CN101560433B - Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution - Google Patents
Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution Download PDFInfo
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- CN101560433B CN101560433B CN2009100275323A CN200910027532A CN101560433B CN 101560433 B CN101560433 B CN 101560433B CN 2009100275323 A CN2009100275323 A CN 2009100275323A CN 200910027532 A CN200910027532 A CN 200910027532A CN 101560433 B CN101560433 B CN 101560433B
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- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 30
- 239000011777 magnesium Substances 0.000 title claims abstract description 30
- 230000007797 corrosion Effects 0.000 title claims abstract description 16
- 238000005260 corrosion Methods 0.000 title claims abstract description 16
- 239000008233 hard water Substances 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 239000002199 base oil Substances 0.000 claims abstract description 6
- 150000007524 organic acids Chemical class 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- -1 metasilicate Chemical compound 0.000 claims description 19
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 11
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 claims description 9
- 239000013543 active substance Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000005555 metalworking Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 3
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 claims description 3
- 229940054266 2-mercaptobenzothiazole Drugs 0.000 claims description 3
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 claims description 3
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 3
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 3
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- FXMBKAAULHJRKL-UHFFFAOYSA-N [amino(dimethoxy)silyl]oxymethane Chemical compound CO[Si](N)(OC)OC FXMBKAAULHJRKL-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 238000005576 amination reaction Methods 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 3
- 150000007520 diprotic acids Chemical class 0.000 claims description 3
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 150000003918 triazines Chemical class 0.000 claims description 3
- 229960004418 trolamine Drugs 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims 3
- 239000003352 sequestering agent Substances 0.000 claims 2
- 229910000861 Mg alloy Inorganic materials 0.000 abstract description 10
- 239000003112 inhibitor Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000314 lubricant Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000645 desinfectant Substances 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 239000002173 cutting fluid Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses an anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution, which is composed of organic acid, organic amine, corrosion inhibitor, base oil, synthetic ester, surfactant, water and other additives. The invention employs particular surfactant to improve the anti-magnesium hard water performance of the product, employs specialcompound corrosion inhibitor to enhance the anticorrosion performance of the product, and compounds a plurality of rust inhibitors, lubricants, disinfectants and defoaming agents, the product has exc ellent anti-magnesium hard water performance, anti-magnesium corrosion performance and operating safety performance, and can heighten the service performance and processing performance of the product greatly. Meanwhile, the product, which is good for environmental protection, is an environmentally-friendly magnesium alloy cutting solution with excellent performances.
Description
Technical field:
The present invention relates to a kind of water-soluble metalworking liquid.
Background technology:
It is little (about 1.8g/cm3 that magnesiumalloy has density; Be approximately 2/3 of aluminium; Iron 1/4), specific tenacity is high, thermal diffusivity is good, anti-electromagnetic interference capability is strong, Young's modulus is big; Therefore advantages such as shock absorbing property is good have a wide range of applications in fields such as Aeronautics and Astronautics, automotive industrys, to reach light-weighted purpose.
But because the chemical property of magnesiumalloy is active, brought big difficulty to processing, mg ion can dissolve in the cutting fluid in a large number in the course of processing, causes the magnesium hardness fast rise of cutting fluid, thereby causes the layering of cutting fluid and can not use.The corrosion discoloration problem very easily takes place in the magnesium alloy anticorrosion poor-performing in the course of processing simultaneously, also very easily produces hydrogen, influences the operation processing safety.And conventional at present magnesium alloy cutting fluid is because of ubiquity anti-magnesium hard water poor-performing; Work-ing life is shorter; And problem such as anti-magnesium corrosive nature is relatively poor, and the hydrogen generating capacity is more, and operational security is not good; Therefore the processing request that can't adapt to magnesiumalloy must develop the water-soluble metalworking liquid that satisfies the harsh excellent performance that requires of magnesiumalloy processing.
Summary of the invention:
The object of the present invention is to provide a kind of anti-magnesium hard water excellence, the excellent anti-magnesium hard water anti-magnesium corrosion environmentally-friendly type water-soluble metalworking liquid of corrosion resistance.
Technical solution of the present invention is:
A kind of anti-magnesium hard water anti-magnesium corrosion environmentally-friendly type water-soluble metalworking liquid is characterized in that: be made up of following composition by weight:
Organic acid 5～30%
Organic amine 1～10%
Inhibiter 1～10%
Base oil 30～60%
Synthetic ester 10～40%
Tensio-active agent 10～40%
Water 1～10%
Other additive 0.5～5%.
Organic acid is C
6～C
14Straight chain diprotic acid, C
8～C
12Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or triazines multi-carboxylic acid compounds.
Organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol or diethylaminoethanol.
Inhibiter is benzotriazole, methyl benzotriazazole, 2-mercapto benzothiazole, silicate, metasilicate, tetraethoxysilane, amination modifying siloxanes, amino Trimethoxy silane, polyalkoxysilane, alkyl polyoxyethylene SULPHOSUCCINIC ACID ESTER or alkyl phosphonic acid.
Base oil is MO or hydrogenated oil, synthetic oil.
Synthetic ester is trihydroxymethylpropanyl ester, pentaerythritol ester, the different monooctyl ester of oleic acid, Octyl adipate or Wickenol 155.
Tensio-active agent is aliphatic alcohol polyethenoxy (5～12) ether, alkylphenol-polyethenoxy (5～12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, fatty acid amide, aliphatic alcohol polyethenoxy (5～12) ester, soap, sulphonate, aliphatic acid polyethenoxy (5～12) ether or composite modified tensio-active agent.
Other additive is one or more in sterilant, skimmer, the Ao's mixture.
Sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, methyl-N-benzimidazole-2-carbamate, s-triazine or benzoate; Skimmer is silicone emulsion, polyether silicone oil or polyethers; Ao's mixture is YD 30, disodium edta, sulfonate type tetrahydroglyoxaline or HEDP.
The present invention has excellent anti-magnesium hard water performance, and this product can anti-11000mg/l magnesium hard water, can increase substantially the work-ing life of product; The present invention has the excellent magnesium corrosive nature that prevents, prevents that effectively magnesium from adding the corrosion discoloration problem in man-hour (trade mark is an AZ31 magnesiumalloy sheet, 50 ℃, nondiscoloration under the 24hr condition).This product has excellent job safety performance simultaneously, greatly reduces the hydrogen generating capacity (unit hydrogen generating capacity can reduce more than a times than like product) that adds man-hour, is applicable to the various magnesiumalloy materials of processing, guarantees operational security.
The present invention adopts special tensio-active agent to improve the corrosion resistance of product anti-magnesium hard water performance, special composite corrosion inhibitor raising product; And composite multiple rust-preventive agent, lubricant, sterilant and skimmer; Product has excellent anti-magnesium hard water performance, excellent magnesium corrosive nature and the job safety performance of preventing, can increase substantially the use properties and the processing characteristics of product.The Product Green environmental protection is a kind of excellent performance environmental-friendly magnesium alloy cutting fluid simultaneously.
Below in conjunction with embodiment the present invention is described further.
Embodiment:
Embodiment 1:
Following composition by weight is mixed stirring, gets product:
Sebacic acid 10%
Oleic acid 5%
Diethylolamine 8%
Methyl benzotriazazole 2%
MO 35%
Trihydroxymethylpropanyl ester 20%
Aliphatic alcohol polyethenoxy (9) ether 5%
Aliphatic alcohol polyethenoxy polyethenoxy ether 10%
5-chloro-2-methyl-4-isothiazoline-3-ketone 0.5%
Silicone emulsion 0.5%
Water 4%.
Embodiment 2:
A kind of anti-magnesium hard water anti-magnesium corrosion environmentally-friendly type water-soluble metalworking liquid, form by following composition by weight mixing:
Organic acid 5～30% (example 5%, 20%, 30%)
Organic amine 1～10% (example 1%, 5%, 10%)
Inhibiter 1～10% (example 1%, 5%, 10%)
Base oil 30～60% (example 30%, 45%, 60%)
Synthetic ester 10～40% (example 10%, 20%, 40%)
Tensio-active agent 10～40% (example 10%, 20%, 40%)
Water 1～10% (example 1%, 5%, 10%)
Other additive 0.5～5% (example 0.5%, 2%, 5%).
The consumption sum of above-mentioned each component is 100%.
Organic acid is C
6～C
14Straight chain diprotic acid, C
8～C
12Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or triazines multi-carboxylic acid compounds.
Organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol or diethylaminoethanol.
Inhibiter is benzotriazole, methyl benzotriazazole, 2-mercapto benzothiazole, silicate, metasilicate, tetraethoxysilane, amination modifying siloxanes, amino Trimethoxy silane, polyalkoxysilane, alkyl polyoxyethylene SULPHOSUCCINIC ACID ESTER or alkyl phosphonic acid.
Base oil is MO or hydrogenated oil, synthetic oil.
Synthetic ester is trihydroxymethylpropanyl ester, pentaerythritol ester, the different monooctyl ester of oleic acid, Octyl adipate or Wickenol 155.
Tensio-active agent is aliphatic alcohol polyethenoxy (5～12) ether, alkylphenol-polyethenoxy (5～12) ether, aliphatic alcohol polyethenoxy polyethenoxy ether, fatty acid amide, aliphatic alcohol polyethenoxy (5～12) ester, soap, sulphonate, aliphatic acid polyethenoxy (5～12) ether or composite modified tensio-active agent.
Other additive is one or more in sterilant, skimmer, the Ao's mixture.
Sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, methyl-N-benzimidazole-2-carbamate, s-triazine or benzoate; Skimmer is silicone emulsion, polyether silicone oil or polyethers; Ao's mixture is YD 30, disodium edta, sulfonate type tetrahydroglyoxaline or HEDP.
Claims (2)
1. anti-magnesium hard water anti-magnesium corrosion environmentally-friendly type water-soluble metalworking liquid is characterized in that: be made up of following composition by weight:
Organic acid is C
6～C
14Straight chain diprotic acid, C
8～C
12Lipid acid, p-tert-butyl benzoic acid, p-Nitrobenzenecarboxylic acid or triazines multi-carboxylic acid compounds;
Organic amine is Monoethanolamine MEA BASF, diethylolamine, trolamine, a Yi Bingchunan, HSDB 338, tri-isopropanolamine, morpholine, dicyclohexyl amine, N-methylmorpholine, 2-amino-2-methyl-1-propanol or diethylaminoethanol;
Inhibiter is benzotriazole, methyl benzotriazazole, 2-mercapto benzothiazole, silicate, metasilicate, tetraethoxysilane, amination modifying siloxanes, amino Trimethoxy silane, polyalkoxysilane, alkyl polyoxyethylene SULPHOSUCCINIC ACID ESTER or alkyl phosphonic acid;
Base oil is MO or synthetic oil;
Synthetic ester is trihydroxymethylpropanyl ester, pentaerythritol ester, the different monooctyl ester of oleic acid, Octyl adipate or Wickenol 155;
Tensio-active agent is aliphatic alcohol polyethenoxy 5～12 ethers, alkylphenol-polyethenoxy 5～12 ethers, aliphatic alcohol polyethenoxy polyethenoxy ether, fatty acid amide, aliphatic alcohol polyethenoxy 5～12 esters, soap, sulphonate or aliphatic acid polyethenoxy 5～12 ethers; Other additive is one or more in sterilant, skimmer, the sequestrant.
2. anti-magnesium hard water anti-magnesium corrosion environmentally-friendly type water-soluble metalworking liquid according to claim 1 is characterized in that: sterilant is 5-chloro-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone, methyl-N-benzimidazole-2-carbamate, s-triazine or benzoate; Skimmer is silicone emulsion, polyether silicone oil or polyethers; Sequestrant is YD 30, disodium edta, sulfonate type tetrahydroglyoxaline or HEDP.
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| CN2009100275323A CN101560433B (en) | 2009-05-11 | 2009-05-11 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
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|---|---|---|---|
| CN2009100275323A CN101560433B (en) | 2009-05-11 | 2009-05-11 | Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution |
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| CN101560433A CN101560433A (en) | 2009-10-21 |
| CN101560433B true CN101560433B (en) | 2012-03-07 |
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| CN101886021A (en) * | 2010-07-07 | 2010-11-17 | 范成立 | Magnesium alloy cutting fluid and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1291408A1 (en) * | 2001-09-07 | 2003-03-12 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Nonflammable water-based cutting fluid composition |
| CN1548505A (en) * | 2003-05-24 | 2004-11-24 | 启东尤希路化学工业有限公司 | Water soluble cutting fluid |
| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN101092693A (en) * | 2007-07-03 | 2007-12-26 | 启东尤希路化学工业有限公司 | Environmental protective type wet skin pass rolling fluid of anti yellow spots |
-
2009
- 2009-05-11 CN CN2009100275323A patent/CN101560433B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1291408A1 (en) * | 2001-09-07 | 2003-03-12 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Nonflammable water-based cutting fluid composition |
| CN1548505A (en) * | 2003-05-24 | 2004-11-24 | 启东尤希路化学工业有限公司 | Water soluble cutting fluid |
| CN1730633A (en) * | 2005-08-09 | 2006-02-08 | 启东尤希路化学工业有限公司 | Hard water resistant water-soluble cutting solution |
| CN101092693A (en) * | 2007-07-03 | 2007-12-26 | 启东尤希路化学工业有限公司 | Environmental protective type wet skin pass rolling fluid of anti yellow spots |
Non-Patent Citations (1)
| Title |
|---|
| 王丽华，杨铁金.水基合成切削液的研制.《齐齐哈尔大学学报》.2009,第25卷(第1期),71-73. * |
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