CN1324418A - 转印法中所用图案载体,以及为获得该载体以非晶形糖浆于涂布纸材的分散液中的应用 - Google Patents
转印法中所用图案载体,以及为获得该载体以非晶形糖浆于涂布纸材的分散液中的应用 Download PDFInfo
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Abstract
用于转印纺织品的图案载体,包括空气渗透性(Bendtsen孔度)大于500ml/min、吸水度相当于Cobb数至少50的纸材。该纸以含非结晶糖浆的羧甲基纤维素水分散液涂布,优选涂布量每平方米30g分散液。其后于该纸上印上单色或多色图案,各彩色图案含水溶性或水分散性染料,与具暂时性粘合作用的易溶性增稠载体相混合,所述增稠剂优选羧甲基纤维素型。采用糖浆,优选山梨糖醇进行涂布,便可使用标准吸收性原纸作为图案载体纸基,从而提供明显的成本和产量上的优势。
Description
技术领域
本发明涉及其上印有彩色图案用于转印湿纺织品的成卷纸材图案载体。本发明也涉及以本身已知的糖浆,作为涂布纸卷的分散液成分,为获得有特殊性能的图案载体的应用。
背景技术
图案转印法是已知技术并被广泛采用,该技术涉及将预先印上的图案从成卷图案载体连续转印到成卷湿纺织品上,其中两种卷材的转印区连续相接触,该转印区是以一对或多对压辊形式使之不断接触的(参见附图)。
自从20年代以来,该工艺的主要不同类型已为人知,但直到50年代后期才开始在工业上实施。各种类型转印技术,特别在下述专利文件下公开过:US-PS Nos.1 651 470和1 783 606,FR-PS Nos.1034 816和1 036 510,DK专利申请Nos.5666/68和1 566/69,SE-PS No.137 674,GB-PS Nos.1 430 832和1 480 328,US-PS Nos.1,965,257和1,993,524,DE公开说明书Nos.2 710 158和2 702 300和US-PS No.4 057 864。这些公开文献中所述方法一个共同性是,如果不实施加热和/或采用以挥发有机溶剂为基础的染料,均不可能获得可接受的结果。经常是,要获得有用的结果需要如此长的时间,以致于事实上该工艺已经不是连续印制的问题了。
因此,当本发明人在80年代后期成功地开创一种转印方法,可以同时避免加热和采用有机溶剂,便是转印法的一个重大突破。该方法公开于DK-PS No 169 135,其特征在于适当挑选图案载体和染料配方、精确控制纺织品的润湿、并施以适当的高压,由此可以相当高的加工速度获得特别良好的再现结果。且正如前述,不用加热并独特地采用水基染料配制物。除了有关生产上的优点和特别优良的产品质量外,上述专利的方法也有明显的关系到环境和能量的优势,并且大大改善了工作环境。
然而这一开创性的方法也有其局限性。为了更为精确,该方法对作为图案载体的纸有特别的要求,即为了按所需印染速度涂布上彩色图案,所述纸必需有特殊性质。所用纸必需使用只稍有吸收性的质量,为了避免涂布的不同色彩变得模糊不清,必需在每种颜色涂布的间隔时间内深冷纸材、使色彩固结。纸的印刷通过如图所示的网屏印刷装置进行。根据上述专利的方法,各印刷网屏之间需配有图中未画出的冷却辊。涂布过的纸材绕冷却辊运行,使之冷却至-20℃以下。以这种方式,可以避免各网屏所涂色彩混为一潭。然而,这一“冷冻”法自然会使整个工艺大为复杂化、增加了成本。因此,人们希望能提供一种图案载体,其上的彩色不会相互污染,甚至以很高印染速度也可以做到,从而不需要在各色彩涂布之间加以冷却。
为了改变低的吸收性能,挑选适当物质来涂布纸面是本身已知的方法。DE公开说明书No.35 04 814公开了一种纺织品转印法,其中以羧甲基纤维素涂布的纸作为图案载体。DE已接纳的公开说明书No.2701 392也公开了一种转印法,该方法使用涂有羧甲基纤维素的纸作图案载体,并借助加热和/或加压使染料由图案载体转印到织物上。
使用羧甲基纤维素涂布纸面是众所周知的。根据上述DF专利No169 135,图案载体需稍有吸收性,因此要使用涂布过的纸。使用羧甲基纤维素、藻酸盐或者聚乙烯或聚丙烯酸酯水分散液来涂布,优选羧甲基纤维素,因其易得而性能优良。但是羧甲基纤维素本身,并不足以为标准吸收性的原纸提供所希望的吸收性能。
有关采用糖类来制造转印纸的报道,只在日本专利申请No44-16135中介绍过。但该申请只涉及到转印彩色图案到瓷器和陶器中的转印纸。加入一种或多种单糖或低聚糖到含纤维素衍生物的水溶性糊状物中,以其涂布纸上,发现当图案转印到瓷器或陶器上以后,该纸更容易从这些器皿上除去。而且,使用含有所述糖的转印纸,在陶瓷器被烧制后其图案十分清晰。根据上述日本专利申请,该转印纸必需涂两次,底层涂只含纤维素衍生物的水溶液涂料,而上层涂加有经挑选的糖的相同溶液涂料。然后在涂层上再涂防水层,根据实施例,所述防水层是乙酰基纤维素的30%丙酮溶液。因此该已知转印纸比本发明的涂布纸要复杂得多,且用于完全不同的目的。
本发明简述
现出人意料地发现,用含有非结晶糖浆的羧甲基纤维素水分散液涂布标准吸收性纸,可由所述纸制得所述的图案载体。该涂料有出乎预料的性能,即该涂料能使来自印染染料的水分立即渗透,而染料浓缩物与羧甲基纤维素一起保留于表面。结果纸面保持干燥,而各种色彩图案不会变得模糊不清。这些彩色图案可以容易地在随后的转印期间被再次从纸上除去。
因此本发明涉及有彩色图案印于其上的成卷纸材图案载体,于一对或多对辊筒之间使该纸材和织物加压穿过,而将其用于整卷湿纺织品的转印,不需加热,但在使纺织品只短暂受压的线性压力下其厚度减小,接着便自然胀开,由此彩色图案便从图案载体上被吸收进织物内。根据本发明的图案载体,其特征在于,它由空气渗透性(Bendtsen孔度)大于500ml/分(根据标准DIN 53120T1测定)、吸水性相应Cobb数(Cobb60)至少50(根据标准SCAN-P12:64测定)的纸制成,并用含非结晶糖浆的羧甲基纤维素水分散液涂布该纸,涂布量优选每平方米涂分散液约30g,此后将一种或多种色彩的图案印于该纸上。各彩色图案含有水溶性或水分散性染料,与易溶性增稠载体(带有暂时性粘合作用)混合,该载体优选羧甲基纤维素型。
为纸材提供出人意料的有用性能的分散液成分是非结晶糖浆,优选山梨醇糖浆。该产品常用于食品工业,而用于普通纸涂料鲜为人知。因此该产品从未用作普通纸涂料且随后用于涉及纺织品转印的图案载体。
因此本发明也涉及非结晶糖浆的应用,将其用作涂布纸材的水分散液成分,由此获得图案载体,该载体表面能立即透过来自印染染料的水分,而所述染料则与羧甲基纤维素一起保留于表面。
本发明有几个突出优点。第一,图案载体纸的选择比从前要宽容得多,因为可以使用普通标准吸收性原纸,这比现有技术使用的纸要便宜得多。而且本发明的涂布纸有利于将彩色图案印于其上,并不需要技术熟练人员,因而也无需培训雇员,由此,该涂布纸上彩色图案的印制较之从前远远可达更高水平。当染料消耗与从前所用纸相同时,其浪费比例则明显降低,特别是转印于纤维素纤维或天然纤维更是如此。该制好的印染纸可与从前的相同方式使用,即以DK-PSNo.169 135所述相同方法和同样机器使用。结果有与该专利相同的结果,即不使用挥发性溶剂、不加热、而以高产率转印于纺织品上,同时可使用标准吸收性原纸作图案载体,当印制图案载体时,各印刷网屏间的任何形式的干燥或冷却装置均不需要。
挑选来的原纸用含非结晶糖浆的羧甲基纤维素水分散液以复盖层的形式涂布,优选涂布量为每平方米纸面约30g分散液。典型的分散液组成如下(按重量计):68% 水20% 糖浆12% 羧甲基纤维素(干重)。
借助网屏辊将纸的印染面涂布,也可以在生产原纸时,于造纸机上按相同循环操作进行联机涂布。经过涂布的纸然后由许多印染网屏(A、B、C、D…)进行印染,如附图所示,由此借助各种颜色的网屏将所需彩色图案印上。因有所述涂料赋予的特殊性质,使涂上的色彩立即变干,结果无需中间干燥和冷冻处理,该纸可以直接由一个网屏向下一个网屏行进。该印染纸速通常为每分钟60-80米,即约1米/秒。即使这么高的速度,根据本发明,该纸的印染也没什么问题,因为表面变干和色彩固化如此之快(在1秒钟以内),以致其通过网屏A之后,而远未到达网屏B之前,该纸表面便已完全干燥。当通过最后印染网屏(图中D)后,所需彩色图案获得时,再使该印染后的纸最后干燥,然后卷于辊上。
转印于整卷纺织品上按本身已知方式进行,即在碱性浴中将纺织品润湿,并加以控制地使其加压,使之达到一定的润湿度,然后将其与印染过的纸相贴以适当的高压从一对或多对加压辊之间通过。最后将纺织品上印上的色彩按本身已知方法固色,而用过的图案载体被再循环,即将纸加以再利用。
所用糖浆优选以山梨糖醇为基础,但其它糖也可以用,例如葡萄糖、果糖、甘露糖、半乳糖、木糖、阿拉伯糖、核糖等。一种特别优选的糖浆是Cerestar公司的产品“Sorlidex 200”。该产品主要含山梨糖醇,但也含少量甘露糖醇(约1.1%)以及还原糖(约0.1%)。
水分散液中也含羧甲基纤维素,例如可以是“Ambergum1221”,它是水溶性阴离子纤维素聚合物,购自Aqualon公司。该产品也宜用作印染用彩色配方的成分。
本发明的新型图案载体,特别适合采用DK-PS No.169 135的方法将其用于转印纤维素纤维和其它天然纤维。原则上,任何水溶性或水分散性染料,例如直接染料、阳离子染料、铬络合物染料、活性染料、以及颜料等图形都可以印于本发明的图案载体上。这些染料中,特别优选活性染料。
此外,本发明的图案载体可用于将分散染料印染于合成纤维织品上。还可以采用“喷墨”印刷方式将彩色图案印于本发明图案载体上,且酸性染料图案也可印于其上。
由下述实施例更详细地说明本发明。
实施例
下面的实施例使用购自Cham Tenero公司的牌号为“Transferroto Classico”型814机器上光原纸。该纸1千格令的定量以克表示为65.0克/米2。根据标准DIN 53120 T1测定其“Bendtsen孔度”(空气渗透性)为700ml/min,其吸水度相应于根据标准SCAN-P12:64测定的Cobb数(即Cobb60)为55.5,根据标准DIN EN ISO 1924-2测定其相对湿强度为9.5%、而临界强度为63.6N/15mm。
以含下述成分的水分散液涂布该纸的印染面:
83.4kg “Sorbidex 200”
50.0kg “Ambergum1221”
羧甲基纤维素(CMC)将其在283.6kg水中搅拌。为了能够观察到该涂层,如果需要的话,可在分散液中加入一些调色剂,如1.25kg染料Pigmatex红和Pigmatex黄(各一半)。
实施例1
将两色图案印于成卷的纤维素纤维织物上(粘胶纤维和棉)。印花之前按常规方式将该织品预处理,即使之完全清洁,如果要在辊缘上成卷,则必需紧贴辊缘固牢。
在Stork RT印染机上,通过圆筒状网屏,将两色图案印于经过涂布的纸上,所述两色染料浆液组成如下:配方1
活性染料(Rematrans Rot 358) 100g
天然增稠剂(CMC钠) 120g
合成增稠剂(Alcoprint RTA) 6.8g
消泡剂(Alcopol 0 60%) 1.1g
络合剂(Ladiquest 1097) 11g
软化水补足至 1000g配方2
活性染料(Rematrans Blau 257) 200g
天然增稠剂(CMC钠) 120g
合成增稠剂(Alcoprint RTA) 6.8g
消泡剂(Alcopol 0 60%) 1.1g
络合剂(Ladiquest 1097) 11g
软化水补足至 1000g
将该两色图案在“棉工艺”标准印染机上从纸材上转印到纺织品上、所述成卷的纺织品事先用下述混合物润湿过:
NaOH,34°Bé 50g/l
硅酸钠,36°Bé 100g/l
络合剂(Ladiquest 1997) 1g/l
软化水补足至 1l
该纺织品上液体吸收率为约65%。
由本身已知的所谓“冷却-上定色剂-分批处理”法使染料在该织物上固色。实施例2
将相同织物按实施例1同样预处理。以“喷墨印刷”全宽度机(140-180cm)将多色图案印于经过涂布的纸上。以Rematrans品牌的浓缩着色剂用于该机器,优选下述产品:
Rematrans Gelb 089
- Goldgelb 070
- Orange 035
- Rot 004
- Rot 358
- Blau 267
- Blau 257
- Türkis 216
- Grün 201
- Schwarz 288
- Schwarz 263
- Schwarz 258
将该纸上的彩色图案印于实施例1的织物上,如实施例1所述,其后将色彩在该织品上固色。
实施例3
将两色图案印于按常规方法处理过的聚酰胺织品上。
在Stork RT印染机上,通过圆筒状网屏将两色图案印于经涂布过的纸上,所述两色染料浆液组成如下:
配方1:
酸性染料(Erionyl Blau) 300g
天然增稠剂(Na-GMC) 150g
络合剂 10g
软化水补足至 1000g
用NaOH调节pH到8
配方2:
酸性染料(Erionyl Bordeaux) 400g
天然增稠剂(Na-CMC) 100g
络合剂 10g
软化水补足至 1000g
用NaOH调节pH到8。
在“棉织工艺”标准机上,将纸上的两色图案转印到织物上,所述织物在下述组合物的液体浴中预先润湿过:
天然增稠剂CMC钠 5g
软化水补足至 1000g
用酸/缓冲剂将pH调至3。
该织物的液体吸收率为约45%
通过所谓的“冷却-上固色剂-分批处理法”将染料在织品上固色。
实施例4
将三色图案印于聚酯纺织品上,所述织品经过常规预处理。
在Stork RT印染机上,通过圆筒状网屏,将三色图案印于经过涂布的纸上。该三色染料浆液组成如下:
配方1:
Teraprint Rot 5g(分散染料) 100g
Lyoprint TFA 27g
Lyoprint AP 7g
Lyoprint BS Conc. 90g
NaOH 5g
配方2:
Teraprint Gelb G(分散染料) 100g
Lyoprint TFA 27g
Lyoprint AP 7g
Lyoprint BS Conc. 90g
NaOH 5g
配方3:
Teraprint Blau 6R(分散染料) 100g
Lyoprint TFA 27g
Lyoprint AP 7g
Lyoprint BS Conc. 90g
NaOH 5g
在Lemaire HTP标准转印机上,将该彩色图案从纸上转印到纺织品上。该机器运行时设定为215℃,接触时间为25秒。
然后将其干燥。当织品离开机器时彩色被固定。
Claims (5)
1.有彩色图案印于其上的成卷纸材图案载体,于一对或多对辊筒之间,使该纸材和纺织品施压穿过,而将该纸卷上图案转印于润湿的整卷纺织品上,无需加热,但在使纺织品短暂受压的线性压力下,该织品厚度减小,随之自然胀开,由此彩色图案便从图案载体上被吸收进纺织品上,其特征在于,制成该图案载体的纸,其空气渗透性(Bendtsen孔度),根据标准DIN 53120T1测定为大于500ml/min,与Cobb数相应的吸水度,根据标准SCAN-P12:64测定(Cobb60)为至少50,所述纸以含有非结晶糖浆的羧甲基纤维素水分散液涂布,其涂布量优选每平方米约涂30g分散液,此后将单色或多色图案印于该纸上,各色图案含有水溶性或水分散性染料与具暂时性粘合作用的易溶性增稠载体混合,优选羧甲基纤维素型增稠载体。
2.根据权利要求1的图案载体,其特征在于,所用糖浆含山梨糖醇作为主要成分。
3.根据权利要求2的图案载体,其特征在于,所用糖浆除含山梨糖醇外,还含少量甘露糖醇和还原糖。
4.根据权利要求3的图案载体,其特征在于,所用糖浆占分散液重量的约20%。
5.非结晶糖浆用作涂布纸材的水分散液成分的用途,由此获得图案载体,其表面可以立即透过来自印染染料的水分,而所述染料则与羧甲基纤维素一起保留于表面上。
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CN103797185B (zh) * | 2011-05-10 | 2016-05-04 | 比弗文书和绘图媒体公司 | 转移图案印刷用纸 |
CN102673110A (zh) * | 2011-05-12 | 2012-09-19 | 王天友 | 一种多功能印刷定位机及其生产工艺 |
CN102673110B (zh) * | 2011-05-12 | 2014-03-26 | 王天友 | 一种多功能印刷定位机及其生产工艺 |
CN110719977A (zh) * | 2017-06-08 | 2020-01-21 | Tam公司 | 纺织品转移印花的工艺 |
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