DE68927018T3 - Pfropfcopolymere und Mischungen derselben mit Polyolefinen - Google Patents
Pfropfcopolymere und Mischungen derselben mit PolyolefinenInfo
- Publication number
- DE68927018T3 DE68927018T3 DE68927018T DE68927018T DE68927018T3 DE 68927018 T3 DE68927018 T3 DE 68927018T3 DE 68927018 T DE68927018 T DE 68927018T DE 68927018 T DE68927018 T DE 68927018T DE 68927018 T3 DE68927018 T3 DE 68927018T3
- Authority
- DE
- Germany
- Prior art keywords
- polyolefin
- graft copolymer
- weight
- polymer
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000578 graft copolymer Polymers 0.000 title claims abstract description 181
- 239000000203 mixture Substances 0.000 title claims abstract description 180
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 116
- 229920000642 polymer Polymers 0.000 claims abstract description 135
- 239000000178 monomer Substances 0.000 claims abstract description 90
- 239000002904 solvent Substances 0.000 claims abstract description 50
- 239000003999 initiator Substances 0.000 claims abstract description 33
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 30
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 30
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 29
- 239000007787 solid Substances 0.000 claims abstract description 26
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229920002959 polymer blend Polymers 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract 2
- -1 ethylene, propylene, butylene Chemical group 0.000 claims description 211
- 229920001155 polypropylene Polymers 0.000 claims description 137
- 239000004743 Polypropylene Substances 0.000 claims description 135
- 239000012141 concentrate Substances 0.000 claims description 51
- 150000003254 radicals Chemical class 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 42
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000004698 Polyethylene Substances 0.000 claims description 30
- 230000004907 flux Effects 0.000 claims description 29
- 229920000573 polyethylene Polymers 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 25
- 229920001577 copolymer Polymers 0.000 claims description 25
- 229920006112 polar polymer Polymers 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 22
- 238000001125 extrusion Methods 0.000 claims description 20
- 239000000835 fiber Substances 0.000 claims description 20
- 229920000058 polyacrylate Polymers 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000000465 moulding Methods 0.000 claims description 16
- 229920006113 non-polar polymer Polymers 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- 239000008188 pellet Substances 0.000 claims description 12
- 229920001748 polybutylene Polymers 0.000 claims description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 11
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- LEDIWWJKWAMGLD-UHFFFAOYSA-N bis(2-methylundecan-2-yl) disulfide Chemical compound CCCCCCCCCC(C)(C)SSC(C)(C)CCCCCCCCC LEDIWWJKWAMGLD-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 125000005395 methacrylic acid group Chemical class 0.000 claims description 7
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 7
- 239000004800 polyvinyl chloride Substances 0.000 claims description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- 230000008961 swelling Effects 0.000 claims description 7
- 229920001567 vinyl ester resin Polymers 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 150000001993 dienes Chemical class 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920000515 polycarbonate Polymers 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 5
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 150000008064 anhydrides Chemical class 0.000 claims description 5
- 238000003490 calendering Methods 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
- 229920001021 polysulfide Polymers 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 239000005077 polysulfide Substances 0.000 claims description 4
- 150000008117 polysulfides Polymers 0.000 claims description 4
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
- 238000010101 extrusion blow moulding Methods 0.000 claims description 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 2
- 238000010102 injection blow moulding Methods 0.000 claims description 2
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 8
- 229920000193 polymethacrylate Polymers 0.000 claims 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims 4
- 125000003107 substituted aryl group Chemical group 0.000 claims 4
- 125000005346 substituted cycloalkyl group Chemical group 0.000 claims 4
- 239000012442 inert solvent Substances 0.000 claims 1
- 229920000638 styrene acrylonitrile Polymers 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 19
- 239000000155 melt Substances 0.000 abstract description 18
- 238000001816 cooling Methods 0.000 abstract description 13
- 230000000704 physical effect Effects 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 description 44
- 239000011347 resin Substances 0.000 description 44
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 36
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 28
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 28
- 239000000463 material Substances 0.000 description 24
- 230000000694 effects Effects 0.000 description 22
- 239000000243 solution Substances 0.000 description 22
- 238000006116 polymerization reaction Methods 0.000 description 20
- 239000000654 additive Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 18
- 230000006872 improvement Effects 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
- 229920001903 high density polyethylene Polymers 0.000 description 15
- 239000004700 high-density polyethylene Substances 0.000 description 15
- 238000007665 sagging Methods 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 229920000092 linear low density polyethylene Polymers 0.000 description 13
- 239000004707 linear low-density polyethylene Substances 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
- 239000002253 acid Substances 0.000 description 12
- 239000004926 polymethyl methacrylate Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 238000001746 injection moulding Methods 0.000 description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 10
- 230000002829 reductive effect Effects 0.000 description 10
- 239000003381 stabilizer Substances 0.000 description 10
- 239000004604 Blowing Agent Substances 0.000 description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 9
- 230000008025 crystallization Effects 0.000 description 9
- 238000010561 standard procedure Methods 0.000 description 9
- 239000000454 talc Substances 0.000 description 9
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- 230000000996 additive effect Effects 0.000 description 8
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- 229920001519 homopolymer Polymers 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
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- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 238000010899 nucleation Methods 0.000 description 8
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- 150000007513 acids Chemical class 0.000 description 7
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- 229910052751 metal Inorganic materials 0.000 description 7
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- 238000005266 casting Methods 0.000 description 6
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- 229920001684 low density polyethylene Polymers 0.000 description 6
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- 239000003607 modifier Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920002943 EPDM rubber Polymers 0.000 description 5
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 5
- 229920005629 polypropylene homopolymer Polymers 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 4
- HGBBKKWVSQBIMM-UHFFFAOYSA-N 2-pyrrolidin-1-yl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine Chemical compound O1C(C)(C)C(C)(C)OB1C1=CC=C(N2CCCC2)N=C1 HGBBKKWVSQBIMM-UHFFFAOYSA-N 0.000 description 4
- 229920013665 Ampacet Polymers 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- 125000006545 (C1-C9) alkyl group Chemical group 0.000 description 2
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 2
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 2
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- 239000002667 nucleating agent Substances 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
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- 150000003839 salts Chemical class 0.000 description 2
- HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 description 2
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- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 1
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- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
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- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
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- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
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- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
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- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
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- CXOHVCKJGLFRKZ-AATRIKPKSA-N tert-butyl (e)-but-2-eneperoxoate Chemical compound C\C=C\C(=O)OOC(C)(C)C CXOHVCKJGLFRKZ-AATRIKPKSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
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- 229920001169 thermoplastic Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Materials For Medical Uses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Door And Window Frames Mounted To Openings (AREA)
- Image Generation (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17464888A | 1988-03-29 | 1988-03-29 | |
US07/315,501 US4957974A (en) | 1988-03-29 | 1989-03-01 | Graft copolymers and blends thereof with polyolefins |
DK552689A DK552689A (da) | 1988-03-29 | 1989-11-06 | Formet fast genstand |
Publications (3)
Publication Number | Publication Date |
---|---|
DE68927018D1 DE68927018D1 (de) | 1996-10-02 |
DE68927018T2 DE68927018T2 (de) | 1997-03-20 |
DE68927018T3 true DE68927018T3 (de) | 2003-01-02 |
Family
ID=27222107
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE68927018T Expired - Fee Related DE68927018T3 (de) | 1988-03-29 | 1989-03-28 | Pfropfcopolymere und Mischungen derselben mit Polyolefinen |
DE3910062A Withdrawn DE3910062A1 (de) | 1988-03-29 | 1989-03-28 | Pfropfcopolymeres, verfahren zu seiner herstellung und daraus hergestellte mischungen |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3910062A Withdrawn DE3910062A1 (de) | 1988-03-29 | 1989-03-28 | Pfropfcopolymeres, verfahren zu seiner herstellung und daraus hergestellte mischungen |
Country Status (11)
Country | Link |
---|---|
US (1) | US4957974A (ja) |
EP (1) | EP0335649B2 (ja) |
JP (1) | JP2781197B2 (ja) |
CN (2) | CN1041765A (ja) |
AT (1) | ATE141933T1 (ja) |
DE (2) | DE68927018T3 (ja) |
DK (1) | DK149389A (ja) |
FI (1) | FI891479A (ja) |
GB (1) | GB2216892B (ja) |
NL (1) | NL8900757A (ja) |
NO (1) | NO175537C (ja) |
Families Citing this family (91)
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US5229456A (en) * | 1988-03-29 | 1993-07-20 | Rohm And Haas Company | Graft copolymers and blends thereof with polyolefins |
US5128410A (en) * | 1988-03-29 | 1992-07-07 | Rohm And Haas Company | Graft copolymers and blends thereof with polyolefins |
JPH02158614A (ja) * | 1988-12-13 | 1990-06-19 | Mitsubishi Rayon Co Ltd | メタクリルイミド含有樹脂重合体およびそれを含む熱可塑性樹脂組成物 |
US5147932A (en) * | 1989-03-01 | 1992-09-15 | Rohm And Haas Company | Polyolefin compositions with improved impact strength |
US5061751A (en) * | 1989-06-02 | 1991-10-29 | Exxon Chemical Patents Inc. | Vinylpyrrolidone grafted polyolefins in polymer blends and composites |
FR2651785B1 (fr) * | 1989-09-14 | 1991-12-06 | Atochem | Alliages a base d'un copolymere ethylene alcool vinylique a propriete barriere aux gaz, thermoformable et/ou resistant a la flexion repetee. |
CA2025393A1 (en) * | 1989-09-27 | 1991-03-28 | Newman Bortnick | Graft copolymer impact modifier |
EP0435171B1 (en) * | 1989-12-22 | 1998-03-18 | Nippon Oil And Fats Company, Limited | Sliding property improving agent |
JP3039560B2 (ja) * | 1989-12-27 | 2000-05-08 | 日本石油化学株式会社 | 熱可塑性樹脂組成物およびその用途 |
JPH03203943A (ja) * | 1989-12-28 | 1991-09-05 | Nippon Petrochem Co Ltd | 熱可塑性樹脂組成物 |
CA2033591A1 (en) * | 1990-01-16 | 1991-07-17 | Casmir S. Ilenda | Imidized segmented copolymers |
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ATE143984T1 (de) * | 1990-07-16 | 1996-10-15 | Basf Ag | Gepfropfte und vernetzte propylencopolymerisate |
DE4030564A1 (de) * | 1990-09-27 | 1992-04-02 | Hoechst Ag | Pfropfpolymer auf basis von ultrahochmolekularem polyethylen |
EP0503909A1 (en) * | 1991-03-14 | 1992-09-16 | Chevron Research And Technology Company | Substantially non-crosslinked maleic anhydride-modified ethylene polymers and process for preparing same |
FR2676452B1 (fr) * | 1991-05-16 | 1993-09-03 | Atochem | Compositions a base de polymere de chlorure de vinyle et de polyolefine a proprietes rheologiques ameliorees leur procede de synthese et leur utilisation. |
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DE102007011825B3 (de) | 2007-03-12 | 2008-05-15 | Deutsche Gumtec Ag | Verfahren zur Modifizierung von Gummi- und Thermoplastabfällen mittels Pfropfung während eines Mahlprozesses sowie Verwendung der so modifizierten Gummi-und Thermoplastabfälle |
US20080311328A1 (en) * | 2007-06-13 | 2008-12-18 | Hitoshi Kimura | Non-halogen flame retardant resin composition and non-halogen flame retardant electric wire and cable |
KR101365631B1 (ko) | 2011-11-14 | 2014-02-20 | 롯데케미칼 주식회사 | 폴리올레핀 그래프트 공중합체 및 이를 포함하는 폴리올레핀계 수지 조성물 |
CN103073830B (zh) * | 2013-02-16 | 2015-04-29 | 哈尔滨中大型材科技股份有限公司 | 一种马来酸酐接枝氯化聚氯乙烯复合材料的制备方法 |
CN103275282B (zh) * | 2013-06-04 | 2015-05-13 | 南昌航空大学 | 丙烯酸类聚合物接枝碳纤维多尺度增强体的制备方法 |
US10538611B2 (en) | 2014-04-18 | 2020-01-21 | Nippon A&L Inc. | Graft copolymer and thermoplastic resin composition |
ES2824678T3 (es) * | 2014-12-22 | 2021-05-13 | Dupont Ind Biosciences Usa Llc | Combinación polimérica que contiene poli alfa-1,3-glucano |
US11261278B2 (en) | 2017-12-22 | 2022-03-01 | Rohm And Haas Company | Graft copolymer composition |
US11279787B2 (en) | 2017-12-22 | 2022-03-22 | Rohm And Haas Company | Method of making a graft polymer |
DE102019118856A1 (de) | 2019-07-11 | 2021-01-14 | Voss Automotive Gmbh | Ternäres Polymerblend, insbesondere zur Rohrextrusion, thermoplastisches Kunststoffrohr aus einem derartigen Blend sowie dessen Verwendung |
CN110746697A (zh) * | 2019-11-12 | 2020-02-04 | 福建安达福新材料科技有限公司 | 一种pa/pp超临界发泡复合材料及其制备方法 |
CN113563527B (zh) * | 2020-04-29 | 2024-07-02 | 中国石油化工股份有限公司 | 一种接枝改性聚丙烯材料及其制备方法与应用 |
CN111806008A (zh) * | 2020-07-10 | 2020-10-23 | 上海叶心材料科技有限公司 | 改性聚烯烃覆铁膜 |
CN114456509B (zh) * | 2021-11-15 | 2023-12-05 | 廊坊北化高分子材料有限公司 | 一种用于低熔垂炭黑母粒的改性聚烯烃及其制备方法 |
CN115594919B (zh) * | 2022-10-19 | 2023-12-08 | 南京金陵塑胶化工有限公司 | 一种聚丙烯复合材料及制备方法 |
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GB927519A (en) * | 1960-08-02 | 1963-05-29 | Grace W R & Co | Improvements in polyethylene compositions and their production |
BE632249A (ja) * | 1962-05-17 | |||
US3483273A (en) * | 1966-03-31 | 1969-12-09 | Ppg Industries Inc | Graft copolymers of unsaturated hydrocarbon interpolymers |
US3700754A (en) * | 1967-02-23 | 1972-10-24 | American Cyanamid Co | Compositions of polymers of methyl methacrylate and polymers of ethylene |
SE358891B (ja) * | 1968-03-08 | 1973-08-13 | Mitsubishi Petrochemical Co | |
US3641207A (en) * | 1969-07-15 | 1972-02-08 | Uniroyal Inc | Thermoplastic resin blend of polysulfone resin and an ethylenepropylene terpolymer or graft derivative thereof |
US3866227A (en) † | 1973-03-15 | 1975-02-11 | Rca Corp | Doppler tracker receiver |
IT1063217B (it) * | 1976-04-22 | 1985-02-11 | Snam Progetti | Processo per la preparazione di materiali termoplastici e materiali cosi ottenuti |
DE2740449C2 (de) * | 1977-09-08 | 1986-08-21 | Röhm GmbH, 6100 Darmstadt | Verfahren zur Herstellung von Schmierölzusätzen |
US4426493A (en) * | 1978-08-10 | 1984-01-17 | Borg-Warner Chemicals, Inc. | Graft polyblend flow improvers for PVC |
ZA81322B (en) * | 1980-01-23 | 1982-03-31 | Rohm & Haas | The preparation of graft copolymers, poly (vinyl chloride) compositions containing them and reactors useful in preparing them |
US4595726A (en) † | 1984-10-04 | 1986-06-17 | Hercules Incorporated | N-alkyl methacrylate modified polypropylene |
-
1989
- 1989-03-01 US US07/315,501 patent/US4957974A/en not_active Expired - Lifetime
- 1989-03-28 GB GB8906940A patent/GB2216892B/en not_active Expired - Fee Related
- 1989-03-28 NL NL8900757A patent/NL8900757A/nl not_active Application Discontinuation
- 1989-03-28 DE DE68927018T patent/DE68927018T3/de not_active Expired - Fee Related
- 1989-03-28 EP EP89303029A patent/EP0335649B2/en not_active Expired - Lifetime
- 1989-03-28 DE DE3910062A patent/DE3910062A1/de not_active Withdrawn
- 1989-03-28 DK DK149389A patent/DK149389A/da not_active Application Discontinuation
- 1989-03-28 AT AT89303029T patent/ATE141933T1/de not_active IP Right Cessation
- 1989-03-28 FI FI891479A patent/FI891479A/fi not_active IP Right Cessation
- 1989-03-29 NO NO891303A patent/NO175537C/no unknown
- 1989-03-29 JP JP1080238A patent/JP2781197B2/ja not_active Expired - Fee Related
- 1989-03-29 CN CN89101872A patent/CN1041765A/zh active Pending
- 1989-03-29 CN CN94100179A patent/CN1092782A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
DE3910062A1 (de) | 1989-10-26 |
ATE141933T1 (de) | 1996-09-15 |
NL8900757A (nl) | 1989-10-16 |
EP0335649A2 (en) | 1989-10-04 |
FI891479A (fi) | 1989-09-30 |
DK149389A (da) | 1989-09-30 |
EP0335649B1 (en) | 1996-08-28 |
GB8906940D0 (en) | 1989-05-10 |
GB2216892B (en) | 1992-10-21 |
US4957974A (en) | 1990-09-18 |
NO175537B (no) | 1994-07-18 |
GB2216892A (en) | 1989-10-18 |
JPH0222316A (ja) | 1990-01-25 |
NO175537C (no) | 1994-10-26 |
JP2781197B2 (ja) | 1998-07-30 |
DE68927018D1 (de) | 1996-10-02 |
NO891303L (no) | 1989-12-27 |
CN1041765A (zh) | 1990-05-02 |
EP0335649B2 (en) | 2002-09-04 |
FI891479A0 (fi) | 1989-03-28 |
DK149389D0 (da) | 1989-03-28 |
NO891303D0 (no) | 1989-03-29 |
EP0335649A3 (en) | 1991-07-10 |
DE68927018T2 (de) | 1997-03-20 |
CN1092782A (zh) | 1994-09-28 |
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