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WO2002011213A1 - Transducteur photoélectrique sensibilisé par un colorant - Google Patents

Transducteur photoélectrique sensibilisé par un colorant Download PDF

Info

Publication number
WO2002011213A1
WO2002011213A1 PCT/JP2001/006404 JP0106404W WO0211213A1 WO 2002011213 A1 WO2002011213 A1 WO 2002011213A1 JP 0106404 W JP0106404 W JP 0106404W WO 0211213 A1 WO0211213 A1 WO 0211213A1
Authority
WO
WIPO (PCT)
Prior art keywords
dye
photoelectric transducer
solar cell
sensitized photoelectric
sensitized
Prior art date
Application number
PCT/JP2001/006404
Other languages
English (en)
French (fr)
Inventor
Masaaki Ikeda
Koichiro Shigaki
Teruhisa Inoue
Original Assignee
Nippon Kayaku Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kabushiki Kaisha filed Critical Nippon Kayaku Kabushiki Kaisha
Priority to CA2417502A priority Critical patent/CA2417502C/en
Priority to JP2002516837A priority patent/JP5054269B2/ja
Priority to DE60140752T priority patent/DE60140752D1/de
Priority to EP01984384A priority patent/EP1311001B1/en
Priority to US10/333,305 priority patent/US7141735B2/en
Priority to KR1020037000983A priority patent/KR100792381B1/ko
Publication of WO2002011213A1 publication Critical patent/WO2002011213A1/ja

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M14/00—Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/311—Phthalocyanine
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
    • H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/652—Cyanine dyes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/653—Aromatic compounds comprising a hetero atom comprising only oxygen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/654—Aromatic compounds comprising a hetero atom comprising only nitrogen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6574—Polycyclic condensed heteroaromatic hydrocarbons comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)
PCT/JP2001/006404 2000-07-27 2001-07-25 Transducteur photoélectrique sensibilisé par un colorant WO2002011213A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2417502A CA2417502C (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion device
JP2002516837A JP5054269B2 (ja) 2000-07-27 2001-07-25 色素増感光電変換素子
DE60140752T DE60140752D1 (de) 2000-07-27 2001-07-25 Farbstoffsensibilisierter photoelektrischer wandler
EP01984384A EP1311001B1 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric transducer
US10/333,305 US7141735B2 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion device
KR1020037000983A KR100792381B1 (ko) 2000-07-27 2001-07-25 색소 증감 광전 변환소자

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000-226864 2000-07-27
JP2000226864 2000-07-27

Publications (1)

Publication Number Publication Date
WO2002011213A1 true WO2002011213A1 (fr) 2002-02-07

Family

ID=18720405

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2001/006404 WO2002011213A1 (fr) 2000-07-27 2001-07-25 Transducteur photoélectrique sensibilisé par un colorant

Country Status (9)

Country Link
US (1) US7141735B2 (ja)
EP (1) EP1311001B1 (ja)
JP (1) JP5054269B2 (ja)
KR (1) KR100792381B1 (ja)
CN (1) CN100492671C (ja)
CA (1) CA2417502C (ja)
DE (1) DE60140752D1 (ja)
TW (1) TW595034B (ja)
WO (1) WO2002011213A1 (ja)

Cited By (37)

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EP1367667A1 (en) * 2001-03-07 2003-12-03 Nippon Kayaku Kabushiki Kaisha Pigment sensitizing photoelectric conversion element
WO2004011555A1 (ja) 2002-07-29 2004-02-05 Mitsubishi Paper Mills Limited 有機系色素、光電変換材料、半導体電極および光電変換素子
JP2004095450A (ja) * 2002-09-02 2004-03-25 National Institute Of Advanced Industrial & Technology 有機色素を光増感剤とする半導体薄膜電極、光電変換素子及び光電気化学太陽電池
WO2004082061A1 (ja) * 2003-03-14 2004-09-23 Nippon Kayaku Kabushiki Kaisha 色素増感光電変換素子
JP2005011800A (ja) * 2003-05-26 2005-01-13 Konica Minolta Holdings Inc 光電変換材料用半導体、光電変換素子及び太陽電池
JP2005097561A (ja) * 2003-08-27 2005-04-14 Toyo Ink Mfg Co Ltd 光機能材料
JP2006079898A (ja) * 2004-09-08 2006-03-23 Nippon Kayaku Co Ltd 色素増感光電変換素子
JP2006185911A (ja) * 2004-11-30 2006-07-13 Mitsubishi Paper Mills Ltd 半導体電極および光電変換素子
JP2006286609A (ja) * 2005-03-07 2006-10-19 Mitsubishi Paper Mills Ltd 光電変換材料、半導体電極並びにそれを用いた光電変換素子
WO2006134939A1 (ja) 2005-06-14 2006-12-21 Nippon Kayaku Kabushiki Kaisha 色素増感光電変換素子
WO2007007671A1 (ja) 2005-07-07 2007-01-18 Nippon Kayaku Kabushiki Kaisha 光電変換素子用シール剤及びそれを用いた光電変換素子
JP2007115673A (ja) * 2005-09-22 2007-05-10 Mitsubishi Paper Mills Ltd 光電変換材料、半導体電極並びにそれを用いた光電変換素子
WO2007100033A1 (ja) 2006-03-02 2007-09-07 Nippon Kayaku Kabushiki Kaisha 色素増感光電変換素子
JP2007234580A (ja) * 2006-02-02 2007-09-13 Sony Corp 色素増感型光電変換装置
WO2008004580A1 (fr) 2006-07-05 2008-01-10 Nippon Kayaku Kabushiki Kaisha Cellule solaire sensible à la coloration
CN100377421C (zh) * 2003-03-14 2008-03-26 日本化药株式会社 色素增感的光电转换器件
JP2008071648A (ja) * 2006-09-14 2008-03-27 Mitsubishi Paper Mills Ltd 光電変換材料、半導体電極並びにそれを用いた光電変換素子
JP2008179641A (ja) * 2001-06-19 2008-08-07 Hayashibara Biochem Lab Inc エチレン化合物
US7615640B2 (en) 2002-07-29 2009-11-10 Mitsubishi PaperMillsLtd. Organic dye, photoelectric conversion material, semiconductor electrode and photoelectric conversion device
WO2010002154A2 (ko) 2008-06-30 2010-01-07 주식회사 동진쎄미켐 신규한 유기염료 및 이의 제조방법
WO2010021378A1 (ja) 2008-08-22 2010-02-25 日本化薬株式会社 色素増感型光電変換素子
JP2010103115A (ja) * 2008-10-23 2010-05-06 Tripod Technology Corp 色素増感型太陽電池
EP2192159A2 (en) 2008-11-28 2010-06-02 Samsung Electro-Mechanics Co., Ltd Dye compound for dye-sensitized solar cells, dye-sensitized photoelectric converter and dye-sensitized solar cells
WO2010067996A2 (ko) 2008-12-09 2010-06-17 주식회사 동진쎄미켐 트리알콕시실릴기 함유 신규 유기염료 및 이의 제조방법
US7851701B2 (en) 2001-07-06 2010-12-14 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
JP2011502187A (ja) * 2007-10-25 2011-01-20 ソニー株式会社 分子構造内にアンカー基を含む色素
US7915524B2 (en) 2003-02-20 2011-03-29 Nippon Kayaku Kabushiki Kaisha Sealing agent for photoelectric conversion device and photoelectric conversion device using the same
US7977570B2 (en) 2005-05-24 2011-07-12 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
US8044219B2 (en) 2005-05-13 2011-10-25 Agc Seimi Chemical., Ltd. Amino group-containing heterocyclic derivatives and sensitizing dyes for photoelectric conversion containing the heterocyclic derivatives
WO2011145551A1 (ja) 2010-05-17 2011-11-24 日本化薬株式会社 熱硬化型光電変換素子用シール剤を用いた光電変換素子
EP2418257A2 (en) 2007-05-28 2012-02-15 Dongjin Semichem Co., Ltd. Novel organic dye and method of preparing the same
EP2471785A1 (en) 2007-10-15 2012-07-04 Dongjin Semichem Co., Ltd. Novel thiophene-based dye and preparation thereof
WO2013147145A1 (ja) 2012-03-30 2013-10-03 日本化薬株式会社 色素増感光電変換素子
WO2014084296A1 (ja) 2012-11-30 2014-06-05 日本化薬株式会社 色素増感太陽電池
WO2014136710A1 (ja) 2013-03-05 2014-09-12 公立大学法人首都大学東京 新規化合物及びそれを用いた光電変換素子
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JP5142307B2 (ja) * 2000-11-28 2013-02-13 独立行政法人産業技術総合研究所 有機色素を光増感剤とする半導体薄膜電極、光電変換素子
KR20030065957A (ko) * 2002-02-02 2003-08-09 한국전자통신연구원 폴리비닐리덴 플로라이드 함유 겔형 고분자 전해질을포함하는 염료감응 태양전지
US20040256002A1 (en) * 2002-07-29 2004-12-23 Tamotsu Horiuchi Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device
KR101056440B1 (ko) * 2003-09-26 2011-08-11 삼성에스디아이 주식회사 염료감응 태양전지
KR100578798B1 (ko) * 2003-12-12 2006-05-11 삼성에스디아이 주식회사 염료감응 태양전지 및 그 제조 방법
KR100589322B1 (ko) * 2004-02-03 2006-06-14 삼성에스디아이 주식회사 고효율 염료감응 태양전지 및 그 제조 방법
KR100589323B1 (ko) * 2004-02-03 2006-06-14 삼성에스디아이 주식회사 광 흡수파장대가 확장된 염료감응 태양전지 및 그 제조방법
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TWI449187B (zh) * 2007-12-26 2014-08-11 Ind Tech Res Inst 太陽能電池的電解液與染料敏化太陽能電池
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JP2012516062A (ja) * 2009-01-22 2012-07-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 不飽和複素環式化合物を含むポリ（ビニルブチラール）封止材を有する太陽電池モジュール
US9368729B2 (en) 2009-10-13 2016-06-14 Basf Se Mixtures for producing photoactive layers for organic solar cells and organic photodetectors
US20130118570A1 (en) * 2010-01-07 2013-05-16 Nec Corporation Dye for photoelectric conversion, semiconductor electrode, photoelectric conversion element, solar cell, and novel pyrroline-based compound
JP2011204662A (ja) * 2010-03-05 2011-10-13 Sony Corp 光電変換素子およびその製造方法ならびに電子機器
KR20130028912A (ko) * 2010-03-16 2013-03-20 우베 고산 가부시키가이샤 치환 바이피리딜기를 갖는 이핵 루테늄 착물 색소를 포함하는 광전 변환 소자, 및 광화학 전지
JP2012019131A (ja) * 2010-07-09 2012-01-26 Sony Corp 光電変換素子及び固体撮像装置
US10196526B2 (en) 2011-02-23 2019-02-05 Dexerials Corporation Transparent conductive film, information input device, and electronic device
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ITMI20120674A1 (it) 2012-04-23 2013-10-24 Cnrs Ct Nat De La Rech He Scient Colorante organico per cella solare sensibile ai coloranti
ITMI20121672A1 (it) 2012-10-05 2014-04-06 Eni Spa Colorante organico per una cella solare sensibilizzata da colorante
ITMI20130208A1 (it) 2013-02-14 2014-08-15 Eni Spa Colorante organico per una cella solare sensibilizzata da colorante
ITMI20131621A1 (it) 2013-10-01 2015-04-02 Cnrs Ct Nat De La Rech He Scient Colorante organico per una cella solare sensibilizzata con colorante
ITMI20131899A1 (it) 2013-11-15 2015-05-16 C N R S Ct Nat De La Rec Herche Scienti Colorante organico per una cella solare sensibilizzata da colorante
CN104292216B (zh) * 2014-09-05 2016-08-24 昆明理工大学 一种含芘基的对称性苯并咪唑类钌配合物及其制备方法
EP3124552B1 (en) 2015-07-28 2018-04-11 Université de Nantes Trans-disubstituted benzodiazaporphyrins as sensitizers for solar cells
KR101964093B1 (ko) 2017-08-28 2019-04-01 한국화학연구원 신규 캐소드 버퍼층 소재 및 이를 포함하는 유기광전소자
CN110317291B (zh) * 2018-03-30 2021-06-08 长春理工大学 含有萘并吡喃的酞菁高分子聚合物及其合成方法

Citations (5)

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CA2417502A1 (en) 2003-01-27
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EP1311001A4 (en) 2007-02-21
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TW595034B (en) 2004-06-21
EP1311001A1 (en) 2003-05-14
JP5054269B2 (ja) 2012-10-24
CN100492671C (zh) 2009-05-27
US20030152827A1 (en) 2003-08-14
KR20030026984A (ko) 2003-04-03
KR100792381B1 (ko) 2008-01-08
CN1441969A (zh) 2003-09-10
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