CN107266023B - Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method - Google Patents
Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method Download PDFInfo
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- CN107266023B CN107266023B CN201710475109.4A CN201710475109A CN107266023B CN 107266023 B CN107266023 B CN 107266023B CN 201710475109 A CN201710475109 A CN 201710475109A CN 107266023 B CN107266023 B CN 107266023B
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- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 38
- 239000011449 brick Substances 0.000 title claims abstract description 28
- 239000010977 jade Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000007921 spray Substances 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 238000010304 firing Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003086 colorant Substances 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 229910052744 lithium Inorganic materials 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 239000013078 crystal Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 229910052664 nepheline Inorganic materials 0.000 claims description 5
- 239000010434 nepheline Substances 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 239000010435 syenite Substances 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- 238000005498 polishing Methods 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 4
- 238000005211 surface analysis Methods 0.000 claims description 4
- 238000004018 waxing Methods 0.000 claims description 4
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052656 albite Inorganic materials 0.000 claims description 3
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000007688 edging Methods 0.000 claims description 3
- 238000007641 inkjet printing Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 230000035515 penetration Effects 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005457 optimization Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 5
- 241000579895 Chlorostilbon Species 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 4
- 239000010976 emerald Substances 0.000 abstract description 4
- 230000000149 penetrating effect Effects 0.000 abstract description 4
- 229910052876 emerald Inorganic materials 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 35
- 239000000243 solution Substances 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 239000010437 gem Substances 0.000 description 4
- 229910001751 gemstone Inorganic materials 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 229910052640 jadeite Inorganic materials 0.000 description 3
- 239000005543 nano-size silicon particle Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 229910052604 silicate mineral Inorganic materials 0.000 description 2
- 230000036548 skin texture Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- PQLVXDKIJBQVDF-UHFFFAOYSA-N acetic acid;hydrate Chemical compound O.CC(O)=O PQLVXDKIJBQVDF-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5024—Silicates
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
- C04B2235/3203—Lithium oxide or oxide-forming salts thereof
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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Abstract
Surface of the invention is gentle, and as jade has, flower polished brick in porcelain character is seeped in the ink-jet of translucency and preparation method includes green body, billet surface acidulant and penetration-assisting agent, on the basis of the production technology not to existing porcelain seep curlicue polished bricks makes great change, formula composition of the emphasis to green body, the formula composition of billet surface acidulant, the formula composition of penetration-assisting agent, spray the spray amount of surface acidulant and penetration-assisting agent and the adjustment and optimization of kiln firing process, it is gentle as beautiful to make ink-jet obtained seep flower polished brick in porcelain character product surface, various colors, it is bright-coloured, ink-jet is seeped floral pattern and is penetrated into inside green body up to 2mm, and pattern texture clear and natural, beautiful texture is strong, product is translucent shape, translucency is good, it is overleaf irradiated with flashlight or light, shadow and interiors of products pattern can be clearly seen in front, such as rare natural penetrating emerald Unique decorative effect as jade and Agate；The technology has stronger universality simultaneously, is easy in industry promote.
Description
Technical field:
The present invention relates to the preparation technical field of porcelain seep curlicue polished bricks, more particularly, to a kind of surface is gentle as jade has
Flower polished brick in porcelain character and preparation method are seeped in the ink-jet of translucency.
Background technique:
The rare stone material such as jade, Agate is a kind of tcrude ore of bijouterie, it has quality fine and smooth, soft and moist, logical
Thoroughly, the features such as rich in color, after chiseling and carving meticulously, your gas is full.Since their permeabilities are good, have fine-textured skin, is soft and moist, these
Raw ore stone material be used as wall by some high-grade places after sanding and polishing, intersperse feature wall etc. it is high-grade decorate, due to these
The stone material of high value gemstone grade has special permeability, and under the irradiation of its back side light, internal stone material skin texture can be from just
Face reveals out, and more seem splendid, high-grade elegance, your gas is full, collection dicoration, appreciating and one, by numerous new
High official scholar's pursues, and holds at high price, and conventional ceramic Wall or floor tile is with the continuous innovation of decoration technique, picture on surface,
Color, the effect of texture can reach the surface effect of the rare stone material such as jade, Agate, but the inside flesh of these stone materials
Reason and the current conventional ceramic Wall or floor tile of permeability are also unable to reach, if can be the inside skin texture and permeability of these rare stone materials
It is replicated on ceramic wall and floor bricks product, makes this increasingly rareness, the rare Gem Grade stone material to something can only be found by accident, and not through seeking, by common wall
The paving of brick, along with interspersing for light, to make splendid, high-grade grace at home, more dignitary's gas will necessarily be filled in ceramics
Apparent technological innovation is generated in decorations technology, leads the new development of ceramic decoration technology, and there is considerable economic benefit.
Summary of the invention:
It is an object of the invention to overcome disadvantages mentioned above, a kind of gentle ink-jet for having translucency such as jade in surface is provided and seeps flower porcelain
Matter polished bricks and preparation method pass through on the basis of not making great change to existing porcelain seep curlicue polished bricks production technology
To the formula composition of green body, the formula composition of billet surface acidulant, the formula composition of penetration-assisting agent, spray billet surface acidulant
The adjustment and optimization of spray amount, the spray amount, kiln firing process of spray penetration-assisting agent, so that it is ceramic polished to spend ink-jet infiltration obtained
Brick product surface is gentle as floral pattern clear and natural is seeped in jade, various colors, ink-jet and pattern penetrates into inside green body up to 2mm, production
Be translucent shape, translucency of product is good, and with flashlight or light in product back side illuminaton, shadow and inside can be clearly seen in front
Pattern, while the color, texture and the surface that penetrate into interiors of products pattern are almost the same, it is high-visible, three-dimensional sense is strong, there is bird with red feathers
Unique decorative effect as the rare penetrating Gem Grade stone material such as emerald stone, Agate, and product surface quality is good, resistant is strong, hard
The defects of degree is high, wearability is strong, pin-free, fusion hole, through Micro-Structure Analysis, product surface analysis has been expired as in natural jadeite jade
Sodium aluminum silicate mineral as lagoriolite (AlNaSi2O6) fine crystals.The technology has stronger universality simultaneously, easily
It is promoted in industry.
In order to solve the above technical problems, the invention is realized by the following technical scheme:
Flower polished brick in porcelain character is seeped in the gentle ink-jet for having translucency such as jade in surface of the invention comprising:
Green body: it is prepared by following weight percent composition:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%
~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition
3%~4%, the sum of all components are 100%；The auxiliary material that added weight percentage is 0.8%~1.2%；
Wherein: the auxiliary material includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；The green body is 1200
DEG C~1220 DEG C of temperature lower calcinations after be translucent shape；
Billet surface acidulant: it is prepared by following parts by weight of component:
20~40 parts of acetic acid, 60~80 parts of water；
The spray amount of the billet surface acidulant is 30~50g/ ㎡；
Penetration-assisting agent: it is prepared by following parts by weight component:
60~80 parts of silica solution, 20~40 parts of acetate emulsion；
The penetration-assisting agent spray amount is 40~60g/ ㎡.
The invention further relates to a kind of surface it is gentle as jade have translucency ink-jet seep flower polished brick in porcelain character preparation method,
The following steps are included:
A, the preparation of green body:
The weight percent of the component of green body are as follows:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%
~0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition
3%~4%, the sum of all components are 100%；
By the weight percent content of the component of above-mentioned green body, the potassium feldspar and albite and quartz of corresponding proportion are chosen
Mixed sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage are 0.8%
~1.2% auxiliary material, it at fineness is that 250 meshes tail over as mass percent that it is fine crushing through ball milling, which to add suitable water,
0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is formed under pressure limit with automatic hydraulic press, then
By throwing base, dry kiln is drying to obtain green body；
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition；
B, the preparation of billet surface acidulant, prepares by weight:
20~40 parts of acetic acid and 60~80 parts of water are mixed together and stirred evenly up to billet surface acidulant；
C, the preparation of penetration-assisting agent, prepares by weight:
60~80 parts of silica solution and 20~40 parts of acetate emulsion are mixed together and stirred evenly up to penetration-assisting agent；
D, the preparation and firing of product:
The green body that above-mentioned steps A is prepared first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B system
The spray amount of standby obtained billet surface acidulant, billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into
The penetration-assisting agent arrived, the spray amount of penetration-assisting agent are 40~60g/ ㎡, need the ink-jet of different colours seeping flower further according to product design
Ink carries out rational sorting, then carries out inkjet printing and seeps flower, enters back into roller kiln burning at maximum sintering temperature range is 1200
DEG C~1220 DEG C, total firing time range is 90~120 minutes, and when the temperature region firing of 1100 DEG C~1150 DEG C of guarantee
Between the total firing time of Zhan 20%, then by edging, polishing, waxing to get finished product.
The present invention seeps the preparation method system of flower polished brick in porcelain character by the gentle ink-jet for having translucency such as jade in the surface
Standby finished surface various colors, clear patterns are natural, bright in luster, three-dimensional sense is strong and ink-jet is seeped floral pattern penetration depth and reached
2mm；Finger touches gentle as beautiful, and product is translucent shape, and translucency is good, with flashlight or light in product back side illuminaton, In
Shadow and internal pattern can be clearly seen in front, and through Micro-Structure Analysis, lagoriolite (AlNaSi has been expired in product surface analysis2O6)
Fine crystals.
Surface of the invention is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method:
By the optimization formed to body recipe, introduce in body recipe containing P2O5Lithium porcelain stone raw material (such as river of composition
The lithium porcelain stone of Xi great Feng porcelain stone company), the LiO in one side lithium porcelain stone2And P2O5It is strong flux, fusing point is low, can be in high temperature
The melting for accelerating Free quartz, increases the transparency of melt body, to guarantee the light transmission of product；Another aspect LiO2、P2O5Also
The color development of flower ink is seeped in the ink-jet helped to penetrate into green body, makes rich in color, gorgeous.LiO is introduced simultaneously2It can also generate
Tiny crystallization, P2O5It is Nucleating Agent, therefore LiO2、P2O5To lagoriolite AlNaSi2O4The generation of fine crystals also acts as rush
Into effect.
Nepheline syenite feedstock is introduced in body recipe, since the mineral of nepheline syenite are mainly feldspar and rosy clouds
Stone (Na, K) AlSiO4Solid solution, it starts to melt at 1060 DEG C or so, can dissolve quartz at high temperature, therefore after its melting
Viscosity is higher, therefore not only ensure that the light transmission of product, it is ensured that green body is unlikely to deform in high temperature firing, and heat is steady
Property and mechanical strength are all high.
Simultaneously body recipe composition optimization also assure green body in high temperature with the nanosilicon in the silica solution of penetration-assisting agent
Reaction, in Surface Creation lagoriolite (AlNaSi2O6) fine crystals, and this crystal is a kind of superfine amorphous structure
Grain, spherical in shape, the partial size with very little, particle are existed with the aggregations of different caking property, as natural in jadeite (emerald)
Sodium aluminum silicate mineral；It is straight saturating and unobstructed that these crystal can not only make light, while also because its is spherical in shape, fine and closely woven degree
Height, gentle exquisiteness after polished waxing are soft and moist, fine and smooth such as the emerald after processing.
The optimization and spray of billet surface acidulant formula composition are acidified the preferred of dosage, ensure that the degree of porosity of billet surface
And the aperture of stomata, advantageous ink-jet seep the seepage velocity and depth of flower ink, ensure that the color of pattern and the plumpness of texture,
It is not deep enough to be permeated because of pattern, the production for the defects of lacking flower, pattern texture, lacking unity and coherence is caused in later period polishing process
It is raw.
The optimization of penetration-assisting agent formula composition and spray penetration-assisting agent amount it is preferred, on the one hand ensure that in penetration-assisting agent in silica solution
Nano-silicon energy and green body generate lagoriolite (AlNaSi in high temperature2O6) fine crystals, because nano-silicon partial size is small, distribution is equal
It is even, large specific surface area, high surface, not only ensure that ink-jet seep flower ink color development, also easily with the Na in green body2O、
Al2O3、SiO2Equal oxides reaction, in Surface Creation lagoriolite fine crystals；The acetate emulsion in penetration-assisting agent can be with simultaneously
Guarantee that ink-jet seeps flower ink rapid condensation into fine particle, be deposited in the stomata formed by the effect of billet surface acidulant,
It will not be to other place diffusions, to guarantee the globality of pattern, clarity and the depth of infiltration.
The optimization of firing process is suitably kept the temperature in 1100 DEG C~1150 DEG C temperature regions, on the one hand ensure that base
The transparency of body melt body in high temperature, it is ensured that the light transmission of product；On the other hand, it is kept the temperature in this region, favorably
In lagoriolite (AlNaSi2O6) fine crystals generation.
Surface of the invention is gentle, and as jade has, flower polished brick in porcelain character is seeped in the ink-jet of translucency and preparation method has the following advantages:
1, due to optimize the formula composition of green body, the formula composition of billet surface acidulant, the formula composition of penetration-assisting agent,
Adjustment and optimization of the spray amount of billet surface acidulant, the spray amount of penetration-assisting agent and firing process etc., to make the production of manufacture
Product surface is gentle as beautiful, and product is translucent shape, and floral pattern clean mark, rich in color, bright-coloured is seeped in ink-jet, and seeps floral pattern and seep
Saturating depth reaches 2mm, and translucency is good, with flashlight or light in product back side illuminaton, can be seen clearly that shadow and product in front
Internal pattern, and the pattern texture at picture on surface and inside 2mm, color are almost the same, have natural penetrating jadeite jade
Unique decorative effect as the rare Gem Grade stone material such as stone, Agate.Through Micro-Structure Analysis, alumina silicate has been expired in product surface analysis
Sodium (AlNaSi2O6) fine crystals.
2, the product surface flatness, the modulus of rupture, flexural strength, wearability, thermal shock resistance, radioactivity reach GB/
A category alignment request in T4100-2015 annex G, GB6566-2010.
3, the product seeps the production technology of flower polished bricks using existing ink-jet, it is easy to accomplish industrialized scale.
Detailed description of the invention:
Fig. 1 is the process flow for preparing the gentle ink-jet for having translucency such as jade in surface of the invention and seeping flower polished brick in porcelain character
Figure.
Specific embodiment:
Below with reference to embodiment, invention is further described in detail.
Embodiment 1:
The preparation method of flower polished brick in porcelain character is seeped in a kind of gentle ink-jet for having translucency such as jade in surface comprising following step
It is rapid:
A, green body is prepared:
Chemical composition composition such as the following table 1 of green body:
The chemical composition table (weight percent, %) of table 1, green body
| Component | SiO2 | Al2O3 | Fe2O3+TiO2 | CaO+MgO | K2O | Na2O | LiO2 | P2O5 | Loss on ignition |
| 1# | 68 | 22 | 0.4 | 0.2 | 4 | 2 | 0.2 | 0.2 | 3 |
| 2# | 69 | 21 | 0.35 | 0.3 | 3 | 2.9 | 0.3 | 0.15 | 3 |
| 3# | 70 | 20 | 0.3 | 0.4 | 2 | 3 | 0.2 | 0.1 | 4 |
| 4# | 68.5 | 20.5 | 0.3 | 0.2 | 3.9 | 2.5 | 0.4 | 0.2 | 3.5 |
| 5# | 68 | 21.3 | 0.4 | 0.3 | 2.4 | 4 | 0.3 | 0.1 | 3.2 |
Prepare green body: by the potassium feldspar and albite of 1 green body chemical composition of table selection corresponding proportion and mixing for quartz
Close sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~
1.2% auxiliary material, it at fineness is that 250 meshes tail over as mass percent that it is fine crushing through ball milling, which to add suitable water,
0.5%~0.7% and containing mass percent be 33%~35% moisture glaze slip, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2Pressure limit under formed with automatic hydraulic press,
Green body is drying to obtain using throwing base, dry kiln；Additional auxiliary material therein include sodium tripolyphosphate, metasilicate pentahydrate sodium and
Sodium carbonate；Lithium porcelain stone raw material therein, which is selected, contains P2O5The lithium porcelain stone raw material of composition, such as the lithium porcelain stone of Jiangxi great Feng porcelain stone company
In, contain 1% or so P2O5；
B, billet surface acidulant is prepared:
The formula composition of billet surface acidulant such as the following table 2:
The formula composition table (parts by weight) of table 2, billet surface acidulant
| Component | Acetic acid | Water |
| 1# | 20 | 80 |
| 2# | 30 | 70 |
| 3# | 40 | 60 |
Acetic acid is weighed by the formula composition of 2 billet surface acidulant of table and water is mixed together and stirs evenly up to billet surface
Acidulant；
C, penetration-assisting agent is prepared:
The formula composition of penetration-assisting agent such as the following table 3:
The formula composition table (parts by weight) of table 3, penetration-assisting agent
| Component | Silica solution | Acetate emulsion |
| 1# | 80 | 20 |
| 2# | 60 | 40 |
| 3# | 70 | 30 |
Silica solution is weighed by the formula composition of 3 penetration-assisting agent of table and acetate emulsion is mixed together to stir evenly and helps infiltration to obtain the final product
Agent；
D, the preparation and firing of product:
The green body that above-mentioned steps A is prepared first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B system
The spray amount of standby obtained billet surface acidulant, billet surface acidulant is 30~50g/ ㎡, then sprays above-mentioned steps C and be prepared into
The penetration-assisting agent arrived, the spray amount of penetration-assisting agent are 40~60g/ ㎡, need the ink-jet of different colours seeping flower further according to product design
Ink carries out rational sorting, then carries out inkjet printing and seeps flower, enters back into roller kiln burning at maximum sintering temperature range is 1200
DEG C~1220 DEG C, total firing time range is 90~120 minutes, and when the temperature region firing of 1100 DEG C~1150 DEG C of guarantee
Between the total firing time of Zhan 20%, then by edging, polishing, waxing to get finished product.Wherein flower ink is seeped in the ink-jet
As flower ink is seeped in the ink-jet of Italian U.S. high (METCO), Guangdong Dowstone Technologies Co., Ltd..
The present invention seeps the preparation method of flower polished brick in porcelain character by a kind of gentle ink-jet for having translucency such as jade in above-mentioned surface,
Polished brick in porcelain character product pattern various colors, the clean mark being prepared are natural, bright in luster, three-dimensional sense is strong, from product side
Portion can be seen that ink-jet is seeped floral pattern and penetrated into up to 2mm inside brick body, and surface and internal pattern texture and color are basic
Unanimously, beautiful texture is strong, the gentle exquisiteness of finger touch-surface, and product is translucent shape, and translucency is good, is being produced with flashlight or light
Shadow and such as natural penetrating rare jade of internal pattern texture, color, Ma can be clearly seen in front in product back side illuminaton
Unique decorative effect as Nao stone, high-grade elegant, your gas is full, after product surface is corroded with HF, then through Micro-Structure Analysis, produces
Analyse full lagoriolite (AlNaSi in product surface2O6) fine crystals, and product flatness is good, intensity is high, wear resistance is high, pin-free, molten
The defects of hole.Through testing product indices such as the following table 4.
Table 4: product quality inspection result (900 × 900mm of specification)
In conclusion only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form；It is all
The those of ordinary skill of the industry can implement the present invention by the above and swimmingly；But all technology people for being familiar with this profession
Member without departing from the scope of the present invention, repair by a little change for making using disclosed above technology contents
Decorations and the equivalent variations developed, are equivalent embodiment of the invention；Meanwhile all substantial technologicals according to the present invention are to the above reality
The change, modification and differentiation for applying any equivalent variations made by example, still fall within technical solution of the present invention protection scope it
It is interior.
Claims (3)
1. the preparation method that flower polished brick in porcelain character is seeped in a kind of gentle ink-jet for having translucency such as jade in surface, it is characterised in that:
Itself the following steps are included:
A, the preparation of green body:
The weight percent of the component of green body are as follows:
SiO268%~70%, Al2O320%~22%, Fe2O3+TiO20.3%~0.4%, CaO+MgO 0.2%~
0.4%, K2O 2%~4%, Na2O 2%~4%, Li2O 0.2%~0.4%, P2O50.1%~0.2%, loss on ignition 3%
~4%, the sum of all components are 100%；
By the weight percent content of the component of above-mentioned green body, the mixing of the potassium feldspar and albite and quartz of corresponding proportion is chosen
Sand, pyrophyllite raw material, Nepheline syenite feedstock, lithium porcelain stone raw material, raw clay and added weight percentage be 0.8%~
1.2% auxiliary material, it at fineness is that 250 meshes tail over as mass percent that it is fine crushing through ball milling, which to add suitable water,
0.5%~0.7% and containing mass percent be 33%~35% moisture slurry, through except iron sieving spray drying be made containing quality
Percentage is the powder of 6%~7% moisture, in 440~480 kilograms per centimeters2It is formed under pressure limit with automatic hydraulic press, then
By throwing base, dry kiln is drying to obtain green body；
Additional auxiliary material therein includes sodium tripolyphosphate, metasilicate pentahydrate sodium and sodium carbonate；
Lithium porcelain stone raw material therein is containing P2O5The lithium porcelain stone raw material of composition；
B, the preparation of billet surface acidulant, prepares by weight:
20~40 parts of acetic acid and 60~80 parts of water are mixed together and stirred evenly up to billet surface acidulant；
C, the preparation of penetration-assisting agent, prepares by weight:
60~80 parts of silica solution and 20~40 parts of acetate emulsion are mixed together and stirred evenly up to penetration-assisting agent；
D, the preparation and firing of product:
The green body that above-mentioned steps A is prepared first passes through surface cleaning, then spray cooling, then sprays above-mentioned steps B and be prepared into
The spray amount of the billet surface acidulant arrived, billet surface acidulant is 30~50g/ ㎡, then sprays what above-mentioned steps C was prepared
Penetration-assisting agent, the spray amount of penetration-assisting agent are 40~60g/ ㎡, need to seep the ink-jet of different colours into flower ink further according to product design
Carry out rational sorting, then carry out inkjet printing and seep flower, enter back into roller kiln burning at, maximum sintering temperature range be 1200 DEG C~
1220 DEG C, total firing time range is 90~120 minutes, and guarantees that 1100 DEG C~1150 DEG C of temperature region firing time accounts for
The 20% of total firing time, then by edging, polishing, waxing to get finished product.
2. the preparation side that flower polished brick in porcelain character is seeped in a kind of gentle ink-jet for having translucency such as jade in surface according to claim 1
Method, it is characterised in that:
The finished product spray prepared by the preparation method that flower polished brick in porcelain character is seeped in the gentle ink-jet for having translucency such as jade in the surface
Ink seeps floral pattern penetration depth and reaches 2mm, and product is translucent shape, and lagoriolite fine crystals have been expired in product surface analysis.
3. flower polished brick in porcelain character is seeped in a kind of gentle ink-jet for having translucency such as jade in surface, it is characterised in that:
Its preparation side that flower polished brick in porcelain character is seeped by the gentle ink-jet for having translucency such as jade in surface of any of claims 1 or 2
Method obtains.
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| PCT/CN2017/000743 WO2018232547A1 (en) | 2017-06-21 | 2017-12-20 | Inkjet color-penetrated polished porcelain tile with surface being gentle as jade and having light transmittance and preparation method therefor |
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| CN107266023B (en) * | 2017-06-21 | 2019-10-29 | 广东宏宇新型材料有限公司 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
| CN108503330B (en) * | 2018-04-08 | 2020-10-27 | 清远市简一陶瓷有限公司 | Light-transmitting marble tile |
| CN108975892B (en) * | 2018-08-27 | 2021-01-22 | 佛山石湾鹰牌陶瓷有限公司 | Method for preparing ink-jet flower-penetrating jade polished brick and ink-jet flower-penetrating jade polished brick |
| CN108975891B (en) * | 2018-08-27 | 2021-11-05 | 佛山石湾鹰牌陶瓷有限公司 | Ink-jet flower-penetrating jade polished brick and preparation method thereof |
| CN109053171B (en) * | 2018-08-27 | 2021-01-26 | 佛山石湾鹰牌陶瓷有限公司 | Unfired brick and inkjet pattern-penetrating jade polished brick |
| CN110483024B (en) * | 2019-09-06 | 2022-06-17 | 清远市简一陶瓷有限公司 | High-flatness ceramic tile blank and preparation method thereof |
| CN110963792B (en) * | 2019-12-19 | 2022-04-22 | 广东宏陶陶瓷有限公司 | Porcelain polished brick of 80-degree whiteness and color ratio mutton tallow and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330342A (en) * | 2015-10-15 | 2016-02-17 | 蒙娜丽莎集团股份有限公司 | One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof |
| CN105367131A (en) * | 2015-12-07 | 2016-03-02 | 蒙娜丽莎集团股份有限公司 | Ink-jet penetrated polished semitransparent ceramic sheet, and preparation method thereof |
| CN106007662A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Ink jet pattern seeping marble tile |
| CN106007806A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Preparation method of ink jet pattern seeping marble tile |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
| CN106278387A (en) * | 2016-08-15 | 2017-01-04 | 广东宏宇新型材料有限公司 | There is glazed tile of gold decorative effect and preparation method thereof on surface |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1016542B1 (en) * | 1998-12-28 | 2004-03-24 | Canon Kabushiki Kaisha | Recording medium and method of manufacturing the same |
| TW201231567A (en) * | 2010-08-31 | 2012-08-01 | Du Pont | Ink-jet ink comprising cross-linked pigment dispersion and a polymeric binder |
| CN104860720B (en) * | 2015-05-07 | 2017-01-04 | 广东宏陶陶瓷有限公司 | Ceramic decoration high temperature scarlet color ink-jet ink and preparation method and applications |
| CN105924134B (en) * | 2016-04-25 | 2018-05-25 | 广东宏宇新型材料有限公司 | There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface |
| CN107266023B (en) * | 2017-06-21 | 2019-10-29 | 广东宏宇新型材料有限公司 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
-
2017
- 2017-06-21 CN CN201710475109.4A patent/CN107266023B/en active Active
- 2017-12-20 WO PCT/CN2017/000743 patent/WO2018232547A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330342A (en) * | 2015-10-15 | 2016-02-17 | 蒙娜丽莎集团股份有限公司 | One-time sintered super-flat ink-jet penetrating porcelain tiles with three-dimensional decorative effects, and manufacturing method thereof |
| CN105367131A (en) * | 2015-12-07 | 2016-03-02 | 蒙娜丽莎集团股份有限公司 | Ink-jet penetrated polished semitransparent ceramic sheet, and preparation method thereof |
| CN106007662A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Ink jet pattern seeping marble tile |
| CN106007806A (en) * | 2016-05-24 | 2016-10-12 | 四川省新万兴瓷业有限公司 | Preparation method of ink jet pattern seeping marble tile |
| CN106278387A (en) * | 2016-08-15 | 2017-01-04 | 广东宏宇新型材料有限公司 | There is glazed tile of gold decorative effect and preparation method thereof on surface |
| CN106280710A (en) * | 2016-08-23 | 2017-01-04 | 佛山市彩贵新型材料有限公司 | A kind of ceramic ink jet oozes colored ink permeation-promoter and application process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陶瓷渗花墨水的性能及研究状况;张翼;《佛山陶瓷》;20160831(第8期);第2-3页 * |
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