JPS6359129B2 - - Google Patents
Info
- Publication number
- JPS6359129B2 JPS6359129B2 JP55089862A JP8986280A JPS6359129B2 JP S6359129 B2 JPS6359129 B2 JP S6359129B2 JP 55089862 A JP55089862 A JP 55089862A JP 8986280 A JP8986280 A JP 8986280A JP S6359129 B2 JPS6359129 B2 JP S6359129B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver
- nucleus
- salt
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052709 silver Inorganic materials 0.000 claims description 36
- 239000004332 silver Substances 0.000 claims description 36
- -1 silver halide Chemical class 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 18
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 13
- 125000000623 heterocyclic group Chemical group 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 229920006255 plastic film Polymers 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229920001600 hydrophobic polymer Polymers 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 26
- 239000000975 dye Substances 0.000 description 20
- 230000006866 deterioration Effects 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 7
- 239000000084 colloidal system Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 5
- 235000010724 Wisteria floribunda Nutrition 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine group Chemical group N1=CCC2=CC=CC=C12 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 125000004964 sulfoalkyl group Chemical group 0.000 description 2
- 150000003536 tetrazoles Chemical group 0.000 description 2
- 150000003557 thiazoles Chemical class 0.000 description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- LBUJPTNKIBCYBY-UHFFFAOYSA-N 1,2,3,4-tetrahydroquinoline Chemical group C1=CC=C2CCCNC2=C1 LBUJPTNKIBCYBY-UHFFFAOYSA-N 0.000 description 1
- XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical class OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 description 1
- AIGNCQCMONAWOL-UHFFFAOYSA-N 1,3-benzoselenazole Chemical class C1=CC=C2[se]C=NC2=C1 AIGNCQCMONAWOL-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical class C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- YLVACWCCJCZITJ-UHFFFAOYSA-N 1,4-dioxane-2,3-diol Chemical compound OC1OCCOC1O YLVACWCCJCZITJ-UHFFFAOYSA-N 0.000 description 1
- SIQZJFKTROUNPI-UHFFFAOYSA-N 1-(hydroxymethyl)-5,5-dimethylhydantoin Chemical compound CC1(C)N(CO)C(=O)NC1=O SIQZJFKTROUNPI-UHFFFAOYSA-N 0.000 description 1
- FYBFGAFWCBMEDG-UHFFFAOYSA-N 1-[3,5-di(prop-2-enoyl)-1,3,5-triazinan-1-yl]prop-2-en-1-one Chemical compound C=CC(=O)N1CN(C(=O)C=C)CN(C(=O)C=C)C1 FYBFGAFWCBMEDG-UHFFFAOYSA-N 0.000 description 1
- SAVMNSHHXUMFRQ-UHFFFAOYSA-N 1-[bis(ethenylsulfonyl)methoxy-ethenylsulfonylmethyl]sulfonylethene Chemical compound C=CS(=O)(=O)C(S(=O)(=O)C=C)OC(S(=O)(=O)C=C)S(=O)(=O)C=C SAVMNSHHXUMFRQ-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 150000001473 2,4-thiazolidinediones Chemical class 0.000 description 1
- YKUDHBLDJYZZQS-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one Chemical compound OC1=NC(Cl)=NC(Cl)=N1 YKUDHBLDJYZZQS-UHFFFAOYSA-N 0.000 description 1
- AXCGIKGRPLMUDF-UHFFFAOYSA-N 2,6-dichloro-1h-1,3,5-triazin-4-one;sodium Chemical compound [Na].OC1=NC(Cl)=NC(Cl)=N1 AXCGIKGRPLMUDF-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- PHPYXVIHDRDPDI-UHFFFAOYSA-N 2-bromo-1h-benzimidazole Chemical class C1=CC=C2NC(Br)=NC2=C1 PHPYXVIHDRDPDI-UHFFFAOYSA-N 0.000 description 1
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical class C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 1
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 1
- JFJWVJAVVIQZRT-UHFFFAOYSA-N 2-phenyl-1,3-dihydropyrazole Chemical compound C1C=CNN1C1=CC=CC=C1 JFJWVJAVVIQZRT-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical class O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- UTMDJGPRCLQPBT-UHFFFAOYSA-N 4-nitro-1h-1,2,3-benzotriazole Chemical class [O-][N+](=O)C1=CC=CC2=NNN=C12 UTMDJGPRCLQPBT-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical class NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229920002085 Dialdehyde starch Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical class O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical class C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000005205 dihydroxybenzenes Chemical class 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- AKCUHGBLDXXTOM-UHFFFAOYSA-N hydroxy-oxo-phenyl-sulfanylidene-$l^{6}-sulfane Chemical class SS(=O)(=O)C1=CC=CC=C1 AKCUHGBLDXXTOM-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002545 isoxazoles Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003236 pyrrolines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- JAQKNUMURQDRKV-UHFFFAOYSA-N sodium;triazine Chemical compound [Na].C1=CN=NN=C1 JAQKNUMURQDRKV-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 150000003852 triazoles Chemical group 0.000 description 1
- 150000008130 triterpenoid saponins Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
- G03C1/346—Organic derivatives of bivalent sulfur, selenium or tellurium
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
æ¬çºæã¯ããã²ã³åéé»çœå°ç»çŽã«é¢ãããã®
ã§ãããç¹ã«æ°Žäžæµžéæ§ã®æ¯æäœäžã«åœ¢æããé
ç»åã®çµæã«äŒŽãå£åãé²æ¢ããé»çœå°ç»çŽã«é¢
ãããã®ã§ãã ããã²ã³åéåçæå ææã®åéã«ãããŠã¯é
ç»åã¯æè¬ã«ã©ãŒç»åïŒè²çŽ ç»åïŒããå ç¢ã§ã
ãããã«é·æéä¿åããå¿ èŠã®ããæ å ±ã®èšé²ã«
é©ããŠãããããããªãããããéç»åãçµæã«
䌎ã€ãŠå£åããåŸåãæã¡ããã®åŸåã¯ç¹ã«ãã©
ã¹ããã¯ãã€ã«ã ãªã©ã®æ°Žäžæµžéæ§ã®æ¯æäœãçš
ããããŠããå Žåã«å€§ããããšãããã€ãããã©
ã¹ããã¯ãã€ã«ã ãªã©ã®æ°Žäžæµžéæ§ã®æ¯æäœã¯ã
äžè¬ã«ãçŽãåžãªã©ã®æ°Žæµžéæ§ã®æ¯æäœããã匷
床ãé«ãã®ã§é·æéã®ä¿åã«ã¯é©ããŠãããšèšã
ããããã®äžæ¹ã§äžè¿°ãããããªé²ç»åã®å£åã®
åŸåã倧ãããããšãããžã¬ã³ããååšããã®ã§
ããïŒãã®ãããªæ°Žäžæµžéæ§æ¯æäœäžã®éç»åã®
å£åã«ã€ããŠã¯Photographic Science and
Engineeringèªç¬¬ïŒå·»253ã261é ïŒ1963幎ïŒãè±
åœç¹èš±ïŒå ¬éïŒç¬¬2019024Aå·ãªã©ã«å ±åãããŠ
ããã æ¬çºæã¯æ°Žäžæµžéæ§ã®æ¯æäœãçšããæã«çã
ãéç»åã®çµæã«äŒŽãå£åãé²æ¢ããããšãç®ç
ãšãããã®ã§ããã ããªãã¡æ¬çºæã¯æ°Žäžæµžéæ§ã®æ¯æäœã®äžã«å°
ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€å±€ãæããé»çœ
å°ç»çŽã«ãããŠã該乳å€å±€åã¯ãã®é£æ¥å±€äžã«æ·»
å ãããã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšããŠã®ç¹å®
ã®æ§é ãæããååç©ãçšããããšãç¹åŸŽãšãã
ãã®ã§ããã ããã§ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã¯ã¡ã«ã«ã
ãåºãæããã«ããªé²æ¢å€ãæãããæ¬çºæã§äœ¿
çšããã¡ã«ã«ããç³»ã«ããªé²æ¢å€ã¯ãã®ãã¡äžèš
äžè¬åŒïŒïŒã§è¡šããããååç©ã§ããã äžè¬åŒïŒïŒ åŒäžãïŒã¯æ°ŽçŽ ååãâNH4åºåã¯ã¢ã«ã«ãªé
å±ãè¡šãããã¯æ°ŽçŽ ååãã¢ã«ãã«åºåã¯ã¢ãª
ãŒã«åºãè¡šããã該ã¢ã«ãã«åºã¯å¥œãŸããã¯ççŽ
æ°ïŒãïŒã®ãã®ïŒäŸãã°ã¡ãã«åºããšãã«åºãã
ããã«åºãããã·ã«åºããªã¯ãã«åºïŒã§ããã該
ã¢ãªãŒã«åºã¯å¥œãŸããã¯ççŽ æ°ïŒã10ã®ãã®ïŒäŸ
ãã°ããšãã«åºããããã«åºïŒã§ããã ã¯çœ®æåºãæããŠãããïŒå¡ã®è€çŽ ç°ã圢æ
ããã«å¿ èŠãªåå矀åã¯ãã³ãŒã³ç°ãšçž®åããïŒ
å¡ã®è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šããã
該ïŒå¡ã®è€çŽ ç°ãšããŠã¯ã€ãããŸãŒã«ç°ãããªã¢
ãŸãŒã«ç°ãããã©ãŸãŒã«ç°ãªã©ã奜ãŸããã該è€
çŽ ç°ã®çœ®æåšãšããŠã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åº
ïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«åºããã
ã·ã«åºããªã¯ãã«åºãªã©ïŒãççŽ æ°ïŒã10ã®ã¢ãª
ãŒã«åºïŒäŸãã°ããšãã«åºããããã«åºïŒã奜ãŸ
ãããåèšãã³ãŒã³ç°ã«çž®åããïŒå¡ã®è€çŽ ç°ãš
ããŠã¯ãã³ãºã€ãããŸãŒã«åºã奜ãŸããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯è©²åŒäžã®å°
ãªããšãïŒåã®ççŽ ååãã«ã«ããã·åºè¥ããã¯
ãã®å¡©ãã«ã«ãã¢ã€ã«åºïŒâCONH2ïŒãããã
ãã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©ãã¢ããåºïŒâ
NH2ïŒãåã¯äœçŽã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ
æ°ïŒãïŒã®ãã®ãäŸãã°ã¡ããã·åºããšããã·
åºãããããã·åºã§çœ®æãããŠãããã®ãšããã
ãã®äžã§ãç¹ã«ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã¹
ã«ãåºè¥ããã¯ãã®å¡©ã奜ãŸããã äžè¬åŒïŒïŒã§è¡šããããååç©ã®äžã§ã次ã®
äžè¬åŒïŒïŒåã¯äžè¬åŒïŒïŒã§è¡šããããåå
ç©ãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒ åŒäžR2ã¯åèšãã氎溶æ§åºã§çœ®æãããã¢ã«
ãã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒãïŒã®ãã®ïŒåã¯å
èšãã氎溶æ§åºã§çœ®æãããã¢ãªãŒã«åºïŒå¥œãŸã
ãã¯ççŽ æ°ïŒã10ã®ãã®ïŒãè¡šããã氎溶æ§åºãš
ããŠã¯ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã«ã«ãã¢ã€
ã«åºãããããã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©å
ã¯ã¢ããåºã奜ãŸãããäžã§ãã«ã«ããã·åºè¥ã
ãã¯ãã®å¡©ãã¹ã«ãåºè¥ããã¯ãã®å¡©ãç¹ã«å¥œãŸ
ããã äžè¬åŒïŒïŒ åŒäžR3ãR4ã¯åã æ°ŽçŽ ååãããã²ã³ååå
ã¯åèšãã氎溶æ§åºãè¡šããããã ããR3ãšR4
ã®å°ãªããšãäžæ¹ã¯æ°Žæº¶æ§åºã§ããã氎溶æ§åºãš
ããŠã¯ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã«ã«ãã¢ã€
ã«åºãããããã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©ã
ã¢ããåºåã¯äœçŽã¢ã«ã³ãã·åºããããäžã§ãã«
ã«ããã·åºè¥ããã¯ãã®å¡©ãã¹ã«ãåºè¥ããã¯ã
ã®å¡©ãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒãšïŒïŒã®äžã§ã¯äžè¬åŒïŒïŒã§
è¡šããããååç©ã®å¹æããã倧ããã 次ã«æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©
ã®å ·äœäŸãæ²ããã ãããäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å ¬ç¥
ã§ããããŸãäŸãã°ç¹å ¬æ42â21842å·ãç¹éæ
53â50169å·åå ¬å ±ïŒè±åœç¹èš±ç¬¬1275701å·æ现
æžïŒD.A.Berges etalãâJournal of
Heterocyclic Chemistryâã第15å·»981é ïŒ1978
幎ïŒïŒâThe Chemstry of Heterocyclic
CompoundsâãImidazole and Derivertives
part ã336ã339é åã³384é ïŒE.Hoggarthã
âJournal of Chemical Societyâ1949幎巻ã
1160ã1167é ïŒãªã©ã«èšèŒã®æ¹æ³åã³ããã«æºã
ãæ¹æ³ã«ãã€ãŠå®¹æã«åæã§ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ããã²ã³å
éä¹³å€å±€åã¯ãã®é£æ¥å±€ã«æ·»å ããããæ·»å ææ
ã¯å¥œãŸããã¯åå±€ã®å¡åžåã§ãããå¡åžåŸã«è©²å
åç©ã®æº¶æ¶²ãå¡åžå±€ã«å«æµžããããªã©ã®æ段ããš
ãããšãã§ããã åèšäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å¥œãŸã
ãã¯éïŒã¢ã«åœã1.0Ã10-4ã¢ã«ä¹è³ïŒÃ10-3ã¢
ã«ãç¹ã«å¥œãŸããã¯ïŒÃ10-4ã¢ã«ä¹è³5.2Ã10-3
ã¢ã«ã®ç¯å²ã§äœ¿çšããã æ¬çºæã®é»çœå°ç»çŽã®æ¯æäœã¯ãçœè²åãã©ã¹
ããã¯ãã€ã«ã åã¯çæ°Žæ§é«ååã§äž¡é¢ã©ãããŒ
ãããçŽæ¯æäœã§ããã æ¬çºæã§çšãããããã®æ¯æäœã«ã¯å¿ èŠã«å¿ã
ãŠè¬ååŠçãæŸé»åŠçã玫å€ç·åŠçãªã©ã®è¡šé¢æŽ»
æ§ååŠçãæœãããŠããããããŸããã®è¡šé¢æŽ»æ§
ååŠçã«ä»£ããŠè¥ããã¯ãããšå ±ã«äžå¡å±€ãå¡èš
ãããŠãããã æ¬çºæã«ãããŠçšããããããã²ã³åéæå æ
æäžã®ããã²ã³åéã¯ãå¡©åéãå¡©èåéãèå
éãæ²èåéãŸãã¯æ²å¡©èåéã«ãããªããã®ã§
ãããããã²ã³åéç²åã®å¹³åç²åŸã¯ç¹ã«åããª
ãã3ÎŒãã倧ã§ãªãããšã奜ãŸããã ããã²ã³åéä¹³å€ã¯ãååŠå¢æãè¡ããªããã
ãããæªåŸçïŒprimitiveïŒä¹³å€ãçšããããšã
ã§ããããéåžžã¯ååŠå¢æããããååŠå¢æã®ã
ãã«ã¯ãåèšGlafkidesãŸãã¯Zelikmanãã®èæž
ãããã¯H.Frieserç·šDie Grundlagen der
Photographischen Prozesse mit
SilberhalogenidenãïŒAkademische
Verlagsgesellschaftã1968ïŒã«èšèŒã®æ¹æ³ãçš
ããããšãã§ããã ããªãã¡ã ããªç¡«é žå¡©ãããªå°¿çŽ é¡ããã¢ãŸãŒã«é¡ãããŒ
ããã³é¡çã®ååç©ã掻æ§ãŒã©ãã³ãçšããç¡«é»
å¢ææ³ã 第äžããå¡©ãã¢ãã³é¡ãããã©ãžã³é¡ããã«ã
ã¢ããžã³ã¹ã«ãã€ã³é¡ãã·ã©ã³ååç©ãªã©ãçšã
ãéå å¢ææ³ã éé¯å¡©ã®ä»çœéãã€ãªãžãŠã ããã©ãžãŠã çã®
åšæåŸè¡šæã®éå±ã®é¯å¡©ãçšãã貎éå±å¢ææ³
ãªã©ã«åç¬ãŸãã¯çµã¿åããŠçšããããšãã§ã
ãã åãæ床äžæãã³ã³ãã©ã¹ãäžæããŸãã¯çŸå
ä¿é²ã®ç®çã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸ
ãã¯ãã®ãšãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°
äœãããªãšãŒãã«ååç©ãããªã¢ãããªãªã³é¡ã
åçŽã¢ã³ã¢ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿
çŽ èªå°äœãã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªã
ã³é¡çãå«ãã§ããããäŸãã°ç±³åœç¹èš±2400532
å·ãå2423549å·ãå2716062å·ãå3617280å·ã
å3772021å·ãå3808003å·çã«èšèŒããããã®ãš
çšããããšãã§ããã æ¬çºæã«æŒãŠã¯åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³
ãã€ããšããŠãŒã©ãã³ãçšããã®ãæå©ã§ãã
ãããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§
ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ããé ž
åŠçãŒã©ãã³ãçšããŠãããããŒã©ãã³å æ°Žå解
ç©ããŒã©ãã³é µçŽ å解ç©ãçšããããšãã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯ãå¡åžå©å€ã垯é»é²æ¢ãã¹ããª
æ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®å ¬ç¥ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ãã°ãªã·ããŒã«èªå°äœïŒããš
ãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãªãçïŒãå€
䟡ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«
ãšã¹ãã«é¡ãåãããŠã¬ã¿ã³é¡ãŸãã¯ãšãŒãã«é¡
ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒããªãã«ããã€ã
ç³»ãµããã³ãã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«
é¡ãã¢ã«ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«â
âã¢ã«ãã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«
é¡ãã¹ã«ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«
ããšãã«ãšãŒãã«é¡ãªã©ã®ã¢ããªã³çé¢æŽ»æ§å€ïŒ
ã¢ããé žé¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ã
ãã¢ã«ãã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«
ãã¿ã€ã³é¡ãã¢ãã³ã€ããé¡ãã¢ãã³ãªãã·ãé¡
ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã¢ãã³å¡©é¡ãè
èªæãããã¯è³éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãã
ãªãžããŠã ãã€ãããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããã³èèªæãŸãã¯è€çŽ ç°ã
å«ããã¹ãããŠã ãŸãã¯ã¹ã«ãããŠã å¡©é¡ãªã©ã®
ã«ããªã³çé¢æŽ»æ§å€ãçšããããšãã§ããããª
ããæ¬çºæã§ã¯ããªã¢ã«ãã¬ã³ãªãã·ãç³»ã®çé¢
掻æ§å€ã¯äœ¿çšããªãã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ä»åºŠå®å®æ§ã®æ¹è¯ãªã©ã®
ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶æ§åæããªããŒã®åæ£
ç©ãå«ãããšãã§ãããããšãã°ã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ãã·ã¢ã«ãã«ïŒã¡ã¿ïŒ
ã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒ
ããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããããã«ãšã¹ãã«
ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãªããããªã«ããªã¬
ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ãããã¯çµåãããŸ
ãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿ã¢ã¯ãªã«é žãαïŒ
βâäžé£œåãžã«ã«ãã³é žãããããã·ã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããªã¢ã«ãã«ïŒã¡ã¿ïŒ
ã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ããªã³é žãªã©ãšã®çµ
åããåéäœæåãšããããªããŒãçšããããšã
ã§ããã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ç¡æ©ãŸãã¯ææ©ã®ç¡¬èå€ã
å«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°ãã
é ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢ã«ã
ãããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ããããª
ã©ïŒãâã¡ãããŒã«ååç©ïŒãžã¡ãããŒã«å°¿çŽ ã
ã¡ãããŒã«ãžã¡ãã«ããã³ãã€ã³ãªã©ïŒããžãªã
ãµã³èªå°äœïŒïŒïŒïŒâãžããããã·ãžãªããµã³ãª
ã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯
ãªãã€ã«âãããµãããââããªã¢ãžã³ããã¹
ïŒããã«ã¹ã«ããã«ïŒã¡ãã«ãšãŒãã«ãªã©ïŒã掻æ§
ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«âïŒâããã
ãã·ââããªã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡
ïŒã ã³ã¯ãã«é žãã ã³ããšããã·ã¯ãã«é žãªã©ïŒã
ã€ãœãªããµãŸãŒã«é¡ããžã¢ã«ãããã§ãç²ãïŒâ
ã¯ãã«âïŒâããããã·ããªã¢ãžãã«åãŒã©ãã³
ãªã©ããåç¬ãŸãã¯çµåããŠçšããããšãã§ã
ãã æ¬çºæã®åçä¹³å€ã¯ãã¡ãã³è²çŽ é¡ãã®ä»ã«ã
ã€ãŠåå å¢æãããŠãããçšããããè²çŽ ã«ã¯ã
ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·ã¢ãã³
è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©ãŒã·ã¢
ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²çŽ ãã
ãã³ãããªããœããŒã«è²çŽ ãå å«ããããç¹ã«æ
çšãªè²çŽ ãã¡ãã·ã¢ãã³è²çŽ ããã³è€åã¡ãã·ã¢
ãã³è²çŽ ã«å±ããè²çŽ ã§ããããããã®è²çŽ é¡ã«
ã¯å¡©åºæ§ç°ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©
çšãããæ žã®ãããããé©çšã§ãããããªãã¡ã
ãããªã³æ žããªããµãŸãªã³æ žããã¢ãŸãªã³æ žãã
ããŒã«æ žããªããµãŸãŒã«æ žããã¢ãŸãŒã«æ žãã»ã¬
ããŸãŒã«æ žãã€ãããŸãŒã«æ žãããã©ãŸãŒã«æ žã
ããªãžã³æ žãªã©ïŒãããã®æ žã«èç°åŒçåæ°ŽçŽ ç°
ãèåããæ žïŒããã³ãããã®æ žã«è³éŠæçåæ°Ž
çŽ ç°ãèåããæ žãããªãã¡ãã€ã³ãã¬ãã³æ žã
ãã³ãºã€ã³ãã¬ãã³æ žãã€ã³ããŒã«æ žããã³ãºãª
ããµãŸãŒã«æ žãããããªããµãŸãŒã«æ žããã³ãŸã
ã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žããã³ãŸã»ã¬ã
ãŸãŒã«æ žããã³ãºã€ãããŸãŒã«æ žããããªã³æ žãª
ã©ãé©çšã§ããããããã®æ žã¯ççŽ ååäžã«çœ®æ
ãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«ãã€
ã«ã¿ãŒææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²
æ¢ãã®ä»çš®ã ã®ç®çã§æ°Žæº¶æ§ææïŒãªããœããŒã«
ææããããªããœããŒã«ææãã¹ããªã«ææãã¡
ãã·ã¢ãã³ææãã·ã¢ãã³ææåã³ã¢ãŸææãª
ã©ãïŒãå«æããŠããã æ¬çºæã®ããã²ã³åéåçæå ææã¯ã¡ã«ã«ã
ãç³»ã«ããªé²æ¢å€ãšããŠã¯åèšäžè¬åŒïŒïŒã§è¡š
ããããååç©ã®ã¿ãå«æãããã®ã§ããããã¡
ã«ã«ããç³»ååç©ä»¥å€ã®å ¬ç¥ã®ã«ããªé²æ¢å€åã¯
å®å®å€ã¯ããã䜵çšããŠããã䜵çšãããã«ããª
é²æ¢å€åã¯å®å®å€ãšããŠã¯ããã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãã
ãŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢
ãã³ãºã€ãããŸãŒã«é¡ãã¢ããããªã¢ãŸãŒã«é¡ã
ãã³ãºããªã¢ãŸãŒã«é¡ãããããã³ãºããªã¢ãŸãŒ
ã«é¡ããã³ãŒã³ããªã¹ã«ãã³é žé¡ããã³ãŒã³ã¹ã«
ãã€ã³é žé¡ããã³ãŒã³ã¹ã«ãã³é žã¢ãããã¢ã¶ã€
ã³ãã³é¡ãäŸãã°ããªã¢ã¶ã€ã³ãã³é¡ãããã©ã¢
ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒïŒ
ïŒïŒ3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒããªã©ãã
ãã æ¬çºæã«æŒããåçåãåŸãããã®é²å ã¯éåžž
ã®æ¹æ³ãçšããŠè¡ãªãã°ãããããªãã¡ãèªç¶å
ïŒæ¥å ïŒãã¿ã³ã°ã¹ãã³é»ç¯ãèå ç¯ãæ°Žéç¯ãã
ã»ãã³ã¢ãŒã¯ç¯ãççŽ ã¢ãŒã¯ç¯ããã»ãã³ãã©ã
ã·ãŠç¯ãé°æ¥µç·ç®¡ãã©ã€ã³ã°ã¹ããããªã©å ¬ç¥ã®
å€çš®ã®å æºããããã§ãçšããããšãã§ãããé²
å æéã¯éåžžã«ã¡ã©ã§çšãããã1/1000ç§ããïŒ
ç§ã®é²å æéã¯ãã¡ããã1/1000ç§ããçãé²
å ãããšãã°ãã»ãã³éå ç¯ãé°æ¥µç·ç®¡ãçšãã
ïŒïŒïŒïŒ4ã1/106ç§ã®é²å ãçšããããšãã§ãããã
ïŒç§ããé·ãé²å ãçšããããšãåºæ¥ãã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®éç»
ç»åã圢æããçŸååŠçæ¹æ³ã®ãããã«ãçšãã
ããšãã§ãããåŠç液ã«ã¯å ¬ç¥ã®ãã®ãçšããã
ãšãã§ãããåŠç枩床ã¯æ®é18âãã50âã®éã«
éžã°ãããã18âããäœã枩床ãŸãã¯50âããã
ã枩床ãšããŠããããé»çœåçåŠçã«çšããçŸå
液ã¯ãç¥ãããŠããçŸåäž»è¬ãå«ãããšãã§ã
ããçŸåäž»è¬ãšããŠã¯ããžããããã·ãã³ãŒã³é¡
ïŒããšãã°ãã€ããããã³ïŒãïŒâãã©ãŸãªãã³é¡
ïŒããšãã°ïŒâããšãã«âïŒâãã©ãŸãªãã³ïŒãã¢
ããããšããŒã«é¡ïŒããšãã°ïŒ®âã¡ãã«ââã¢
ããããšããŒã«ïŒãïŒâããšãã«âïŒâãã©ãŸãª
ã³é¡ãã¢ã¹ã³ã«ãã³é žãåã³ç±³åœç¹èš±4067872å·
ã«èšèŒã®ïŒïŒïŒïŒïŒïŒïŒâããã©ããããããªã³
ç°ãšã€ã³ãã¬ã³ç°ãšãçž®åãããããªè€çŽ ç°åå
ç©é¡ãªã©ããåç¬ãããã¯çµåããŠçšããããšã
ã§ãããçŸå液ã«ã¯äžè¬ã«ãã®ä»å ¬ç¥ã®ä¿æå€ã
ã¢ã«ã«ãªå€ãPHç·©è¡å€ãã«ããªé²æ¢å€ãªã©ãå«
ã¿ãããã«å¿ èŠã«å¿ã溶解å©å€ãè²èª¿å€ãçŸåä¿
é²å€ãçé¢æŽ»æ§å€ãæ¶æ³¡å€ã硬氎è»åå€ã硬è
å€ãç²æ§ä»äžå€ãªã©ãå«ãã§ããããæ¬çºæã®æ
å ææã¯ãéåžžãä¿æå€ãšããŠã®äºç¡«é žã€ãªã³ã
0.15ã¢ã«ïŒä»¥äžå«æããçŸå液ã§åŠçãããã å®ç液ãšããŠã¯äžè¬ã«çšããããçµæã®ãã®ã
çšããããšãã§ãããå®çå€ãšããŠã¯ããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ã®ã»ããå®çå€ãšããŠã®å¹æ
ãç¥ãããŠããææ©ç¡«é»ååç©ãçšããããšãã§
ãããå®ç液ã«ã¯ç¡¬èå€ãšããŠæ°Žæº¶æ§ã¢ã«ãããŠ
ã å¡©ãå«ãã§ãããã æ¬çºæã®ããã²ã³åéåçæå ææã¯äžè¬åŒ
ïŒïŒã§è¡šããããååç©ãã«ããªé²æ¢å€ãšããŠ
䜿çšããŠããããã«ãæ°Žäžæµžéæ§ã®æ¯æäœã䜿çš
ããŠããã«ããããããéåžžã®é»çœåçåŠçã®ã¿
ãçµãŠåœ¢æããéç»åã®å®å®æ§ãé«ãçµæã«ãã€
ãŠå£åããããšããªããããããã«ããªãå åã«
æå¶ããããšããå©ç¹ãæããã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ããã«ãžãšããæ³ã§ç²åæ²æ®¿ãããéåžžã®æ¹æ³
ã§ç©ççæããè±å¡©åŠçããæŽã«ç¡«é»å¢æåã³é
å¢æãããæ²èåéä¹³å€ïŒèåé99ã¢ã«ïŒ ïŒã«
ïŒïŒïŒâãžã¯ããâïŒâããããã·âïŒïŒïŒïŒïŒ
âããªã¢ãžã³ãããªãŠã å¡©ïŒç¡¬èå€ïŒåã³ããã·
ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ïŒå¡åžå©å€ïŒã
å ããæŽã«éïŒã¢ã«ãããå1.7Ã10-3ã¢ã«ã®äž
èšç¬¬ïŒè¡šèšèŒã®ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å
ãã次ãã§ãããã®å¡åžæ¶²ã第ïŒè¡šã«èšèŒããæ¯
æäœäžã«å¡åžééã20mgïŒïœm2ã«ãªãããã«ããŠ
è©ŠæïŒïŒãïŒïŒãäœè£œããã
ã§ãããç¹ã«æ°Žäžæµžéæ§ã®æ¯æäœäžã«åœ¢æããé
ç»åã®çµæã«äŒŽãå£åãé²æ¢ããé»çœå°ç»çŽã«é¢
ãããã®ã§ãã ããã²ã³åéåçæå ææã®åéã«ãããŠã¯é
ç»åã¯æè¬ã«ã©ãŒç»åïŒè²çŽ ç»åïŒããå ç¢ã§ã
ãããã«é·æéä¿åããå¿ èŠã®ããæ å ±ã®èšé²ã«
é©ããŠãããããããªãããããéç»åãçµæã«
䌎ã€ãŠå£åããåŸåãæã¡ããã®åŸåã¯ç¹ã«ãã©
ã¹ããã¯ãã€ã«ã ãªã©ã®æ°Žäžæµžéæ§ã®æ¯æäœãçš
ããããŠããå Žåã«å€§ããããšãããã€ãããã©
ã¹ããã¯ãã€ã«ã ãªã©ã®æ°Žäžæµžéæ§ã®æ¯æäœã¯ã
äžè¬ã«ãçŽãåžãªã©ã®æ°Žæµžéæ§ã®æ¯æäœããã匷
床ãé«ãã®ã§é·æéã®ä¿åã«ã¯é©ããŠãããšèšã
ããããã®äžæ¹ã§äžè¿°ãããããªé²ç»åã®å£åã®
åŸåã倧ãããããšãããžã¬ã³ããååšããã®ã§
ããïŒãã®ãããªæ°Žäžæµžéæ§æ¯æäœäžã®éç»åã®
å£åã«ã€ããŠã¯Photographic Science and
Engineeringèªç¬¬ïŒå·»253ã261é ïŒ1963幎ïŒãè±
åœç¹èš±ïŒå ¬éïŒç¬¬2019024Aå·ãªã©ã«å ±åãããŠ
ããã æ¬çºæã¯æ°Žäžæµžéæ§ã®æ¯æäœãçšããæã«çã
ãéç»åã®çµæã«äŒŽãå£åãé²æ¢ããããšãç®ç
ãšãããã®ã§ããã ããªãã¡æ¬çºæã¯æ°Žäžæµžéæ§ã®æ¯æäœã®äžã«å°
ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€å±€ãæããé»çœ
å°ç»çŽã«ãããŠã該乳å€å±€åã¯ãã®é£æ¥å±€äžã«æ·»
å ãããã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšããŠã®ç¹å®
ã®æ§é ãæããååç©ãçšããããšãç¹åŸŽãšãã
ãã®ã§ããã ããã§ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã¯ã¡ã«ã«ã
ãåºãæããã«ããªé²æ¢å€ãæãããæ¬çºæã§äœ¿
çšããã¡ã«ã«ããç³»ã«ããªé²æ¢å€ã¯ãã®ãã¡äžèš
äžè¬åŒïŒïŒã§è¡šããããååç©ã§ããã äžè¬åŒïŒïŒ åŒäžãïŒã¯æ°ŽçŽ ååãâNH4åºåã¯ã¢ã«ã«ãªé
å±ãè¡šãããã¯æ°ŽçŽ ååãã¢ã«ãã«åºåã¯ã¢ãª
ãŒã«åºãè¡šããã該ã¢ã«ãã«åºã¯å¥œãŸããã¯ççŽ
æ°ïŒãïŒã®ãã®ïŒäŸãã°ã¡ãã«åºããšãã«åºãã
ããã«åºãããã·ã«åºããªã¯ãã«åºïŒã§ããã該
ã¢ãªãŒã«åºã¯å¥œãŸããã¯ççŽ æ°ïŒã10ã®ãã®ïŒäŸ
ãã°ããšãã«åºããããã«åºïŒã§ããã ã¯çœ®æåºãæããŠãããïŒå¡ã®è€çŽ ç°ã圢æ
ããã«å¿ èŠãªåå矀åã¯ãã³ãŒã³ç°ãšçž®åããïŒ
å¡ã®è€çŽ ç°ã圢æããã«å¿ èŠãªåå矀ãè¡šããã
該ïŒå¡ã®è€çŽ ç°ãšããŠã¯ã€ãããŸãŒã«ç°ãããªã¢
ãŸãŒã«ç°ãããã©ãŸãŒã«ç°ãªã©ã奜ãŸããã該è€
çŽ ç°ã®çœ®æåšãšããŠã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åº
ïŒäŸãã°ã¡ãã«åºããšãã«åºããããã«åºããã
ã·ã«åºããªã¯ãã«åºãªã©ïŒãççŽ æ°ïŒã10ã®ã¢ãª
ãŒã«åºïŒäŸãã°ããšãã«åºããããã«åºïŒã奜ãŸ
ãããåèšãã³ãŒã³ç°ã«çž®åããïŒå¡ã®è€çŽ ç°ãš
ããŠã¯ãã³ãºã€ãããŸãŒã«åºã奜ãŸããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯è©²åŒäžã®å°
ãªããšãïŒåã®ççŽ ååãã«ã«ããã·åºè¥ããã¯
ãã®å¡©ãã«ã«ãã¢ã€ã«åºïŒâCONH2ïŒãããã
ãã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©ãã¢ããåºïŒâ
NH2ïŒãåã¯äœçŽã¢ã«ã³ãã·åºïŒå¥œãŸããã¯ççŽ
æ°ïŒãïŒã®ãã®ãäŸãã°ã¡ããã·åºããšããã·
åºãããããã·åºã§çœ®æãããŠãããã®ãšããã
ãã®äžã§ãç¹ã«ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã¹
ã«ãåºè¥ããã¯ãã®å¡©ã奜ãŸããã äžè¬åŒïŒïŒã§è¡šããããååç©ã®äžã§ã次ã®
äžè¬åŒïŒïŒåã¯äžè¬åŒïŒïŒã§è¡šããããåå
ç©ãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒ åŒäžR2ã¯åèšãã氎溶æ§åºã§çœ®æãããã¢ã«
ãã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒãïŒã®ãã®ïŒåã¯å
èšãã氎溶æ§åºã§çœ®æãããã¢ãªãŒã«åºïŒå¥œãŸã
ãã¯ççŽ æ°ïŒã10ã®ãã®ïŒãè¡šããã氎溶æ§åºãš
ããŠã¯ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã«ã«ãã¢ã€
ã«åºãããããã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©å
ã¯ã¢ããåºã奜ãŸãããäžã§ãã«ã«ããã·åºè¥ã
ãã¯ãã®å¡©ãã¹ã«ãåºè¥ããã¯ãã®å¡©ãç¹ã«å¥œãŸ
ããã äžè¬åŒïŒïŒ åŒäžR3ãR4ã¯åã æ°ŽçŽ ååãããã²ã³ååå
ã¯åèšãã氎溶æ§åºãè¡šããããã ããR3ãšR4
ã®å°ãªããšãäžæ¹ã¯æ°Žæº¶æ§åºã§ããã氎溶æ§åºãš
ããŠã¯ã«ã«ããã·åºè¥ããã¯ãã®å¡©ãã«ã«ãã¢ã€
ã«åºãããããã·åºãã¹ã«ãåºè¥ããã¯ãã®å¡©ã
ã¢ããåºåã¯äœçŽã¢ã«ã³ãã·åºããããäžã§ãã«
ã«ããã·åºè¥ããã¯ãã®å¡©ãã¹ã«ãåºè¥ããã¯ã
ã®å¡©ãç¹ã«å¥œãŸããã äžè¬åŒïŒïŒãšïŒïŒã®äžã§ã¯äžè¬åŒïŒïŒã§
è¡šããããååç©ã®å¹æããã倧ããã 次ã«æ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©
ã®å ·äœäŸãæ²ããã ãããäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å ¬ç¥
ã§ããããŸãäŸãã°ç¹å ¬æ42â21842å·ãç¹éæ
53â50169å·åå ¬å ±ïŒè±åœç¹èš±ç¬¬1275701å·æ现
æžïŒD.A.Berges etalãâJournal of
Heterocyclic Chemistryâã第15å·»981é ïŒ1978
幎ïŒïŒâThe Chemstry of Heterocyclic
CompoundsâãImidazole and Derivertives
part ã336ã339é åã³384é ïŒE.Hoggarthã
âJournal of Chemical Societyâ1949幎巻ã
1160ã1167é ïŒãªã©ã«èšèŒã®æ¹æ³åã³ããã«æºã
ãæ¹æ³ã«ãã€ãŠå®¹æã«åæã§ããã äžè¬åŒïŒïŒã§è¡šããããååç©ã¯ããã²ã³å
éä¹³å€å±€åã¯ãã®é£æ¥å±€ã«æ·»å ããããæ·»å ææ
ã¯å¥œãŸããã¯åå±€ã®å¡åžåã§ãããå¡åžåŸã«è©²å
åç©ã®æº¶æ¶²ãå¡åžå±€ã«å«æµžããããªã©ã®æ段ããš
ãããšãã§ããã åèšäžè¬åŒïŒïŒã§è¡šããããååç©ã¯å¥œãŸã
ãã¯éïŒã¢ã«åœã1.0Ã10-4ã¢ã«ä¹è³ïŒÃ10-3ã¢
ã«ãç¹ã«å¥œãŸããã¯ïŒÃ10-4ã¢ã«ä¹è³5.2Ã10-3
ã¢ã«ã®ç¯å²ã§äœ¿çšããã æ¬çºæã®é»çœå°ç»çŽã®æ¯æäœã¯ãçœè²åãã©ã¹
ããã¯ãã€ã«ã åã¯çæ°Žæ§é«ååã§äž¡é¢ã©ãããŒ
ãããçŽæ¯æäœã§ããã æ¬çºæã§çšãããããã®æ¯æäœã«ã¯å¿ èŠã«å¿ã
ãŠè¬ååŠçãæŸé»åŠçã玫å€ç·åŠçãªã©ã®è¡šé¢æŽ»
æ§ååŠçãæœãããŠããããããŸããã®è¡šé¢æŽ»æ§
ååŠçã«ä»£ããŠè¥ããã¯ãããšå ±ã«äžå¡å±€ãå¡èš
ãããŠãããã æ¬çºæã«ãããŠçšããããããã²ã³åéæå æ
æäžã®ããã²ã³åéã¯ãå¡©åéãå¡©èåéãèå
éãæ²èåéãŸãã¯æ²å¡©èåéã«ãããªããã®ã§
ãããããã²ã³åéç²åã®å¹³åç²åŸã¯ç¹ã«åããª
ãã3ÎŒãã倧ã§ãªãããšã奜ãŸããã ããã²ã³åéä¹³å€ã¯ãååŠå¢æãè¡ããªããã
ãããæªåŸçïŒprimitiveïŒä¹³å€ãçšããããšã
ã§ããããéåžžã¯ååŠå¢æããããååŠå¢æã®ã
ãã«ã¯ãåèšGlafkidesãŸãã¯Zelikmanãã®èæž
ãããã¯H.Frieserç·šDie Grundlagen der
Photographischen Prozesse mit
SilberhalogenidenãïŒAkademische
Verlagsgesellschaftã1968ïŒã«èšèŒã®æ¹æ³ãçš
ããããšãã§ããã ããªãã¡ã ããªç¡«é žå¡©ãããªå°¿çŽ é¡ããã¢ãŸãŒã«é¡ãããŒ
ããã³é¡çã®ååç©ã掻æ§ãŒã©ãã³ãçšããç¡«é»
å¢ææ³ã 第äžããå¡©ãã¢ãã³é¡ãããã©ãžã³é¡ããã«ã
ã¢ããžã³ã¹ã«ãã€ã³é¡ãã·ã©ã³ååç©ãªã©ãçšã
ãéå å¢ææ³ã éé¯å¡©ã®ä»çœéãã€ãªãžãŠã ããã©ãžãŠã çã®
åšæåŸè¡šæã®éå±ã®é¯å¡©ãçšãã貎éå±å¢ææ³
ãªã©ã«åç¬ãŸãã¯çµã¿åããŠçšããããšãã§ã
ãã åãæ床äžæãã³ã³ãã©ã¹ãäžæããŸãã¯çŸå
ä¿é²ã®ç®çã§ãäŸãã°ããªã¢ã«ãã¬ã³ãªãã·ããŸ
ãã¯ãã®ãšãŒãã«ããšã¹ãã«ãã¢ãã³ãªã©ã®èªå°
äœãããªãšãŒãã«ååç©ãããªã¢ãããªãªã³é¡ã
åçŽã¢ã³ã¢ããŠã å¡©ååç©ããŠã¬ã¿ã³èªå°äœãå°¿
çŽ èªå°äœãã€ãããŸãŒã«èªå°äœãïŒâãã©ãŸãªã
ã³é¡çãå«ãã§ããããäŸãã°ç±³åœç¹èš±2400532
å·ãå2423549å·ãå2716062å·ãå3617280å·ã
å3772021å·ãå3808003å·çã«èšèŒããããã®ãš
çšããããšãã§ããã æ¬çºæã«æŒãŠã¯åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³
ãã€ããšããŠãŒã©ãã³ãçšããã®ãæå©ã§ãã
ãããã以å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§
ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒã¹ç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã¹èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã ãŒã©ãã³ãšããŠã¯ç³ç°åŠçãŒã©ãã³ã®ã»ããé ž
åŠçãŒã©ãã³ãçšããŠãããããŒã©ãã³å æ°Žå解
ç©ããŒã©ãã³é µçŽ å解ç©ãçšããããšãã§ããã æ¬çºæã®æå ææã®åçä¹³å€å±€ãŸãã¯ä»ã®èŠªæ°Ž
æ§ã³ãã€ãå±€ã«ã¯ãå¡åžå©å€ã垯é»é²æ¢ãã¹ããª
æ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ããã³åçç¹æ§æ¹è¯
ïŒããšãã°çŸåä¿é²ã硬調åãå¢æïŒãªã©çš®ã ã®
ç®çã§çš®ã ã®å ¬ç¥ã®çé¢æŽ»æ§å€ãå«ãã§ãããã ããšãã°ãµããã³ãã°ãªã·ããŒã«èªå°äœïŒããš
ãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»ãªãçïŒãå€
䟡ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«
ãšã¹ãã«é¡ãåãããŠã¬ã¿ã³é¡ãŸãã¯ãšãŒãã«é¡
ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ïŒããªãã«ããã€ã
ç³»ãµããã³ãã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«
é¡ãã¢ã«ãã«ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«â
âã¢ã«ãã«ã¿ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«
é¡ãã¹ã«ãã¢ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«
ããšãã«ãšãŒãã«é¡ãªã©ã®ã¢ããªã³çé¢æŽ»æ§å€ïŒ
ã¢ããé žé¡ãã¢ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ã
ãã¢ã«ãã«ç¡«é žãŸãã¯çé žãšã¹ãã«é¡ãã¢ã«ãã«
ãã¿ã€ã³é¡ãã¢ãã³ã€ããé¡ãã¢ãã³ãªãã·ãé¡
ãªã©ã®äž¡æ§çé¢æŽ»æ§å€ïŒã¢ã«ãã«ã¢ãã³å¡©é¡ãè
èªæãããã¯è³éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãã
ãªãžããŠã ãã€ãããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽ
ã¢ã³ã¢ããŠã å¡©é¡ãããã³èèªæãŸãã¯è€çŽ ç°ã
å«ããã¹ãããŠã ãŸãã¯ã¹ã«ãããŠã å¡©é¡ãªã©ã®
ã«ããªã³çé¢æŽ»æ§å€ãçšããããšãã§ããããª
ããæ¬çºæã§ã¯ããªã¢ã«ãã¬ã³ãªãã·ãç³»ã®çé¢
掻æ§å€ã¯äœ¿çšããªãã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ä»åºŠå®å®æ§ã®æ¹è¯ãªã©ã®
ç®çã§ãæ°Žäžæº¶ãŸãã¯é£æº¶æ§åæããªããŒã®åæ£
ç©ãå«ãããšãã§ãããããšãã°ã¢ã«ãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã¢ã«ã³ãã·ã¢ã«ãã«ïŒã¡ã¿ïŒ
ã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒ
ããïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããããã«ãšã¹ãã«
ïŒããšãã°é ¢é žããã«ïŒãã¢ã¯ãªããããªã«ããªã¬
ãã€ã³ãã¹ãã¬ã³ãªã©ã®åç¬ãããã¯çµåãããŸ
ãã¯ããããšã¢ã¯ãªã«é žãã¡ã¿ã¢ã¯ãªã«é žãαïŒ
βâäžé£œåãžã«ã«ãã³é žãããããã·ã¢ã«ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã¹ã«ããªã¢ã«ãã«ïŒã¡ã¿ïŒ
ã¢ã¯ãªã¬ãŒããã¹ãã¬ã³ã¹ã«ããªã³é žãªã©ãšã®çµ
åããåéäœæåãšããããªããŒãçšããããšã
ã§ããã æ¬çºæã®åçæå ææã«ã¯ãåçä¹³å€å±€ãã®ä»
ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ç¡æ©ãŸãã¯ææ©ã®ç¡¬èå€ã
å«æããŠãããäŸãã°ã¯ãã å¡©ïŒã¯ãã æã°ãã
é ¢é žã¯ãã ãªã©ïŒãã¢ã«ãããé¡ïŒãã«ã ã¢ã«ã
ãããã°ãªãªããµãŒã«ãã°ã«ã¿ãŒã«ã¢ã«ããããª
ã©ïŒãâã¡ãããŒã«ååç©ïŒãžã¡ãããŒã«å°¿çŽ ã
ã¡ãããŒã«ãžã¡ãã«ããã³ãã€ã³ãªã©ïŒããžãªã
ãµã³èªå°äœïŒïŒïŒïŒâãžããããã·ãžãªããµã³ãª
ã©ïŒã掻æ§ããã«ååç©ïŒïŒïŒïŒïŒïŒâããªã¢ã¯
ãªãã€ã«âãããµãããââããªã¢ãžã³ããã¹
ïŒããã«ã¹ã«ããã«ïŒã¡ãã«ãšãŒãã«ãªã©ïŒã掻æ§
ããã²ã³ååç©ïŒïŒïŒïŒâãžã¯ãã«âïŒâããã
ãã·ââããªã¢ãžã³ãªã©ïŒãã ã³ããã²ã³é žé¡
ïŒã ã³ã¯ãã«é žãã ã³ããšããã·ã¯ãã«é žãªã©ïŒã
ã€ãœãªããµãŸãŒã«é¡ããžã¢ã«ãããã§ãç²ãïŒâ
ã¯ãã«âïŒâããããã·ããªã¢ãžãã«åãŒã©ãã³
ãªã©ããåç¬ãŸãã¯çµåããŠçšããããšãã§ã
ãã æ¬çºæã®åçä¹³å€ã¯ãã¡ãã³è²çŽ é¡ãã®ä»ã«ã
ã€ãŠåå å¢æãããŠãããçšããããè²çŽ ã«ã¯ã
ã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ãã³è²çŽ ãè€åã·ã¢ãã³
è²çŽ ãè€åã¡ãã·ã¢ãã³è²çŽ ãããããŒã©ãŒã·ã¢
ãã³è²çŽ ãããã·ã¢ãã³è²çŽ ãã¹ããªã«è²çŽ ãã
ãã³ãããªããœããŒã«è²çŽ ãå å«ããããç¹ã«æ
çšãªè²çŽ ãã¡ãã·ã¢ãã³è²çŽ ããã³è€åã¡ãã·ã¢
ãã³è²çŽ ã«å±ããè²çŽ ã§ããããããã®è²çŽ é¡ã«
ã¯å¡©åºæ§ç°ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©
çšãããæ žã®ãããããé©çšã§ãããããªãã¡ã
ãããªã³æ žããªããµãŸãªã³æ žããã¢ãŸãªã³æ žãã
ããŒã«æ žããªããµãŸãŒã«æ žããã¢ãŸãŒã«æ žãã»ã¬
ããŸãŒã«æ žãã€ãããŸãŒã«æ žãããã©ãŸãŒã«æ žã
ããªãžã³æ žãªã©ïŒãããã®æ žã«èç°åŒçåæ°ŽçŽ ç°
ãèåããæ žïŒããã³ãããã®æ žã«è³éŠæçåæ°Ž
çŽ ç°ãèåããæ žãããªãã¡ãã€ã³ãã¬ãã³æ žã
ãã³ãºã€ã³ãã¬ãã³æ žãã€ã³ããŒã«æ žããã³ãºãª
ããµãŸãŒã«æ žãããããªããµãŸãŒã«æ žããã³ãŸã
ã¢ãŸãŒã«æ žãããããã¢ãŸãŒã«æ žããã³ãŸã»ã¬ã
ãŸãŒã«æ žããã³ãºã€ãããŸãŒã«æ žããããªã³æ žãª
ã©ãé©çšã§ããããããã®æ žã¯ççŽ ååäžã«çœ®æ
ãããŠããŠãããã ã¡ãã·ã¢ãã³è²çŽ ãŸãã¯è€åã¡ãã·ã¢ãã³è²çŽ
ã«ã¯ã±ãã¡ãã¬ã³æ§é ãæããæ žãšããŠããã©ãŸ
ãªã³âïŒâãªã³æ žãããªããã³ãã€ã³æ žãïŒâã
ãªãªããµãŸãªãžã³âïŒïŒïŒâãžãªã³æ žããã¢ãŸãª
ãžã³âïŒïŒïŒâãžãªã³æ žãããŒããã³æ žãããªã
ã«ãããŒã«é žæ žãªã©ã®ïŒãïŒå¡ç°ç¯ç°æ žãé©çšã
ãããšãã§ããã æ¬çºæã®æå ææã«ã¯èŠªæ°Žæ§ã³ãã€ãå±€ã«ãã€
ã«ã¿ãŒææãšããŠããããã¯ã€ã©ãžãšãŒã·ãšã³é²
æ¢ãã®ä»çš®ã ã®ç®çã§æ°Žæº¶æ§ææïŒãªããœããŒã«
ææããããªããœããŒã«ææãã¹ããªã«ææãã¡
ãã·ã¢ãã³ææãã·ã¢ãã³ææåã³ã¢ãŸææãª
ã©ãïŒãå«æããŠããã æ¬çºæã®ããã²ã³åéåçæå ææã¯ã¡ã«ã«ã
ãç³»ã«ããªé²æ¢å€ãšããŠã¯åèšäžè¬åŒïŒïŒã§è¡š
ããããååç©ã®ã¿ãå«æãããã®ã§ããããã¡
ã«ã«ããç³»ååç©ä»¥å€ã®å ¬ç¥ã®ã«ããªé²æ¢å€åã¯
å®å®å€ã¯ããã䜵çšããŠããã䜵çšãããã«ããª
é²æ¢å€åã¯å®å®å€ãšããŠã¯ããã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãã
ãŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢
ãã³ãºã€ãããŸãŒã«é¡ãã¢ããããªã¢ãŸãŒã«é¡ã
ãã³ãºããªã¢ãŸãŒã«é¡ãããããã³ãºããªã¢ãŸãŒ
ã«é¡ããã³ãŒã³ããªã¹ã«ãã³é žé¡ããã³ãŒã³ã¹ã«
ãã€ã³é žé¡ããã³ãŒã³ã¹ã«ãã³é žã¢ãããã¢ã¶ã€
ã³ãã³é¡ãäŸãã°ããªã¢ã¶ã€ã³ãã³é¡ãããã©ã¢
ã¶ã€ã³ãã³é¡ïŒç¹ã«ïŒâããããã·çœ®æïŒïŒïŒ
ïŒïŒ3aïŒïŒïŒããã©ã¢ã¶ã€ã³ãã³é¡ïŒããªã©ãã
ãã æ¬çºæã«æŒããåçåãåŸãããã®é²å ã¯éåžž
ã®æ¹æ³ãçšããŠè¡ãªãã°ãããããªãã¡ãèªç¶å
ïŒæ¥å ïŒãã¿ã³ã°ã¹ãã³é»ç¯ãèå ç¯ãæ°Žéç¯ãã
ã»ãã³ã¢ãŒã¯ç¯ãççŽ ã¢ãŒã¯ç¯ããã»ãã³ãã©ã
ã·ãŠç¯ãé°æ¥µç·ç®¡ãã©ã€ã³ã°ã¹ããããªã©å ¬ç¥ã®
å€çš®ã®å æºããããã§ãçšããããšãã§ãããé²
å æéã¯éåžžã«ã¡ã©ã§çšãããã1/1000ç§ããïŒ
ç§ã®é²å æéã¯ãã¡ããã1/1000ç§ããçãé²
å ãããšãã°ãã»ãã³éå ç¯ãé°æ¥µç·ç®¡ãçšãã
ïŒïŒïŒïŒ4ã1/106ç§ã®é²å ãçšããããšãã§ãããã
ïŒç§ããé·ãé²å ãçšããããšãåºæ¥ãã æ¬çºæã®æå ææã®åçåŠçã«ã¯ãå ¬ç¥ã®éç»
ç»åã圢æããçŸååŠçæ¹æ³ã®ãããã«ãçšãã
ããšãã§ãããåŠç液ã«ã¯å ¬ç¥ã®ãã®ãçšããã
ãšãã§ãããåŠç枩床ã¯æ®é18âãã50âã®éã«
éžã°ãããã18âããäœã枩床ãŸãã¯50âããã
ã枩床ãšããŠããããé»çœåçåŠçã«çšããçŸå
液ã¯ãç¥ãããŠããçŸåäž»è¬ãå«ãããšãã§ã
ããçŸåäž»è¬ãšããŠã¯ããžããããã·ãã³ãŒã³é¡
ïŒããšãã°ãã€ããããã³ïŒãïŒâãã©ãŸãªãã³é¡
ïŒããšãã°ïŒâããšãã«âïŒâãã©ãŸãªãã³ïŒãã¢
ããããšããŒã«é¡ïŒããšãã°ïŒ®âã¡ãã«ââã¢
ããããšããŒã«ïŒãïŒâããšãã«âïŒâãã©ãŸãª
ã³é¡ãã¢ã¹ã³ã«ãã³é žãåã³ç±³åœç¹èš±4067872å·
ã«èšèŒã®ïŒïŒïŒïŒïŒïŒïŒâããã©ããããããªã³
ç°ãšã€ã³ãã¬ã³ç°ãšãçž®åãããããªè€çŽ ç°åå
ç©é¡ãªã©ããåç¬ãããã¯çµåããŠçšããããšã
ã§ãããçŸå液ã«ã¯äžè¬ã«ãã®ä»å ¬ç¥ã®ä¿æå€ã
ã¢ã«ã«ãªå€ãPHç·©è¡å€ãã«ããªé²æ¢å€ãªã©ãå«
ã¿ãããã«å¿ èŠã«å¿ã溶解å©å€ãè²èª¿å€ãçŸåä¿
é²å€ãçé¢æŽ»æ§å€ãæ¶æ³¡å€ã硬氎è»åå€ã硬è
å€ãç²æ§ä»äžå€ãªã©ãå«ãã§ããããæ¬çºæã®æ
å ææã¯ãéåžžãä¿æå€ãšããŠã®äºç¡«é žã€ãªã³ã
0.15ã¢ã«ïŒä»¥äžå«æããçŸå液ã§åŠçãããã å®ç液ãšããŠã¯äžè¬ã«çšããããçµæã®ãã®ã
çšããããšãã§ãããå®çå€ãšããŠã¯ããªç¡«é ž
å¡©ãããªã·ã¢ã³é žå¡©ã®ã»ããå®çå€ãšããŠã®å¹æ
ãç¥ãããŠããææ©ç¡«é»ååç©ãçšããããšãã§
ãããå®ç液ã«ã¯ç¡¬èå€ãšããŠæ°Žæº¶æ§ã¢ã«ãããŠ
ã å¡©ãå«ãã§ãããã æ¬çºæã®ããã²ã³åéåçæå ææã¯äžè¬åŒ
ïŒïŒã§è¡šããããååç©ãã«ããªé²æ¢å€ãšããŠ
䜿çšããŠããããã«ãæ°Žäžæµžéæ§ã®æ¯æäœã䜿çš
ããŠããã«ããããããéåžžã®é»çœåçåŠçã®ã¿
ãçµãŠåœ¢æããéç»åã®å®å®æ§ãé«ãçµæã«ãã€
ãŠå£åããããšããªããããããã«ããªãå åã«
æå¶ããããšããå©ç¹ãæããã 以äžã«å®æœäŸãæ²ãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æã
ãã å®æœäŸ ïŒ ããã«ãžãšããæ³ã§ç²åæ²æ®¿ãããéåžžã®æ¹æ³
ã§ç©ççæããè±å¡©åŠçããæŽã«ç¡«é»å¢æåã³é
å¢æãããæ²èåéä¹³å€ïŒèåé99ã¢ã«ïŒ ïŒã«
ïŒïŒïŒâãžã¯ããâïŒâããããã·âïŒïŒïŒïŒïŒ
âããªã¢ãžã³ãããªãŠã å¡©ïŒç¡¬èå€ïŒåã³ããã·
ã«ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ïŒå¡åžå©å€ïŒã
å ããæŽã«éïŒã¢ã«ãããå1.7Ã10-3ã¢ã«ã®äž
èšç¬¬ïŒè¡šèšèŒã®ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å
ãã次ãã§ãããã®å¡åžæ¶²ã第ïŒè¡šã«èšèŒããæ¯
æäœäžã«å¡åžééã20mgïŒïœm2ã«ãªãããã«ããŠ
è©ŠæïŒïŒãïŒïŒãäœè£œããã
ãè¡šã
ãè¡šã
è©ŠæïŒïŒãïŒïŒã®åã
ã«ã€ã次ã«èšããã
ãã«ããŠã«ããªç¹æ§éç»åã®çµæå£åç¹æ§ã枬å®
ãããçµæã第ïŒè¡šã«èšãã (A) ã«ããªç¹æ§ã®æž¬å® è©ŠæïŒïŒãïŒïŒã50âã80ïŒ RHã®æç®±
äžã«å ¥ããŠïŒæ¥éæŸçœ®ããåŸåè©ŠæãMDAâ
ïŒïŒå¯å£«åçãã€ã«ã æå®çŸå液ïŒçŸå液ãçš
ããŠ27âã§ïŒåéæªé²å çŸåããåæ¢ãå®çã
æ°ŽæŽãè¡ã€ãŠåè©Šæã®ã«ããªæ¿åºŠã枬å®ããã (B) éç»åã®çµæå£åç¹æ§ã®æž¬å® è©ŠæïŒïŒãïŒïŒãã¹ããããŠãšããžãä»
ããŠé²å ããèªåçŸåæ©ïŒAPâïŒãå¯å£«åç
ãã€ã«ã (æ ª)補ïŒãçšããŠå¯å£«MDâ285çŸå液
ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã§30âã18ç§éçŸå
ããå®çãæ°ŽæŽã也ç¥ãè¡ã€ããåŠçæžã®åè©Š
æã宀枩ã80ïŒ RHã®éæãªç®±ã®äžã«24æéæŸ
眮ããã®ã¡ãåèšã®ç®±ã®äžã«éé žåæ°ŽçŽ æ°ŽïŒïŒ
ïŒ ïŒ20mlãããŒã«ãŒã«å ¥ããŠèšçœ®ãæŽã«æ宀äž
ã§20wã®èå ç¯ããã®å ãåœãŠãªããïŒæéæŸ
眮ããïŒãã®è©Šéšæ³ã¯Photographic Science
and Engineeringèªã第ïŒå·»253ã261é ïŒ1963
幎ïŒã®èšèŒã«äŸã€ããã®ã§ããïŒãæŸçœ®åŸç»å
éšã«çããéç»åã®å£åã®åºŠåã芳å¯ããå£å
ãéåžžã«å€§ããïŒÃÃïŒã倧ããïŒÃïŒãå°ã
ïŒâ³ïŒãããããŠå°ãïŒãïŒãå šããªãïŒããïŒ
ã®ïŒæ®µéã«è©äŸ¡ããã
ãã«ããŠã«ããªç¹æ§éç»åã®çµæå£åç¹æ§ã枬å®
ãããçµæã第ïŒè¡šã«èšãã (A) ã«ããªç¹æ§ã®æž¬å® è©ŠæïŒïŒãïŒïŒã50âã80ïŒ RHã®æç®±
äžã«å ¥ããŠïŒæ¥éæŸçœ®ããåŸåè©ŠæãMDAâ
ïŒïŒå¯å£«åçãã€ã«ã æå®çŸå液ïŒçŸå液ãçš
ããŠ27âã§ïŒåéæªé²å çŸåããåæ¢ãå®çã
æ°ŽæŽãè¡ã€ãŠåè©Šæã®ã«ããªæ¿åºŠã枬å®ããã (B) éç»åã®çµæå£åç¹æ§ã®æž¬å® è©ŠæïŒïŒãïŒïŒãã¹ããããŠãšããžãä»
ããŠé²å ããèªåçŸåæ©ïŒAPâïŒãå¯å£«åç
ãã€ã«ã (æ ª)補ïŒãçšããŠå¯å£«MDâ285çŸå液
ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã§30âã18ç§éçŸå
ããå®çãæ°ŽæŽã也ç¥ãè¡ã€ããåŠçæžã®åè©Š
æã宀枩ã80ïŒ RHã®éæãªç®±ã®äžã«24æéæŸ
眮ããã®ã¡ãåèšã®ç®±ã®äžã«éé žåæ°ŽçŽ æ°ŽïŒïŒ
ïŒ ïŒ20mlãããŒã«ãŒã«å ¥ããŠèšçœ®ãæŽã«æ宀äž
ã§20wã®èå ç¯ããã®å ãåœãŠãªããïŒæéæŸ
眮ããïŒãã®è©Šéšæ³ã¯Photographic Science
and Engineeringèªã第ïŒå·»253ã261é ïŒ1963
幎ïŒã®èšèŒã«äŸã€ããã®ã§ããïŒãæŸçœ®åŸç»å
éšã«çããéç»åã®å£åã®åºŠåã芳å¯ããå£å
ãéåžžã«å€§ããïŒÃÃïŒã倧ããïŒÃïŒãå°ã
ïŒâ³ïŒãããããŠå°ãïŒãïŒãå šããªãïŒããïŒ
ã®ïŒæ®µéã«è©äŸ¡ããã
ãè¡šã
ãè¡šã
第ïŒè¡šããæãããªããã«ãããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã€ã«ã ããŒã¹ïŒæ°Žäžæµžéæ§ã®æ¯æ
äœïŒãçšããå Žåã¯ã氎溶æ§åºãæããªãã¡ã«ã«
ããç³»ã«ããªé²æ¢å€ã䜿çšãããšéç»åã®å£åã
çãããïŒè©ŠæïŒïŒãïŒïŒïŒããŸã氎溶æ§åºã¯æ
ãããäžè¬åŒïŒïŒä»¥å€ã®æ§é ãæã€ã¡ã«ã«ãã
ç³»ã«ããªé²æ¢å€ã䜿çšããŠãéç»åã®å£åã¯é¿ã
ãããªãïŒè©ŠæïŒïŒïŒãäžæ¹ãã¡ã«ã«ããç³»ã«ã
ãªé²æ¢å€ãæ·»å ããªããã°éç»åã®å£åã¯çããª
ããã«ããªã倧ããåçãšããŠã®äœ¿çšã«èããªã
ïŒè©ŠæïŒïŒïŒã ããã«å¯ŸããŠãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã
ãŠæ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©ãå«
æããè©ŠæïŒïŒãïŒïŒã¯ã«ããªã®çºçããªã
ããã«éç»åã®å£åãçããªããšããé¡èãªå¹æ
ãåŸãããããããŠæ¬çºæã®äžã§ã氎溶æ§åºãšã
ãŠã¹ã«ãåºåã¯ã«ã«ããã·åºãæã€ååç©ããã
奜ãŸãããæŽã«äžè¬åŒïŒïŒã§è¡šããããååç©
ããã奜ããããšããããã å®æœäŸ ïŒ ããã«ãžãšããæ³ã§ç²åæ²æ®¿ãããéåžžã®æ¹æ³
ã§ç©ççæããè±å¡©åŠçããæŽã«ç¡«é»å¢æããã
é žæ§æ³å¡©èåéä¹³å€ïŒèåé50ã¢ã«ïŒ ïŒã«ïŒïŒïŒ
âãžã¯ããâïŒâããããã·âïŒïŒïŒïŒïŒâããª
ã¢ãžã³ãããªãŠã å¡©ïŒç¡¬èå€ïŒåã³ããã·ã«ãã³
ãŒã³ã¹ã«ãã³é žãããªãŠã ïŒå¡åžå©å€ïŒãå ãã
æŽã«éïŒã¢ã«ãããå1.7Ã10-3ã¢ã«ã®äžèšç¬¬ïŒ
è¡šèšèŒã®ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å ãã次
ãã§ãããã®å¡åžæ¶²ãããªãšãã¬ã³ã§äž¡é¢ã¢ãã
ãŒãããçŽæ¯æäœäžã«å¡åžééã16mgïŒïœm2ã«ãª
ãããã«å¡åžããŠè©ŠæïŒXIïŒãïŒïŒãäœè£œã
ãã ãããè©ŠæïŒXIïŒãïŒïŒã®åã ã«ã€ã次ã«
èšããããã«ããŠã«ããªç¹æ§ãåã³éç»åã®çµæ
å£åç¹æ§ã枬å®ãããçµæã第ïŒè¡šã«èšãã (A) ã«ããªç¹æ§ã®æž¬å® å®æœäŸïŒã®ã«ããªç¹æ§ã®æž¬å®æ³ã«ãããæŸçœ®
æéãïŒæ¥éãšããæªé²å çŸåãããããŒã«
ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒãïŒïŒïŒã®æ¯çã§æ°Ž
ã§çšéããçŸå液ã䜿ã30âãïŒåéè¡ã以å€
ã¯åãæ§ã«æäœããŠãåå°æ¿åºŠã枬å®ããã (B) éç»åã®çµæå£åç¹æ§ã®æž¬å® è©ŠæïŒXIïŒãïŒïŒãã¹ããããŠãšããžã
ä»ããŠé²å ãèªåçŸåæ©ãçšããŠå¯å£«DPâã
ãããŒã«ïŒ£çŸå液ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã§
32âã24ç§éçŸåããå®çãæ°ŽæŽã也ç¥ãè¡ã€
ããåŠçæžã®åè©Šæãè±åœç¹èš±ïŒå ¬éïŒç¬¬
2019024Aå·æ现æžã«èšèŒãããããã«äºé žå
çªçŽ ã¬ã¹ïŒ3000ppmïŒé°å²æ°ã®ãã€ããããäž
ã«20åéæŸçœ®ããããšæžå€ïŒæ¥å äžïŒã«ïŒæ¥é
æŸçœ®ãããæŸçœ®åŸç»åéšã«çããéç»åã®å£å
ã®åºŠåã枬å®ãå®æœäŸïŒãšåæ§ã«è©äŸ¡ããã
ãã¿ã¬ãŒããã€ã«ã ããŒã¹ïŒæ°Žäžæµžéæ§ã®æ¯æ
äœïŒãçšããå Žåã¯ã氎溶æ§åºãæããªãã¡ã«ã«
ããç³»ã«ããªé²æ¢å€ã䜿çšãããšéç»åã®å£åã
çãããïŒè©ŠæïŒïŒãïŒïŒïŒããŸã氎溶æ§åºã¯æ
ãããäžè¬åŒïŒïŒä»¥å€ã®æ§é ãæã€ã¡ã«ã«ãã
ç³»ã«ããªé²æ¢å€ã䜿çšããŠãéç»åã®å£åã¯é¿ã
ãããªãïŒè©ŠæïŒïŒïŒãäžæ¹ãã¡ã«ã«ããç³»ã«ã
ãªé²æ¢å€ãæ·»å ããªããã°éç»åã®å£åã¯çããª
ããã«ããªã倧ããåçãšããŠã®äœ¿çšã«èããªã
ïŒè©ŠæïŒïŒïŒã ããã«å¯ŸããŠãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã
ãŠæ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©ãå«
æããè©ŠæïŒïŒãïŒïŒã¯ã«ããªã®çºçããªã
ããã«éç»åã®å£åãçããªããšããé¡èãªå¹æ
ãåŸãããããããŠæ¬çºæã®äžã§ã氎溶æ§åºãšã
ãŠã¹ã«ãåºåã¯ã«ã«ããã·åºãæã€ååç©ããã
奜ãŸãããæŽã«äžè¬åŒïŒïŒã§è¡šããããååç©
ããã奜ããããšããããã å®æœäŸ ïŒ ããã«ãžãšããæ³ã§ç²åæ²æ®¿ãããéåžžã®æ¹æ³
ã§ç©ççæããè±å¡©åŠçããæŽã«ç¡«é»å¢æããã
é žæ§æ³å¡©èåéä¹³å€ïŒèåé50ã¢ã«ïŒ ïŒã«ïŒïŒïŒ
âãžã¯ããâïŒâããããã·âïŒïŒïŒïŒïŒâããª
ã¢ãžã³ãããªãŠã å¡©ïŒç¡¬èå€ïŒåã³ããã·ã«ãã³
ãŒã³ã¹ã«ãã³é žãããªãŠã ïŒå¡åžå©å€ïŒãå ãã
æŽã«éïŒã¢ã«ãããå1.7Ã10-3ã¢ã«ã®äžèšç¬¬ïŒ
è¡šèšèŒã®ã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å ãã次
ãã§ãããã®å¡åžæ¶²ãããªãšãã¬ã³ã§äž¡é¢ã¢ãã
ãŒãããçŽæ¯æäœäžã«å¡åžééã16mgïŒïœm2ã«ãª
ãããã«å¡åžããŠè©ŠæïŒXIïŒãïŒïŒãäœè£œã
ãã ãããè©ŠæïŒXIïŒãïŒïŒã®åã ã«ã€ã次ã«
èšããããã«ããŠã«ããªç¹æ§ãåã³éç»åã®çµæ
å£åç¹æ§ã枬å®ãããçµæã第ïŒè¡šã«èšãã (A) ã«ããªç¹æ§ã®æž¬å® å®æœäŸïŒã®ã«ããªç¹æ§ã®æž¬å®æ³ã«ãããæŸçœ®
æéãïŒæ¥éãšããæªé²å çŸåãããããŒã«
ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒãïŒïŒïŒã®æ¯çã§æ°Ž
ã§çšéããçŸå液ã䜿ã30âãïŒåéè¡ã以å€
ã¯åãæ§ã«æäœããŠãåå°æ¿åºŠã枬å®ããã (B) éç»åã®çµæå£åç¹æ§ã®æž¬å® è©ŠæïŒXIïŒãïŒïŒãã¹ããããŠãšããžã
ä»ããŠé²å ãèªåçŸåæ©ãçšããŠå¯å£«DPâã
ãããŒã«ïŒ£çŸå液ïŒå¯å£«åçãã€ã«ã (æ ª)補ïŒã§
32âã24ç§éçŸåããå®çãæ°ŽæŽã也ç¥ãè¡ã€
ããåŠçæžã®åè©Šæãè±åœç¹èš±ïŒå ¬éïŒç¬¬
2019024Aå·æ现æžã«èšèŒãããããã«äºé žå
çªçŽ ã¬ã¹ïŒ3000ppmïŒé°å²æ°ã®ãã€ããããäž
ã«20åéæŸçœ®ããããšæžå€ïŒæ¥å äžïŒã«ïŒæ¥é
æŸçœ®ãããæŸçœ®åŸç»åéšã«çããéç»åã®å£å
ã®åºŠåã枬å®ãå®æœäŸïŒãšåæ§ã«è©äŸ¡ããã
ãè¡šã
第ïŒè¡šãããããªãšãã¬ã³ã§äž¡é¢ã©ãããŒãã
ããçŽæ¯æäœãçšããå Žåã¯ã氎溶æ§åºããããª
ãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å ãããšéç»å
ã®å£åãçãããïŒè©ŠæïŒXIïŒïŒããŸã氎溶æ§åºã¯
æã€ãæ¬çºæã®äžè¬åŒïŒïŒä»¥å€ã®æ§é ãæã€ã¡
ã«ã«ããç³»ã«ããªé²æ¢å€ãçšããŠãéç»åã®å£å
ã¯é¿ããããªãïŒè©ŠæïŒXIIïŒïŒã ããã«å¯ŸããŠãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã
ãŠæ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©ãå«
æããè©ŠæïŒïŒãïŒïŒåã³ïŒïŒã¯ã«ã
ãªã®çºçããªãéç»åã®å£åãçããªããšããé¡
èãªå¹æãåŸããããåŸã€ãŠæ¬çºæã«ããå¹æã¯
極ããŠç¹ç°ãªãã®ã§ããããšãããã€ãã
ããçŽæ¯æäœãçšããå Žåã¯ã氎溶æ§åºããããª
ãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãæ·»å ãããšéç»å
ã®å£åãçãããïŒè©ŠæïŒXIïŒïŒããŸã氎溶æ§åºã¯
æã€ãæ¬çºæã®äžè¬åŒïŒïŒä»¥å€ã®æ§é ãæã€ã¡
ã«ã«ããç³»ã«ããªé²æ¢å€ãçšããŠãéç»åã®å£å
ã¯é¿ããããªãïŒè©ŠæïŒXIIïŒïŒã ããã«å¯ŸããŠãã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãšã
ãŠæ¬çºæã®äžè¬åŒïŒïŒã§è¡šããããååç©ãå«
æããè©ŠæïŒïŒãïŒïŒåã³ïŒïŒã¯ã«ã
ãªã®çºçããªãéç»åã®å£åãçããªããšããé¡
èãªå¹æãåŸããããåŸã€ãŠæ¬çºæã«ããå¹æã¯
極ããŠç¹ç°ãªãã®ã§ããããšãããã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ çœè²åãã©ã¹ããã¯ãã€ã«ã åã¯çæ°Žæ§é«å
åã§äž¡é¢ãã©ãããŒãããçŽæ¯æäœã®äžã«å°ãªã
ãšãïŒå±€ã®ããã²ã³åéä¹³å€å±€ãæããé»çœçšå
çå°ç»çŽã«ãããŠã該乳å€å±€åã¯ãã®é£æ¥å±€äžã«
æ·»å ãããã¡ã«ã«ããç³»ã«ããªé²æ¢å€ãäžèšäžè¬
åŒïŒïŒã§è¡šããããååç©ã§ããããšãç¹åŸŽãš
ããé»çœçšåçå°ç»çŽ äžè¬åŒïŒïŒ åŒäžãïŒã¯æ°ŽçŽ ååãâNH4åºåã¯ã¢ã«ã«ãª
éå±ãè¡šãããã¯æ°ŽçŽ ååãã¢ã«ãã«åºåã¯
ã¢ãªãŒã«åºãè¡šãããã¯çœ®æåºãæããŠãã
ãïŒå¡ã®è€çŽ ç°åã¯ãã³ãŒã³ç°ãçž®åããïŒå¡
ã®è€çŽ ç°ã圢æããã®ã«å¿ èŠãªåå矀ãè¡šã
ãã äœãã該åŒäžã®å°ãªããšãïŒåã®ççŽ ååã¯
ã«ã«ããã·åºãããã¯ãã®å¡©ãã«ã«ãã¢ã€ã«
åºãããããã·åºãã¹ã«ãåºãããã¯ãã®å¡©ã
ã¢ããåºåã³äœçŽã¢ã«ã³ãã·åºããéžã°ããåº
ãšçµåããŠãããã®ãšããã
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8986280A JPS5714836A (en) | 1980-07-01 | 1980-07-01 | Photographic sensitive silver halide material |
| DE19813125707 DE3125707A1 (de) | 1980-07-01 | 1981-06-30 | Photographische lichtempfindliche silberhalogenidelemente |
| GB8120210A GB2080963B (en) | 1980-07-01 | 1981-06-30 | Silver halide photographic light-sensitive elements |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8986280A JPS5714836A (en) | 1980-07-01 | 1980-07-01 | Photographic sensitive silver halide material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5714836A JPS5714836A (en) | 1982-01-26 |
| JPS6359129B2 true JPS6359129B2 (ja) | 1988-11-17 |
Family
ID=13982585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8986280A Granted JPS5714836A (en) | 1980-07-01 | 1980-07-01 | Photographic sensitive silver halide material |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5714836A (ja) |
| DE (1) | DE3125707A1 (ja) |
| GB (1) | GB2080963B (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5971047A (ja) * | 1982-10-18 | 1984-04-21 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææã®çŸååŠçæ¹æ³ |
| GB2153101B (en) * | 1983-11-08 | 1986-09-24 | Fuji Photo Film Co Ltd | Silver halide photographic light-sensitive material |
| GB2176304B (en) * | 1985-06-07 | 1989-12-06 | Fuji Photo Film Co Ltd | Silver halide photographic emulsions |
| JPS622248A (ja) * | 1985-06-27 | 1987-01-08 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéåçæå ææ |
| JPS6259952A (ja) * | 1985-09-11 | 1987-03-16 | Konishiroku Photo Ind Co Ltd | ããã²ã³åéé»çœåçæå ææã®åŠçæ¹æ³ |
| JPH077194B2 (ja) * | 1986-05-19 | 1995-01-30 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ã«ã©âç»å圢ææ¹æ³ããã³ããã²ã³åéã«ã©âåçæå ææ |
| JPH0727210B2 (ja) * | 1987-02-13 | 1995-03-29 | äžè±è£œçŽæ ªåŒäŒç€Ÿ | å¹³çå°å·ç |
| JPS6413539A (en) * | 1987-07-07 | 1989-01-18 | Mitsubishi Paper Mills Ltd | Silver halide photographic sensitive material |
| JPS63265241A (ja) * | 1987-04-23 | 1988-11-01 | Fuji Photo Film Co Ltd | ããã²ã³åéåçæå ææã®åŠçæ¹æ³ |
| JPH07119943B2 (ja) * | 1987-12-29 | 1995-12-20 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææ |
| US5284740A (en) * | 1989-01-20 | 1994-02-08 | Fuji Photo Film Co., Ltd. | Silver halide color photographic material |
| JP2703121B2 (ja) * | 1990-04-27 | 1998-01-26 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
| JP5425930B2 (ja) | 2009-11-18 | 2014-02-26 | ååé ç²Ÿæ ªåŒäŒç€Ÿ | é»æ°æ³³ååææ¹æ³ |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5348723A (en) * | 1976-10-15 | 1978-05-02 | Konishiroku Photo Ind Co Ltd | Silver halide photographic photosensitive material |
| JPS53127714A (en) * | 1977-04-13 | 1978-11-08 | Mitsubishi Paper Mills Ltd | Sunk image stabilising method |
| JPS54119917A (en) * | 1978-03-10 | 1979-09-18 | Konishiroku Photo Ind Co Ltd | Photosensitive material of silver halide for photography |
-
1980
- 1980-07-01 JP JP8986280A patent/JPS5714836A/ja active Granted
-
1981
- 1981-06-30 DE DE19813125707 patent/DE3125707A1/de not_active Withdrawn
- 1981-06-30 GB GB8120210A patent/GB2080963B/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5348723A (en) * | 1976-10-15 | 1978-05-02 | Konishiroku Photo Ind Co Ltd | Silver halide photographic photosensitive material |
| JPS53127714A (en) * | 1977-04-13 | 1978-11-08 | Mitsubishi Paper Mills Ltd | Sunk image stabilising method |
| JPS54119917A (en) * | 1978-03-10 | 1979-09-18 | Konishiroku Photo Ind Co Ltd | Photosensitive material of silver halide for photography |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3125707A1 (de) | 1982-04-08 |
| JPS5714836A (en) | 1982-01-26 |
| GB2080963A (en) | 1982-02-10 |
| GB2080963B (en) | 1985-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4668605A (en) | Method for formation of high contrast negative images | |
| JPS61267759A (ja) | ãã¬ãã£ãç»åã®åœ¢ææ¹æ³åã³çŸå液 | |
| JPH0571082B2 (ja) | ||
| JPH0571927B2 (ja) | ||
| JPS6359129B2 (ja) | ||
| JPH042935B2 (ja) | ||
| JPH0473858B2 (ja) | ||
| JPS6140092B2 (ja) | ||
| JPH0677130B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH02132432A (ja) | ããã²ã³åéåçæå ææåã³ãããçšããç»å圢ææ¹æ³ | |
| JPH034890B2 (ja) | ||
| JPH0961972A (ja) | ããã²ã³åéåçæå ææã®åŠçæ¹æ³ | |
| JPH0548895B2 (ja) | ||
| JPH0548894B2 (ja) | ||
| JPH0269736A (ja) | ããã²ã³åéåçæå ææåã³åŠçæ¹æ³ | |
| JP3051898B2 (ja) | ããã²ã³åéåçæå ææåã³ãã®çŸååŠçæ¹ | |
| JPS6329749A (ja) | ããã²ã³åéåçæå ææ | |
| JPS60192936A (ja) | ããã²ã³åéåçæå ææ | |
| JPH02124559A (ja) | ãã¬åããã²ã³åéåçæå ææ | |
| JPH0778608B2 (ja) | é»çœçšããã²ã³åéåçæå ææ | |
| JPS63201646A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0255348A (ja) | ããã²ã³åéåçæå ææåã³ãããçšããç»å圢ææ¹æ³ | |
| JPH0380294B2 (ja) | ||
| JPH0444027A (ja) | èå§æ§ãæ¹è¯ãããããã²ã³åéåçæå ææ | |
| JPH1069035A (ja) | ããã²ã³åéåçæå ææã®åŠçæ¹æ³ |