CN102503435A - Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles - Google Patents
Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles Download PDFInfo
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- CN102503435A CN102503435A CN2011102847199A CN201110284719A CN102503435A CN 102503435 A CN102503435 A CN 102503435A CN 2011102847199 A CN2011102847199 A CN 2011102847199A CN 201110284719 A CN201110284719 A CN 201110284719A CN 102503435 A CN102503435 A CN 102503435A
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Abstract
The invention discloses a preparation method for high-temperature once-fired fully-polished glazed porcelain tiles, which includes steps of moulding blank by a press, ground coat applying, clinker dry particle distributing, fixing agent spraying, firing at high temperature, polishing, sorting and the like. Using the method to prepare the fully-polished glazed porcelain tiles only needs the once-firing technique, so that production cost can be reduced greatly, energy is saved, exhaust emission is reduced, and the preparation method is accordant to current national green industry policies.
Description
Technical field
The present invention relates to a kind of preparation method of full throwing glaze porcelain brick, specifically relate to the preparation method that a kind of high temperature once burns full throwing glaze porcelain brick.
Background technology
Produce the crystallite composite brick at present and all adopt firing process twice with the full glazed brick of throwing.At first, with base substrate biscuiting or biscuiting after executing ground-coat enamel and stamp on the base substrate, make base substrate porcelainization, water-intake rate≤0.1%; Secondly, cloth 30～80 purpose crystallite frits or transparent dry granular carry out glaze firing again on base substrate; Polish at last and sorting.This production process is because earlier through biscuiting, back glaze firing abbreviates twice firing usually as.Since many once-firings of double-firing process process, so energy consumption is high, labor hour is many, produce land used and factory building takes up an area of greatly, and manufacturing cost is high; The product defects that has also increased simultaneously the breakage of product and produced therefrom.In addition, because the porcelainization fully of the base substrate after the biscuiting, when glaze firing; The porcelain base can not bear and be rapidly heated; Otherwise base substrate can ftracture because of being rapidly heated, and the general glaze firing time is about 2.5 hours, and once-firing only needs about 1.5 hours; From this respect, once-firing can further reduce production costs.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of and reduces production costs, reduces that the high temperature of discharge amount of exhaust gas once burns the preparation method of full throwing glaze porcelain brick.
The technical scheme that technical solution problem of the present invention is adopted is: high temperature once burns the preparation method of full throwing glaze porcelain brick, comprises the step of following order:
Step 1: utilize the press-molding base substrate, the percent of firing shrinkage of said base substrate≤11%, the base substrate firing temperature is at 1180～1220 ℃;
Step 2: on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm, the beginning agglomerating temperature of said ground-coat enamel >=1100 ℃;
Step 3: executing cloth 30～80 purposes frit dry granular spherical in shape on the base substrate of ground-coat enamel, quantity is 3.0～4.0g/cm
2, the fusing point of said frit>=1170 ℃, the yield point of frit>=1210 ℃;
Step 4: spray fixing agent;
Step 5: send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes;
Step 6: polish and sorting.
As the improvement of technique scheme, the component of said frit and part by weight are: SiO
255～68, Al
2O
313～19.5, KNaO 3～8, and CaO 2～15, and MgO 0～2, and ZnO 0～4, B
2O
33～7, BaO 0～4.
As another improvement of technique scheme, the component of said frit and part by weight are: SiO
255～71, Al
2O
33～4.3, KNaO 6～7, and CaO 4～15, and MgO 0～6, ZnO2～6, B
2O
31～10, BaO 0～8.
The invention has the beneficial effects as follows: utilize the present invention to prepare full throwing glaze porcelain brick and only need single firing process; Can reduce production costs significantly, save the energy, and reduced the exhaust gas discharging amount; Alleviated pollution, met the present pollution-free industry policy of country environment.
Embodiment
Through embodiment the present invention is further specified below.
Embodiment 1:
At first; Get by weight percentage 23% new can mud, Jiangmen sand of 25%, Qingyuan City's aloxite of 8%, 25% riverhead sodium stone flour, Huizhou sand of 10%, Xinfeng stone flour of 8%, 1% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1220 ℃, and the shrinking percentage after burning till is 11%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 13% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 5% clear frit is processed; It begins the agglomerating temperature is 1160 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 26.88% common feldspar, 5.44% talcum, 7.22% calcite, 26.75% quartz, 2.30% barium carbonate, 3.59% zinc oxide, 7.90% boric acid, 6.47% soda ash by weight percentage, 13.45% aluminum oxide is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
255, Al
2O
319.5 KNaO 8, CaO 4.5, and MgO 2, ZnO4, B
2O
35, BaO 2.Its fusing point is 1200 ℃, and yield point is 1240 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain transparent full throwing glaze porcelain brick.
Embodiment 2:
At first; Get by weight percentage 8% new can mud, Qingyuan City's mud of 15%, Qingyuan City's aloxite of 8%, 5% pure and fresh aloxite, Xinfeng sodium sand of 26%, Qingyuan City's stone flour of 18%, 20% Xinyi sand, 5.5% silver small cup sand, 2.5% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1180 ℃, and the shrinking percentage after burning till is 10%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.。
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 10% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 8% clear frit is processed; It begins the agglomerating temperature is 1100 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 26.80% common feldspar, 5.43% talcum, 7.19% calcite, 29.38% quartz, 4.01% barium carbonate, 3.58% zinc oxide, 7.88% boric acid, 6.45% soda ash by weight percentage, 9.28% aluminum oxide is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
258, Al
2O
315.0 KNaO 8, CaO 4.5, and MgO 2, ZnO4, B
2O
35, BaO 3.5.Its fusing point is 1170 ℃, and yield point is 1210 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain transparent full throwing glaze porcelain brick.
Embodiment 3:
At first; Get by weight percentage 23% new can mud, Jiangmen sand of 25%, Qingyuan City's aloxite of 8%, 25% riverhead sodium stone flour, Huizhou sand of 10%, Xinfeng stone flour of 8%, 1% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1220 ℃, and the shrinking percentage after burning till is 11%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 13% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 5% clear frit is processed; It begins the agglomerating temperature is 1160 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 2.78% common feldspar, 6.07% talcum, 6.50% calcite, 59.10% quartz, 4.66% barium carbonate, 5.45% zinc oxide, 4.80% boric acid, 5.97% soda ash by weight percentage, 4.67% saltpetre is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
271, Al
2O
33.0 KNaO 6.8, CaO 4.0, and MgO 2.2, and ZnO 6, B
2O
33, BaO 4.Its fusing point is 1200 ℃, and yield point is 1240 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain the milky white full glaze porcelain brick of throwing.
Embodiment 4:
At first; Get by weight percentage 8% new can mud, Qingyuan City's mud of 15%, Qingyuan City's aloxite of 8%, 5% pure and fresh aloxite, Xinfeng sodium sand of 26%, Qingyuan City's stone flour of 18%, 20% Xinyi sand, 5.5% silver small cup sand, 2.5% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1180 ℃, and the shrinking percentage after burning till is 10%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 10% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 8% clear frit is processed; It begins the agglomerating temperature is 1100 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 3.87% common feldspar, 6.0% talcum, 15.0% calcite, 54.85% quartz, 4.6% barium carbonate, 3.6% zinc oxide, 1.58% boric acid, 6.12% soda ash by weight percentage, 4.37% saltpetre is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
268, Al
2O
34.3 KNaO 7, CaO 9.5, and MgO 2.2, and ZnO 4, B
2O
31, BaO 4.0.Its fusing point is 1170 ℃, and yield point is 1210 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain the milky white full glaze porcelain brick of throwing.
Embodiment 5:
At first; Get by weight percentage 23% new can mud, Jiangmen sand of 25%, Qingyuan City's aloxite of 8%, 25% riverhead sodium stone flour, Huizhou sand of 10%, Xinfeng stone flour of 8%, 1% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1220 ℃, and the shrinking percentage after burning till is 11%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 13% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 5% clear frit is processed; It begins the agglomerating temperature is 1160 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 9.54% potassium felspar sand, 2.7% burning talcum, 3.18% calcite, 53.95% quartz, 4.7% barium carbonate, 1.84% zinc oxide, 4.52% boric acid, 2.68% soda ash by weight percentage, 10.11% aluminum oxide is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
268, Al
2O
313, KNaO 3, and CaO 2, and MgO 1, and ZnO 2, B
2O
37, BaO 4.Its fusing point is 1200 ℃, and yield point is 1240 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain transparent full throwing glaze porcelain brick.
Embodiment 6:
At first; Get by weight percentage 8% new can mud, Qingyuan City's mud of 15%, Qingyuan City's aloxite of 8%, 5% pure and fresh aloxite, Xinfeng sodium sand of 26%, Qingyuan City's stone flour of 18%, 20% Xinyi sand, 5.5% silver small cup sand, 2.5% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1180 ℃, and the shrinking percentage after burning till is 10%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.。
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 10% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 8% clear frit is processed; It begins the agglomerating temperature is 1100 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 18.75% potassium felspar sand, 22.88% calcite, 35.95% quartz, 4.52% boric acid, 6.37% soda ash by weight percentage, 11.55% aluminum oxide is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
258, Al
2O
317.0 KNaO 7, CaO 15, B
2O
33.Its fusing point is 1170 ℃, and yield point is 1210 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain transparent full throwing glaze porcelain brick.
Embodiment 7:
At first; Get by weight percentage 23% new can mud, Jiangmen sand of 25%, Qingyuan City's aloxite of 8%, 25% riverhead sodium stone flour, Huizhou sand of 10%, Xinfeng stone flour of 8%, 1% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1220 ℃, and the shrinking percentage after burning till is 11%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 13% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 5% clear frit is processed; It begins the agglomerating temperature is 1160 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 9.76% potassium felspar sand, 6.33% calcite, 56.25% quartz, 1.78% zinc oxide, 15.6% boric acid, 8.53% soda ash by weight percentage, 1.76% aluminum oxide is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
271, Al
2O
34.0 KNaO 7, CaO 4.0, and ZnO 4, B
2O
310.Its fusing point is 1200 ℃, and yield point is 1240 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain the milky white full glaze porcelain brick of throwing.
Embodiment 8:
At first; Get by weight percentage 8% new can mud, Qingyuan City's mud of 15%, Qingyuan City's aloxite of 8%, 5% pure and fresh aloxite, Xinfeng sodium sand of 26%, Qingyuan City's stone flour of 18%, 20% Xinyi sand, 5.5% silver small cup sand, 2.5% black stone powder processes blank raw material, with the base substrate of press-molding 600mm * 600mm.The firing temperature of this base substrate is 1180 ℃, and the shrinking percentage after burning till is 10%, and the coefficient of expansion that burns till the back base substrate is 8.0～9.2 * 10
-6Between (20～600 ℃), burn till water-intake rate≤0.1% of back base substrate.
Secondly, on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm.The ground-coat enamel of executing be get 35% albite, 15% calcite, 10% burning talcum, 2% burning ZnO, 7% zirconium silicate, 10% aluminum oxide, 3% quartz, 5% burning kaolin, 5% air knife soil by weight percentage, 8% clear frit is processed; It begins the agglomerating temperature is 1100 ℃, and the coefficient of expansion that burns till the back ground-coat enamel is 7.8～9.4 * 10
-6Between (20～600 ℃).
Then, utilize screen printing or rotary printing or spray ink Printing to decorate.
Then, cloth 30～80 purpose frit dry granulars on base substrate, quantity is 3.0～4.0g/cm
2The frit of getting by get 17.12% potassium felspar sand, 14.88% burning talcum, 21.75% calcite, 23.76% quartz, 8.56% barium carbonate, 1.67% zinc oxide, 7.36% boric acid by weight percentage, 4.88% soda ash is processed; Produce and adopt tank furnace; Under 1500～1560 ℃ temperature, found, the back adopts the breaking method of collision type to obtain.Its component and part by weight are: SiO
255, Al
2O
33, KNaO 6, and CaO 15, and MgO 6, and ZnO 2, B
2O
35, BaO8.Its fusing point is 1170 ℃, and yield point is 1210 ℃.
Follow, send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes.
At last, polish and sorting, obtain the milky white full glaze porcelain brick of throwing.
Claims (3)
1. high temperature once burns the preparation method of full throwing glaze porcelain brick, it is characterized in that comprising the step of following order:
Step 1: utilize the press-molding base substrate, the percent of firing shrinkage of said base substrate≤11%, the base substrate firing temperature is at 1180～1220 ℃;
Step 2: on base substrate, execute ground-coat enamel, the thickness of ground-coat enamel is 0.15～0.25mm, the beginning agglomerating temperature of said ground-coat enamel >=1100 ℃;
Step 3: executing cloth 30～80 purposes frit dry granular spherical in shape on the base substrate of ground-coat enamel, quantity is 3.0～4.0g/cm
2, the fusing point of said frit>=1170 ℃, the yield point of frit>=1210 ℃;
Step 4: spray fixing agent;
Step 5: send into and carry out sintering in the pottery kiln, firing time is: room temperature～1000 ℃ are 35～40 minutes, and 1000～1180 ℃ is 7～10 minutes, and 1180～1220 ℃ is 6～8 minutes, and 1220～200 ℃ is 34～36 minutes;
Step 6: polish and sorting.
2. high temperature according to claim 1 once burns the preparation method of full throwing glaze porcelain brick, it is characterized in that, the component of said frit and part by weight are: SiO
255～68, Al
2O
313～19.5, KNaO 3～8, and CaO 2～15, and MgO 0～2, and ZnO 0～4, B
2O
33～7, BaO 0～4.
3. high temperature according to claim 1 once burns the preparation method of full throwing glaze porcelain brick, it is characterized in that, the component of said frit and part by weight are: SiO
255～71, Al
2O
33～4.3, KNaO 6～7, and CaO 4～15, and MgO 0～6, and ZnO 2～6, B
2O
31～10, BaO 0～8.
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| CN104829267A (en) * | 2015-05-04 | 2015-08-12 | 广东蒙娜丽莎新型材料集团有限公司 | High wear resistance in-glaze decoration ceramic brick and preparation method thereof |
| CN105272375A (en) * | 2015-10-29 | 2016-01-27 | 佛山市中成硅酸盐科技有限公司 | Wear resistant and high-hardness diamond glaze, preparation method and application |
| CN106431502A (en) * | 2016-09-03 | 2017-02-22 | 佛山市高明贝斯特陶瓷有限公司 | Production process of tile with natural jade texture |
| CN109180203A (en) * | 2018-09-28 | 2019-01-11 | 湖南益嘉瓷业有限公司 | Mud of resistance to chafing dish and preparation method thereof |
| CN109867446A (en) * | 2019-03-15 | 2019-06-11 | 蒙娜丽莎集团股份有限公司 | The super flat frit dry granular glaze of one kind throws brick and preparation method thereof entirely |
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| CN105272375A (en) * | 2015-10-29 | 2016-01-27 | 佛山市中成硅酸盐科技有限公司 | Wear resistant and high-hardness diamond glaze, preparation method and application |
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| CN109180203A (en) * | 2018-09-28 | 2019-01-11 | 湖南益嘉瓷业有限公司 | Mud of resistance to chafing dish and preparation method thereof |
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