BR9813297A - Processos de produção de um copolìmero de enxerto, e para produzir um óleo lubrificante, e, produto - Google Patents
Processos de produção de um copolìmero de enxerto, e para produzir um óleo lubrificante, e, produtoInfo
- Publication number
- BR9813297A BR9813297A BR9813297-0A BR9813297A BR9813297A BR 9813297 A BR9813297 A BR 9813297A BR 9813297 A BR9813297 A BR 9813297A BR 9813297 A BR9813297 A BR 9813297A
- Authority
- BR
- Brazil
- Prior art keywords
- copolymer
- producing
- methods
- extruder
- monomer
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M151/00—Lubricating compositions characterised by the additive being a macromolecular compound containing sulfur, selenium or tellurium
- C10M151/02—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/02—Polyethene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/02—Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Graft Or Block Polymers (AREA)
- Lubricants (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
"PROCESSOS DE PRODUçãO DE UM COPOLìMERO DE ENXERTO, E PARA PRODUZIR UM óLEO LUBRIFICANTE, E, PRODUTO". Apresentam-se processos para produzir copolímeros de enxerto. Os processos compreendem as etapas de: (a) prover (i) um copolímero de etileno/propileno (EP) ou outro polímero enxertável, (ii) um monómero etilenicamente insaturado contendo enxofre, nitrogênio e/ou oxigênio, e (iii) uma quantidade de um iniciador suficiente para enxertar dito monómero e o copolímero de EP ou outro polímero enxertável; (b) introduzir dito copolímero de EP ou outro polímero enxertável em uma extrusora; (c) introduzir dito monómero na extrusora; (d) introduzir dito iniciador na extrusora; em que pelo menos um dos reagentes acima identificados em (a) é introduzido na presença de um solvente polar; e (e) reagir dito copolímero de EP ou outro polímero enxertável, monómero e iniciador, mediante operação da dita extrusora, dessa forma formando o copolímero de enxerto. Esta invenção diz respeito também a processos de produzir um melhorador do índice de viscosidade dispersante e processos para produzir um óleo lubrificante. Esta invenção ainda diz respeito a produtos copoliméricos de enxerto, produzidos pelos processos acima mencionados.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US6368997P | 1997-10-28 | 1997-10-28 | |
PCT/GB1998/003208 WO1999021902A1 (en) | 1997-10-28 | 1998-10-28 | Processes for preparing grafted copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9813297A true BR9813297A (pt) | 2000-08-29 |
Family
ID=22050841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9813297-0A BR9813297A (pt) | 1997-10-28 | 1998-10-28 | Processos de produção de um copolìmero de enxerto, e para produzir um óleo lubrificante, e, produto |
Country Status (10)
Country | Link |
---|---|
US (2) | US6410652B1 (pt) |
EP (1) | EP1025138B1 (pt) |
JP (1) | JP4377545B2 (pt) |
CN (1) | CN1147515C (pt) |
AT (1) | ATE290027T1 (pt) |
AU (1) | AU757434B2 (pt) |
BR (1) | BR9813297A (pt) |
CA (1) | CA2308442C (pt) |
DE (1) | DE69829197T2 (pt) |
WO (1) | WO1999021902A1 (pt) |
Families Citing this family (69)
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BR9813297A (pt) * | 1997-10-28 | 2000-08-29 | Castrol Ltd | Processos de produção de um copolìmero de enxerto, e para produzir um óleo lubrificante, e, produto |
US20040071980A1 (en) * | 2000-07-12 | 2004-04-15 | Mcbain Douglas S. | Method for in-mold coating a polyolefin article |
US8058354B2 (en) * | 2001-02-09 | 2011-11-15 | Eastman Chemical Company | Modified carboxylated polyolefins and their use as adhesion promoters |
US6548606B1 (en) | 2002-01-23 | 2003-04-15 | Infineum International Ltd. | Method of forming grafted copolymers |
EP2484660A3 (en) | 2002-05-24 | 2013-03-13 | Castrol Limited | Preparation of monomers for grafting to polyolefins |
US7163913B2 (en) | 2003-07-01 | 2007-01-16 | Infineum International Limited | Viscosity index improvers for lubricating oil compositions |
US7514393B2 (en) | 2003-11-21 | 2009-04-07 | Castrol Limited | Preparation of functional monomers for grafting to low molecular weight polyalkenes and their use in the preparation of dispersants and lubricating oil compositions containing dispersant polyalkenes |
DE102004005172A1 (de) * | 2004-02-02 | 2005-08-18 | Aventis Pharma Deutschland Gmbh | Indazolderivate als Inhibitoren der Hormon Sensitiven Lipase |
ITMI20040751A1 (it) * | 2004-04-16 | 2004-07-16 | Polimeri Europa Spa | Procedimento per modificare le proprieta' reologiche di polimeri ep d m e miscele di ep d m con poli-alfaolefine |
US20070191242A1 (en) * | 2004-09-17 | 2007-08-16 | Sanjay Srinivasan | Viscosity modifiers for lubricant compositions |
US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
US8058355B2 (en) * | 2004-10-06 | 2011-11-15 | Eastman Chemical Company | Modified chlorinated carboxylated polyolefins and their use as adhesion promoters |
WO2006088693A2 (en) * | 2005-02-14 | 2006-08-24 | The Lubrizol Corporation | Novel viscosity modifying dispersant |
US8703872B2 (en) * | 2005-03-11 | 2014-04-22 | Castrol Limited | Multiple function graft polymer |
BRPI0610105A2 (pt) | 2005-04-28 | 2010-05-25 | Castrol Ltd | polìmero de enxerto dispersante de função múltipla, processo para a sua fabricação, óleo lubrificante e processo de aperfeiçoamento de tratamento de fuligem, controle de viscosidade, controle de lama e controle de verniz de um óleo lubrificante |
CN100584870C (zh) * | 2005-06-03 | 2010-01-27 | 中国科学院长春应用化学研究所 | 稀土化合物参与的功能化聚烯烃树脂的制备方法 |
EP2128232A1 (en) | 2008-05-20 | 2009-12-02 | Castrol Limited | Lubricating composition for ethanol fueled engines |
KR100996420B1 (ko) * | 2008-12-26 | 2010-11-24 | 호남석유화학 주식회사 | 용융장력이 우수한 폴리프로필렌 수지 조성물 및 그 제조방법 |
US8033751B2 (en) * | 2009-10-08 | 2011-10-11 | Caterpillar Trimble Control Technologies Llc | Gyro compensated inclinometer for cross slope control of concrete screed |
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PL2633009T3 (pl) | 2010-10-26 | 2016-10-31 | Niewodny środek smarny i kompozycje paliwowe zawierające estry kwasów tłuszczowych kwasów hydroksykarboksylowych, i ich zastosowania | |
WO2012168151A1 (en) | 2011-06-09 | 2012-12-13 | Castrol Limited | Compositions, methods and uses |
ES2657913T3 (es) | 2011-12-21 | 2018-03-07 | Infineum International Limited | Lubricación de motor marino |
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WO2013189674A1 (en) | 2012-06-20 | 2013-12-27 | Castrol Limited | Friction modifier and their use in lubricants and fuels |
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US10538611B2 (en) | 2014-04-18 | 2020-01-21 | Nippon A&L Inc. | Graft copolymer and thermoplastic resin composition |
WO2015172846A1 (en) | 2014-05-16 | 2015-11-19 | Ab Nanol Technologies Oy | Additive composition for lubricants |
GB201501991D0 (en) | 2015-02-06 | 2015-03-25 | Castrol Ltd | Uses and compositions |
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GB201901149D0 (en) | 2019-01-28 | 2019-03-20 | Castrol Ltd | Use of ether base stocks |
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GB201914191D0 (en) | 2019-10-02 | 2019-11-13 | Castrol Ltd | Non-metallic phosphorus antiwear additives |
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CN113563522B (zh) * | 2020-04-29 | 2024-07-02 | 中国石油化工股份有限公司 | 一种聚丙烯接枝杂环的改性材料作为绝缘材料的应用和绝缘材料 |
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CN115991021B (zh) * | 2021-10-20 | 2024-09-17 | 中国石油化工股份有限公司 | 一种聚丙烯复合薄膜及其制备方法和应用 |
CN115991032B (zh) * | 2021-10-20 | 2024-08-20 | 中国石油化工股份有限公司 | 一种聚丙烯复合薄膜及其制备方法和应用 |
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US3593011A (en) | 1968-05-09 | 1971-07-13 | Exxon Research Engineering Co | Analogue control device for chemical processes |
US3608001A (en) | 1969-08-26 | 1971-09-21 | Exxon Research Engineering Co | Controlled degradation of polypropylene in extruder-reactor |
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US5298555A (en) * | 1990-01-09 | 1994-03-29 | American Cyanamid Company | Low settling water-in-oil emulsions |
CA2036862A1 (en) | 1990-02-23 | 1991-08-24 | Tony L. Caines | Continuous process for producing adducted epm or epdm oil solution |
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US5523008A (en) * | 1994-10-21 | 1996-06-04 | Castrol Limited | Polar grafted polyolefins, methods for their manufacture, and lubricating oil compositions containing them |
US5663126A (en) | 1994-10-21 | 1997-09-02 | Castrol Limited | Polar grafted polyolefins, methods for their manufacture, and lubricating oil compositions containing them |
BR9813297A (pt) * | 1997-10-28 | 2000-08-29 | Castrol Ltd | Processos de produção de um copolìmero de enxerto, e para produzir um óleo lubrificante, e, produto |
-
1998
- 1998-10-28 BR BR9813297-0A patent/BR9813297A/pt not_active IP Right Cessation
- 1998-10-28 CN CNB988107848A patent/CN1147515C/zh not_active Expired - Fee Related
- 1998-10-28 DE DE69829197T patent/DE69829197T2/de not_active Expired - Lifetime
- 1998-10-28 EP EP98951565A patent/EP1025138B1/en not_active Expired - Lifetime
- 1998-10-28 AU AU97526/98A patent/AU757434B2/en not_active Ceased
- 1998-10-28 WO PCT/GB1998/003208 patent/WO1999021902A1/en active IP Right Grant
- 1998-10-28 CA CA002308442A patent/CA2308442C/en not_active Expired - Fee Related
- 1998-10-28 JP JP2000518007A patent/JP4377545B2/ja not_active Expired - Fee Related
- 1998-10-28 AT AT98951565T patent/ATE290027T1/de not_active IP Right Cessation
-
2000
- 2000-04-06 US US09/529,013 patent/US6410652B1/en not_active Expired - Lifetime
-
2002
- 2002-03-11 US US10/093,517 patent/US6723796B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1025138A1 (en) | 2000-08-09 |
AU9752698A (en) | 1999-05-17 |
JP4377545B2 (ja) | 2009-12-02 |
EP1025138B1 (en) | 2005-03-02 |
US6723796B2 (en) | 2004-04-20 |
AU757434B2 (en) | 2003-02-20 |
CN1278274A (zh) | 2000-12-27 |
DE69829197T2 (de) | 2006-02-16 |
ATE290027T1 (de) | 2005-03-15 |
CA2308442C (en) | 2009-09-01 |
US6410652B1 (en) | 2002-06-25 |
CA2308442A1 (en) | 1999-05-06 |
CN1147515C (zh) | 2004-04-28 |
DE69829197D1 (de) | 2005-04-07 |
JP2001521049A (ja) | 2001-11-06 |
US20020183456A1 (en) | 2002-12-05 |
WO1999021902A1 (en) | 1999-05-06 |
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