CN114381047B - 一种粘结性高的记忆橡胶及其制备方法、应用 - Google Patents
一种粘结性高的记忆橡胶及其制备方法、应用 Download PDFInfo
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- CN114381047B CN114381047B CN202210096381.2A CN202210096381A CN114381047B CN 114381047 B CN114381047 B CN 114381047B CN 202210096381 A CN202210096381 A CN 202210096381A CN 114381047 B CN114381047 B CN 114381047B
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- rubber
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 165
- 239000005060 rubber Substances 0.000 title claims abstract description 165
- 238000002360 preparation method Methods 0.000 title abstract description 16
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 29
- 239000004417 polycarbonate Substances 0.000 claims abstract description 29
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 24
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 24
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 18
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 18
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008117 stearic acid Substances 0.000 claims abstract description 18
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 18
- 239000011593 sulfur Substances 0.000 claims abstract description 15
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 69
- 244000043261 Hevea brasiliensis Species 0.000 claims description 57
- 229920003052 natural elastomer Polymers 0.000 claims description 57
- 229920001194 natural rubber Polymers 0.000 claims description 57
- 239000007789 gas Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 31
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 28
- 229910045601 alloy Inorganic materials 0.000 claims description 28
- 239000000956 alloy Substances 0.000 claims description 28
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical group [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 28
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 17
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- 229920002943 EPDM rubber Polymers 0.000 claims description 15
- 229920005549 butyl rubber Polymers 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 15
- 238000001914 filtration Methods 0.000 claims description 15
- 238000005406 washing Methods 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- 239000012257 stirred material Substances 0.000 claims description 4
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- PXHVJJICTQNCMI-OUBTZVSYSA-N nickel-60 atom Chemical group [60Ni] PXHVJJICTQNCMI-OUBTZVSYSA-N 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 150000003505 terpenes Chemical class 0.000 claims description 3
- 235000007586 terpenes Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000004073 vulcanization Methods 0.000 description 11
- 238000001746 injection moulding Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920003051 synthetic elastomer Polymers 0.000 description 3
- 239000005061 synthetic rubber Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 108010081750 Reticulin Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/02—Protection of pipes or objects of similar shape against external or internal damage or wear against cracking or buckling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/06—Protection of pipes or objects of similar shape against external or internal damage or wear against wear
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/12—Shape memory
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210096381.2A CN114381047B (zh) | 2022-01-26 | 2022-01-26 | 一种粘结性高的记忆橡胶及其制备方法、应用 |
Applications Claiming Priority (1)
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---|---|---|---|
CN202210096381.2A CN114381047B (zh) | 2022-01-26 | 2022-01-26 | 一种粘结性高的记忆橡胶及其制备方法、应用 |
Publications (2)
Publication Number | Publication Date |
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CN114381047A CN114381047A (zh) | 2022-04-22 |
CN114381047B true CN114381047B (zh) | 2023-07-04 |
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CN202210096381.2A Active CN114381047B (zh) | 2022-01-26 | 2022-01-26 | 一种粘结性高的记忆橡胶及其制备方法、应用 |
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CN (1) | CN114381047B (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59193934A (ja) * | 1983-04-18 | 1984-11-02 | Omron Tateisi Electronics Co | プラスチツク成形品 |
KR20100114752A (ko) * | 2009-04-16 | 2010-10-26 | 경상대학교산학협력단 | 실리콘/천연고무 블렌드 및 이를 이용한 성형품 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPP750598A0 (en) * | 1998-12-04 | 1999-01-07 | Cromiac International Pte Ltd | Thermoplastic rubber composition |
CN1233703C (zh) * | 2003-07-31 | 2005-12-28 | 北京化工大学 | 高粘结性热塑性硫化胶的制备方法 |
KR100750220B1 (ko) * | 2006-09-28 | 2007-08-17 | 금호타이어 주식회사 | 형상기억수지를 포함하는 타이어 트레드 고무조성물 |
US8353346B2 (en) * | 2010-04-20 | 2013-01-15 | Baker Hughes Incorporated | Prevention, actuation and control of deployment of memory-shape polymer foam-based expandables |
CN104098795B (zh) * | 2013-04-12 | 2016-09-21 | 中国石油化工股份有限公司 | 一种导电热塑性弹性体及其制备方法 |
CN105837867B (zh) * | 2016-04-12 | 2018-05-15 | 沈阳化工大学 | 一种杜仲胶与聚烯烃热塑性树脂制备tpv材料的方法 |
CN105860159B (zh) * | 2016-06-02 | 2018-11-16 | 上海明凤汽车科技有限公司 | 记忆橡胶组合物、制备方法及其应用 |
CN107022118A (zh) * | 2017-03-20 | 2017-08-08 | 马战峰 | 一种形状记忆高分子聚合物及其制备方法和用途 |
CN107266730A (zh) * | 2017-08-09 | 2017-10-20 | 浙江久运汽车零部件有限公司 | 一种耐摩擦橡胶缓冲垫 |
CN108659276A (zh) * | 2018-05-21 | 2018-10-16 | 芜湖市宝艺游乐科技设备有限公司 | 一种二氧化硅增强杜仲橡胶基形状记忆材料的制备方法 |
-
2022
- 2022-01-26 CN CN202210096381.2A patent/CN114381047B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59193934A (ja) * | 1983-04-18 | 1984-11-02 | Omron Tateisi Electronics Co | プラスチツク成形品 |
KR20100114752A (ko) * | 2009-04-16 | 2010-10-26 | 경상대학교산학협력단 | 실리콘/천연고무 블렌드 및 이를 이용한 성형품 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A memory rubber with high adhesion and its preparation method and application Effective date of registration: 20230912 Granted publication date: 20230704 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Ningbo Haishu sub branch Pledgor: Ningbo Pangu Engineering Technology Co.,Ltd. Registration number: Y2023980056418 |
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Granted publication date: 20230704 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Ningbo Haishu sub branch Pledgor: Ningbo Pangu Engineering Technology Co.,Ltd. Registration number: Y2023980056418 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A memory rubber with high adhesion, its preparation method, and application Granted publication date: 20230704 Pledgee: Zhejiang Tailong Commercial Bank Co.,Ltd. Ningbo Haishu sub branch Pledgor: Ningbo Pangu Engineering Technology Co.,Ltd. Registration number: Y2024330001963 |