CN113265295A - Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate - Google Patents
Environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate Download PDFInfo
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- CN113265295A CN113265295A CN202110588520.9A CN202110588520A CN113265295A CN 113265295 A CN113265295 A CN 113265295A CN 202110588520 A CN202110588520 A CN 202110588520A CN 113265295 A CN113265295 A CN 113265295A
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- 239000012530 fluid Substances 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000011086 high cleaning Methods 0.000 title claims abstract description 7
- 238000005461 lubrication Methods 0.000 title claims abstract description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 11
- 230000001050 lubricating effect Effects 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002199 base oil Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 238000009833 condensation Methods 0.000 claims abstract description 6
- 230000005494 condensation Effects 0.000 claims abstract description 6
- 150000007524 organic acids Chemical class 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- 238000005260 corrosion Methods 0.000 claims abstract description 5
- 230000007797 corrosion Effects 0.000 claims abstract description 5
- 239000003112 inhibitor Substances 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 3
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 claims description 5
- 239000005639 Lauric acid Substances 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 5
- 229960003656 ricinoleic acid Drugs 0.000 claims description 5
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 4
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000003784 tall oil Substances 0.000 claims description 4
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 claims description 3
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 claims description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 3
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- -1 sulfamic acid compound Chemical class 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000003879 lubricant additive Substances 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 9
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229940102253 isopropanolamine Drugs 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010058667 Oral toxicity Diseases 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 231100000418 oral toxicity Toxicity 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/18—Tall oil acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses an environment-friendly water-based gear broaching fluid with high lubrication and high cleaning rate, which consists of organic acid, organic amine, a corrosion inhibitor, a lubricating additive, a surfactant, base oil, water and a defoaming agent. The invention selects surfactant groups with excellent performance, such as ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and the like, and when the product is 5% of diluent, the cleaning rate of residues on the surface of a workpiece is more than or equal to 99.3%, and the cleaning rate is high.
Description
Technical Field
The invention relates to a water-based gear broaching fluid.
Background
Broaching refers to cutting a very thin metal layer from a workpiece in sequence tooth by using a special broach so that the surface reaches higher dimensional accuracy and lower roughness. This is a highly efficient processing method.
Since the cutting speed of the broaching is low and the increase in cutting temperature is small, the relief angle is preferably small in consideration of the regrinding, but this makes it difficult for the broaching oil to penetrate, and makes it complicated in terms of the generation of the chips, the surface quality, and the machining accuracy, and therefore, it is very important to select an appropriate and high-performance broaching oil. For a long time, users have traditionally used oily broaching oils, which have the advantages: the preparation process is mature, the use history is long, the wear resistance, extreme pressure property and lubricity are good, and the product is not aged or deteriorated and can be used for a long time. But there are some outstanding drawbacks: firstly, the cooling performance is poor, the workpiece is easy to deform due to the heat generated by the accumulation during broaching, and the work error occurs; secondly, the broaching resistance is large, chips are not easy to remove, the surface of a workpiece is easy to scratch (the smoothness is affected) and the broach is easy to scrape (the service life is shortened); thirdly, the cleaning performance is poor, and the workpiece and the broach are easy to rust. The aqueous broaching solution which is marketed in the last decade not only overcomes the disadvantages, but also is easy to treat (environment-friendly) due to low resource consumption (low carbon) and low waste liquid, and is favored by users. However, the current commercial aqueous broaching fluids also have some problems to be solved: firstly, the lubricating property is poor, the cleaning rate is low, and the use requirements of the gear broaching processing technique which is continuously promoted by customers are difficult to meet; secondly, the formula contains toxic and harmful substances such as chlorine, phosphorus and the like, is poor in safety and sanitation quality, and cannot meet the increasingly concerned environment-friendly requirement of people. These drawbacks seriously affect and restrict the application of aqueous broaching fluids in the market, especially in the high-end market.
Disclosure of Invention
The invention aims to provide the environment-friendly water-based gear broaching fluid with good lubricating property, high cleaning rate, high product safety and sanitary quality, high lubricating and high cleaning rate.
The technical solution of the invention is as follows:
the utility model provides a high lubrication, high cleaning rate, environment-friendly aqueous gear broaching liquid which characterized by: the paint consists of the following components in percentage by weight:
10 to 25 percent of organic acid
10 to 15 percent of organic amine
0.5 to 3 percent of corrosion inhibitor
5 to 10 percent of lubricating additive
7 to 15 percent of surfactant
25 to 35 percent of base oil
5 to 20 percent of water
0.3 to 2 percent of defoaming agent.
The organic acid is lauric acid, C10~C12One or more of straight chain dibasic acid, sulfamic acid compound, tall oil fatty acid, polymerized ricinoleic acid, erucic acid and vegetable oleic acid.
The organic amine is one or more of triisopropanolamine, monoisopropanolamine and diethylaminoethanol.
The lubricant additive is one or more of high base number synthetic calcium sulfonate (base number 300mgKOH/g, 400mgKOH/g, 500 mgKOH/g).
The corrosion inhibitor is one or more of benzotriazole and 2-mercaptobenzothiazole.
The surfactant is one or more of ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and castor oil polyoxyethylene ether.
The defoaming agent is one or more of emulsified silicone oil and methyl silicone oil.
The product of the invention selects a special lubricant calcium petroleum sulfonate and a long-chain organic acid group. Maximum no-seizing load P at 5% dilution of the productB1972N, sintering load PD>7848N, excellent lubricating property.
The invention selects surfactant groups with excellent performance, such as ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and the like. When the product is diluted by 5 percent, the cleaning rate of residues on the surface of the workpiece is more than or equal to 99.3 percent, and the cleaning rate is high.
The raw materials of the invention do not use poisonous and harmful substances (selecting the design formula of the replaceable substances with excellent performance and friendly to human and environment) which endanger the environment and human body such as chlorine, phosphorus and the like, and the product has high safety and sanitation quality (the product is acute)Oral toxicity LD50>5000mg/kg, acute inhalation toxicity LC50>5000mg/m3The respiratory tract mucosa stimulation intensity reaches 0 grade).
The present invention will be further described with reference to the following examples.
Detailed Description
Example 1:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
8 percent of isopropanolamine
Diethylaminoethanol 6%
Polymerized ricinoleic acid 6%
Tall oil fatty acid 4%
Vegetable oil acid 7%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Ethylenediamine polyoxyethylene polyoxypropylene condensation compound 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1972N, sintering load PDIs 8000N; the cleaning rate of the residues on the surface of the workpiece is 99.7%.
Example 2:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
Triisopropanolamine 7%
Diethylaminoethanol 7%
Polymerized ricinoleic acid 6%
Tall oil fatty acid 4%
Erucic acid 7%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Ethylenediamine polyoxyethylene polyoxypropylene condensation compound 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1776N, sintering load PD6082N; the cleaning rate of the residues on the surface of the workpiece is 99.4%.
Example 3:
mixing and stirring certain weight components under certain conditions to obtain a product:
5 percent of lauric acid
0.5 percent of benzotriazole
8 percent of isopropanolamine
Diethylaminoethanol 6%
Polymerized ricinoleic acid 6%
5 percent of sulfamic acid compound
Vegetable oil acid 6%
8 percent of castor oil polyoxyethylene ether
High base number synthetic calcium sulfonate 7%
Secondary alkanol polyoxyethylene polyoxypropylene block polyether 2.5%
30.5 percent of base oil
0.5 percent of emulsified silicone oil
15 percent of water
Maximum no-seizing load P at 5% dilution of the productB1874N, sintering load PD6082N; the cleaning rate of the residues on the surface of the workpiece is 99.3 percent.
Example 1 was finally selected as the final formulation based on product lubricity and wash rate results.
Claims (7)
1. The utility model provides a high lubrication, high cleaning rate, environment-friendly aqueous gear broaching liquid which characterized by: the paint consists of the following components in percentage by weight:
10 to 25 percent of organic acid
10 to 15 percent of organic amine
0.5 to 3 percent of corrosion inhibitor
5 to 10 percent of lubricating additive
7 to 15 percent of surfactant
25 to 35 percent of base oil
5 to 20 percent of water
0.3 to 2 percent of defoaming agent.
2. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the organic acid is lauric acid, C10~C12One or more of straight chain dibasic acid, sulfamic acid compound, tall oil fatty acid, polymerized ricinoleic acid, erucic acid and vegetable oleic acid.
3. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the organic amine is one or more of triisopropanolamine, monoisopropanolamine and diethylaminoethanol.
4. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the lubricant additive is one or more of high base number synthetic calcium sulfonate (base number 300mgKOH/g, 400mgKOH/g, 500 mgKOH/g).
5. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the corrosion inhibitor is one or more of benzotriazole and 2-mercaptobenzothiazole.
6. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the surfactant is one or more of ethylenediamine polyoxyethylene polyoxypropylene condensation compound, secondary alkanol polyoxyethylene polyoxypropylene block polyether and castor oil polyoxyethylene ether.
7. The high-lubricity, high-cleaning-rate, environmentally-friendly aqueous gear broaching fluid of claim 1, which is characterized in that: the defoaming agent is one or more of emulsified silicone oil and methyl silicone oil.
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| CN116751623A (en) * | 2023-06-30 | 2023-09-15 | 合肥工业大学智能制造技术研究院 | High-performance environment-friendly microemulsion cutting fluid |
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Application publication date: 20210817 |