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JPH08502303A - 長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法 - Google Patents

長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法

Info

Publication number
JPH08502303A
JPH08502303A JP6509106A JP50910694A JPH08502303A JP H08502303 A JPH08502303 A JP H08502303A JP 6509106 A JP6509106 A JP 6509106A JP 50910694 A JP50910694 A JP 50910694A JP H08502303 A JPH08502303 A JP H08502303A
Authority
JP
Japan
Prior art keywords
polymer
group
catalyst
branched
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6509106A
Other languages
English (en)
Japanese (ja)
Inventor
ブラント、パトリック
キャニック、ジョー・アン・メアリー
ディアス、アンソニー・ジェイ
バームバーガ、ロバート・リー
リシアルディ、ゲアリー・フレデリック
ヘンドリクス、ポール・マーク
Original Assignee
エクソン・ケミカル・パテンツ・インク
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by エクソン・ケミカル・パテンツ・インク filed Critical エクソン・ケミカル・パテンツ・インク
Publication of JPH08502303A publication Critical patent/JPH08502303A/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • C08F290/042—Polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
JP6509106A 1992-09-29 1993-09-17 長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法 Pending JPH08502303A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US95453992A 1992-09-29 1992-09-29
US07/954,539 1992-09-29
PCT/US1993/008833 WO1994007930A1 (fr) 1992-09-29 1993-09-17 Polymeres a chaines ramifiees longues et leur procede de fabrication

Publications (1)

Publication Number Publication Date
JPH08502303A true JPH08502303A (ja) 1996-03-12

Family

ID=25495576

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6509106A Pending JPH08502303A (ja) 1992-09-29 1993-09-17 長鎖分岐ポリマー及び長鎖分岐ポリマーを製造する方法

Country Status (7)

Country Link
EP (1) EP0662980A1 (fr)
JP (1) JPH08502303A (fr)
KR (1) KR950703595A (fr)
AU (1) AU4928993A (fr)
CA (1) CA2145635A1 (fr)
RU (1) RU95110681A (fr)
WO (1) WO1994007930A1 (fr)

Cited By (16)

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WO2002008306A1 (fr) 2000-07-26 2002-01-31 Mitsui Chemicals, Inc. Polymere et son procede de production
JP2002523575A (ja) * 1998-08-26 2002-07-30 エクソンモービル・ケミカル・パテンツ・インク 分枝ポリプロピレン組成物
JP2003518523A (ja) * 1999-07-29 2003-06-10 ザ ダウ ケミカル カンパニー 改良されたシラン官能基含有オレフィンインターポリマー及びその誘導体
JP2004346304A (ja) * 2003-04-28 2004-12-09 Tosoh Corp ポリエチレンおよびその製造方法
JP2005248013A (ja) * 2004-03-04 2005-09-15 Tosoh Corp 粒子状ポリエチレンおよびその製造方法
JP2006152091A (ja) * 2004-11-26 2006-06-15 Tosoh Corp 耐熱性フィルム
JP2006168225A (ja) * 2004-12-16 2006-06-29 Tosoh Corp 易引き裂き性フィルム
JP2006299167A (ja) * 2005-04-22 2006-11-02 Tosoh Corp インフレーションフィルム
WO2009066689A1 (fr) 2007-11-19 2009-05-28 Mitsui Chemicals, Inc. Composé métallocène ponté, catalyseur de polymérisation d'oléfines utilisant le composé et polymère de l'éthylène obtenu à l'aide du catalyseur
JP2010037417A (ja) * 2008-08-04 2010-02-18 Tosoh Corp オレフィン重合用触媒およびポリオレフィンの製造方法
KR101124271B1 (ko) * 2003-04-28 2012-03-27 도소 가부시키가이샤 폴리에틸렌 조성물 및 그 제조방법
JP2012139848A (ja) * 2010-12-28 2012-07-26 Japan Polyethylene Corp 包装材料およびそれを用いた液体包装袋
KR20160108586A (ko) 2014-12-09 2016-09-19 미쯔이가가꾸가부시끼가이샤 프로필렌계 수지 조성물
JP2018525504A (ja) * 2015-08-25 2018-09-06 エクソンモービル・ケミカル・パテンツ・インク その場で油生成を伴うエチレンコポリマー
KR102363604B1 (ko) * 2021-06-29 2022-02-15 세종대학교산학협력단 아지도 포르메이트의 무촉매 C-H 삽입 반응을 통해 제조된 긴 사슬 가지 달린 α-올레핀 중합체 및 그의 제조방법
WO2023277333A1 (fr) * 2021-06-29 2023-01-05 세종대학교산학협력단 POLYMÈRE D'α-OLÉFINE RAMIFIÉ À LONGUE CHAÎNE PRÉPARÉ PAR RÉACTION D'INSERTION DE C-H NON CATALYTIQUE DE FORMIATE D'AZIDE, ET PROCÉDÉ POUR LE PRÉPARER

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WO2003020779A1 (fr) 2001-08-31 2003-03-13 Kaneka Corporation Copolymere greffe de polyolefine produit avec un catalyseur de polymerisation de coordination a base d'un complexe de metal de transition apparaissant dans une periode ulterieure et procede pour preparer ce copolymere
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
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WO2006120418A1 (fr) * 2005-05-10 2006-11-16 Ineos Europe Limited Copolymeres innovants
AR060641A1 (es) 2006-05-17 2008-07-02 Dow Global Technologies Inc Proceso de polimerizacion de solucion de polietileno de alta temperatura
US8921466B2 (en) 2010-01-15 2014-12-30 Reliance Industries Limited Concurrent solid and melt state grafting of coagents for making long chain branched polypropylene via direct reactive extrusion process
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KR101747396B1 (ko) 2014-12-15 2017-06-14 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
WO2017165009A1 (fr) 2016-03-23 2017-09-28 Exxonmobil Chemical Patents, Inc. Polyéthylènes haute densité séquencés en peigne et leurs procédés de fabrication
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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002523575A (ja) * 1998-08-26 2002-07-30 エクソンモービル・ケミカル・パテンツ・インク 分枝ポリプロピレン組成物
JP2003518523A (ja) * 1999-07-29 2003-06-10 ザ ダウ ケミカル カンパニー 改良されたシラン官能基含有オレフィンインターポリマー及びその誘導体
US6995229B2 (en) 2000-07-26 2006-02-07 Mitsui Chemicals, Inc. Polymer and process for producing the same
WO2002008306A1 (fr) 2000-07-26 2002-01-31 Mitsui Chemicals, Inc. Polymere et son procede de production
JP2004346304A (ja) * 2003-04-28 2004-12-09 Tosoh Corp ポリエチレンおよびその製造方法
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WO1994007930A1 (fr) 1994-04-14
EP0662980A1 (fr) 1995-07-19
AU4928993A (en) 1994-04-26
CA2145635A1 (fr) 1994-04-14
KR950703595A (ko) 1995-09-20

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