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KR960029361A - 에폭시수지용 경화제 - Google Patents

에폭시수지용 경화제 Download PDF

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Publication number
KR960029361A
KR960029361A KR1019960000478A KR19960000478A KR960029361A KR 960029361 A KR960029361 A KR 960029361A KR 1019960000478 A KR1019960000478 A KR 1019960000478A KR 19960000478 A KR19960000478 A KR 19960000478A KR 960029361 A KR960029361 A KR 960029361A
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KR
South Korea
Prior art keywords
epoxy resin
epoxy
curing agent
resin
bicyclo
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Application number
KR1019960000478A
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English (en)
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KR100247299B1 (ko
Inventor
미나토 카라사와
라쿠지 시미즈
Original Assignee
사토 아키오
미쯔이도오아쯔가가꾸 가부시기가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 사토 아키오, 미쯔이도오아쯔가가꾸 가부시기가이샤 filed Critical 사토 아키오
Publication of KR960029361A publication Critical patent/KR960029361A/ko
Application granted granted Critical
Publication of KR100247299B1 publication Critical patent/KR100247299B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)

Abstract

본 발명은, 2,5-및 2,6-비스(아미노 메텔)-비시클로[2,2,1]헵탄; 아미노기의 활성수소 1당량, 및 에폭시수지; 비스페놀류 또는 노보락수지와 에피클로로히드린과의 반응생성물, 에폭시당량 150~300g/eq 또한 1분자속에 에폭시기를 2개 이상 함유한 것, 특히 비스페놀 A디글리시딜에테르 또는 비스테놀 F디글리시딜에테르, 에폭시기 0.025~0.50당량의 반응에 의해 얻게되는 에폭시수지경화제로, 반응온도는 40~120℃이며, 대상의 에폭시수지 100중량부에 대해서, 이 경화제의 배합량은 20~75중량부이다. 또한, 이 경화제는, 상온에서의 경화속도가 빠르고, 그것을 사용해서 경화한 에폭시수지는, 외관이 좋고, 접착성, 내수성, 내약품성에 매우 뛰어난 것으로, 이것은, 도료, 토목건축재로, 접착제, 주형용수지, 적층물 등의 용도에 호적한 효과가 있는 것을 특징으로 한다.

Description

에폭시수지용 경화제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 2,5- 및 2,6-비스(아미노 메틸)-비시클로 [2,2,1] 헵탄과 에폭시수지를 반응시켜서 얻게되는 것을 특징으로 하는 에폭시수지용경화제.
  2. 제1항에 있어서, 이 에폭시수지가 비스페놀류와 에피클로로히드린, 또는 노보락수지와 에피클로로히드린을 반응시켜서 얻게되는 것을 특징으로 하는 에폭시주지용경화제.
  3. 제1항에 있어서, 이 에폭시수지가 에폭시당량 150~300g/eq, 또한 1분자속에 에폭시기를 2개 이상 함유하는 것을 특징으로 하는 에폭시수지용경화제.
  4. 제1항에 있어서, 이 에폭시수지가 비스페놀 A디글리시딜에테르 및 또는 비스페놀 F디글리시딜에테르인 것을 특징으로 하는 에폭시수지용경화제.
  5. 제1항에 있어서, 2,5- 및 2,6-비스(아미노 메틸)-비시클로 [2,2,1] 헵탄속의 아미노기의 활성 수소1당량에 대해, 이 에폭시수지속의 에폭시기가 0.025~0.50당량의 범위인 것을 특징으로 하는 에폭시수지용경화제.
  6. 제1항에 있어서, 2,5- 및 2,6-비스(아미노 메틸)-비시클로 [2,2,1] 헵탄속의 아미노기의 활성 수소1당량에 대해, 이 에폭시수지속의 에폭시기가 0.05~0.25당량의 범위인 것을 특징으로 하는 에폭시수지용경화제.
  7. 제5항에 있어서, 2,5- 및 2,6-비스(아미노 메틸)-비시클로 [2,2,1] 헵탄과 이 에폭시수지와의 반응온도가 40~120℃인 것을 특징으로 하는 에폭시수지용경화제.
  8. 제6항에 있어서, 2,5- 및 2,6-비스(아미노 메틸)-비시클로 [2,2,1] 헵탄과 이 에폭시수지와의 반응온도가 40~120℃인 것을 특징으로 하는 에폭시수지용경화제.
  9. 제1항에 있어서, 대상의 에폭시수지 100중량부에 대한 배합량이 20~75중량부의 범위인 것을 특징으로 하는 에폭시수지용경화제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960000478A 1995-01-17 1996-01-12 에폭시수지용 경화제 KR100247299B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP494095 1995-01-17
JP95-4940 1995-01-17

Publications (2)

Publication Number Publication Date
KR960029361A true KR960029361A (ko) 1996-08-17
KR100247299B1 KR100247299B1 (ko) 2000-04-01

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KR1019960000478A KR100247299B1 (ko) 1995-01-17 1996-01-12 에폭시수지용 경화제

Country Status (3)

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US (1) US5631332A (ko)
EP (1) EP0722965A3 (ko)
KR (1) KR100247299B1 (ko)

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JP2917884B2 (ja) * 1995-12-19 1999-07-12 東洋製罐株式会社 水性塗料
US6362254B2 (en) * 1998-03-12 2002-03-26 Shearwater Corporation Poly(ethylene glycol) derivatives with proximal reactive groups
TW200303439A (en) * 2002-02-04 2003-09-01 Mitsui Chemicals Inc Method for producing liquid crystal display cell and sealing agent for liquid crystal display cell
RU2357992C2 (ru) * 2004-08-10 2009-06-10 Чугоку Марин Пейнтс, Лтд. Антикоррозийный покрывающий состав с высоким содержанием нелетучих компонентов, быстро отверждающийся антикоррозийный покрывающий состав с высоким содержанием нелетучих компонентов, способ покрытия корабля или подобной конструкции, антикоррозийная пленка с высоким содержанием нелетучих компонентов и быстро отверждающаяся антикоррозийная пленка с высоким содержанием нелетучих компонентов, получаемые при покрытии, и корабль и подводная конструкция, покрытые этими пленками
US8039201B2 (en) * 2007-11-21 2011-10-18 Az Electronic Materials Usa Corp. Antireflective coating composition and process thereof
US20100015550A1 (en) * 2008-07-17 2010-01-21 Weihong Liu Dual damascene via filling composition
JP2016518504A (ja) * 2013-05-16 2016-06-23 ブルー キューブ アイピー エルエルシー 改良された耐薬品性を有するアミン硬化剤
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CA2977647A1 (en) * 2015-02-27 2016-09-01 3M Innovative Properties Company Two-part structural adhesive
GB2578737B (en) 2018-11-05 2022-02-23 Aev Holding Ltd Curable epoxy resin and use thereof
EP3999571B1 (en) * 2019-07-19 2024-07-17 Blue Cube IP LLC Phenolic hardener for epoxy powder coatings
CN110804000B (zh) * 2019-11-11 2020-09-22 山东益丰生化环保股份有限公司 一种二氰基降冰片烷的制备方法
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Also Published As

Publication number Publication date
US5631332A (en) 1997-05-20
EP0722965A3 (en) 1996-09-04
KR100247299B1 (ko) 2000-04-01
EP0722965A2 (en) 1996-07-24

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