CN1337979A - 热塑性橡胶组合物 - Google Patents
热塑性橡胶组合物 Download PDFInfo
- Publication number
- CN1337979A CN1337979A CN99816015A CN99816015A CN1337979A CN 1337979 A CN1337979 A CN 1337979A CN 99816015 A CN99816015 A CN 99816015A CN 99816015 A CN99816015 A CN 99816015A CN 1337979 A CN1337979 A CN 1337979A
- Authority
- CN
- China
- Prior art keywords
- rubber
- matrix
- thermoplastics
- natural rubber
- compatilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 105
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims description 11
- 229920001971 elastomer Polymers 0.000 claims abstract description 213
- 239000005060 rubber Substances 0.000 claims abstract description 213
- 239000011159 matrix material Substances 0.000 claims abstract description 190
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 139
- 229920001194 natural rubber Polymers 0.000 claims abstract description 139
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 137
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 114
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 102
- 150000002825 nitriles Chemical class 0.000 claims abstract description 50
- 229920000728 polyester Polymers 0.000 claims abstract description 27
- 229920003192 poly(bis maleimide) Polymers 0.000 claims abstract description 22
- 229920000098 polyolefin Polymers 0.000 claims abstract description 20
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 20
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 16
- 150000002118 epoxides Chemical class 0.000 claims abstract description 16
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 13
- 150000002367 halogens Chemical class 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 229920002678 cellulose Polymers 0.000 claims abstract description 12
- 239000004814 polyurethane Substances 0.000 claims abstract description 12
- 229920002635 polyurethane Polymers 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920002647 polyamide Polymers 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 7
- 239000004952 Polyamide Substances 0.000 claims abstract description 6
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 3
- 229920003023 plastic Polymers 0.000 claims description 73
- 239000004033 plastic Substances 0.000 claims description 73
- 238000000034 method Methods 0.000 claims description 34
- -1 sovprene Substances 0.000 claims description 31
- 238000002156 mixing Methods 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 25
- 239000000126 substance Substances 0.000 claims description 25
- 239000003963 antioxidant agent Substances 0.000 claims description 24
- 230000003078 antioxidant effect Effects 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 21
- 150000001408 amides Chemical class 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 17
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 claims description 17
- 239000003921 oil Substances 0.000 claims description 16
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000004743 Polypropylene Substances 0.000 claims description 14
- 229920001155 polypropylene Polymers 0.000 claims description 14
- 229920003987 resole Polymers 0.000 claims description 13
- 229920001903 high density polyethylene Polymers 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 238000004073 vulcanization Methods 0.000 claims description 12
- 229920002292 Nylon 6 Polymers 0.000 claims description 11
- 229920013649 Paracril Polymers 0.000 claims description 10
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 10
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 10
- 229920003051 synthetic elastomer Polymers 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 9
- 150000002978 peroxides Chemical class 0.000 claims description 9
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 9
- 239000004800 polyvinyl chloride Substances 0.000 claims description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 230000026030 halogenation Effects 0.000 claims description 7
- 238000005658 halogenation reaction Methods 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 229920006222 acrylic ester polymer Polymers 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 6
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 239000010690 paraffinic oil Substances 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 6
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 5
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 5
- 235000019439 ethyl acetate Nutrition 0.000 claims description 5
- 229920002681 hypalon Polymers 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 229920002223 polystyrene Polymers 0.000 claims description 5
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 5
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical group OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 3
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000008380 degradant Substances 0.000 claims description 3
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000011117 high nitrile polymer Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 125000005504 styryl group Chemical group 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 claims description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 claims description 2
- VXPSQDAMFATNNG-UHFFFAOYSA-N 3-[2-(2,5-dioxopyrrol-3-yl)phenyl]pyrrole-2,5-dione Chemical group O=C1NC(=O)C(C=2C(=CC=CC=2)C=2C(NC(=O)C=2)=O)=C1 VXPSQDAMFATNNG-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004606 Fillers/Extenders Substances 0.000 claims description 2
- 229920000571 Nylon 11 Polymers 0.000 claims description 2
- 229920000299 Nylon 12 Polymers 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- 229910000085 borane Inorganic materials 0.000 claims description 2
- 229920006218 cellulose propionate Polymers 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 238000002425 crystallisation Methods 0.000 claims description 2
- 230000008025 crystallization Effects 0.000 claims description 2
- 230000003544 deproteinization Effects 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 2
- 150000001451 organic peroxides Chemical class 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 238000012958 reprocessing Methods 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 2
- 229920006173 natural rubber latex Polymers 0.000 claims 2
- 239000013043 chemical agent Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 6
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920000141 poly(maleic anhydride) Polymers 0.000 abstract 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 24
- 229920000459 Nitrile rubber Polymers 0.000 description 21
- IPJGAEWUPXWFPL-UHFFFAOYSA-N 1-[3-(2,5-dioxopyrrol-1-yl)phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC(N2C(C=CC2=O)=O)=C1 IPJGAEWUPXWFPL-UHFFFAOYSA-N 0.000 description 17
- 230000008569 process Effects 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 230000009477 glass transition Effects 0.000 description 8
- 230000004580 weight loss Effects 0.000 description 8
- 238000000465 moulding Methods 0.000 description 7
- 230000035939 shock Effects 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000005987 sulfurization reaction Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 239000000395 magnesium oxide Substances 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 229920001084 poly(chloroprene) Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000002411 thermogravimetry Methods 0.000 description 5
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 5
- 229920002943 EPDM rubber Polymers 0.000 description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000005061 synthetic rubber Substances 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 2
- 229920001342 Bakelite® Polymers 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004637 bakelite Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229920006178 high molecular weight high density polyethylene Polymers 0.000 description 2
- 229940072322 hylan Drugs 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000005502 peroxidation Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
- UDYXMTORTDACTG-UHFFFAOYSA-N 1,1,3-tributylthiourea Chemical compound CCCCNC(=S)N(CCCC)CCCC UDYXMTORTDACTG-UHFFFAOYSA-N 0.000 description 1
- AEUZJPHUNWZRCJ-UHFFFAOYSA-N 1-butyl-2-propan-2-ylbenzene Chemical group CCCCC1=CC=CC=C1C(C)C AEUZJPHUNWZRCJ-UHFFFAOYSA-N 0.000 description 1
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- CZNRFEXEPBITDS-UHFFFAOYSA-N 2,5-bis(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=C(C(C)(C)CC)C=C1O CZNRFEXEPBITDS-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 206010027476 Metastases Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000012317 TBTU Substances 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QKNALXSEDPJVFW-UHFFFAOYSA-J [Sn].[Sn](Cl)(Cl)(Cl)Cl Chemical compound [Sn].[Sn](Cl)(Cl)(Cl)Cl QKNALXSEDPJVFW-UHFFFAOYSA-J 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 210000002659 acromion Anatomy 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- 230000009401 metastasis Effects 0.000 description 1
- JFHJOMSTWVDDHW-UHFFFAOYSA-N methyl prop-2-enoate;prop-2-enenitrile Chemical compound C=CC#N.COC(=O)C=C JFHJOMSTWVDDHW-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert-Butyl hydroperoxide Substances CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/04—Oxidation
- C08C19/06—Epoxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPP7505 | 1998-12-04 | ||
| AUPP7505A AUPP750598A0 (en) | 1998-12-04 | 1998-12-04 | Thermoplastic rubber composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1337979A true CN1337979A (zh) | 2002-02-27 |
Family
ID=3811715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99816015A Pending CN1337979A (zh) | 1998-12-04 | 1999-12-03 | 热塑性橡胶组合物 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1171524A1 (id) |
| CN (1) | CN1337979A (id) |
| AU (1) | AUPP750598A0 (id) |
| BR (1) | BR9915932A (id) |
| CA (1) | CA2353614A1 (id) |
| ID (1) | ID29940A (id) |
| MX (1) | MXPA01005606A (id) |
| WO (1) | WO2000034383A1 (id) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100392038C (zh) * | 2006-03-13 | 2008-06-04 | 株洲市宏大高分子材料厂 | 改性tpu耐磨密封材料及其制备方法与用途 |
| CN101429295B (zh) * | 2007-09-20 | 2011-07-13 | 固特异轮胎和橡胶公司 | 具有含纤维素的部件的轮胎 |
| CN102958989A (zh) * | 2010-06-29 | 2013-03-06 | 伊士曼化工公司 | 纤维素酯组合物和纤维素酯/弹性体组合物以及它们的制造方法 |
| CN103657014A (zh) * | 2013-12-09 | 2014-03-26 | 成都动能健身服务有限公司 | 一种健身球及其制造方法 |
| CN104373501A (zh) * | 2014-10-08 | 2015-02-25 | 安徽奥丰汽车配件有限公司 | 新型材质的汽车减振器托盘 |
| CN105131206A (zh) * | 2015-09-23 | 2015-12-09 | 江苏蓝湾生物科技有限公司 | 一种医用除臭橡胶材料的制备方法 |
| CN105131492A (zh) * | 2015-08-18 | 2015-12-09 | 合肥市再德高分子材料有限公司 | 一种复合改性高性能天然橡胶材料 |
| CN105745280A (zh) * | 2013-11-20 | 2016-07-06 | 巴斯夫欧洲公司 | 包含热塑性聚氨酯组合物和环氧官能苯乙烯丙烯酸系共聚物的热塑性聚氨酯发泡制品 |
| CN105860020A (zh) * | 2016-04-19 | 2016-08-17 | 滁州环球聚氨酯科技有限公司 | 一种高强度疏水阻燃聚氨酯电缆外护套 |
| CN105968491A (zh) * | 2016-05-20 | 2016-09-28 | 温州泓呈祥科技有限公司 | 一种包含阻燃复配剂ldhs/sba-15的电缆绝缘材料及用途 |
| CN106009449A (zh) * | 2016-05-25 | 2016-10-12 | 北京化工大学 | 一种耐高温耐油热塑性硫化胶及其制备方法 |
| CN107189321A (zh) * | 2017-06-20 | 2017-09-22 | 安徽悦尔伟塑料机械有限公司 | Tpe/pvac复合保鲜盒盖及其制备方法 |
| CN107429165A (zh) * | 2015-03-10 | 2017-12-01 | 阿科玛法国公司 | 热塑性组合物和预浸体、由所述预浸体制得的复合材料以及所述复合材料的用途 |
| CN107674269A (zh) * | 2017-11-06 | 2018-02-09 | 张永宏 | 静电吸附膜生产模具表面材料的制备方法 |
| CN110099801A (zh) * | 2016-12-15 | 2019-08-06 | 米其林集团总公司 | 包括含有由亲二烯体交联的带有共轭二烯基团的聚合物的橡胶组合物的轮胎 |
| CN113480787A (zh) * | 2018-10-25 | 2021-10-08 | 常熟市斯泰普新材料有限公司 | 一种橡胶材料 |
| CN113549339A (zh) * | 2021-08-05 | 2021-10-26 | 温州市荣奇鞋业有限公司 | 一种休闲鞋鞋底及其制备方法 |
| CN116515179A (zh) * | 2023-06-29 | 2023-08-01 | 中裕铁信交通科技股份有限公司 | 一种隧道橡塑止水带及其制备方法和应用 |
| CN116622132A (zh) * | 2023-05-12 | 2023-08-22 | 深圳市好年璟科技有限公司 | 一种耐老化橡胶塑料复合材料及其制备方法 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6656582B2 (en) | 2000-06-16 | 2003-12-02 | Tokai Rubber Industries, Ltd. | Rubber product with metallic structure and method of producing the same |
| JP3799968B2 (ja) * | 2000-06-16 | 2006-07-19 | 東海ゴム工業株式会社 | 耐久性に優れた防振ゴムの製造方法 |
| WO2003018078A1 (en) * | 2001-08-31 | 2003-03-06 | Mihai Curtescu | Curable compositions containing polymeric hydrogels and process for manufacturing technical articles and staples products therefrom |
| EP1881037A4 (en) * | 2005-05-10 | 2011-11-30 | Yokohama Rubber Co Ltd | THEMOPLASTIC ELASTOMER COMPOSITION |
| US20070238833A1 (en) * | 2006-04-10 | 2007-10-11 | Christian Leboeuf | Polyamide composition comprising a modifier |
| US9273195B2 (en) * | 2010-06-29 | 2016-03-01 | Eastman Chemical Company | Tires comprising cellulose ester/elastomer compositions |
| US9708475B2 (en) | 2011-12-07 | 2017-07-18 | Eastman Chemical Company | Cellulose esters in highly-filled elastomeric systems |
| US20160075866A1 (en) * | 2014-09-12 | 2016-03-17 | Teknor Apex Company | Compositions for capstock applications |
| DE102015215327A1 (de) * | 2015-08-11 | 2017-02-16 | Continental Reifen Deutschland Gmbh | Kautschukmischung und Fahrzeugreifen |
| US10077343B2 (en) | 2016-01-21 | 2018-09-18 | Eastman Chemical Company | Process to produce elastomeric compositions comprising cellulose ester additives |
| KR101862058B1 (ko) | 2016-10-06 | 2018-06-29 | 넥쌍 | 에틸렌 비닐 아세테이트 공중합체 및 니트릴 고무를 포함하는 가교된 조성물 |
| EP3456763A1 (en) * | 2017-09-19 | 2019-03-20 | Feng Tay Enterprises Co., Ltd. | Thermoplastic vulcanizate composition |
| US10364336B2 (en) | 2017-09-22 | 2019-07-30 | Feng Tay Enterprises Co., Ltd. | Thermoplastic vulcanizate composition, method of forming the same and product thereof |
| BR102018014526B1 (pt) * | 2018-07-16 | 2023-11-07 | Sidnei Winston Nasser | Composição polimérica injetável, artefato de borracha e método para fabricação de um artefato de borracha |
| EP3689935A1 (en) * | 2019-01-30 | 2020-08-05 | Politechnika Gdanska | Thermoplastic polyurethane-rubber composite and method for obtaining thermoplastic polyurethane-rubber composite |
| CN113372521B (zh) * | 2020-03-10 | 2023-11-21 | 山东圣泉新材料股份有限公司 | 一种改性酚醛树脂及其制备方法和其作为增粘树脂的应用 |
| CN115073912A (zh) * | 2021-03-15 | 2022-09-20 | 彰洋材料股份有限公司 | 热塑性硫化胶组成物及其制备方法与鞋材 |
| CN115197480A (zh) * | 2021-04-09 | 2022-10-18 | 中国石油化工股份有限公司 | 一种nr/pp热塑性弹性体材料组合物及其制备方法和应用 |
| CN113185845B (zh) * | 2021-05-21 | 2022-04-29 | 湖北工业大学 | 一种基于活化废胶粉的沥青改性材料的制备方法及应用 |
| CN114381047B (zh) * | 2022-01-26 | 2023-07-04 | 宁波磐固工程技术有限公司 | 一种粘结性高的记忆橡胶及其制备方法、应用 |
| CN115678121A (zh) * | 2022-09-08 | 2023-02-03 | 深圳海源恒业高新材料科技研发有限公司 | 一种天然橡胶基热塑性硫化橡胶及制备方法 |
| CN117167484B (zh) * | 2023-08-31 | 2024-03-19 | 广东东方管业有限公司 | 一种动态密封橡胶圈及其制备方法和应用 |
| CN117402418B (zh) * | 2023-12-11 | 2024-02-27 | 河北润驰流体科技有限公司 | 一种高耐磨橡胶软管及其制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1473241A (en) * | 1974-01-25 | 1977-05-11 | Dunlop Ltd | 3-dimensional patterned articles of moulded rubber |
| US4515851A (en) * | 1982-10-25 | 1985-05-07 | Becton, Dickinson And Company | Slip resistant surfaces |
| JPS60162628A (ja) * | 1984-02-02 | 1985-08-24 | Chiriyuu Takaron Kk | 複合プラスチツクシ−トの製造方法 |
| JPS61188138A (ja) * | 1985-02-15 | 1986-08-21 | 株式会社ブリヂストン | 防食構造体 |
| JPS63152471A (ja) * | 1986-12-13 | 1988-06-24 | 池田物産株式会社 | カ−ペツトの製造方法 |
| JPH0813907B2 (ja) * | 1987-11-27 | 1996-02-14 | 日本合成ゴム株式会社 | 防振・防音・遮音材用ゴム組成物 |
| JP2518012B2 (ja) * | 1988-05-25 | 1996-07-24 | 日本合成ゴム株式会社 | 積層体 |
| JP3056316B2 (ja) * | 1992-02-06 | 2000-06-26 | 積水化学工業株式会社 | 積層用シート及びその製造方法 |
| US5641562A (en) * | 1994-12-30 | 1997-06-24 | Kimberly-Clark Worldwide Inc. | Water-shrinkable film |
-
1998
- 1998-12-04 AU AUPP7505A patent/AUPP750598A0/en not_active Abandoned
-
1999
- 1999-12-03 ID IDW00200101188A patent/ID29940A/id unknown
- 1999-12-03 WO PCT/AU1999/001074 patent/WO2000034383A1/en not_active Application Discontinuation
- 1999-12-03 EP EP99960711A patent/EP1171524A1/en not_active Withdrawn
- 1999-12-03 CA CA002353614A patent/CA2353614A1/en not_active Abandoned
- 1999-12-03 BR BR9915932-5A patent/BR9915932A/pt not_active Application Discontinuation
- 1999-12-03 MX MXPA01005606A patent/MXPA01005606A/es unknown
- 1999-12-03 CN CN99816015A patent/CN1337979A/zh active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100392038C (zh) * | 2006-03-13 | 2008-06-04 | 株洲市宏大高分子材料厂 | 改性tpu耐磨密封材料及其制备方法与用途 |
| CN101429295B (zh) * | 2007-09-20 | 2011-07-13 | 固特异轮胎和橡胶公司 | 具有含纤维素的部件的轮胎 |
| CN102958989A (zh) * | 2010-06-29 | 2013-03-06 | 伊士曼化工公司 | 纤维素酯组合物和纤维素酯/弹性体组合物以及它们的制造方法 |
| CN105745280A (zh) * | 2013-11-20 | 2016-07-06 | 巴斯夫欧洲公司 | 包含热塑性聚氨酯组合物和环氧官能苯乙烯丙烯酸系共聚物的热塑性聚氨酯发泡制品 |
| CN105745280B (zh) * | 2013-11-20 | 2019-03-15 | 巴斯夫欧洲公司 | 包含热塑性聚氨酯组合物和环氧官能苯乙烯丙烯酸系共聚物的热塑性聚氨酯发泡制品 |
| CN103657014A (zh) * | 2013-12-09 | 2014-03-26 | 成都动能健身服务有限公司 | 一种健身球及其制造方法 |
| CN103657014B (zh) * | 2013-12-09 | 2016-02-17 | 成都动能健身服务有限公司 | 一种健身球及其制造方法 |
| CN104373501A (zh) * | 2014-10-08 | 2015-02-25 | 安徽奥丰汽车配件有限公司 | 新型材质的汽车减振器托盘 |
| CN107429165A (zh) * | 2015-03-10 | 2017-12-01 | 阿科玛法国公司 | 热塑性组合物和预浸体、由所述预浸体制得的复合材料以及所述复合材料的用途 |
| CN105131492A (zh) * | 2015-08-18 | 2015-12-09 | 合肥市再德高分子材料有限公司 | 一种复合改性高性能天然橡胶材料 |
| CN105131206A (zh) * | 2015-09-23 | 2015-12-09 | 江苏蓝湾生物科技有限公司 | 一种医用除臭橡胶材料的制备方法 |
| CN105860020A (zh) * | 2016-04-19 | 2016-08-17 | 滁州环球聚氨酯科技有限公司 | 一种高强度疏水阻燃聚氨酯电缆外护套 |
| CN105968491A (zh) * | 2016-05-20 | 2016-09-28 | 温州泓呈祥科技有限公司 | 一种包含阻燃复配剂ldhs/sba-15的电缆绝缘材料及用途 |
| CN106009449A (zh) * | 2016-05-25 | 2016-10-12 | 北京化工大学 | 一种耐高温耐油热塑性硫化胶及其制备方法 |
| CN110099801A (zh) * | 2016-12-15 | 2019-08-06 | 米其林集团总公司 | 包括含有由亲二烯体交联的带有共轭二烯基团的聚合物的橡胶组合物的轮胎 |
| CN107189321A (zh) * | 2017-06-20 | 2017-09-22 | 安徽悦尔伟塑料机械有限公司 | Tpe/pvac复合保鲜盒盖及其制备方法 |
| CN107674269A (zh) * | 2017-11-06 | 2018-02-09 | 张永宏 | 静电吸附膜生产模具表面材料的制备方法 |
| CN113480787A (zh) * | 2018-10-25 | 2021-10-08 | 常熟市斯泰普新材料有限公司 | 一种橡胶材料 |
| CN113549339A (zh) * | 2021-08-05 | 2021-10-26 | 温州市荣奇鞋业有限公司 | 一种休闲鞋鞋底及其制备方法 |
| CN116622132A (zh) * | 2023-05-12 | 2023-08-22 | 深圳市好年璟科技有限公司 | 一种耐老化橡胶塑料复合材料及其制备方法 |
| CN116515179A (zh) * | 2023-06-29 | 2023-08-01 | 中裕铁信交通科技股份有限公司 | 一种隧道橡塑止水带及其制备方法和应用 |
| CN116515179B (zh) * | 2023-06-29 | 2023-09-01 | 中裕铁信交通科技股份有限公司 | 一种隧道橡塑止水带及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2353614A1 (en) | 2000-06-15 |
| AUPP750598A0 (en) | 1999-01-07 |
| WO2000034383A1 (en) | 2000-06-15 |
| ID29940A (id) | 2001-10-25 |
| EP1171524A1 (en) | 2002-01-16 |
| MXPA01005606A (es) | 2003-07-14 |
| BR9915932A (pt) | 2001-12-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1337979A (zh) | 热塑性橡胶组合物 | |
| CN1168772C (zh) | 非极性热塑性弹性体和极性热塑性聚合物的相容共混物 | |
| CN1190460C (zh) | 低弹性率高分子组合物及应用该组合物的密封材料 | |
| US5621045A (en) | Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber | |
| CN1066761C (zh) | 硫化的聚烯烃塑弹体组合物及其制备方法 | |
| CN1974663A (zh) | 可交联组合物,由此得到的热塑性弹性体及其用途 | |
| CN1094070A (zh) | 改进低温性能的热塑性弹性体 | |
| CN1367801A (zh) | 高度结晶的无规乙烯/α－烯烃/多烯烃共聚体 | |
| CN1016789B (zh) | 生产具有减少透气性的硫化橡胶的方法 | |
| US20060142492A1 (en) | Dynamic vulcanization of non-nitrile rubbers in fluoroplastic polymers | |
| US6492454B1 (en) | Rubber composition containing rubber, mercapto-triazine and epoxy grafter polymer | |
| CN1154696C (zh) | 聚酰胺树脂组合物 | |
| CN1643055A (zh) | 烯烃热塑性弹性体及其模件 | |
| CN1139686A (zh) | 具有改进的高温性能的热塑性弹性体 | |
| CN1425552A (zh) | 包含evoh和聚酰胺防渗层的硫化弹性体管 | |
| JP2006169523A (ja) | 過酸化物硬化ｈｘｎｂｒ−ポリアミド熱可塑性樹脂加硫物の多段製造法 | |
| EP0324312B1 (en) | Polymer alloy | |
| CN1175052C (zh) | 高劲度高强度的热塑性树脂模制品 | |
| CN1753942A (zh) | 用于工程热塑性塑料/聚烯烃共混物的相容剂 | |
| CN1257528A (zh) | 用于由挤出吹塑料方法制造制品的聚酰胺组合物和获得的制品 | |
| CN1178982C (zh) | 苯乙烯树脂及其组合物 | |
| CN1993425A (zh) | 抗冲改性的聚酰胺组合物 | |
| JP3622470B2 (ja) | ポリアミド繊維強化ゴム組成物とその製造法 | |
| CN1192454A (zh) | 以含有1,2－二氟乙烯和丁二烯－丙烯腈弹性体结构单元的含氟聚合物为主要成分的组合物 | |
| JP4239638B2 (ja) | オレフィン系熱可塑性エラストマーおよびその成形体 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| C10 | Entry into substantive examination | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |