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WO2002011213A1 - Dye-sensitized photoelectric transducer - Google Patents

Dye-sensitized photoelectric transducer Download PDF

Info

Publication number
WO2002011213A1
WO2002011213A1 PCT/JP2001/006404 JP0106404W WO0211213A1 WO 2002011213 A1 WO2002011213 A1 WO 2002011213A1 JP 0106404 W JP0106404 W JP 0106404W WO 0211213 A1 WO0211213 A1 WO 0211213A1
Authority
WO
WIPO (PCT)
Prior art keywords
dye
photoelectric transducer
solar cell
sensitized photoelectric
sensitized
Prior art date
Application number
PCT/JP2001/006404
Other languages
French (fr)
Japanese (ja)
Inventor
Masaaki Ikeda
Koichiro Shigaki
Teruhisa Inoue
Original Assignee
Nippon Kayaku Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kabushiki Kaisha filed Critical Nippon Kayaku Kabushiki Kaisha
Priority to CA2417502A priority Critical patent/CA2417502C/en
Priority to JP2002516837A priority patent/JP5054269B2/en
Priority to DE60140752T priority patent/DE60140752D1/en
Priority to EP01984384A priority patent/EP1311001B1/en
Priority to US10/333,305 priority patent/US7141735B2/en
Priority to KR1020037000983A priority patent/KR100792381B1/en
Publication of WO2002011213A1 publication Critical patent/WO2002011213A1/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M14/00—Electrochemical current or voltage generators not provided for in groups H01M6/00 - H01M12/00; Manufacture thereof
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/311—Phthalocyanine
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/341—Transition metal complexes, e.g. Ru(II)polypyridine complexes
    • H10K85/344—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising ruthenium
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/652—Cyanine dyes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/653—Aromatic compounds comprising a hetero atom comprising only oxygen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/654—Aromatic compounds comprising a hetero atom comprising only nitrogen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6574—Polycyclic condensed heteroaromatic hydrocarbons comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
    • H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)

Abstract

A semiconductor device sensitized with an organic dye and a solar cell comprising it, more specifically, a photoelectric transducer composed of fine semiconductor particles sensitized with a dye having an acrylic acid site and a solar cell comprising it. Inexpensive photoelectric transducer and solar cell having high conversion efficiency can be produced.
PCT/JP2001/006404 2000-07-27 2001-07-25 Dye-sensitized photoelectric transducer WO2002011213A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2417502A CA2417502C (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion device
JP2002516837A JP5054269B2 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion element
DE60140752T DE60140752D1 (en) 2000-07-27 2001-07-25 COLOR-SENSITIVATED PHOTOELECTRIC TRANSFORMER
EP01984384A EP1311001B1 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric transducer
US10/333,305 US7141735B2 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion device
KR1020037000983A KR100792381B1 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric conversion device

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000-226864 2000-07-27
JP2000226864 2000-07-27

Publications (1)

Publication Number Publication Date
WO2002011213A1 true WO2002011213A1 (en) 2002-02-07

Family

ID=18720405

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2001/006404 WO2002011213A1 (en) 2000-07-27 2001-07-25 Dye-sensitized photoelectric transducer

Country Status (9)

Country Link
US (1) US7141735B2 (en)
EP (1) EP1311001B1 (en)
JP (1) JP5054269B2 (en)
KR (1) KR100792381B1 (en)
CN (1) CN100492671C (en)
CA (1) CA2417502C (en)
DE (1) DE60140752D1 (en)
TW (1) TW595034B (en)
WO (1) WO2002011213A1 (en)

Cited By (37)

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EP1367667A1 (en) * 2001-03-07 2003-12-03 Nippon Kayaku Kabushiki Kaisha Pigment sensitizing photoelectric conversion element
WO2004011555A1 (en) 2002-07-29 2004-02-05 Mitsubishi Paper Mills Limited Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device
JP2004095450A (en) * 2002-09-02 2004-03-25 National Institute Of Advanced Industrial & Technology Semiconductor thin film electrode using organic dye as photosensitizer, photoelectric conversion element, and optical electrochemical solar battery
WO2004082061A1 (en) * 2003-03-14 2004-09-23 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
JP2005011800A (en) * 2003-05-26 2005-01-13 Konica Minolta Holdings Inc Semiconductor for photoelectric conversion material, photoelectric conversion device and solar cell
JP2005097561A (en) * 2003-08-27 2005-04-14 Toyo Ink Mfg Co Ltd Optical functional material
JP2006079898A (en) * 2004-09-08 2006-03-23 Nippon Kayaku Co Ltd Dye-sensitized photoelectric conversion element
JP2006185911A (en) * 2004-11-30 2006-07-13 Mitsubishi Paper Mills Ltd Semiconductor electrode and photoelectric converting element
JP2006286609A (en) * 2005-03-07 2006-10-19 Mitsubishi Paper Mills Ltd Photoelectric conversion material, semiconductor electrode, and photoelectric conversion element using it
WO2006134939A1 (en) 2005-06-14 2006-12-21 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
WO2007007671A1 (en) 2005-07-07 2007-01-18 Nippon Kayaku Kabushiki Kaisha Sealing agent for photoelectric converter and photoelectric converter using same
JP2007115673A (en) * 2005-09-22 2007-05-10 Mitsubishi Paper Mills Ltd Photoelectric conversion material, semiconductor electrode, and photoelectric conversion element using it
WO2007100033A1 (en) 2006-03-02 2007-09-07 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
JP2007234580A (en) * 2006-02-02 2007-09-13 Sony Corp Dye sensitized photoelectric conversion device
WO2008004580A1 (en) 2006-07-05 2008-01-10 Nippon Kayaku Kabushiki Kaisha Dye-sensitized solar cell
CN100377421C (en) * 2003-03-14 2008-03-26 日本化药株式会社 Dye-sensitized photoelectric conversion device
JP2008071648A (en) * 2006-09-14 2008-03-27 Mitsubishi Paper Mills Ltd Photoelectric conversion material, semiconductor electrode, and photoelectric conversion element using it
JP2008179641A (en) * 2001-06-19 2008-08-07 Hayashibara Biochem Lab Inc Ethylenic compound
US7615640B2 (en) 2002-07-29 2009-11-10 Mitsubishi PaperMillsLtd. Organic dye, photoelectric conversion material, semiconductor electrode and photoelectric conversion device
WO2010002154A2 (en) 2008-06-30 2010-01-07 주식회사 동진쎄미켐 Novel organic dye and method for preparing same
WO2010021378A1 (en) 2008-08-22 2010-02-25 日本化薬株式会社 Dye-sensitized photovoltaic device
JP2010103115A (en) * 2008-10-23 2010-05-06 Tripod Technology Corp Dye-sensitized solar cell
EP2192159A2 (en) 2008-11-28 2010-06-02 Samsung Electro-Mechanics Co., Ltd Dye compound for dye-sensitized solar cells, dye-sensitized photoelectric converter and dye-sensitized solar cells
WO2010067996A2 (en) 2008-12-09 2010-06-17 주식회사 동진쎄미켐 Novel organic dye containing trialkoxysilyl group and method for preparing same
US7851701B2 (en) 2001-07-06 2010-12-14 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
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US7915524B2 (en) 2003-02-20 2011-03-29 Nippon Kayaku Kabushiki Kaisha Sealing agent for photoelectric conversion device and photoelectric conversion device using the same
US7977570B2 (en) 2005-05-24 2011-07-12 Nippon Kayaku Kabushiki Kaisha Dye-sensitized photoelectric conversion device
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WO2013147145A1 (en) 2012-03-30 2013-10-03 日本化薬株式会社 Dye-sensitized photoelectric conversion element
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WO2014136710A1 (en) 2013-03-05 2014-09-12 公立大学法人首都大学東京 Novel compound and photoelectric conversion element using same
US9296728B2 (en) 2012-01-20 2016-03-29 Regents Of The University Of Minnesota Therapeutic compounds
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JP5142307B2 (en) * 2000-11-28 2013-02-13 独立行政法人産業技術総合研究所 Semiconductor thin film electrode and photoelectric conversion element using organic dye as photosensitizer
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EP1311001A4 (en) 2007-02-21
EP1311001B1 (en) 2009-12-09
TW595034B (en) 2004-06-21
EP1311001A1 (en) 2003-05-14
JP5054269B2 (en) 2012-10-24
CN100492671C (en) 2009-05-27
US20030152827A1 (en) 2003-08-14
KR20030026984A (en) 2003-04-03
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CN1441969A (en) 2003-09-10
CA2417502C (en) 2012-01-10

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