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CN108384668A - High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers - Google Patents

High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers Download PDF

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Publication number
CN108384668A
CN108384668A CN201810379707.6A CN201810379707A CN108384668A CN 108384668 A CN108384668 A CN 108384668A CN 201810379707 A CN201810379707 A CN 201810379707A CN 108384668 A CN108384668 A CN 108384668A
Authority
CN
China
Prior art keywords
50mpa
ultra
special
numerical control
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810379707.6A
Other languages
Chinese (zh)
Inventor
俞威
阿部聪
林丽静
李士红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
Original Assignee
QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Shanghai Yushiro Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd, Shanghai Yushiro Chemical Industry Co Ltd filed Critical QIDONG YOUXILU CHEMICAL INDUSTRY Co Ltd
Priority to CN201810379707.6A priority Critical patent/CN108384668A/en
Publication of CN108384668A publication Critical patent/CN108384668A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3209Amines or imines with one to four nitrogen atoms; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3218Alkanolamines or alkanolimines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3281Heterocyclic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of dilution of high magnification, the special-purpose aqueous cleaning agents of 50MPa ultra-high pressure numerical control cleaning centers, are made of dodecanedicarboxylic acid, isononanoic acid, triisopropanolamine, 2 amino, 2 methyl, 1 propyl alcohol, benzotriazole, D2000 polyetheramines, polyethers, N aminoethyl r aminopropyl trimethoxysilanes, polyethyleneimine, silicon emulsion, water.Easily manufactured, favorable working performance of the invention.

Description

High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers
Technical field
The present invention relates to a kind of ultra-high pressure numerical control cleaning center waterborne cleaning agents.
Background technology
With the development of metal-processing industry, the operating mode and metal material of intermetallic composite coating become increasingly complex, to cleaning equipment Comprehensive performance require it is higher and higher, while to the comprehensive performance of matching used waterborne cleaning agent require it is also higher and higher.
It is traditional by formula cleaning showers mode, due to bad to complicated workpiece cleaning performance, be unable to reach thoroughly clear The purpose of wash clean, market of just gradually fading out.As cleaning equipment is gradually functionalized, articulated robot leading portion fills the clear of nozzle The mode of washing initially enters market, to solve can turnover cleaning, it is cleaner than being cleaned by formula cleaning way.But it is more The cleaning equipment of articulated robot leading portion dress nozzle mode, which exists, is bad at linearly operating, if inserted the nozzle into clear in pore hole If washing, its speed can only be reduced to original 1/10 or so degree, and efficiency reduces;Nozzle precision is relatively low, since nozzle is pacified Mounted in long-armed front end, cause positional precision bad.It is accordingly used in the various structures of aerospace, automobile, construction implement etc. Complicated precise part generally has residual burr, the chips such as blind hole, inclined hole, accurate face etc., mode is sprayed using above two It is all unable to reach disposable cleaning performance, but the straight friendship compound cleaning center of multi-joint can meet various complicated precisions The cleaning requirement of component.It is straight to hand over the compound cleaning center of multi-joint that switch different cleaning sprays according to the structure of cleaned workpiece Mouth, and 5 dimension operations, the cleaning of six faces can be carried out;When cleaning center configuration high-pressure pump can provide the super-pressure of 30MPa--50MPa Clean power, so that it may achieve the effect that except chip, go flash removed, desanding are three-in-one integrally to complete, artificial desanding or people can be saved The process of work deburring to substantially reduce production cost, and because of the super-pressure cleaning ability that the equipment has, makes to mating The cleaning ability of waterborne cleaning agent requires to substantially reduce, so the cleaning agent of highly diluted multiplying power can be used.But the equipment because Configured with high-precision filtration system(Filtering accuracy is between 10 microns -5 microns), so to matching used waterborne cleaning agent Antifoam performance and defoaming enduring quality require it is very high;In order to save production cost, the advanced cleaning equipment is made full use of, visitor Family would generally clean different structure, unlike material in cleaning center on the same stage(Ferrous metal, non-ferrous metal)Workpiece, so wanting Matching used waterborne cleaning agent versatility is asked to be eager to excel(There should be good rust-preventing characteristic to ferrous metal while also to prevent coloured Metal changes colour).
Presently commercially available waterborne cleaning agent cannot meet the compound cleaning center visitor of straight friendship multi-joint there is also many drawbacks The synthesis requirement at family.First, resistance to metal erosion supression property is poor(Clean ferrous metal when easily get rusty, clean it is easy when non-ferrous metal Discoloration), and cleaning ferrous metal and non-ferrous metal, poor universality cannot be taken into account;Second is that antifoam performance and defoaming maintenance are poor(Disappear Steep time > 60s;Antifoam performance maintenance is poor, after filtering foam time > 300s), it is difficult to meet super-pressure defoaming demand; It is used third, 20--30 times can only be diluted, it is high to produce and use cost.
Invention content
The purpose of the present invention is to provide a kind of easily manufactured, favorable working performance high magnification dilution, 50MPa super-pressure numbers Control the special-purpose aqueous cleaning agent of cleaning center.
Technical solution of the invention is:
A kind of dilution of high magnification, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers, it is characterized in that:By following weight Percentage at being grouped as:
Dodecanedicarboxylic acid 7.0%
Isononanoic acid 5%
Triisopropanolamine 3.0%
2-amino-2-methyl-1-propanol 6.0%
Benzotriazole 0.8%
D2000 polyetheramines 0.5%
Polyethers 3%
N- aminoethyl-r- aminopropyl trimethoxysilanes 2%
Polyethyleneimine 0.8%
Silicon emulsion 0.5%
Remaining ingredient is water.
The D2000 polyetheramines can use T3000 polyethers to replace.
Present invention has the advantages that:
1. the corrosion resistance of product can be greatly improved(Non-ferrous metal corrosion test:55 DEG C of constant temperature for 24 hours under the conditions of red copper testing piece It is non-discolouring with ADC12 aluminum test pieces, it is bright as new;Ferrous metal corrosion test:35 DEG C of constant temperature for 24 hours under the conditions of case-iron shavings without Rust spot).And ferrous metal, non-ferrous metal are capable of washing, and it is versatile;100 times of uses can be diluted, life is greatly reduced for user Produce cost.
2. product defoaming is strong(1% dilution of concentration of the 600ml products, speed of agitator are prepared in the high foot beaker of 1L 8000rpm stirs 5min, and the time < 10s defoamed completely is recorded after stopping stirring).Antifoam performance maintenance is good(In the height of 1L 1% dilution of concentration of the 600ml products is prepared in foot beaker, speed of agitator 8000rpm stirs 5min, is recorded after stopping stirring Then 1% graphite powder is added in the time defoamed completely, after stirring evenly, mixed liquor is passed through 0.45 μ mixed cellulose ester membranes It is filtered, filtrate is carried out to high-speed stirred evaluation antifoam performance again, then refilter and revalue after adding graphite powder mixing, by three It is secondary to repeat after filtering, foam time≤15s.), demand is defoamed to meet super-pressure, and this product is spent by high-precision Still there is uniformly excellent antifoam performance after filter system).
3. Biostatic type ingredients isopropanol amine is added in this product, which does not kill microorganism, by micro- life The attack of object will not rapidly be decomposed, and maintain the pH stable of working fluid, to avoid microorganism excessive multiplication from causing to process The problem of degradation of liquid active ingredient causes decline and the lost of life of working fluid performance.(Resistance to corruption performance test:Resistance to corruption is surveyed Examination starts aerobic plate count 10 in 30 days3, test to aerobic plate count at 60 days is still 103).
4. formula, without using poisonous and harmful substances such as heavy metal, aromatic hydrocarbon, product safety hygienic quality is high(Acute oral Toxicity LD50 >=5000mg/kg, acute inhalation toxicity LC50 >=5000mg/m3, respiratory mucosa stimulate≤1 grade), to people and ring Border is friendly.
With reference to embodiment, the invention will be further described.
Specific implementation mode
A kind of dilution of high magnification, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers, by following weight percents Ingredient through be mixed be made:
Dodecanedicarboxylic acid 7.0%
Isononanoic acid 5%
Triisopropanolamine 3.0%
2-amino-2-methyl-1-propanol 6.0%
Benzotriazole 0.8%
D2000 polyetheramines 0.5%
Polyethers 3%
N- aminoethyl-r- aminopropyl trimethoxysilanes 2%
Polyethyleneimine 0.8%
Silicon emulsion 0.5%
Remaining ingredient is water.
The D2000 polyetheramines can use T3000 polyethers to replace.

Claims (2)

1. a kind of high magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers, it is characterized in that:By following heavy Amount percentage at being grouped as:
Dodecanedicarboxylic acid 7.0%
Isononanoic acid 5%
Triisopropanolamine 3.0%
2-amino-2-methyl-1-propanol 6.0%
Benzotriazole 0.8%
D2000 polyetheramines 0.5%
Polyethers 3%
N- aminoethyl-r- aminopropyl trimethoxysilanes 2%
Polyethyleneimine 0.8%
Silicon emulsion 0.5%
Remaining ingredient is water.
2. high magnification dilution according to claim 1, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers, It is characterized in:The D2000 polyetheramines can use T3000 polyethers to replace.
CN201810379707.6A 2018-04-25 2018-04-25 High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers Pending CN108384668A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810379707.6A CN108384668A (en) 2018-04-25 2018-04-25 High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810379707.6A CN108384668A (en) 2018-04-25 2018-04-25 High magnification dilution, the special-purpose aqueous cleaning agent of 50MPa ultra-high pressure numerical control cleaning centers

Publications (1)

Publication Number Publication Date
CN108384668A true CN108384668A (en) 2018-08-10

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Country Status (1)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN102250676A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 High-performance environmentally-friendly semisynthetic water-soluble metal working fluid
CN103046066A (en) * 2013-01-08 2013-04-17 上海尤希路化学工业有限公司 High-performance and environment-friendly water-based cleaning agent
CN104674246A (en) * 2015-03-18 2015-06-03 启东尤希路化学工业有限公司 Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron
CN105861185A (en) * 2016-05-21 2016-08-17 俞凤鸣 Water-based cleaning agent
CN106479761A (en) * 2015-08-28 2017-03-08 比亚迪股份有限公司 Use in printed circuit board waterborne cleaning agent composition and cleaning agent and its preparation method and application

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560433A (en) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 Anti-magnesium hard water anti-magnesium corrosion environmentally-friendly water soluble cutting solution
CN102250676A (en) * 2011-06-15 2011-11-23 启东尤希路化学工业有限公司 High-performance environmentally-friendly semisynthetic water-soluble metal working fluid
CN103046066A (en) * 2013-01-08 2013-04-17 上海尤希路化学工业有限公司 High-performance and environment-friendly water-based cleaning agent
CN104674246A (en) * 2015-03-18 2015-06-03 启东尤希路化学工业有限公司 Universal ultrahigh-pressure spraying and environmental-protection semi-aqueous cleaning agent for aluminum and iron
CN106479761A (en) * 2015-08-28 2017-03-08 比亚迪股份有限公司 Use in printed circuit board waterborne cleaning agent composition and cleaning agent and its preparation method and application
CN105861185A (en) * 2016-05-21 2016-08-17 俞凤鸣 Water-based cleaning agent

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Application publication date: 20180810

RJ01 Rejection of invention patent application after publication