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JPH0517710A - Metallic paint and method for coating therewith - Google Patents

Metallic paint and method for coating therewith

Info

Publication number
JPH0517710A
JPH0517710A JP19344191A JP19344191A JPH0517710A JP H0517710 A JPH0517710 A JP H0517710A JP 19344191 A JP19344191 A JP 19344191A JP 19344191 A JP19344191 A JP 19344191A JP H0517710 A JPH0517710 A JP H0517710A
Authority
JP
Japan
Prior art keywords
coating
metallic
coated
silver
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19344191A
Other languages
Japanese (ja)
Inventor
Norio Fujita
則男 藤田
Masahiro Endo
正浩 遠藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Paint Co Ltd
Original Assignee
Kansai Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Paint Co Ltd filed Critical Kansai Paint Co Ltd
Priority to JP19344191A priority Critical patent/JPH0517710A/en
Publication of JPH0517710A publication Critical patent/JPH0517710A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0078—Pigments consisting of flaky, non-metallic substrates, characterised by a surface-region containing free metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE:To obtain a new paint capable of forming a coating film having medium tone and exhibiting strong glitter by successively coating the surface of a glass flake with silver and nickel in the order and using the obtained flaky particle as metallic pigment. CONSTITUTION:A glass flake preferably having a longitudinal dimension of 5-40mum and a thickness of 1/5 to 1/20 of the longitudinal dimension is used as a core, the surface of the core is coated with preferably pure silver by electroless plating, etc., to a thickness of 0.01-0.3mum (especially 0.02-0.3mum) and the coated surface is further coated with pure nickel under the same condition to the same thickness and the obtained flaky particle is used as a component of the objective paint.

Description

【発明の詳細な説明】Detailed Description of the Invention

【０００１】[0001]

【産業上の利用分野】本発明は新規なメタリック塗料お
よびその塗装方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a novel metallic paint and its coating method.

【０００２】[0002]

【従来の技術及びその課題】メタリック塗料による塗膜
は、該塗膜中に含有せしめたリン片状のメタリック顔料
に外部からの入射光が反射してキラキラと輝き、該塗膜
の各種色調と相俟って変化に富んだ美粧性にすぐれた独
特の外観を呈し、特に自動車、オートバイなどの外板に
多く施されている。2. Description of the Related Art A coating film made of a metallic paint has a scaly metallic pigment contained in the coating film which reflects incident light from the outside and shines brightly. Together, they have a unique appearance with a wide variety of aesthetic appeal, and are often applied to the outer panels of automobiles and motorcycles in particular.

【０００３】従来、上記メタリック顔料として、リン片
状のアルミニウム粉；酸化チタンや酸化鉄などの金属酸
化物によって被覆された雲母片粒子；グラファイト粒
子；α−酸化鉄結晶粒子を主成分とする酸化鉄粒子；な
どが多く用いられている。しかしながら、これらのメタ
リック顔料では通常の光輝性（キラキラと輝く感じ）を
有しているが、さらにこれらよりも強い光輝性を呈する
メタリック塗膜の開発が望まれており、これらのメタリ
ック顔料では不十分であった。また、これらのうち、光
輝性にすぐれた酸化鉄粒子は比重が大きく塗料中で沈降
しやすいという問題点を有している。Conventionally, as the metallic pigment, flaky aluminum powder; mica flakes particles coated with a metal oxide such as titanium oxide or iron oxide; graphite particles; oxidation mainly composed of α-iron oxide crystal particles. Iron particles; etc. are often used. However, although these metallic pigments have a normal glittering property (glittering feeling), it is desired to develop a metallic coating film exhibiting a glittering property stronger than these, and these metallic pigments are not suitable. Was enough. Further, among these, iron oxide particles having excellent glitter have a problem that they have a large specific gravity and tend to settle in the coating material.

【０００４】[0004]

【課題を解決するための手段】本発明の目的は強い光輝
性を呈することができ、しかも上記した欠陥のすべてを
解消したメタリック塗料およびその塗装法を開発すると
ころにあり、鋭意研究の結果、メタリック顔料として銀
およびニッケルで複層被覆したガラスフレークを用いる
ことによって上記目的が達成できることを見い出し本発
明を完成した。The object of the present invention is to develop a metallic paint capable of exhibiting a strong luster and to eliminate all of the above-mentioned defects and a coating method therefor. As a result of earnest research, The present invention has been completed by finding that the above object can be achieved by using glass flakes coated with silver and nickel in multiple layers as the metallic pigment.

【０００５】すなわち、本発明は、（１）ガラスフレー
クの表面を銀およびニッケルの順で複層被覆してなるり
ん片状粒子をメタリック顔料として含有せしめてなるメ
タリック塗料、および（２）メタリック塗料を塗装し、
次いで該塗面にクリヤー塗料を塗装する工程において、
該メタリック塗料のメタリック顔料がガラスフレークの
表面を銀およびニッケルの順で複層被覆してなるりん片
状粒子であることを特徴とするメタリック塗装法に関す
る。That is, the present invention relates to (1) a metallic paint containing glass flakes having a surface coated with a plurality of layers of silver and nickel in this order as a metallic pigment, and (2) a metallic paint. Painted,
Then, in the step of applying a clear paint on the coated surface,
The present invention relates to a metallic coating method, wherein the metallic pigment of the metallic paint is flaky particles obtained by coating the surfaces of glass flakes with silver and nickel in this order.

【０００６】本発明におけるメタリック塗料は、特定の
メタリック顔料、ビヒクル成分および溶剤を主成分とす
る液状塗料であり、さらに必要に応じて着色顔料などを
配合することもできる。The metallic coating material of the present invention is a liquid coating material containing a specific metallic pigment, a vehicle component and a solvent as the main components, and a coloring pigment and the like can be blended if necessary.

【０００７】本発明で用いるメタリック顔料は、ガラス
フレークの表面に銀およびニッケルの順で複層に被覆し
てなる光輝性顔料である。具体的には、ガラスフレーク
を芯部とし、まずその表面を銀で被覆し、次いでその銀
の表面をニッケルで被覆してなり、つまりガラスフレー
クの表面に銀層およびニッケル層を設けた顔料である。
芯部のガラスフレークはりん片状ガラス粒子であって、
その大きさは長手方向寸法が５〜４０μ、厚さは長手方
向の１／５〜１／２０の範囲が好ましく、ＳｉＯ2を主
成分とし、ＺｎＯやＢ2Ｏ2およびその他の成分を若干量
含むことがある。また該ガラスフレークの表面を銀で被
覆する方法としては無電界メッキが適している。被覆量
は、銀の膜厚に基いて０．０１〜０．３μ、特に０．０
２〜０．３μが好ましい。被覆する銀は純銀であること
が好ましいが、これのみに限定されない。さらに、銀被
覆したガラスフレークの表面にニッケルを被覆する方法
は、ニッケルを用いること以外は被覆量も含めて上記銀
被覆と同様な方法で行える。被覆するニッケルは純ニッ
ケルが好ましいが、これのみに限定されない。また、こ
のように複数被覆したガラスフレークは、その表面を適
宜表面処理しておくことが好ましい。The metallic pigment used in the present invention is a bright pigment in which the surface of glass flake is coated with a plurality of layers in the order of silver and nickel. Specifically, a glass flake is used as a core, the surface of which is first coated with silver, and then the surface of silver is coated with nickel, that is, a pigment in which a silver layer and a nickel layer are provided on the surface of the glass flake. is there.
The glass flakes of the core are flaky glass particles,
The size is preferably 5 to 40 μm in the longitudinal direction, and the thickness is preferably in the range of 1/5 to 1/20 in the longitudinal direction. SiO 2 is the main component and ZnO, B 2 O 2 and other components are slightly contained. May be included. Electroless plating is suitable as a method for coating the surface of the glass flakes with silver. The coating amount is 0.01 to 0.3 μ, particularly 0.0 based on the thickness of silver.
2 to 0.3 μ is preferable. The silver to be coated is preferably pure silver, but is not limited thereto. Further, the method of coating the surface of the silver-coated glass flake with nickel can be performed in the same manner as the silver coating, including the coating amount, except that nickel is used. The nickel to be coated is preferably pure nickel, but is not limited thereto. In addition, it is preferable that the surface of the glass flakes thus coated with a plurality of pieces is appropriately surface-treated.

【０００８】ビヒクル成分は基体樹脂と架橋剤とを主成
分とする架橋硬化性樹脂組成物が好ましく、基体樹脂と
しては架橋性官能基を有するアクリル樹脂、ポリエステ
ル樹脂又はアルキド樹脂などがあげられ、架橋剤として
はメチロール化および（又は）アルキルエーテル化メラ
ミン樹脂や尿素樹脂、ポリイソシアネート化合物（ブロ
ック化物も含む）が好ましい。また、自己硬化性樹脂や
熱可塑性樹脂も使用できる。The vehicle component is preferably a crosslinkable curable resin composition containing a base resin and a crosslinking agent as main components, and examples of the base resin include acrylic resins, polyester resins and alkyd resins having a crosslinkable functional group. As the agent, a methylolated and / or alkyl etherified melamine resin, a urea resin, and a polyisocyanate compound (including a blocked compound) are preferable. Further, a self-curing resin or a thermoplastic resin can also be used.

【０００９】溶剤としては塗料用有機溶剤および（又
は）水が使用できる。Organic solvents for paints and / or water can be used as the solvent.

【００１０】本発明において、ニッケルなどを被覆した
ガラスフレーク（メタリック顔料）の配合量はビヒクル
成分１００重量部（固形分）あたり０．１〜３０重量部
が好ましい。In the present invention, the amount of glass flake (metallic pigment) coated with nickel or the like is preferably 0.1 to 30 parts by weight per 100 parts by weight (solid content) of the vehicle component.

【００１１】本発明のメタリック塗料は上記各成分に、
さらに必要に応じて着色顔料、他のメタリック顔料（例
えば、アルミニウム顔料、酸化鉄顔料など）および干渉
色顔料（例えば、マイカ、金属酸化物で被覆したマイカ
など）から選ばれた１種又は２種以上を上記ニッケルな
どを被覆したガラスフレーク状メタリック顔料に基づく
メタリック感を阻害しない程度に配合することができ
る。The metallic paint of the present invention contains the above-mentioned components,
Further, if necessary, one or two selected from color pigments, other metallic pigments (eg, aluminum pigments, iron oxide pigments, etc.) and interference color pigments (eg, mica, mica coated with metal oxides, etc.). The above can be blended to such an extent that the metallic feel of the glass flake metallic pigment coated with nickel or the like is not impaired.

【００１２】本発明のメタリック塗料の形態は有機溶液
型、ハイソリッド型、非水分散液型、水溶液型および水
分散型などがあげられ、それ自体既知の方法で調製でき
る。Examples of the form of the metallic coating material of the present invention include an organic solution type, a high solid type, a non-aqueous dispersion type, an aqueous solution type and a water dispersion type, which can be prepared by a method known per se.

【００１３】本発明のメタリック塗装法は上記本発明の
メタリック塗料を塗装し、次いで該塗面にクリヤー塗料
を塗装するところに特徴がある。The metallic coating method of the present invention is characterized in that the metallic coating material of the present invention is applied, and then a clear coating material is applied to the coated surface.

【００１４】クリヤー塗料は基体樹脂および架橋剤を主
成分とし、さらに必要に応じて有機溶剤、水、顔料など
を配合してなる透明塗膜を形成する塗料で、それ自体既
知のものが使用できる。The clear coating composition is a coating composition containing a base resin and a cross-linking agent as main components, and if necessary, an organic solvent, water, a pigment and the like to form a transparent coating film, which can be known per se. .

【００１５】クリヤー塗料における基体樹脂は耐候性、
平滑性、鮮映性などのすぐれたものが好ましく、例えば
アクリル樹脂、ポリエステル樹脂、アルキド樹脂および
フッ素樹脂などがあげられ、これらは架橋剤と反応しう
る官能基（例えば、水酸基、カルボキシル基、エポキシ
基、グリシジル基）を有していることが好ましい。架橋
剤は該基体樹脂と反応し、三次元に架橋硬化させるため
のもので、具体的にはメチロール化および（又は）アル
キルエーテル化メラミン樹脂や尿素樹脂、ポリイソシア
ネート化合物（ブロック化物も含む）などがあげられ
る。The base resin in the clear coating is weather resistant,
Those having excellent smoothness and sharpness are preferable, and examples thereof include acrylic resins, polyester resins, alkyd resins, and fluororesins, which are functional groups capable of reacting with a crosslinking agent (for example, hydroxyl group, carboxyl group, epoxy resin). Group, a glycidyl group). The cross-linking agent is for reacting with the base resin to three-dimensionally cross-link and cure. Specifically, a methylolated and / or alkyl etherified melamine resin, a urea resin, a polyisocyanate compound (including a blocked compound), etc. Can be given.

【００１６】該クリヤー塗料は、着色顔料などを透明感
を低下させない範囲内で配合することができ、また、そ
の形態は粉体型であってもさしつかえないが、有機溶剤
および（又は）水を溶媒もしくは分散媒とする液状が好
ましい。The clear coating composition may be mixed with a coloring pigment within a range that does not deteriorate the transparency, and its form may be a powder type, but an organic solvent and / or water may be added. A liquid form of a solvent or a dispersion medium is preferable.

【００１７】本発明の塗装法は上記したメタリック塗料
およびクリヤー塗料を塗装するところに特徴がある。The coating method of the present invention is characterized by coating the above metallic paint and clear paint.

【００１８】被塗物（例えば、金属やプラスチック）を
必要に応じて表面処理、プライマー塗装および中塗り塗
装を行なったのち、上記メタリック塗料を塗装する。塗
装膜厚は制限されないが硬化塗膜に基づいて１０〜３０
μが好ましい。該メタリック塗膜を常温〜１６０℃にお
いて硬化したのち又は未硬化の状態で、該塗膜面に上記
クリヤー塗料を塗装する。クリヤー塗膜は硬化塗膜に基
づいて２０〜１００μの範囲が適している。クリヤー塗
料を塗装後、室温〜１６０℃で硬化させることが好まし
い。クリヤー塗膜は単一層でよいが、必要に応じて２層
以上であってもよい。The object to be coated (for example, metal or plastic) is subjected to surface treatment, primer coating and intermediate coating as required, and then the metallic coating is coated. The coating film thickness is not limited, but is 10 to 30 based on the cured coating film.
μ is preferred. After the metallic coating film is cured at room temperature to 160 ° C. or in an uncured state, the clear coating composition is applied to the coating film surface. The clear coating film is preferably in the range of 20 to 100μ based on the cured coating film. After applying the clear paint, it is preferred to cure at room temperature to 160 ° C. The clear coating film may be a single layer, but may be two or more layers if necessary.

【００１９】本発明のメタリック塗料を用いて形成され
るメタリック塗膜のメタリック感（光輝性）は、従来の
メタリック顔料を用いたものに比べて著しくすぐれてお
り、太陽光以外であってもキラキラと輝いたメタリック
塗膜が得られる。また、ニッケルなどを被覆したガラス
フレーク顔料は比重が約３であるため塗料中で殆ど沈降
しない。The metallic coating film formed by using the metallic coating material of the present invention has a significantly better metallic feeling (brightness) than that obtained by using a conventional metallic pigment, and the metallic coating film is glittering even in other than sunlight. A shiny metallic coating is obtained. Further, since the glass flake pigment coated with nickel or the like has a specific gravity of about 3, it hardly precipitates in the paint.

【００２０】ガラスフレークに被覆した銀被覆はシルバ
ー調の光輝性を有し、同様にニッケル被覆はダーク調の
光輝性があり、本発明のごとく、この両者を複層にする
とグレー調となり、ミデイアムトーンでしかも光輝性に
すぐれた塗色に仕上げることができる。The silver coating coated on the glass flakes has a silver-like brilliance, and similarly, the nickel coating has a dark-like brilliance. As in the present invention, when both of them are made into a multi-layer, a gray tone is obtained. It is possible to finish the paint with excellent tone and gloss.

【００２１】また、ニッケル単独被覆ですぐれた光輝性
を表面するには銀被覆に比べて被覆量が２〜３倍となる
ので、凝集しやすく、分散安定性が劣化するおそれがあ
る。しかし、この両者を複層にすることによって、ニッ
ケルの被覆量を低減でき、分散安定性が改良された。さ
らに、銀自体は化学的に活性であるが、本発明では、そ
の面をさらにニッケルで被覆しているので、活性度が低
減し、安定性が向上する。Further, in order to obtain excellent luster by coating with nickel alone, the coating amount becomes 2 to 3 times that of silver coating, so that aggregation tends to occur and dispersion stability may deteriorate. However, by forming both of them in a multi-layer structure, the coating amount of nickel can be reduced and the dispersion stability is improved. Furthermore, although silver itself is chemically active, in the present invention, its surface is further coated with nickel, so that the activity is reduced and the stability is improved.

【００２２】以下、本発明を実施例によって更に具体的
に説明する。なお、部及び％は重量部及び重量％を示
す。 実施例１ メタリック塗料：スチレン１５％、メチルメタアクリレ
ート１５％、ブチルメタアクリレート４０％、２−エチ
ルヘキシルアクリレート１３％、ヒドロキシエチルメタ
アクリレート１５％およびアクリル酸２％を重合開始剤
アソビスイソブチロニトリルを用いてキシロール中で共
重合せしめて、加熱残分５０％、溶液酸価８０、溶液粘
度Ｙ（ガードナー、２５℃）のアクリル樹脂溶液ＡＣ−
１を得た。Hereinafter, the present invention will be described in more detail with reference to Examples. In addition, a part and% show a weight part and weight%. Example 1 Metallic paint: Styrene 15%, methyl methacrylate 15%, butyl methacrylate 40%, 2-ethylhexyl acrylate 13%, hydroxyethyl methacrylate 15% and acrylic acid 2% were used as a polymerization initiator asobisisobutyronitrile. Copolymerized in xylol using a heating residue of 50%, a solution acid value of 80, a solution viscosity of Y (Gardner, 25 ° C.), an acrylic resin solution AC-
Got 1.

【００２３】このアクリル樹脂溶液ＡＣ−１を用いて下
記配合でメタリック塗料を作成した。Using this acrylic resin solution AC-1, a metallic paint was prepared with the following composition.

【００２４】 [0024]

【００２５】（注１） 三井東圧化学（株）製商品名ユ
ーバン２８ＳＥ （注２） 日本板硝子（株）メタシャイン ＲＣＦＳＸ−２０１５ＰＮ（１０２２） （ガラスフレーク：平均厚さ２±１μ、長手方向１５±
５μ、銀メッキ厚さ：０．０５μ、ニッケルメッキ厚さ
０．１μ） （注３） キャボット（アメリカ）製商品名カーボンブ
ラックＢＰ−１３００(Note 1) Mitsui Toatsu Chemicals Co., Ltd. product name U-ban 28SE (Note 2) Nippon Sheet Glass Co., Ltd. Metashine RCFSX-2015PN (1022) (Glass flakes: average thickness 2 ± 1 μ, longitudinal direction 15) ±
5μ, silver plating thickness: 0.05μ, nickel plating thickness 0.1μ) (Note 3) Product name Carbon Black BP-1300 manufactured by Cabot (USA)

【００２６】上記各成分を混合、分散し、ついで酢酸エ
チル３５部、トルエン３５部、イソブタノール１０部、
スワゾール１０００（丸善石油製）２０部からなる混合
溶剤で粘度１４秒（フォードカップ＃４／２０℃）に調
整した。The above components were mixed and dispersed, and then 35 parts of ethyl acetate, 35 parts of toluene, 10 parts of isobutanol,
The viscosity was adjusted to 14 seconds (Ford cup # 4/20 ° C.) with a mixed solvent consisting of 20 parts of Swazol 1000 (manufactured by Maruzen Sekiyu KK).

【００２７】比較例１〜２ 下記配合で実施例１と同様にして２種類の比較用メタリ
ック塗料を調製した。Comparative Examples 1 and 2 Two kinds of metallic paints for comparison were prepared in the same manner as in Example 1 with the following composition.

【００２８】 [0028]

【００２９】（注４） スパークロン １５００Ｘ（テ
イカ（株）製品） （注５） 東洋アルミニウム（株）製品アルペースト７
６４０ＮＳ(Note 4) Sparklon 1500X (Taika Co., Ltd. product) (Note 5) Toyo Aluminum Co., Ltd. product Alpaste 7
640NS

【００３０】実施例２、比較例３〜４ メタリック塗装：リン酸亜鉛化成処理を施した厚さ０．
８mmのダル銅板上にエポキシポリアミン系カチオン電着
塗料を硬化塗膜約２０μとなるよう電着塗装して１６０
℃で３０分間焼き付けた後、＃４００のサンドペーパー
で研ぎ、石油ベンジンで拭いて脱脂する。ついで自動車
用中塗りサーフェーサーを硬化塗膜約２５μとなるよう
エアースプレー塗装し、１４０℃で３０分間焼き付けた
後、＃４００のサンドペーパーで水研ぎし、水切り乾燥
する。ついで石油ベンジンで脱脂し試験用の素材とす
る。Example 2, Comparative Examples 3 to 4 Metallic coating: Zinc phosphate conversion treatment applied to a thickness of 0.1.
Epoxy polyamine-based cationic electrodeposition paint is applied on an 8 mm dull copper plate to give a cured coating film of about 20 μ, and then 160
After baking for 30 minutes at ℃, sharpen with # 400 sandpaper, wipe with petroleum benzine to degrease. Then, an intermediate coat surfacer for automobiles is air-spray coated so that a cured coating film has a thickness of about 25 μm, baked at 140 ° C. for 30 minutes, sanded with # 400 sandpaper, drained and dried. Then, degreasing with petroleum benzine is used as the material for the test.

【００３１】その上に前記実施例１及び比較例１、２で
得たメタリック塗料をエアースプレーガン（岩田塗装機
（株）製ワイダー＃７１）を用いて硬化膜厚が１５〜２
０μになる様に塗布しさらに常温で５分間放置した後、
熱硬化形メラミン樹脂・アクリル樹脂系クリヤー塗料を
硬化膜厚が３５〜４０μになる様エアースプレーにより
塗布する。そして１０分間常温で放置した後電気熱風乾
燥機で、１４０℃×３０分間加熱硬化せしめメタリック
塗膜を形成した（実施例２及び比較例３、４）。On top of that, the metallic paints obtained in Example 1 and Comparative Examples 1 and 2 were cured with an air spray gun (Wider # 71 manufactured by Iwata Coating Machine Co., Ltd.) to a cured film thickness of 15-2.
After coating it to 0μ and leaving it at room temperature for 5 minutes,
A thermosetting melamine resin / acrylic resin-based clear paint is applied by air spray so that the cured film thickness becomes 35 to 40 μm. Then, after leaving it at room temperature for 10 minutes, it was heated and cured at 140 ° C. for 30 minutes with an electric hot air dryer to form a metallic coating film (Example 2 and Comparative Examples 3 and 4).

【００３２】該実施例及び比較例で得たメタリック塗膜
を観察し次の効果を確認した。すなわち、実施例２で得
た塗膜は太陽光の直射においてはアルミニウムや酸化鉄
をはるかにしのぐ独特の光輝感を発現し、日影において
光輝性の減少は少ない。また実施例２のメタリック塗膜
の光輝感は、ハイライトはむろん、あるゆる角度におい
ても同程度であり、又、その光り方は塗膜の表面はむろ
ん、塗膜内部からもダイヤモンドをちりばめたような光
輝感を発しミデイアムトーン調の立体的色感を与える。The metallic coating films obtained in the examples and comparative examples were observed and the following effects were confirmed. That is, the coating film obtained in Example 2 exhibits a unique luster feeling far surpassing that of aluminum or iron oxide under direct sunlight, and the luster is not significantly reduced in the shade. In addition, the metallic coating film of Example 2 has the same brilliance at a certain angle, not to mention the highlight, and the way of shining is not limited to the surface of the coating film, and diamond is also scattered from inside the coating film. It gives off a glittering feeling and gives a three-dimensional color tone of medium tone.

【００３３】一方比較例３、４は酸化鉄やアルミニウム
粉を使用したもので、実施例２で得た塗膜を基準にする
とキラキラした光輝感は劣り、意匠性にとぼしい。On the other hand, Comparative Examples 3 and 4 use iron oxide or aluminum powder, and when the coating film obtained in Example 2 is used as a reference, the glittering feeling is inferior and the design is poor.

Claims (2)

【特許請求の範囲】[Claims] 【請求項１】 ガラスフレークの表面を銀およびニッケ
ルの順で複層被覆してなるりん片状粒子をメタリック顔
料として含有せしめてなるメタリック塗料。1. A metallic coating material comprising, as a metallic pigment, scaly particles obtained by coating the surface of glass flakes with silver and nickel in this order. 【請求項２】 メタリック塗料を塗装し、次いで該塗面
にクリヤー塗料を塗装する工程において、該メタリック
塗料のメタリック顔料がガラスフレークの表面を銀およ
びニッケルの順で複層被覆してなるりん片状粒子である
ことを特徴とするメタリック塗装法。2. A scaly piece obtained by coating a surface of glass flakes with a multilayer of silver and nickel in the step of applying a metallic paint and then applying a clear paint to the coated surface. Metallic coating method characterized in that it is shaped particles.
JP19344191A 1991-07-08 1991-07-08 Metallic paint and method for coating therewith Pending JPH0517710A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19344191A JPH0517710A (en) 1991-07-08 1991-07-08 Metallic paint and method for coating therewith

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19344191A JPH0517710A (en) 1991-07-08 1991-07-08 Metallic paint and method for coating therewith

Publications (1)

Publication Number Publication Date
JPH0517710A true JPH0517710A (en) 1993-01-26

Family

ID=16308044

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19344191A Pending JPH0517710A (en) 1991-07-08 1991-07-08 Metallic paint and method for coating therewith

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Country Link
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FR3103384A1 (en) 2019-11-21 2021-05-28 L'oreal Process for treating keratin fibers comprising a (poly) carbodiimide compound, an aqueous dispersion of particles of polymer (s) and a coloring agent
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WO2021099517A1 (en) 2019-11-21 2021-05-27 L'oreal Composition comprising a (poly)carbodiimide compound and a coloring agent
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FR3109304A1 (en) 2020-04-21 2021-10-22 L'oreal PROCESS FOR DENSIFICATION OF KERATINIC FIBERS BASED ON ACRYLIC SILICONE COPOLYMER AND A COLORING AGENT
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FR3109528A1 (en) 2020-04-24 2021-10-29 L'oreal Composition comprising at least one alkoxysilane of formula (I), at least one non-amino silicone of formula (II) having an average molecular mass of less than or equal to 1500 g / mol and at least one coloring agent
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FR3111558A1 (en) 2020-06-23 2021-12-24 L'oreal Process for treating keratin fibers comprising the application of a makeup removing composition, the keratin fibers having been previously colored
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FR3111810A1 (en) 2020-06-30 2021-12-31 L'oreal Composition comprising a combination of fillers
FR3112951A1 (en) 2020-07-30 2022-02-04 L'oreal Composition comprising at least one amino silicone, at least one non-amino silicone and at least one coloring agent
WO2022023426A1 (en) 2020-07-30 2022-02-03 L'oreal Composition comprising at least one amino silicone, at least one non-amino silicone and at least one colouring agent
FR3113240A1 (en) 2020-08-10 2022-02-11 L'oreal COMPOSITION COMPRISING AT LEAST ONE PARTICULAR SILICONE, AT LEAST ONE ALCANE AND AT LEAST ONE DIRECT COLOR AND/OR AT LEAST ONE PIGMENT
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FR3117032A1 (en) 2020-12-08 2022-06-10 L'oreal Gel composition comprising silica airgel and ethylguar as thickening agents
FR3117843A1 (en) 2020-12-17 2022-06-24 L'oreal Process for dyeing keratin fibers using at least one metallic compound
FR3117861A1 (en) 2020-12-17 2022-06-24 L'oreal Composition comprising at least one silicone of formula (I), at least one silicone of formula (II) and at least one coloring agent
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FR3117860A1 (en) 2020-12-17 2022-06-24 L'oreal Composition comprising at least one silicone of formula (I), at least one silicone of formula (II), at least one metal compound and at least one coloring agent
FR3117842A1 (en) 2020-12-18 2022-06-24 L'oreal Composition comprising at least one alkoxysilane, at least one polyoxyalkylene and at least one coloring agent
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FR3117786A1 (en) 2020-12-18 2022-06-24 L'oreal DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C3-C12 CYCLOALKYL GROUP, AN OIL AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION
FR3117846A1 (en) 2020-12-18 2022-06-24 L'oreal DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C9-C22 ALKYL GROUP, AN OIL AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION
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FR3117853A1 (en) 2020-12-23 2022-06-24 L'oreal Cosmetic composition comprising polymeric particles based on acetoacetate functions
WO2022136110A1 (en) 2020-12-23 2022-06-30 L'oreal Cosmetic composition comprising polymer particles based on acetoacetate functions
FR3117788A1 (en) 2020-12-23 2022-06-24 L'oreal Aqueous dispersion of a specific copolymer and its cosmetic applications
FR3117794A1 (en) 2020-12-23 2022-06-24 L'oreal Aqueous dispersion of a specific copolymer and its cosmetic applications
FR3117855A1 (en) 2020-12-23 2022-06-24 L'oreal : Cosmetic composition comprising a copolymer based on acetoacetate functions
FR3117856A1 (en) 2020-12-23 2022-06-24 L'oréal Cosmetic composition comprising a block copolymer based on acetoacetate functions
WO2022136114A1 (en) 2020-12-23 2022-06-30 L'oreal Aqueous dispersion of a specific copolymer, and cosmetic uses thereof
FR3117854A1 (en) 2020-12-23 2022-06-24 L'oréal Cosmetic composition comprising polymeric particles based on acetoacetate functions
FR3117852A1 (en) 2020-12-23 2022-06-24 L'oréal Cosmetic composition comprising a copolymer based on acetoacetate functions
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FR3118401A1 (en) 2020-12-30 2022-07-01 L'oreal Device with removable applicator comprising a composition containing at least one anti-hair loss agent, at least one pigment and at least one solvent
WO2022144367A1 (en) 2020-12-30 2022-07-07 L'oreal Fragranced cosmetic composition comprising at least one ferulic acid derivative, a dyestuff and a fragrancing material, and process for treating keratin materials and/or clothing using the composition
FR3118420A1 (en) 2020-12-30 2022-07-01 L'oreal Composition comprising at least one anti-hair loss agent, at least one pigment, at least one hydrophobic film-forming polymer, at least one aqueous-phase thickening agent and at least one organic solvent and water
FR3118418A1 (en) 2020-12-30 2022-07-01 L'oreal Perfumed cosmetic composition comprising at least one ferulic acid derivative, a coloring material and a fragrancing material, and process for treating keratin material and/or clothing using the composition
WO2022189572A1 (en) 2021-03-10 2022-09-15 L'oreal Process for removing the colour from previously coloured hair keratin fibers
WO2022189575A1 (en) 2021-03-10 2022-09-15 L'oreal Process for colouring hair keratin fibers comprising the application of a composition comprising at least one (poly)carbodiimide compound and a composition comprising at least one associative polymer and a particular compound
FR3120533A1 (en) 2021-03-10 2022-09-16 L'oreal Process for removing the color from hair keratin fibers which have been previously colored with a specific hair coloring composition
FR3120529A1 (en) 2021-03-10 2022-09-16 L'oreal Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one compound comprising at least one hydroxy function
FR3120527A1 (en) 2021-03-10 2022-09-16 L'oreal Process for dyeing hair keratin fibers comprising the application of a composition comprising at least one (poly)carbodiimide compound and of a composition comprising at least one associative polymer and a particular compound
FR3120532A1 (en) 2021-03-10 2022-09-16 L'oreal Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one non-carboxylic anionic thickening agent
FR3120530A1 (en) 2021-03-10 2022-09-16 L'oreal Hair coloring process comprising the application of a composition comprising at least one (poly)carbodiimide compound and of a composition comprising at least one associative polymer and a particular compound
WO2022189576A1 (en) 2021-03-10 2022-09-15 L'oreal Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one non-carboxylic anionic thickener
WO2022189573A1 (en) 2021-03-10 2022-09-15 L'oreal Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one compound comprising at least one hydroxyl function
WO2022189570A1 (en) 2021-03-10 2022-09-15 L'oreal Process for colouring hair keratin fibers, comprising the application of a composition comprising at least one (poly)carbodiimide compound and a composition comprising at least one associative polymer and a particular compound
WO2022189571A1 (en) 2021-03-10 2022-09-15 L'oreal Process for removing the colour from hair keratin fibers which have been coloured beforehand with a specific hair colouring composition
FR3120528A1 (en) 2021-03-10 2022-09-16 L'oreal Method for removing color from previously colored hair keratin fibers
WO2022258494A1 (en) 2021-06-07 2022-12-15 L'oreal Hair dyeing process comprising the application of a (poly)carbodiimide compound, of a polymer bearing a carboxylic group and of a non-silicone fatty substance
FR3123567A1 (en) 2021-06-07 2022-12-09 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a polymer containing a carboxylic group and a non-silicone fatty substance
FR3125424A1 (en) 2021-07-23 2023-01-27 L'oreal Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one protein
FR3125423A1 (en) 2021-07-23 2023-01-27 L'oreal Cosmetic composition comprising at least one (poly)carbodiimide compound and at least one amino alkoxysilane
FR3125422A1 (en) 2021-07-23 2023-01-27 L'oreal Hair coloring composition comprising at least one (poly)carbodiimide compound, at least one amino alkoxysilane and at least one coloring agent
WO2023001953A1 (en) 2021-07-23 2023-01-26 L'oreal Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one protein
FR3127403A1 (en) 2021-09-28 2023-03-31 L'oreal Composition comprising at least one silicone of formula (I), at least one silicone of formula (II), at least one hydrophobic film-forming polymer chosen from copolymers based on silicone resin and fluid silicone
WO2023057446A1 (en) 2021-10-05 2023-04-13 L'oreal Oily dispersion comprising a polymeric particle and a stabilizer bearing a c9-c22 alkyl group and a plasticizer, and process for treating keratin materials using the oily dispersion
FR3127695A1 (en) 2021-10-05 2023-04-07 L'oreal OILY DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C9-C22 ALKYL GROUP, AND A PLASTICIZER METHOD FOR TREATMENT OF KERATIN MATERIALS USING THE OILY DISPERSION
FR3129605A1 (en) 2021-11-26 2023-06-02 Capsum Method of forming a dispersion comprising drops, and associated apparatus
WO2023094613A1 (en) 2021-11-26 2023-06-01 Capsum Method for forming a dispersion comprising drops, and associated apparatus
WO2023104924A1 (en) 2021-12-09 2023-06-15 L'oreal Composition comprising a combination of polyglycerol esters and a filler
FR3130132A1 (en) 2021-12-09 2023-06-16 L'oreal DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A CYCLOALKYL GROUP, AN OIL, AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION
FR3130133A1 (en) 2021-12-09 2023-06-16 L'oreal Composition comprising a combination of polyglycerol esters and a filler
WO2023107199A1 (en) 2021-12-09 2023-06-15 L'oreal Skin perfecting cosmetic compositions and methods of use
WO2023104730A1 (en) 2021-12-09 2023-06-15 L'oreal Dispersion comprising a polymeric particle, a stabilizer bearing a cycloalkyl group, an oil and water, and process for treating keratin materials using the dispersion
FR3130141A1 (en) 2021-12-13 2023-06-16 L'oreal Process for dyeing hair comprising the application of a composition comprising a (poly)carbodiimide compound, and the application of a composition comprising a silicone elastomer with carboxylic acid functions
WO2023110752A1 (en) 2021-12-13 2023-06-22 L'oreal Process for colouring the hair comprising the application of a composition comprising a (poly)carbodiimide compound, and the application of a composition comprising a silicone elastomer containing carboxylic acid functions
WO2023111269A1 (en) 2021-12-16 2023-06-22 L'oreal Process for colouring the hair, comprising at least the application of a composition comprising a (poly)carbodiimide compound, a silicone acrylic copolymer and at least one colouring agent
WO2023111268A1 (en) 2021-12-16 2023-06-22 L'oreal Hair dyeing process, comprising the application of a (poly)carbodiimide compound of specific formula, a silicone acrylic polymer, two compounds with specific hansen solubility parameters and a colouring agent
FR3130615A1 (en) 2021-12-16 2023-06-23 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer and a coloring agent
FR3130616A1 (en) 2021-12-16 2023-06-23 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a surfactant and a coloring agent
FR3130614A1 (en) 2021-12-16 2023-06-23 L'oreal Hair coloring process comprising at least the application of a composition comprising a (poly)carbodiimide compound, a silicone acrylic copolymer and at least one coloring agent
FR3130617A1 (en) 2021-12-16 2023-06-23 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, two compounds having specific Hansen solubility parameters and a coloring agent
WO2023110754A1 (en) 2021-12-16 2023-06-22 L'oreal Process for colouring the hair comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a surfactant and a colouring agent
FR3130560A1 (en) 2021-12-17 2023-06-23 L'oreal Composition comprising a combination of polyglycerol esters, a mineral UV filter and a liposoluble or specific hydrophobic particulate coloring matter
FR3130596A1 (en) 2021-12-17 2023-06-23 L'oreal Cosmetic and/or dermatological composition comprising at least one merocyanine and at least ascorbic acid and/or one of its derivatives
FR3130595A1 (en) 2021-12-17 2023-06-23 L'oreal Cosmetic or dermatological composition comprising at least one merocyanine and one hydrotrope
WO2023110772A1 (en) 2021-12-17 2023-06-22 L'oreal Cosmetic or dermatological composition comprising at least a merocyanine and a hydrotrope
WO2023110763A1 (en) 2021-12-17 2023-06-22 L'oreal Cosmetic and/or dermatological composition comprising at least one merocyanine and at least ascorbic acid and/or a derivative thereof
FR3131200A1 (en) 2021-12-23 2023-06-30 L'oreal Composition comprising a photo-crosslinkable polymer and a coloring agent
FR3131201A1 (en) 2021-12-23 2023-06-30 L'oreal Method for removing make-up from keratin fibers which have been previously treated with a composition comprising a photo-crosslinkable polymer
WO2023117794A1 (en) 2021-12-23 2023-06-29 L'oreal Composition comprising a photocrosslinkable polymer having a hydrophobic group and a coloring agent
WO2023117954A1 (en) 2021-12-23 2023-06-29 L'oreal Process for removing makeup from keratin fibres which have been treated beforehand with a composition comprising a photocrosslinkable polymer
FR3131529A1 (en) 2021-12-31 2023-07-07 L'oreal Customization kit for a cosmetic composition
WO2023126397A1 (en) 2021-12-31 2023-07-06 L'oreal Kit for customizing a cosmetic composition
FR3131688A1 (en) 2022-01-12 2023-07-14 L'oreal Coatings, methods and systems for optically transformed nails
FR3132220A1 (en) 2022-01-31 2023-08-04 L'oreal skin-perfecting cosmetic compositions and methods of use
FR3134002A1 (en) 2022-03-31 2023-10-06 L'oreal Hair coloring process comprising the application of a composition A comprising an alkoxysilane, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and a silicone resin
FR3134003A1 (en) 2022-03-31 2023-10-06 L'oreal Process for removing color from keratin fibers previously colored with two alkoxysilanes, a film-forming polymer, a non-ionic cellulose polymer and a coloring agent
WO2023187158A1 (en) 2022-03-31 2023-10-05 L'oreal Process for dyeing the hair
WO2023187157A1 (en) 2022-03-31 2023-10-05 L'oreal Hair dyeing process comprising the application of a composition c comprising a metal compound
FR3134001A1 (en) 2022-03-31 2023-10-06 L'oreal Hair coloring process comprising the application of a composition C comprising a metallic compound
FR3134000A1 (en) 2022-03-31 2023-10-06 L'oreal Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and an amino acid
FR3133999A1 (en) 2022-03-31 2023-10-06 L'oreal Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and an amino silicone
FR3137293A1 (en) 2022-06-30 2024-01-05 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group and a coloring agent
FR3137283A1 (en) 2022-06-30 2024-01-05 L'oreal Use of a composition comprising an alkyl or alkylene carbonate for removing color from previously colored keratin hair fibers without damaging the keratin hair fibers
FR3137294A1 (en) 2022-06-30 2024-01-05 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a particular alkaline agent and a coloring agent
FR3137286A1 (en) 2022-06-30 2024-01-05 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, and a coloring agent
FR3137285A1 (en) 2022-06-30 2024-01-05 L'oreal Process for removing color from previously colored keratin hair fibers
FR3137287A1 (en) 2022-06-30 2024-01-05 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, of a compound comprising at least one carboxylic function, and of a coloring agent comprising aluminum
FR3137291A1 (en) 2022-06-30 2024-01-05 L'oreal Aerosol coloring device based on silicone acrylic copolymer, a coloring agent and a propellant gas of the dimethyl ether type
FR3137295A1 (en) 2022-06-30 2024-01-05 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group and a pigment having a particular particle size
FR3137574A1 (en) 2022-07-11 2024-01-12 L'oreal Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer
FR3137575A1 (en) 2022-07-11 2024-01-12 L'oreal Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer
FR3139721A1 (en) 2022-09-16 2024-03-22 L'oreal Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer
FR3140277A1 (en) 2022-09-30 2024-04-05 L'oreal Cosmetic hair care composition comprising at least one particular amino silicone and at least one associative polymer, and cosmetic hair treatment method
FR3140279A1 (en) 2022-09-30 2024-04-05 L'oreal Cosmetic hair care composition comprising at least one particular amino silicone and at least one non-silicone fatty substance, and method for cosmetic treatment of hair
FR3140273A1 (en) 2022-09-30 2024-04-05 L'oreal Cosmetic hair care composition comprising at least one particular amino silicone and at least one coloring agent and/or an optical brightener, and method for cosmetic treatment of hair
WO2024121308A1 (en) 2022-12-09 2024-06-13 L'oreal Fragranced cosmetic composition comprising at least one phloretin derivative, a dyestuff and a fragrancing substance
FR3142887A1 (en) 2022-12-09 2024-06-14 L'oreal Perfumed cosmetic composition comprising at least one phloretin derivative, a coloring material and a perfuming substance, and process for treating keratin material and/or clothing using the composition
WO2024133696A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a (poly)carbodiimide compound, a compound containing at least one carboxylic acid group, an amino silicone and a colouring agent.
FR3143989A1 (en) 2022-12-21 2024-06-28 L'oreal A process for coloring hair comprising the application of a cold plasma treatment and a composition comprising a (poly)carbodiimide compound and a coloring agent
WO2024133693A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a particular composition t and the application of a (poly)carbodiimide compound and a colouring agent
WO2024133719A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers which involves spraying the keratin hair fibers with a composition comprising a (poly)carbodiimide compound and a colouring agent using an airbrush
WO2024133697A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a cold plasma treatment and of a composition comprising a (poly)carbodiimide compound and a colouring agent
WO2024133718A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a composition t comprising an amino acid and the application of a (poly)carbodiimide compound and a colouring agent
WO2024133698A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a (poly)carbodiimide compound and a colouring agent, the application of steam and shaping at a particular temperature.
WO2024133715A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a treatment with a reducing agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent process for dyeing keratin hair fibers comprising the application of a treatment with a reducing agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent
FR3143991A1 (en) 2022-12-21 2024-06-28 L'oreal A method of coloring hair comprising spraying the hair with a composition comprising a (poly)carbodiimide compound and a coloring agent using an airbrush
WO2024133716A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a treatment with an alkaline agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent
FR3143993A1 (en) 2022-12-21 2024-06-28 L'oreal Use of a hair coloring composition comprising a (poly)carbodiimide compound, a compound having at least one carboxylic function and a coloring agent for increasing hair volume
FR3143983A1 (en) 2022-12-21 2024-06-28 L'oreal Hair coloring process comprising the application of a particular composition T and the application of a (poly)carbodiimide compound and a coloring agent
FR3143981A1 (en) 2022-12-21 2024-06-28 L'oreal A process for coloring hair comprising the application of a treatment with an alcohol and a composition comprising a specific (poly)carbodiimide compound and a coloring agent
FR3143994A1 (en) 2022-12-21 2024-06-28 L'oreal A process for coloring hair comprising the application of a treatment with an alkaline agent and a composition comprising a (poly)carbodiimide compound and a coloring agent
FR3143987A1 (en) 2022-12-21 2024-06-28 L'oreal Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group, an amino silicone and a coloring agent
FR3143996A1 (en) 2022-12-21 2024-06-28 L'oreal Process for coloring hair comprising the application of a treatment with a reducing agent and a composition comprising a (poly)carbodiimide compound and a coloring agent
FR3143986A1 (en) 2022-12-21 2024-06-28 L'oreal A process for coloring hair comprising the application of a (poly)carbodiimide compound and a coloring agent, the application of steam and shaping at a particular temperature
FR3143992A1 (en) 2022-12-21 2024-06-28 L'oreal Hair coloring process comprising the application of a composition T comprising an amino acid and the application of a (poly)carbodiimide compound and a coloring agent
FR3143988A1 (en) 2022-12-21 2024-06-28 L'oreal A method of coloring hair comprising applying a composition comprising a (poly)carbodiimide compound, applying heat, and applying a composition comprising a (poly)carbodiimide compound
WO2024133717A1 (en) 2022-12-21 2024-06-27 L'oreal Process for dyeing keratin hair fibers comprising the application of a composition comprising a (poly)carbodiimide compound, the application of heat and the application of a composition comprising a (poly)carbodiimide compound

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