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HU209438B - Selective herbicides containing cyclohexenone-derivative as herbicidal active ingredient and cyano-quinoline-derivative as antidote and process for selective extirpation of weeds - Google Patents

Selective herbicides containing cyclohexenone-derivative as herbicidal active ingredient and cyano-quinoline-derivative as antidote and process for selective extirpation of weeds Download PDF

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Publication number
HU209438B
HU209438B HU911479A HU147991A HU209438B HU 209438 B HU209438 B HU 209438B HU 911479 A HU911479 A HU 911479A HU 147991 A HU147991 A HU 147991A HU 209438 B HU209438 B HU 209438B
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HU
Hungary
Prior art keywords
alkyl
alkoxy
optionally substituted
formula
derivative
Prior art date
Application number
HU911479A
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German (de)
English (en)
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HU911479D0 (en
HUT57539A (en
Inventor
Bruno Wuerzer
Karl-Otto Westphalen
Helmut Hagen
Juergen Pfister
Guenter Brill
Gerhard Nilz
Original Assignee
Basf Ag
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Publication of HU911479D0 publication Critical patent/HU911479D0/hu
Publication of HUT57539A publication Critical patent/HUT57539A/hu
Publication of HU209438B publication Critical patent/HU209438B/hu

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/12—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D215/54—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/48—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D215/54—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 3
    • C07D215/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 3 with oxygen atoms in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Quinoline Compounds (AREA)

Claims (2)

1. Szelektív gyomirtó készítmény, azzal jellemezve, hogy összesen 0,1-95 tömeg% mennyiségben antidotumként (la) vagy (Ib) általános képletű ciano-kinolinszármazék - a képletben
R1 jelentése halogénatom, 2,2-diciano-vinil-, [(5-kinolil-metilén)-hidrazino]-metil, ciano-, nitro- vagy 14 szénatomos alkoxicsoport; adott esetben halogénatommal, ciano- vagy (2-4 szénatomos alkoxi)-karbonil-csoporttal helyettesített 1-4 szénatomos alkilcsoport; pirrolidinil-, piperidinil- vagy morfolinilcsoport; fenil-, fenoxi-, fenil-tio-, fenil-ditio-, fenilszulfonil- vagy pirrolilcsoport, amelyek adott esetben egy vagy több halogénatommal, 1-4 szénatomos alkil-, 1-4 szénatomos halogén-alkil-, nitro-, amino-, 2-4 szénatomos nitro-alkenil- és/vagy benzilcsoporttal helyettesítettek;
R2 jelentése hidrogén- vagy halogénatom, 1-4 szénatomos alkoxicsoport, illetve R3R4N-, R6-(O)CNH- vagy R8CH=N- általános képletű csoport, amelyekben
R3 jelentése hidrogénatom vagy adott esetben hidroxil-, 1-4 szénatomos alkoxi-, amino-, 1-4 szénatomos alkil-amino- vagy di(l—4 szénatomos alkil)-aminocsoporttal helyettesített 1-4 szénatomos alkilcsoport,
R4 jelentése az R3 jelképre megadott jelentésű vagy 1-4 szénatomos alkil-amino-csoport vagy adott esetben (2-4 szénatomos alkoxi)-karbonil-, pirrolidinil- vagy imidazolilcsoporttal helyettesített 1-4 szénatomos alkilcsoport, vagy
R3 és R4 együtt pirrolil-, pirrolidinil-, piperidinilvagy morfolinilcsoportot képez,
R6 jelentése adott esetben (2-4 szénatomos alkoxi)-karbonilcsoporttal helyettesített 1—4 szénatomos alkilcsoport, adott esetben halogénatommal vagy nitrocsoporttal helyettesített fenilcsoport, 1-4 szénatomos alkil-amino-csoport vagy adott esetben halogénatommal helyettesített fenil-amino-csoport,
Rs jelentése fenilcsoport és m értéke 1, 2 vagy 3 vagy környezetbarát sóik és herbicid hatóanyagként (X) általános képletű ciklohexenon-származék - a képletben
Rd jelentése 1-4 szénatomos alkilcsoport,
Re jelentése 1-4 szénatomos alkil-, 3-4 szénatomos alkenil-, 3-4 szénatomos alkinil-, 3-4 szénatomos halogén-alkilcsoport vagy adott esetben halogénatommal szubsztituált tenilcsoport, fenilcsoportot hordozó 3-4 szénatomos alkenilcsoport, ahol az aromás gyűrű halogénatommal, 1—4 szénatomos alkil-, 1—4 szénatomos alkoxi-, 1-4 szénatomos halogén-alkil- és/vagy 1-4 szénatomos halogén-alkoxi-csoporttal mono-, di vagy triszubsztituált lehet;
Rf jelentése adott esetben 1-4 szénatomos alkiltiovagy 1-4 szénatomos alkoxicsoporttal mono- vagy diszubsztituált alkilcsoport; 5- vagy 6-tagú, telített vagy egyszeresen telítetlen ciklusos csoport, amely gyűrűtagként a szénatomokon kívül oxigén- vagy kénatomot is tartalmazhat, és ahol a kénatom szulfoxiddá vagy szulfonná oxidált formában is lehet, továbbá a gyűrű helyettesítőként 1, 2 vagy 3 halogénatomot, illetve hidroxil-, 1-4 szénatomos alkil-, 1—4 szénatomos halogén-alkil-, 1—4 szénatomos alkoxi- és/vagy 1—4 szénatomos alkil-tio-csoportot viselhet; 10-tagú, telített vagy egyszeresen telítetlen, 2 oxigén- vagy kénatomot magában foglaló, adott esetben három 1—4 szénatomos alkil- és/vagy metoxicsoporttal szubsztituált heterociklus; fenil-, piridil-, tiazolil-, pirazolil-, pirrolil- vagy izoxazolilcsoport, amelyek legfeljebb 3 halogénatomot, illetve 1-4 szénatomos alkil-, 1—4 szénatomos halogén-alkil-, 1-4 szénatomos alkoxi-, 1-4 szénatomos alkil-tio-, 3-6 szénatomos alkenil-oxi-, 3-6 szénatomos alkinil-oxi-, 1—4 szénatomos alkoxi-(l3 szénatomos alkil)-, di(l—4 szénatomos alkoxi)(1-3 szénatomos alkil)-, formil- és/vagy benzoilamino-csoportot viselhetnek helyettesítőként;
Rg jelentése hidrogénatom vagy hidroxilcsoport, illetve ha Rf 1-6 szénatomos alkilcsoportot jelent, 1-6 szénatomos alkilcsoport;
Rh jelentése hidrogén- vagy halogénatom, illetve cianocsoport, 1-4 szénatomos alkoxi-karbonil-csoport vagy 1—4 szénatomos alkoxi-imino-csoport; és
R1 jelentése hidrogénatom vagy egyenértékű a környezetet nem károsító kation 0,01:1-10:1 tömegarányú keveréket tartalmazza a szokásos segédanyagokkal együtt.
2. Eljárás szelektív gyomirtásra, illetve haszonnövényeknél a (X) általános képletű ciklohexenon-származék
- a képletben a jelképek az 1. igénypontban megadottak
- okozta károsodás mérséklésére, azzal jellemezve, hogy a haszonnövény vetőmagját vagy vetéskor vagy azt követően, a kelést megelőzően vagy annak folyamán a haszonnövények tenyészhelyét az alkalmazott 0,2-5 kg/ha (X) általános képletű ciklohexenon-származékra vonatkoztatva 1:0,01-10:1 tömegarányban (la) vagy (Ib) általános képletű ciano-kinolin-származékkal - a jelképek az 1. igénypontban megadottak - vagy környezetbarát sójukat egyidejűleg vagy egymást követően kezeljük.
HU911479A 1990-05-03 1991-05-02 Selective herbicides containing cyclohexenone-derivative as herbicidal active ingredient and cyano-quinoline-derivative as antidote and process for selective extirpation of weeds HU209438B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4014171A DE4014171A1 (de) 1990-05-03 1990-05-03 Cyanochinolinverbindungen

Publications (3)

Publication Number Publication Date
HU911479D0 HU911479D0 (en) 1991-11-28
HUT57539A HUT57539A (en) 1991-12-30
HU209438B true HU209438B (en) 1994-06-28

Family

ID=6405624

Family Applications (1)

Application Number Title Priority Date Filing Date
HU911479A HU209438B (en) 1990-05-03 1991-05-02 Selective herbicides containing cyclohexenone-derivative as herbicidal active ingredient and cyano-quinoline-derivative as antidote and process for selective extirpation of weeds

Country Status (8)

Country Link
US (1) US5565408A (hu)
EP (1) EP0459140B1 (hu)
JP (1) JPH04225960A (hu)
KR (1) KR910019982A (hu)
CA (1) CA2041684A1 (hu)
DE (2) DE4014171A1 (hu)
ES (1) ES2091258T3 (hu)
HU (1) HU209438B (hu)

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EA025568B1 (ru) 2010-12-17 2017-01-30 Рита Фармасьютикалз, Инк. Пиразолильные и пиримидинильные трициклические еноны в качестве антиоксидантных модуляторов воспаления
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TWI770527B (zh) 2019-06-14 2022-07-11 美商基利科學股份有限公司 Cot 調節劑及其使用方法
CN114793434A (zh) 2019-10-18 2022-07-26 加利福尼亚大学董事会 作为用于治疗病原性血管病症的药剂的3-苯基磺酰基-喹啉衍生物
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Also Published As

Publication number Publication date
EP0459140B1 (de) 1996-09-11
KR910019982A (ko) 1991-12-19
EP0459140A2 (de) 1991-12-04
DE4014171A1 (de) 1991-11-07
HU911479D0 (en) 1991-11-28
US5565408A (en) 1996-10-15
DE59108164D1 (de) 1996-10-17
CA2041684A1 (en) 1991-11-04
JPH04225960A (ja) 1992-08-14
EP0459140A3 (en) 1992-05-20
HUT57539A (en) 1991-12-30
ES2091258T3 (es) 1996-11-01

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