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ES2557502T3 - Lámina de PMMA con estabilidad a la intemperie especialmente elevada y acción protectora frente a UV elevada - Google Patents

Lámina de PMMA con estabilidad a la intemperie especialmente elevada y acción protectora frente a UV elevada Download PDF

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Publication number
ES2557502T3
ES2557502T3 ES06830801.4T ES06830801T ES2557502T3 ES 2557502 T3 ES2557502 T3 ES 2557502T3 ES 06830801 T ES06830801 T ES 06830801T ES 2557502 T3 ES2557502 T3 ES 2557502T3
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Spain
Prior art keywords
weight
mass
sheet
protective action
synthetic material
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Active
Application number
ES06830801.4T
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English (en)
Inventor
Uwe Numrich
Achim NEUHÄUSER
Thorsten Goldacker
Thomas Arndt
Alexander Laschitsch
Günther DICKHAUT-BAYER
Christoph Krohmer
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Roehm GmbH Darmstadt
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Evonik Roehm GmbH
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Application granted granted Critical
Publication of ES2557502T3 publication Critical patent/ES2557502T3/es
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

Cuerpo moldeado de material sintético constituido por a. un material sintético transparente, y b. una mezcla de estabilizadores UV y filtros UV, caracterizado porque el material sintético transparente es un poli(met)acrilato que presenta la siguiente composición: c. 50 % en peso a un 99,9 % en peso de metacrilato de metilo, d. un 0,1 % en peso a un 50 % en peso de C1 a C4-acrilato, e. un 0 % en peso a un 10 % en peso con los monómeros a. y b. monómeros copolimerizables, y porque la matriz presenta un peso molecular medio de 80 000 g/mol a 180 000 g/mol.

Description

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La hoja se lamina entonces sobre una lámina decorativa de PVC (decoración de madera marrón), a continuación se aplica sobre un soporte de material sintético y se somete a ensayo. Composición de los demás ejemplos Ejemplo 2 Ejemplo 1, menos un 1,95 % en masa de metacrilato de 3-(2-benzotriazololil)2-hidroxi-5-terc-octilbencilo en polímero
+ 2,3 % en masa, referido a la lámina según ejemplo 1, de Tinuvin® 360. Las cantidades de monómero del ejemplo 1 se deben adaptar correspondientemente.
Ejemplo 3 Ejemplo 1, menos un 1,95 % en masa de metacrilato de 3-(2-benzotriazololil)2-hidroxi-5-terc-octilbencilo + 2,3 % en masa, referido a la lámina según ejemplo 1, de Tinuvin® 360 + 0,4 % en masa de Chimassorb 119 (HALS de la firma Ciba SC). Las cantidades de monómero del ejemplo 1 se deben adaptar correspondientemente.
Ejemplo 4 Ejemplo 1, menos un 1,95 % en masa de metacrilato de 3-(2-benzotriazololil)2-hidroxi-5-terc-octilbencilo + 0,75 % en
masa de CGX-UVA 006 (filtro UV de la firma Ciba SC a base de triazina), referido a la lámina según ejemplo 1 + 0,8 % en masa de Tinuvin® 360. Las cantidades de monómero del ejemplo 1 se deben adaptar correspondientemente. Ejemplo 5 Ejemplo 1, menos un 1,95 % en masa de metacrilato de 3-(2-benzotriazololil)2-hidroxi-5-terc-octilbencilo + 0,75 % en
masa de CGX-UVA 006, referido a la lámina según ejemplo 1 + 0,4 % en masa de Chimassorb 119 + 0,8 % en masa de Tinuvin® 360. Las cantidades de monómero del ejemplo 1 se deben adaptar correspondientemente.
Ejemplo 6 Ejemplo 1, menos un 1,95 % en masa de metacrilato de 3-(2-benzotriazololil)2-hidroxi-5-terc-octilbencilo + 0,6 % en masa de CGX-UVA 006, referido a la lámina según ejemplo 1 + 0,4 % en masa de Chimassorb 119 + 1,1 % en masa de Tinuvin® 360. Las cantidades de monómero del ejemplo 1 se deben adaptar correspondientemente.
Ejemplo 7 Lámina adquirible comercialmente, fabricante: Cova. Ejemplo 8 Lámina análoga a la del ejemplo 1, laminándose la hoja sobre una lámina decorativa de PVC roja, aplicándose a
continuación sobre un soporte de material sintético, y sometiéndose a ensayo. Ejemplo 9 Lámina análoga a la del ejemplo 3, laminándose la hoja sobre una lámina decorativa de PVC roja, aplicándose a
continuación sobre un soporte de material sintético, y sometiéndose a ensayo. Ejemplo 10 Lámina análoga a la del ejemplo 5, laminándose la hoja sobre una lámina decorativa de PVC roja, aplicándose a
continuación sobre un soporte de material sintético, y sometiéndose a ensayo.
Las láminas obtenidas se expusieron a la intemperie en Xenotest según ISO 4892-2. La intensidad de radiación ascendia a 180 watios/m2, entre 300 y 400 nm de longitud de onda. Ejemplo 11
10
imagen9

Claims (1)

  1. imagen1
    imagen2
ES06830801.4T 2005-12-23 2006-12-22 Lámina de PMMA con estabilidad a la intemperie especialmente elevada y acción protectora frente a UV elevada Active ES2557502T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005062687 2005-12-23
DE102005062687A DE102005062687A1 (de) 2005-12-23 2005-12-23 PMMA-Folie mit besonders hoher Witterungsbeständigkeit und hoher UV-Schutzwirkung
PCT/EP2006/070146 WO2007074138A1 (de) 2005-12-23 2006-12-22 Pmma - folie mit besonders hoher witterungsbeständigkeit und hoher uv-schutzwirkung

Publications (1)

Publication Number Publication Date
ES2557502T3 true ES2557502T3 (es) 2016-01-26

Family

ID=37692446

Family Applications (1)

Application Number Title Priority Date Filing Date
ES06830801.4T Active ES2557502T3 (es) 2005-12-23 2006-12-22 Lámina de PMMA con estabilidad a la intemperie especialmente elevada y acción protectora frente a UV elevada

Country Status (18)

Country Link
US (1) US8088847B2 (es)
EP (1) EP1963415B1 (es)
JP (1) JP5065292B2 (es)
KR (1) KR101348008B1 (es)
CN (1) CN101341205B (es)
AR (1) AR058865A1 (es)
AU (1) AU2006331323A1 (es)
BR (1) BRPI0620282B1 (es)
CA (1) CA2629654C (es)
DE (1) DE102005062687A1 (es)
ES (1) ES2557502T3 (es)
HK (1) HK1124876A1 (es)
MY (1) MY148535A (es)
PL (1) PL1963415T3 (es)
RU (1) RU2453563C2 (es)
TW (1) TWI373487B (es)
WO (2) WO2007073952A1 (es)
ZA (1) ZA200804344B (es)

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PL1963415T3 (pl) 2016-03-31
BRPI0620282A2 (pt) 2012-04-17
US20080281023A1 (en) 2008-11-13
WO2007074138A1 (de) 2007-07-05
AR058865A1 (es) 2008-02-27
RU2453563C2 (ru) 2012-06-20
US8088847B2 (en) 2012-01-03
JP2009520859A (ja) 2009-05-28
MY148535A (en) 2013-04-30
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TW200801086A (en) 2008-01-01
HK1124876A1 (en) 2009-07-24
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RU2008129874A (ru) 2010-01-27
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DE102005062687A1 (de) 2007-07-05
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