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CN106746642A - A kind of ceramics ooze the supporting glaze of colored ink - Google Patents

A kind of ceramics ooze the supporting glaze of colored ink Download PDF

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Publication number
CN106746642A
CN106746642A CN201610998114.9A CN201610998114A CN106746642A CN 106746642 A CN106746642 A CN 106746642A CN 201610998114 A CN201610998114 A CN 201610998114A CN 106746642 A CN106746642 A CN 106746642A
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CN
China
Prior art keywords
glaze
parts
ink
supporting
ceramics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610998114.9A
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Chinese (zh)
Inventor
陈奕
王平
黎朱强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG DOWSTONE TECHNOLOGY Co Ltd
Original Assignee
GUANGDONG DOWSTONE TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG DOWSTONE TECHNOLOGY Co Ltd filed Critical GUANGDONG DOWSTONE TECHNOLOGY Co Ltd
Priority to CN201610998114.9A priority Critical patent/CN106746642A/en
Publication of CN106746642A publication Critical patent/CN106746642A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The supporting glaze of colored ink is oozed the invention discloses a kind of ceramics, by Al2O3、SiO2、MgO、CaO、K2O、Na2O is constituted.There is glaze of the invention good helping to ooze effect, oozing the penetration depth of colored ink can increase to 0.4~0.6mm, and glaze formula of the present invention is rationally, can cause that the color development of ink is unaffected, a greater degree of that the rich colors for oozing colored ink are presented, the pattern that printing is obtained has more preferable decorative effect.

Description

A kind of ceramics ooze the supporting glaze of colored ink
Technical field
The present invention relates to a kind of the glaze that colored ink is used cooperatively is oozed with ceramic.
Background technology
In recent years, China's Structural ceramics industry is developed rapidly with the national economic development, is developing national economy and is carried People's living standard high is made that significant contribution.China is ceramic tile production manufacturing nation the biggest in the world at present, country of consumption and goes out Mouthful state, but be not also power, ceramic industry there are problems that many numbers of the enterprise, small scale, high energy consumption,.In section Energy emission reduction increasingly causes today that the whole society pays close attention to, and the energy-saving and emission-reduction present situation of building ceramic tiles is caused special attention.
The appearance of ceramic ink jet printing technology significantly improves the decorative effect of ceramics, it is often more important that, will greatly simplify The production decoration technology of ceramics, reduces the pollution and raw materials consumption in production process, promotes the energy-saving and emission-reduction of Production of Ceramics, It is the technological revolution of ceramic decoration technology.But occupy the polished bricks of the domestic share of ceramic tile market 30~40%, due to production process In rubbing down technique, it is impossible to quote this new technology, decoration technique level is difficult to get a promotion, it is difficult to make the pottery of high added value Porcelain products.The grinding and polishing operation of what is more important ceramic polished brick, needs rubbing down to fall 1~2 millimeter of superficial layer, along with grinding tool Loss, 1 square metre of polished bricks of production will produce 2~4 kilograms or so of polished waste material.According to statistics, China's polished bricks in 2014 Yield be 3,500,000,000 square metres, there is this to calculate the quantum of output of polished bricks polished waste material up to 10,000,000 tons.Therefore it is badly in need of new Decoration technique and technique realize the clean manufacturing of polished bricks, and improve the decoration technique level of polished bricks, reduce polished bricks Production cost.
Existing ceramics are printed with ink is permeated, and penetrating power is limited, polished rear substantially without decorative effect or dress Decorations effect extreme difference, limits its application in polished bricks.Additionally, existing ceramics ooze the supporting glaze of colored ink, it is improper such as to constitute, The color development of ink can be influenceed, its decorative effect is reduced.Develop a kind of cooperation ceramics and ooze the matching used glaze of colored ink, improve Ink permeability wherein, while reduce it throwing except amount, is expected to overcome existing ceramic printing technique to be difficult to apply in polished bricks In problem.
The content of the invention
The glaze that colored ink is used cooperatively is oozed it is an object of the invention to provide a kind of ceramics.
The technical solution used in the present invention is:
One kind oozes the supporting glaze of colored ceramic ink, by Al2O3、SiO2、MgO、CaO、K2O、Na2O is constituted.
Preferably, the above-mentioned quality group for oozing the supporting glaze of colored ceramic ink turns into Al2O314~19 parts, SiO268~75 parts, 1~2 part of 1~2 part of MgO, CaO, K23~6 parts of O, Na21~3 part of O;Further, its quality group turns into Al2O316~17 Part, SiO268~73 parts, 1~2 part of MgO, 1~2 part of CaO, K24~5 parts of O, Na21~3 part of O.
It is a kind of beneficial to the glaze paint for oozing colored ink printed, glaze paint is made up of the above-mentioned supporting glaze of colored ceramic ink that oozes.
A kind of ceramics, it has above-mentioned glaze paint, and infiltration is printed in glaze paint decorative pattern.
Particularly, ceramics are polished bricks.
The beneficial effects of the invention are as follows:
There is glaze of the invention good helping to ooze effect, and the penetration depth for oozing colored ink can increase to 0.4~0.6mm, Er Qieben Invention glaze formula rationally, can cause that the color development of ink is unaffected, a greater degree of that the rich colors for oozing colored ink are presented, and beat The pattern that print is obtained has more preferable decorative effect.
Brief description of the drawings
Fig. 1 is that difference oozes the photo after the supporting glaze of colored ceramic ink burns till.
Specific embodiment
With reference to embodiment, technical scheme is further illustrated.
In following examples and comparative example, unless otherwise instructed, described number refers both to mass parts.
The preparation method of glaze:By each raw material according to rational proportioning, ball mill is put into, is milled to and requires fineness, removed Iron sieves for subsequent use.
Embodiment 1
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O316 parts, SiO273 parts, 2 parts of MgO, 2 parts of CaO, K2O 4 Part, Na23 parts of O.
Embodiment 2
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O317 parts, SiO273 parts, 1 part of MgO, 1 part of CaO, K2O 5 Part, Na23 parts of O.
Embodiment 3
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O314 parts, SiO275 parts, 1.5 parts of MgO, 1.5 parts of CaO, K26 parts of O, Na22 parts of O.
Embodiment 4
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O319 parts, SiO268 parts, 2 parts of MgO, 2 parts of CaO, K2O 6 Part, Na23 parts of O.
Embodiment 5
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O317 parts, SiO275 parts, 2 parts of MgO, 2 parts of CaO, K2O 3 Part, Na21 part of O.
Comparative example:
One kind oozes the supporting glaze of colored ceramic ink, consisting of Al2O317 parts, SiO264 parts, 3 parts of MgO, 4 parts of CaO, K2O 3 Part, Na23 parts of 3 parts of 3 parts of O, BaO, ZnO.
Performance detection
Glaze is prepared into glaze slip, glaze is drenched using bell jar slip shower, glaze slip is uniformly imposed on into billet surface, using same ink Water carries out ink-jet and oozes colored decoration to it, after 1200 DEG C are fired, contrasts the ink bleed depth and color development feelings of different glaze Condition is as a result as follows.
Knowable to the experimental data in table, it is of the invention ooze the supporting glaze of colored ceramic ink and can remarkably promote ooze colored ink and ooze Thoroughly, it is goed deep into glaze paint, obtain more preferably decorative effect.
Photo after being burnt till after embodiment 1 and comparative example glaze printing identical ink is as shown in Figure 1.Can be clear by Fig. 1 Find out to Chu, the hair color effect of comparative example is significantly worse than embodiment 1.
Oozing the supporting glaze of colored ceramic ink due to the present invention can effectively improve the penetration depth for oozing colored ink, and this causes it i.e. Make a small amount of polishing, also do not interfere with its pattern so that it can be used for the manufacture of polished bricks, improve existing polished bricks and be difficult to beat The deficiency being patterned, obtains the more preferable polished bricks of decorative effect.

Claims (6)

1. one kind oozes the supporting glaze of colored ceramic ink, by Al2O3、SiO2、MgO、CaO、K2O、Na2O is constituted.
2. according to claim 1 to ooze the supporting glaze of colored ceramic ink, its quality group turns into Al2O314~19 parts, SiO2 68 ~75 parts, 1~2 part of MgO, 1~2 part of CaO, K23~6 parts of O, Na21~3 part of O.
3. according to claim 2 to ooze the supporting glaze of colored ceramic ink, its quality group turns into Al2O316~17 parts, SiO2 68 ~73 parts, 1~2 part of MgO, 1~2 part of CaO, K24~5 parts of O, Na21~3 part of O.
4. a kind of beneficial to the glaze paint for oozing colored ink printed, it is characterised in that:Glaze paint described in claim 1 as oozing colored ceramic ink Supporting glaze is made.
5. a kind of ceramic, it is characterised in that:It has the glaze paint described in claim 4, and infiltration is printed in glaze paint decorative pattern.
6. ceramics according to claim 5, it is characterised in that:Ceramics are polished bricks.
CN201610998114.9A 2016-11-11 2016-11-11 A kind of ceramics ooze the supporting glaze of colored ink Pending CN106746642A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610998114.9A CN106746642A (en) 2016-11-11 2016-11-11 A kind of ceramics ooze the supporting glaze of colored ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610998114.9A CN106746642A (en) 2016-11-11 2016-11-11 A kind of ceramics ooze the supporting glaze of colored ink

Publications (1)

Publication Number Publication Date
CN106746642A true CN106746642A (en) 2017-05-31

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CN201610998114.9A Pending CN106746642A (en) 2016-11-11 2016-11-11 A kind of ceramics ooze the supporting glaze of colored ink

Country Status (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108218235A (en) * 2017-12-18 2018-06-29 佛山科学技术学院 A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks
CN112340991A (en) * 2020-11-25 2021-02-09 珠海市白兔陶瓷有限公司 Ink-jet brick and production process thereof
CN113443926A (en) * 2021-07-19 2021-09-28 广东道氏技术股份有限公司 Digital protective glaze ink with dry particle effect and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101130463A (en) * 2007-07-13 2008-02-27 邱林铿 Production method of ceramic for generating gold crystallization dapple on glaze of ceramic and ceramic glaze used thereof
CN104193415A (en) * 2014-08-29 2014-12-10 佛山市东鹏陶瓷有限公司 Method for manufacturing unburnt ceramic tile clay
CN104829267A (en) * 2015-05-04 2015-08-12 广东蒙娜丽莎新型材料集团有限公司 High wear resistance in-glaze decoration ceramic brick and preparation method thereof
CN105175027A (en) * 2015-09-11 2015-12-23 蒙娜丽莎集团股份有限公司 Ceramic with three-dimensional decoration effect and preparation method thereof
CN105198490A (en) * 2015-09-11 2015-12-30 蒙娜丽莎集团股份有限公司 Preparation method of ink-jet permeable micro-powder polished tile

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101130463A (en) * 2007-07-13 2008-02-27 邱林铿 Production method of ceramic for generating gold crystallization dapple on glaze of ceramic and ceramic glaze used thereof
CN104193415A (en) * 2014-08-29 2014-12-10 佛山市东鹏陶瓷有限公司 Method for manufacturing unburnt ceramic tile clay
CN104829267A (en) * 2015-05-04 2015-08-12 广东蒙娜丽莎新型材料集团有限公司 High wear resistance in-glaze decoration ceramic brick and preparation method thereof
CN105175027A (en) * 2015-09-11 2015-12-23 蒙娜丽莎集团股份有限公司 Ceramic with three-dimensional decoration effect and preparation method thereof
CN105198490A (en) * 2015-09-11 2015-12-30 蒙娜丽莎集团股份有限公司 Preparation method of ink-jet permeable micro-powder polished tile

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108218235A (en) * 2017-12-18 2018-06-29 佛山科学技术学院 A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks
CN112340991A (en) * 2020-11-25 2021-02-09 珠海市白兔陶瓷有限公司 Ink-jet brick and production process thereof
CN113443926A (en) * 2021-07-19 2021-09-28 广东道氏技术股份有限公司 Digital protective glaze ink with dry particle effect and application thereof

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Application publication date: 20170531

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