EP2106925B1 - Self-adhesive underlay film - Google Patents
Self-adhesive underlay film Download PDFInfo
- Publication number
- EP2106925B1 EP2106925B1 EP08153798A EP08153798A EP2106925B1 EP 2106925 B1 EP2106925 B1 EP 2106925B1 EP 08153798 A EP08153798 A EP 08153798A EP 08153798 A EP08153798 A EP 08153798A EP 2106925 B1 EP2106925 B1 EP 2106925B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive
- self
- film
- underpacking
- foil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F30/00—Devices for attaching coverings or make-ready devices; Guiding devices for coverings
- B41F30/04—Devices for attaching coverings or make-ready devices; Guiding devices for coverings attaching to transfer cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N10/00—Blankets or like coverings; Coverings for wipers for intaglio printing
- B41N10/02—Blanket structure
- B41N10/04—Blanket structure multi-layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N6/00—Mounting boards; Sleeves Make-ready devices, e.g. underlays, overlays; Attaching by chemical means, e.g. vulcanising
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N2210/00—Location or type of the layers in multi-layer blankets or like coverings
- B41N2210/06—Backcoats; Back layers; Bottom layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N2210/00—Location or type of the layers in multi-layer blankets or like coverings
- B41N2210/14—Location or type of the layers in multi-layer blankets or like coverings characterised by macromolecular organic compounds
Definitions
- the present invention relates to a self-adhesive backing sheet for offset printing.
- calibrated underlay sheets with and without adhesive are used both on the plate cylinder and on the blanket cylinder. These serve to adjust the perimeter length of the cylinders to the print length. This is necessary because the cylinder depending on the printing press manufacturer have a different depth of puncture and the printing and coating plates and blankets used are different thicknesses. For this purpose, it is necessary to use different thickness paper or cardboard sheets or backing sheets that compensate for these differences
- EP 1 323 527 A1 discloses multilayer backing sheets for rubber blankets.
- Both the calibrated paper and cardboard sheets as well as the backing films have versions with and without self-adhesive equipment. With automatic plate feeder only self-adhesive underlay films are used.
- Self-adhesive films have the advantage that they are easier to assemble because they can not slip.
- a disadvantage of the self-adhesive underlay films is that the change is more time-consuming, since adhesive residues may have to be removed from the cylinder surface. It should be noted that, for example, in web offset for newspaper printing quite a 64 or 128 printing units are used.
- a backing film for offset printing comprising at least one self-adhesive polymer film, wherein the backing film has a thickness of 0.04 to 2.10 mm.
- Good self-adhesive properties can be achieved, for example, with a 180 ° peel test with a take-off speed of 300 mm / min.
- a take-off speed of 300 mm / min are particularly suitable values for the self-adhesive film in the range of 3 to 8 N / 25 mm.
- Suitable materials for the production of self-adhesive polymer films are known to those skilled in principle. Particularly suitable materials are selected from the group of soft PVC, polyurethane, polyethylene, polypropylene, ethyl vinyl acetate and mixtures thereof.
- the pressure-sensitive layer may be combined with a non-adhesive film.
- the non-adhesive plastic film prevents sticking to the overlying offset plate.
- Suitable materials for the non-adhesive plastic film are polyethylene terephthalate, polyurethane, PVC, polyethylene, polypropylene and mixtures thereof.
- the non-adhesive plastic film may have backside matting. For roll offset presses this becomes placed under the blanket and prevents slipping of the cloth on the otherwise smooth foil back.
- the pressure-sensitive polymer film is laminated with a rubber blanket.
- the result is a self-adhesive rubber blanket that can be mounted in a particularly simple and comfortable way.
- a multilayer film consisting of 120 ⁇ m thick soft PVC film (self-adhesive) and a 80 ⁇ m thick PE / HDPE film was produced.
- the film is mounted bubble-free with the self-adhesive soft PVC film side on an offset printing cylinder.
- a multilayer film consisting of a 120 ⁇ m thick soft PVC film and a 25 ⁇ m thick ethylene-vinyl acetate layer was laminated to a 125 ⁇ m polyester film with a 25 ⁇ m thick permanent adhesive.
- the ethylene-vinyl acetate layer is self-adhesive and can be applied bubble-free on an offset rubber cylinder.
- the diameter of the cylinder increases by 590 ⁇ m, the circumference by 1.85 mm.
- a 25 x 500 mm specimen of the material was placed on a sheet steel surface and pressed in accordance with the FINA method with a 1 bar pressure roller. The measurement takes place at 20 ° C. 65% rel. Humidity after a waiting period of 20 min. instead of. The test film is in a 180 ° angle with a progress of 300 mm / min. deducted.
- a self-adhesive 150 microns thick soft PVC film is permanently connected on one side by means of a two-component adhesive with the fabric side of a rubber blanket.
- the resulting self-adhesive rubber blanket can be placed either conventionally on the rubber pressure cylinder as well as by annular assembly as a sleeve mounted on the rubber pressure cylinder.
- a multilayer film consisting of a 150 micron PU film and a 25 micron ethylene-vinyl acetate layer is laminated on the back with a 125 micron thick polyester film by means of a permanent adhesive.
- the polyester film backing is coated with a rubber adhesive (Chemosil 411) by knife coating.
- a non-woven rubber blanket is inextricably vulcanized at 150 ° C by means of an AUMA calender with the film composite on the polyester side.
- the AUMA is a machine used for the vulcanization of elastomers (rubber).
- the elastomer is calendered at about 150 ° C between heated cylinders.
- the self-adhesive ethylene vinyl acetate side is bubble-free mounted on the offset rubber cylinder.
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
Die vorliegende Erfindung betrifft eine selbsthaftende Unterlagenfolie für den Offsetdruck.The present invention relates to a self-adhesive backing sheet for offset printing.
Im Offsetdruck werden sowohl auf dem Plattenzylinder als auch auf dem Gummidrucktuchzylinder kalibrierte Unterlagebögen mit und ohne Kleber eingesetzt. Diese dienen dazu, die Umfanglänge der Zylinder der Drucklänge anzupassen. Dies ist nötig, da die Zylinder abhängig vom Druckmaschinenhersteller einen unterschiedlich tiefen Einstich haben und die eingesetzten Druck-und Lackierplatten und Gummidrucktücher unterschiedlich dick sind. Hierzu ist es notwendig, verschieden dicke Papier- oder Kartonbögen oder Unterlagefolien einzusetzen, die diese Unterschiede ausgleichenIn offset printing, calibrated underlay sheets with and without adhesive are used both on the plate cylinder and on the blanket cylinder. These serve to adjust the perimeter length of the cylinders to the print length. This is necessary because the cylinder depending on the printing press manufacturer have a different depth of puncture and the printing and coating plates and blankets used are different thicknesses. For this purpose, it is necessary to use different thickness paper or cardboard sheets or backing sheets that compensate for these differences
Sowohl bei den kalibrierten Papier- und Kartonbögen als auch bei den Unterlagenfolien existieren Ausführungen mit und ohne selbstklebende Ausrüstung. Bei automatischem Platteneinzug kommen nur selbstklebende Unterlagefolien zum Einsatz.Both the calibrated paper and cardboard sheets as well as the backing films have versions with and without self-adhesive equipment. With automatic plate feeder only self-adhesive underlay films are used.
Selbstklebende Folien haben den Vorteil, dass sie leichter zu montieren sind, da sie nicht verrutschen können. Nachteilig an den selbstklebenden Unterlagefolien ist jedoch, dass der Wechsel zeitaufwendiger ist, da gegebenenfalls Kleberrückstände von der Zylinderoberfläche entfernt werden müssen. Hierbei ist zu bedenken, dass beispielsweise im Rollenoffset für den Zeitungsdruck durchaus 64 oder auch 128 Druckwerke eingesetzt werden.Self-adhesive films have the advantage that they are easier to assemble because they can not slip. A disadvantage of the self-adhesive underlay films, however, is that the change is more time-consuming, since adhesive residues may have to be removed from the cylinder surface. It should be noted that, for example, in web offset for newspaper printing quite a 64 or 128 printing units are used.
Es besteht daher weiterhin ein Bedarf nach verbesserten Unterlagematerialien, die die genannten Nachteile des Standes der Technik überwinden.Therefore, there remains a need for improved backing materials that overcome the aforementioned disadvantages of the prior art.
Gelöst wird die Aufgabe durch eine Unterlagenfolie für den Offsetdruck umfassend mindestens eine selbsthaftende Polymerfolie, wobei die Unterlagenfolie eine Dicke von 0,04 bis 2,10 mm aufweist.The object is achieved by a backing film for offset printing comprising at least one self-adhesive polymer film, wherein the backing film has a thickness of 0.04 to 2.10 mm.
Statt einer selbstklebenden Ausrüstung der kalibrierten Unterlagefolie werden solche eingesetzt, die selbsthaftende Eigenschaften aufweisen. Diese weisen aufgrund ihrer spezifischen, zumindest einseitig weichen Oberfläche gute Haftwerte gegenüber den glatten Zylinderoberflächen auf. Der sogenannte "Glasplatteneffekt" verhindert ein Verschieben auch bei hoher Druckgeschwindigkeit und höheren Temperaturen, bei denen selbstklebende Folien teilweise ihre Scherfestigkeit verlieren.Instead of self-adhesive equipment of the calibrated backing film, those are used which have self-adhesive properties. Due to their specific, at least unilaterally soft surface, these have good adhesion values compared with the smooth cylinder surfaces. The so-called "glass plate effect" prevents displacement even at high printing speeds and higher temperatures, in which self-adhesive films lose some of their shear strength.
Da es sich erfindungsgemäß um ein kleberloses System handelt, können auch keine Rückstände auf den Zylinder verbleiben. Dies erspart eine zeitaufwendige Reinigung und beschleunigt damit den Wechsel der Unterlagen.Since it is a glueless system according to the invention, no residues can remain on the cylinder. This saves a time-consuming cleaning and thus accelerates the change of documents.
Gute selbsthaftende Eigenschaften können beispielsweise mit einem 180° Abzugstest mit einer Abzugsgeschwindigkeit von 300 mm/min erreicht werden. Hierbei liegen besonders geeignete Werte für die selbsthaftende Folie im Bereich von 3 bis 8 N/25 mm.Good self-adhesive properties can be achieved, for example, with a 180 ° peel test with a take-off speed of 300 mm / min. Here are particularly suitable values for the self-adhesive film in the range of 3 to 8 N / 25 mm.
Geeignete Materialen für die Herstellung von selbsthaftenden Polymerfolien sind dem Fachmann grundsätzlich bekannt. Besonders geeignete Materialien werden ausgewählt aus der Gruppe Weich-PVC, Polyurethan, Polyethylen, Polypropylen, Ethylvinylacetat und Mischungen hiervon.Suitable materials for the production of self-adhesive polymer films are known to those skilled in principle. Particularly suitable materials are selected from the group of soft PVC, polyurethane, polyethylene, polypropylene, ethyl vinyl acetate and mixtures thereof.
In einer Ausführungsform kann die selbsthaftende Schicht mit einer nichthaftenden Folie kombiniert werden. Die nichthaftende Kunststofffolie verhindert das Verkleben mit der darüber liegenden Offsetplatte.In one embodiment, the pressure-sensitive layer may be combined with a non-adhesive film. The non-adhesive plastic film prevents sticking to the overlying offset plate.
Geeignete Materialien für die nichthaftende Kunststofffolie sind Polyethylen-Terephthalat, Polyurethan, PVC, Polyethylen, Polypropylen und Mischungen hiervon.Suitable materials for the non-adhesive plastic film are polyethylene terephthalate, polyurethane, PVC, polyethylene, polypropylene and mixtures thereof.
In einer bevorzugten Ausführungsform kann die nichthaftende Kunststofffolie eine Rückseitenmattierung aufweisen. Bei Rollen-Offset-Maschinen wird diese unter dem Gummituch platziert und verhindert das Rutschen des Tuches auf der sonst glatten Folienrückseite.In a preferred embodiment, the non-adhesive plastic film may have backside matting. For roll offset presses this becomes placed under the blanket and prevents slipping of the cloth on the otherwise smooth foil back.
In einer weiteren Ausführungsform ist die selbsthaftende Polymerfolie mit einem Gummidrucktuch laminiert. Es entsteht so ein selbsthaftendes Gummidrucktuch, das in besonders einfacher und komfortabler Weise montiert werden kann.In another embodiment, the pressure-sensitive polymer film is laminated with a rubber blanket. The result is a self-adhesive rubber blanket that can be mounted in a particularly simple and comfortable way.
Die Erfindung wird durch die nachfolgenden Beispiele näher erläutert.The invention is explained in more detail by the following examples.
Es wurde ein Mehrschichtfilm bestehend aus 120 µm dicken Weich-PVC-Folie (selbsthaftend) und einer 80 µm dicken PE/HDPE-Folie hergestellt.A multilayer film consisting of 120 μm thick soft PVC film (self-adhesive) and a 80 μm thick PE / HDPE film was produced.
Die Folie wird mit der selbsthaftenden Weich-PVC-Folienseite auf einen Offsetdruckzylinder blasenfrei aufgezogen. Der Umfang des Zylinders erhöht sich dadurch um 400 µm x 3,14 = 1,256 mm.The film is mounted bubble-free with the self-adhesive soft PVC film side on an offset printing cylinder. The circumference of the cylinder is thereby increased by 400 μm x 3.14 = 1.256 mm.
Es wurde ein Mehrschichtfilm aus einer 120 µm dicken Weich-PVC-Folie und einer 25 µm starken Ethylen-Vinylacetat-Schicht auf eine 125 µm Polyesterfolie mit einem 25 µm dicken Permanentkleber auflaminiert. Die Ethylen-Vinylacetat-Schicht ist selbsthaftend und kann auf einen Offsetgummidruckzylinder blasenfrei aufgezogen werden. Der Durchmesser des Zylinders erhöht sich dadurch um 590µm, der Umfang um 1,85 mm.A multilayer film consisting of a 120 μm thick soft PVC film and a 25 μm thick ethylene-vinyl acetate layer was laminated to a 125 μm polyester film with a 25 μm thick permanent adhesive. The ethylene-vinyl acetate layer is self-adhesive and can be applied bubble-free on an offset rubber cylinder. The diameter of the cylinder increases by 590μm, the circumference by 1.85 mm.
Ein Probenkörper mit einer Größe von 25 x 500 mm des Materials wurde auf eine Stahlblech-Oberfläche aufgelegt und gemäß FINA-Methode mit einer Anpressrolle mit 1 bar Druck angepresst. Die Messung findet bei 20°C. 65% rel. Luftfeuchtigkeit nach einer Wartezeit von 20 min. statt. Dabei wird die Prüffolie in einem 180° Winkel mit einem Fortschritt von 300 mm/min. abgezogen.A 25 x 500 mm specimen of the material was placed on a sheet steel surface and pressed in accordance with the FINA method with a 1 bar pressure roller. The measurement takes place at 20 ° C. 65% rel. Humidity after a waiting period of 20 min. instead of. The test film is in a 180 ° angle with a progress of 300 mm / min. deducted.
Eine selbsthaftende 150 µm dicke Weich-PVC-Folie wird einseitig mittels eines Zweikomponentenklebers permanent mit der Gewebeseite eines Gummidrucktuches verbunden. Das so entstandene selbsthaftende Gummidrucktuch kann sowohl herkömmlich auf dem Gummidruckzylinder platziert werden als auch durch ringförmiges Zusammenfügen als Sleeve auf den Gummidruckzylinder aufgezogen werden.A self-adhesive 150 microns thick soft PVC film is permanently connected on one side by means of a two-component adhesive with the fabric side of a rubber blanket. The resulting self-adhesive rubber blanket can be placed either conventionally on the rubber pressure cylinder as well as by annular assembly as a sleeve mounted on the rubber pressure cylinder.
Ein Mehrschichtfilm bestehend aus einer 150 µm PU-Folie und einer 25 µm Ethylen-Vinylacetat-Schicht wird auf der Rückseite mit einer 125 µm dicken Polyesterfolie mittels eines Permanentklebers laminiert. Die Polyesterfolienrückseite wird mittels Rakelauftrags mit einem Gummithaftmittel (Chemosil 411) beschichtet. Ein gewebeloses Gummidrucktuch wird bei 150°C mittels eines AUMA-Kalanders mit dem Folienverbund auf der Polyesterseite untrennbar vulkanisiert. Die AUMA ist eine Maschine, wie sie zur Vulkanisation von Elastomeren (Gummi) Verwendung findet. Dabei wird das Elastomer bei ca. 150°C zwischen beheizten Zylindern kalandriert. Die selbsthaftende Ethylen-Vinylacetat-Seite wird blasenfrei auf den Offsetgummizylinder aufgezogen.A multilayer film consisting of a 150 micron PU film and a 25 micron ethylene-vinyl acetate layer is laminated on the back with a 125 micron thick polyester film by means of a permanent adhesive. The polyester film backing is coated with a rubber adhesive (Chemosil 411) by knife coating. A non-woven rubber blanket is inextricably vulcanized at 150 ° C by means of an AUMA calender with the film composite on the polyester side. The AUMA is a machine used for the vulcanization of elastomers (rubber). The elastomer is calendered at about 150 ° C between heated cylinders. The self-adhesive ethylene vinyl acetate side is bubble-free mounted on the offset rubber cylinder.
Eine selbsthaftende 300µ dicke Weich PVC-Folie mit rückseitiger Schutzabdeckung wird auf einen Offsetzylinder blasenfrei aufgezogen. Vor Einhängen der Offsetplatte wird die Schutzabdeckung abgezogen. Der Umfang des Zylinders erhöht sich um 600µm x 3,14 = 1,88 mm.A self-adhesive 300μ thick soft PVC film with protective cover on the back is mounted bubble-free on an offset cylinder. Before removing the offset plate, the protective cover is removed. The circumference of the cylinder increases by 600μm x 3.14 = 1.88 mm.
Claims (7)
- Use of an underpacking foil comprising at least one self-adhesive polymer sheet, wherein said underpacking foil has a thickness of from 0.04 to 2.10 mm, as an underpacking foil in offset printing.
- The use according to claim 1, characterized in that said self-adhesive sheet exhibits values of from 3 to 8 N/25 mm in a 180° peeling test with 300 mm/min.
- The use according to claim 1 or 2, characterized in that said self-adhesive polymer sheet is selected from materials from the group of flexible PVC, polyurethane, polyethylene terephthalate, polypropylene, ethylvinyl acetate, and mixtures thereof.
- The use according to at least one of claims 1 to 3, characterized in that said underpacking foil additionally comprises a non-adhesive plastic sheet.
- The use according to claim 4, characterized in that said non-adhesive plastic sheet is selected from the group consisting of polyethylene terephthalate, polyurethane, PVC, polyethylene, polypropylene, and mixtures thereof.
- The use according to at least one of claims 4 or 5, characterized in that said non-adhesive plastic sheet has a matt back coating.
- Rubber printing blanket, characterized in that a rubber printing blanket is laminated with an underpacking foil comprising at least one self-adhesive polymer sheet, wherein said underpacking foil has a thickness of from 0.04 to 2.10 mm.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08153798A EP2106925B1 (en) | 2008-03-31 | 2008-03-31 | Self-adhesive underlay film |
| AT08153798T ATE543658T1 (en) | 2008-03-31 | 2008-03-31 | SELF-ADHESIVE BACKING FILM |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08153798A EP2106925B1 (en) | 2008-03-31 | 2008-03-31 | Self-adhesive underlay film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2106925A1 EP2106925A1 (en) | 2009-10-07 |
| EP2106925B1 true EP2106925B1 (en) | 2012-02-01 |
Family
ID=39732011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP08153798A Not-in-force EP2106925B1 (en) | 2008-03-31 | 2008-03-31 | Self-adhesive underlay film |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2106925B1 (en) |
| AT (1) | ATE543658T1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20110807A1 (en) * | 2011-05-10 | 2012-11-11 | Printgraph Waterless S P A | UNDERWEAR OF A RUBBERIZED FABRIC FOR A CYLINDER OF AN OFFSET PRINTING MACHINE |
| EP2692538B1 (en) * | 2012-07-30 | 2017-03-15 | Folex Coating GmbH | Underlay film for a metal printing blanket |
| DE102015213057A1 (en) * | 2015-07-13 | 2017-01-19 | Contitech Elastomer-Beschichtungen Gmbh | Color transmission medium |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU643436B2 (en) * | 1990-05-18 | 1993-11-18 | Dow Chemical Company, The | Polyolefin laminate cling films |
| JP2726341B2 (en) * | 1990-12-04 | 1998-03-11 | 住友ゴム工業 株式会社 | Offset blanket for printing |
| US5614297A (en) * | 1994-05-19 | 1997-03-25 | Viskase Corporation | Polyolefin stretch film |
| DE19947228A1 (en) | 1999-10-01 | 2001-04-05 | Koenig & Bauer Ag | Printer cylinder possessing rubber offset blanket has self adhesive sheet with slanting edges |
| DE10012261A1 (en) * | 2000-03-14 | 2001-09-27 | Holger Hoefer | Film useful as a label, protective surface or reinforcement, comprises a thick support layer and an adhesive free adhesion coating of plasticized PVC. |
| DE60100546T2 (en) | 2001-11-27 | 2004-03-04 | Printgraph Waterless S.R.L. | Universal base for a rubber-coated fabric on cylinders of offset printing machines |
| EP1520690B1 (en) * | 2003-09-22 | 2011-07-27 | Holger Hoefer | adhesive film |
| DE102006027142B3 (en) * | 2006-06-12 | 2007-05-24 | Koenig & Bauer Ag | Printing cloth unit for printing cloth cylinder of printing press has underlays in form of self-adhesive foil applied to underside of carrier plate |
-
2008
- 2008-03-31 EP EP08153798A patent/EP2106925B1/en not_active Not-in-force
- 2008-03-31 AT AT08153798T patent/ATE543658T1/en active
Also Published As
| Publication number | Publication date |
|---|---|
| ATE543658T1 (en) | 2012-02-15 |
| EP2106925A1 (en) | 2009-10-07 |
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