, namely obtain this product through polishing.
Transparent base glaze is filled between high temperature high abrasion clear frit particle hole as glassy phase, and reaction is formed in conjunction with good buffer layer with it, can not peel off in polishing process.Its chemical composition: SiO
255 ~ 65%, Al
2o
316 ~ 20%, CaO8 ~ 15%, MgO1 ~ 3%, K
2o1 ~ 4%, Na
2o3 ~ 5%, ZnO0 ~ 5%.Fineness 325 mesh screen residue 0.4 ~ 0.8%.
High abrasion clear frit chemistry of particles composition: SiO
252 ~ 58%, Al
2o
325 ~ 30wt%, CaO8 ~ 15%, MgO0.2 ~ 0.5%, K
2o1 ~ 3%, Na
2o0.5 ~ 2%, ZnO1 ~ 5%.
High abrasion clear frit particle fineness: 130 order ~ 180 orders.In too thick production process, slurry easily precipitates, and not easily peels off with base glaze bonding force and affect performance.Too carefully easily be fused to transparent, affect abrasion resistant effect.
Glaze volume is maximum can reach 1000 grams/800 specification bricks, transparent layer thickness 0.2 ~ 0.8mm.
Glaze slip suspension agent adopts Xylo-Mucine, ethylene glycol, polyoxyethylene glycol etc.;
Glaze slip specific gravity control is 1.70 ~ 1.85, and flow rate control is at 20 ~ 40s.
The present invention compared with prior art, its beneficial effect is: because high abrasion frit particle temperature is higher than base glaze, and size ratio base glaze is thick, glaze layer good permeability in production process, be easy to dry, can not because of moisture excessive enter kiln cause fried brick, widened product firing range, glaze volume is large simultaneously, transparent thickness, product fastness to rubbing is high, and penetrating sense, stereoscopic sensation are good, and class is apparently higher than common throwing glazed brick.
Below some exemplary embodiments are listed further better the present invention to be described.Should understand; the above-mentioned embodiment that the present invention describes in detail; and following examples are only not used in for illustration of the present invention and limit the scope of the invention, some nonessential improvement that those skilled in the art's foregoing according to the present invention is made and adjustment all belong to protection scope of the present invention.In addition, concrete proportioning, time, temperature etc. in following processing parameter are also only exemplary, and those skilled in the art can select suitable value in the scope of above-mentioned restriction.
Embodiment 1
After carrying out spray ink Printing or roller printing decoration by existing Antique Imitation Tiles technique, recycling straight line slip shower drenches the transparent of one deck containing 10 ~ 60% high abrasion clear frit particles, and burn till through 1200 DEG C of high temperature, namely last polishing obtains this product.
Concrete steps are as follows:
1) preparation of abrasion-proof particle: by high abrasion clear frit particle (SiO
252 ~ 58%, Al
2o
325 ~ 30wt%, CaO8 ~ 15%, MgO0.2 ~ 0.5%, K
2o1 ~ 3%, Na
2o0.5 ~ 2%, ZnO1 ~ 5%) fragmentation sieves, and is crushed to 130 ~ 180 orders;
2) preparation of transparent base glaze: by transparent (SiO
255 ~ 65%, Al
2o
316 ~ 20%, CaO8 ~ 15%, MgO1 ~ 3%, K
2o1 ~ 4%, Na
2o3 ~ 5%, ZnO0 ~ 5%) ball milling, control fineness 325 mesh screen residue 0.4 ~ 0.8%;
3) preparation of suspension agent: Xylo-Mucine 50%, ethylene glycol 20%, polyoxyethylene glycol 30%;
4) preparation of glaze slip:
Abrasion-proof particle: 50 parts
Transparent base glaze: 100 parts
Suspension agent: 3 parts
The glaze slip proportion prepared is 1.75;
5) glaze slip is drenched: adopt straight line slip shower to be applied to by above-mentioned glaze slip on the base substrate of decoration good pattern, coutroi velocity was at 30 seconds;
6) burn till: the base substrate executing glaze slip is entered klining, maximum sintering temperature is 1200 DEG C, and firing period is 65 minutes;
7) polishing: the finished product after burning till is carried out surface finish process, obtains surperficial high abrasion in-glaze decoration ceramic product.
Through sending country's pottery and the inspection of water heating bathroom product quality supervision and inspection center, result is: wear resistance 6000 turns, 4 grades, see table 1.
Table 1: the survey report at country's pottery and water heating bathroom product quality supervision and inspection center
Comparative example 1
After carrying out spray ink Printing or roller printing decoration by existing Antique Imitation Tiles technique, recycling straight line slip shower drenches one deck not containing the transparent of high abrasion clear frit particle, and burn till through 1200 DEG C of high temperature, namely last polishing obtains common in-glaze decoration ceramic product.
Concrete steps are as follows:
1) preparation of transparent base glaze: by transparent (SiO
255 ~ 65%, Al
2o
316 ~ 20%, CaO8 ~ 15%, MgO1 ~ 3%, K
2o1 ~ 4%, Na
2o3 ~ 5%, ZnO0 ~ 5%) ball milling, control fineness 325 mesh screen residue 0.4 ~ 0.8%;
2) preparation of suspension agent: Xylo-Mucine 50%, ethylene glycol 20%, polyoxyethylene glycol 30%;
3) preparation of glaze slip:
Transparent base glaze: 100 parts
Suspension agent: 3 parts
The glaze slip proportion prepared is 1.75;
4) glaze slip is drenched: adopt straight line slip shower to be applied to by above-mentioned glaze slip on the base substrate of decoration good pattern, coutroi velocity was at 30 seconds;
5) burn till: the base substrate executing glaze slip is entered klining, maximum sintering temperature is 1200 DEG C, and firing period is 65 minutes;
6) polishing: the finished product after burning till is carried out surface finish process, obtains common in-glaze decoration ceramic product.
Through sending country's pottery and the inspection of water heating bathroom product quality supervision and inspection center, result is: wear resistance 1500 turns, 3 grades, see table 2.
Table 2: the survey report at country's pottery and water heating bathroom product quality supervision and inspection center
Claims (11)
1. a high abrasion in-glaze decoration ceramic tile, it is characterized in that, described high abrasion in-glaze decoration ceramic tile comprises the figuratum base substrate of printing and the transparent layer through being fired on the figuratum base substrate of printing, wherein, transparent layer composition comprises transparent base glaze and by the coated high abrasion clear frit particle of transparent base glaze, the fineness of high abrasion clear frit particle is 130 order ~ 180 orders, and composition comprises 52 ~ 58wt%SiO
2, 25 ~ 30wt%Al
2o
3, 8 ~ 15wt%CaO, 0.2 ~ 0.5 wt%MgO, 1 ~ 3 wt%K
2o, 0.5 ~ 2 wt%Na
2o, 1 ~ 5 wt%ZnO.
2. high abrasion in-glaze decoration ceramic tile according to claim 1, is characterized in that, the composition of transparent base glaze comprises 55-65wt% SiO
2, 16-20wt% Al
2o
3, 8-15wt% CaO, 1-3wt% MgO, 1-4wt% K
2o, 3-5wt% Na
2o, 0-5wt% ZnO.
3. high abrasion in-glaze decoration ceramic tile according to claim 1 and 2, is characterized in that, transparent layer thickness 0.2 ~ 0.8mm.
4. high abrasion in-glaze decoration ceramic tile according to claim 1 and 2, is characterized in that, transparent layer is containing 10-60wt% high abrasion clear frit particle.
5. the high abrasion in-glaze decoration ceramic tile according to any one of claim 1-4, it is characterized in that, described transparent layer also comprises the buffer layer between transparent base glaze and high abrasion clear frit particle, and described buffer layer is interpenetrated by the component of base glaze transparent in described sintering process and high abrasion clear frit particle and formed.
6. the preparation method of arbitrary described high abrasion in-glaze decoration ceramic tile in claim 1-5, is characterized in that, comprising:
To print after figuratum base substrate sprays transparent layer slurry, burn till at 1150-1230 DEG C, described high abrasion in-glaze decoration ceramic tile is obtained again after polishing, wherein, transparent layer slurry comprises the high abrasion clear frit particle of 10-60wt%, the transparent base glaze of 30-50wt% and 10-15wt% suspension agent.
7. preparation method according to claim 6, is characterized in that, the powder fineness of transparent base glaze was 325 mesh screen residue 0.4-0.8%.
8. the preparation method according to claim 6 or 7, is characterized in that, suspension agent adopts Xylo-Mucine, ethylene glycol and/or polyoxyethylene glycol.
9. according to described preparation method arbitrary in claim 6-8, it is characterized in that, adopt straight line slip shower to be applied to by transparent layer slurry on the figuratum base substrate of printing.
10., according to described preparation method arbitrary in claim 6-9, it is characterized in that, glaze slip specific gravity control is 1.70 ~ 1.85, and flow rate control is at 20 ~ 40s, and glaze volume is 460-500 grams/m.
11. according to described preparation method arbitrary in claim 6-10, and it is characterized in that, firing time is 60-80 minute.
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Cited By (9)
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|---|---|---|---|---|
| CN105948503A (en) * | 2016-04-29 | 2016-09-21 | 佛山市东鹏陶瓷有限公司 | Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same |
| CN106746642A (en) * | 2016-11-11 | 2017-05-31 | 广东道氏技术股份有限公司 | A kind of ceramics ooze the supporting glaze of colored ink |
| CN107382373A (en) * | 2017-06-16 | 2017-11-24 | 江西和美陶瓷有限公司 | A kind of wear-resisting antiskid Ceramic Tiles and preparation method thereof |
| CN108911510A (en) * | 2018-09-05 | 2018-11-30 | 安徽磐盛新型材料科技有限公司 | A kind of the effect glaze and its application method of architectural pottery incrustation |
| CN109437973A (en) * | 2018-12-26 | 2019-03-08 | 江苏宜翔陶瓷科技有限公司 | A kind of preparation method of the three-dimensional cream-coloured glaze ceramic vessel of reddish brown scatterplot silk soft quality sense |
| CN109665871A (en) * | 2018-12-27 | 2019-04-23 | 佛山欧神诺陶瓷有限公司 | It is a kind of to improve the process for throwing brilliant ceramic brick surface wear-resisting property |
| CN109867446A (en) * | 2019-03-15 | 2019-06-11 | 蒙娜丽莎集团股份有限公司 | The super flat frit dry granular glaze of one kind throws brick and preparation method thereof entirely |
| CN113979789A (en) * | 2021-11-29 | 2022-01-28 | 广东金牌陶瓷有限公司 | Preparation process of golden velvet texture ceramic rock plate and ceramic rock plate |
| CN115521071A (en) * | 2022-10-29 | 2022-12-27 | 广东道氏陶瓷材料有限公司 | Dry particles of composite high-temperature wear-resistant material and ceramic |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105948503A (en) * | 2016-04-29 | 2016-09-21 | 佛山市东鹏陶瓷有限公司 | Wear-resistant transparent glaze and method for preparing glazed tile by utilizing same |
| CN105948503B (en) * | 2016-04-29 | 2018-08-21 | 佛山市东鹏陶瓷有限公司 | A kind of abrasion-resistant clear glaze and the method using its preparation glazed tile |
| CN106746642A (en) * | 2016-11-11 | 2017-05-31 | 广东道氏技术股份有限公司 | A kind of ceramics ooze the supporting glaze of colored ink |
| CN107382373A (en) * | 2017-06-16 | 2017-11-24 | 江西和美陶瓷有限公司 | A kind of wear-resisting antiskid Ceramic Tiles and preparation method thereof |
| CN108911510A (en) * | 2018-09-05 | 2018-11-30 | 安徽磐盛新型材料科技有限公司 | A kind of the effect glaze and its application method of architectural pottery incrustation |
| CN109437973A (en) * | 2018-12-26 | 2019-03-08 | 江苏宜翔陶瓷科技有限公司 | A kind of preparation method of the three-dimensional cream-coloured glaze ceramic vessel of reddish brown scatterplot silk soft quality sense |
| CN109665871A (en) * | 2018-12-27 | 2019-04-23 | 佛山欧神诺陶瓷有限公司 | It is a kind of to improve the process for throwing brilliant ceramic brick surface wear-resisting property |
| CN109867446A (en) * | 2019-03-15 | 2019-06-11 | 蒙娜丽莎集团股份有限公司 | The super flat frit dry granular glaze of one kind throws brick and preparation method thereof entirely |
| CN113979789A (en) * | 2021-11-29 | 2022-01-28 | 广东金牌陶瓷有限公司 | Preparation process of golden velvet texture ceramic rock plate and ceramic rock plate |
| CN115521071A (en) * | 2022-10-29 | 2022-12-27 | 广东道氏陶瓷材料有限公司 | Dry particles of composite high-temperature wear-resistant material and ceramic |
| CN115521071B (en) * | 2022-10-29 | 2023-10-03 | 广东道氏陶瓷材料有限公司 | Dry particle and ceramic of composite high-temperature wear-resistant material |
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