CN102008409B - Liquid shampoo - Google Patents
Liquid shampoo Download PDFInfo
- Publication number
- CN102008409B CN102008409B CN2010105198044A CN201010519804A CN102008409B CN 102008409 B CN102008409 B CN 102008409B CN 2010105198044 A CN2010105198044 A CN 2010105198044A CN 201010519804 A CN201010519804 A CN 201010519804A CN 102008409 B CN102008409 B CN 102008409B
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- China
- Prior art keywords
- parts
- hair
- shampoo
- agent
- conditioner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 title 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 150000001408 amides Chemical class 0.000 claims description 10
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 6
- BWPGKXYWPBQBPV-MWQJAWBESA-N Theasaponin Chemical compound O([C@H]1[C@H](O)[C@H](O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@@H](O)CO1)O[C@H]1[C@@H]([C@@H](O)[C@H](O)CO1)O)O[C@H]1CC[C@]2(C)[C@H]3CC=C4[C@@]([C@@]3(CC[C@H]2[C@@]1(CO)C)C)(C)C[C@@H](O)[C@@]1(CO)[C@@H](OC(C)=O)[C@@H](C(C[C@H]14)(C)C)OC(=O)C(\C)=C/C)C(O)=O)[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O BWPGKXYWPBQBPV-MWQJAWBESA-N 0.000 claims description 6
- BWPGKXYWPBQBPV-ZOADXXHESA-N Theasaponin Natural products O=C(O[C@@H]1[C@@H](OC(=O)C)[C@]2(CO)[C@@H](O)C[C@@]3(C)[C@@]4(C)[C@@H]([C@]5(C)[C@H]([C@@](CO)(C)[C@@H](O[C@@H]6[C@@H](O[C@@H]7[C@H](O[C@@H]8[C@@H](O)[C@H](O)[C@H](O)CO8)[C@H](O)[C@@H](O)CO7)[C@@H](O[C@H]7[C@H](O)[C@@H](O)[C@@H](O)[C@H](CO)O7)[C@H](O)[C@@H](C(=O)O)O6)CC5)CC4)CC=C3[C@@H]2CC1(C)C)/C(=C/C)/C BWPGKXYWPBQBPV-ZOADXXHESA-N 0.000 claims description 6
- 229940025250 camphora Drugs 0.000 claims description 6
- 239000010238 camphora Substances 0.000 claims description 6
- 235000019864 coconut oil Nutrition 0.000 claims description 6
- 239000003240 coconut oil Substances 0.000 claims description 6
- NOOLISFMXDJSKH-UHFFFAOYSA-N p-menthan-3-ol Chemical compound CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 6
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 6
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 6
- 235000013599 spices Nutrition 0.000 claims description 6
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 230000037308 hair color Effects 0.000 claims description 5
- 230000002421 anti-septic effect Effects 0.000 claims description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 3
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims 1
- 229960003415 propylparaben Drugs 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 6
- 239000006260 foam Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 208000003251 Pruritus Diseases 0.000 abstract description 3
- 238000005282 brightening Methods 0.000 abstract 1
- 239000002826 coolant Substances 0.000 abstract 1
- 230000007803 itching Effects 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 11
- 238000003756 stirring Methods 0.000 description 9
- LQGUBLBATBMXHT-UHFFFAOYSA-N chrysophanol Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC(O)=C3C(=O)C2=C1O LQGUBLBATBMXHT-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 238000003556 assay Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- NZPQWZZXRKZCDU-UHFFFAOYSA-N chrysophanol Natural products Cc1cc(O)c2C(=O)c3c(O)cccc3Oc2c1 NZPQWZZXRKZCDU-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- VWDXGKUTGQJJHJ-UHFFFAOYSA-N Catenarin Natural products C1=C(O)C=C2C(=O)C3=C(O)C(C)=CC(O)=C3C(=O)C2=C1O VWDXGKUTGQJJHJ-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 239000010282 Emodin Substances 0.000 description 1
- RBLJKYCRSCQLRP-UHFFFAOYSA-N Emodin-dianthron Natural products O=C1C2=CC(C)=CC(O)=C2C(=O)C2=C1CC(=O)C=C2O RBLJKYCRSCQLRP-UHFFFAOYSA-N 0.000 description 1
- 206010016326 Feeling cold Diseases 0.000 description 1
- YOOXNSPYGCZLAX-UHFFFAOYSA-N Helminthosporin Natural products C1=CC(O)=C2C(=O)C3=CC(C)=CC(O)=C3C(=O)C2=C1O YOOXNSPYGCZLAX-UHFFFAOYSA-N 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- NTGIIKCGBNGQAR-UHFFFAOYSA-N Rheoemodin Natural products C1=C(O)C=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1O NTGIIKCGBNGQAR-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019784 crude fat Nutrition 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- RHMXXJGYXNZAPX-UHFFFAOYSA-N emodin Chemical compound C1=C(O)C=C2C(=O)C3=CC(C)=CC(O)=C3C(=O)C2=C1O RHMXXJGYXNZAPX-UHFFFAOYSA-N 0.000 description 1
- VASFLQKDXBAWEL-UHFFFAOYSA-N emodin Natural products OC1=C(OC2=C(C=CC(=C2C1=O)O)O)C1=CC=C(C=C1)O VASFLQKDXBAWEL-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- FFWOKTFYGVYKIR-UHFFFAOYSA-N physcion Chemical compound C1=C(C)C=C2C(=O)C3=CC(OC)=CC(O)=C3C(=O)C2=C1O FFWOKTFYGVYKIR-UHFFFAOYSA-N 0.000 description 1
- PKUBGLYEOAJPEG-UHFFFAOYSA-N physcion Natural products C1=C(C)C=C2C(=O)C3=CC(C)=CC(O)=C3C(=O)C2=C1O PKUBGLYEOAJPEG-UHFFFAOYSA-N 0.000 description 1
- OISYIJRGMYJBRH-UHFFFAOYSA-N physcione Natural products COc1cc(O)c2C(=O)c3ccc(O)cc3C(=O)c2c1 OISYIJRGMYJBRH-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 150000008130 triterpenoid saponins Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses shampoo, which is prepared from 31-54 parts of surfactant; 0.3-1.0 part of a conditioner; 1.0-2.0 parts of a pearling agent; 0.5-1.8 parts of dehumidifying and cooling agent; 0.05-0.1 part of preservative; 10-20 parts of a hair blackening and brightening agent; citric acid and water in a certain proportion. The invention has simple process, easily obtained raw materials, rich and fine foam, moderate detergency, easy rinsing, no stimulation to hair, skin and eyes, bright, smooth and elastic hair after washing, good dry and wet combing property, cool and comfortable feeling and itching relieving effect.
Description
Technical field
The present invention relates to a kind of articles for washing, relate to a kind of shampoo particularly.
Background technology
Shampoo is claimed shampoo or shampoo, shampoo again.Be to use hair and scalp basic nursing cosmetic product the most widely.The hair-washing hair-care articles for use of selling in the market are various in style, and quality discrepancy is also big.Hair washing and hair care product operation separately are loaded down with trivial details, use inconvenience.
Summary of the invention
The object of the present invention is to provide a kind of dandruff simultaneously, hair color and bright 's shampoo.
Technical scheme of the present invention is following:
A kind of shampoo, by weight, comprising:
31~54 parts in surfactant;
0.3~1.0 part of conditioner;
1.0~2.0 parts of pearling agents;
0.5~1.8 part of dehumidifying freshener;
Antiseptic 0.05-0.1 part;
Bright agent 10-20 of hair color part;
Citric acid 0.1-0.5 part (adjustment PH PH to 5.5-6.5);
Spice 0.1-0.5 part; And
Pure water adds to 100 parts.
Preferably, by weight, described surfactant comprises:
Sodium laureth sulfate 15-25 part;
Coconut oil diethanol amide 3-5 part;
Empgen BB 3-4 part; And
Thea saponin extracting solution 10-20 part.
Wherein, sodium laureth sulfate (AES) is used to do surfactant, foaming agent, detergent.Coconut oil diethanol amide (6501) is used to do non-ionic surface active agent, foaming agent, foam stabilizer, thickening agent.AES and 6501 mixes the use good water solubility, and clean result is good, strong detergency, and foam is abundant.But use the two composition separately, its degreasing power is strong, can make after the hair washing hair send out puckery, not smooth.
Empgen BB (CAB) is used to do amphoteric surfactant, foaming agent, thickening agent, conditioner.
The thea saponin extracting solution.Tea saponin is a kind of soap class surfactant that from teaseed cake dregs, extracts, and its basic structure is by triterpenoid saponin, and structure is sugared, and structure acid is formed.The aqueous solution of tea saponin can produce the persistency foam after vibration, its foaming power is not influenced by water hardness, is a kind of natural non-ionic surface active agent.The present invention adopts above four kinds of surfactants allotment, reaching moderate cleaning force, spumescence and comfortableness,
Preferably, described conditioner is a polyquaternary ammonium salt-10, is used to do antistatic conditioner, softener.
Preferably, described pearling agent is an EGDS, is used to obtain good surface appearance.。
Preferably, by weight, described dehumidifying freshener is:
Camphora 0.2-0.8 part;
Mentholum 0.3-1.0 part.
The Camphora effect: the dehumidifying parasite killing, warming and odynolysis, having one's ideas straightened out, it is dirty to ward off.Mentholum: act on scalp, refrigerant itching-relieving action is arranged.
Preferably, described antiseptic is methyl hydroxybenzoate or propyl ester or methylchloroisothiazandnone.
Preferably, bright agent of described hair color is Radix Polygoni Multiflori extracting solution.Show that through analyzing the Radix Polygoni Multiflori contains chrysophanol, emodin, chrysophanic acid, physcione, chrysophanol are feared ketone, lecithin, crude fat and starch etc.Contain nutritional labelings such as phospholipid in the Radix Polygoni Multiflori extracting solution, can make hairy root nourishing, hair melanin is generated; Can make hair more black; Can also become the hair nutrition conditioner, be used to defend the doctrine, the cosmetics of hair care or hair growth promoting, can make hair be easy to combing; Pitch-black light, Radix Polygoni Multiflori extracting solution can not only be taken care of hair, hair care.
Citric acid, adjustment PH PH to 5.5-6.5.Fructus Citri Limoniae juice has gentle bleaching effect to hair, can dispel unnecessary sebum easily.
Spice: let consumer obtain better use experience, can add variety classes as required.
Raw material of the present invention is easy to get, and technology is simple, and foam is abundant fine and smooth; Detergency is moderate, is easy to rinsing, and is non-stimulated to hair, skin, eyes; Hair after the washing is bright, submissive, high resilience, do, wet cardability is good, feeling cool, pleasant especially, and itching-relieving efficacies is arranged.Life-time service has the hair of the making blackening and the effect that brightens.
The specific embodiment
Embodiment 1
By weight,
1, sodium laureth sulfate (AES) 20%;
2, coconut oil diethanol amide (6501) 4%;
3, empgen BB (CAB) 3.5%;
4, conditioner polyquaternary ammonium salt-10 (JR-400) 0.5%;
5, EGDS 1.5%;
6, the thea saponin extracting solution 15%;
7, Radix Polygoni Multiflori extracting solution 15%;
8, Camphora 0.5%;
9, Mentholum 0.5%;
10, methylchloroisothiazandnone 0.07%;
11, citric acid 0.3% (adjustment PH PH to 6.0)
12, spice 0.3%
13, pure water adds to 100%.
Technological process: take by weighing the water in the prescription, be heated to 75-80 degree centigrade, add the raw material of 1-5 under the stirring condition successively,, add 6,7 components again, stir, when being cooled to below 45 degrees centigrade, add the 8-12 composition to dissolving fully.Stir.Sampling, check pH value, viscosity, color.Qualified back discharging, ageing 24 hours, behind the froth breaking, once more after the assay was approved, the fill warehouse-in is for sale.
Embodiment 2
By weight,
1, sodium laureth sulfate (AES) 25%;
2, coconut oil diethanol amide (6501) 3%;
3, empgen BB (CAB) 4%;
4, conditioner polyquaternary ammonium salt-10 (JR-400) 0.3%;
5, EGDS 2.0%;
6, the thea saponin extracting solution 10%;
7, Radix Polygoni Multiflori extracting solution 20%;
8, Camphora 0.2%;
9, Mentholum 1.0%;
10, methyl hydroxybenzoate 0.05%;
11, citric acid 0.5% (adjustment PH PH to 5.5-6.5)
12, spice 0.5%
13, pure water adds to 100%.
Technological process: take by weighing the water in the prescription, be heated to 75-80 degree centigrade, add the raw material of 1-5 under the stirring condition successively,, add 6,7 components again, stir, when being cooled to below 45 degrees centigrade, add the 8-12 composition to dissolving fully.Stir.Sampling, check pH value, viscosity, color.Qualified back discharging, ageing 24 hours, behind the froth breaking, once more after the assay was approved, the fill warehouse-in is for sale.。
Embodiment 3
By weight,
1, sodium laureth sulfate (AES) 15%;
2, coconut oil diethanol amide (6501) 5%;
3, empgen BB (CAB) 3%;
4, conditioner polyquaternary ammonium salt-10 (JR-400) 0.3%;
5, EGDS 2.0%;
6, the thea saponin extracting solution 10%;
7, Radix Polygoni Multiflori extracting solution 20%;
8, Camphora 0.2%;
9, Mentholum 1.0%;
10, methylchloroisothiazandnone 0.05%;
11, citric acid 0.5% (adjustment PH PH to 5.5-6.5)
12, spice 0.1%
13, pure water adds to 100%.
Technological process: take by weighing the water in the prescription, be heated to 75-80 degree centigrade, add the raw material of 1-5 under the stirring condition successively,, add 6,7 components again, stir, when being cooled to below 45 degrees centigrade, add the 8-12 composition to dissolving fully.Stir.Sampling, check pH value, viscosity, color.Qualified back discharging, ageing 24 hours, behind the froth breaking, once more after the assay was approved, the fill warehouse-in is for sale.
Above-mentionedly be merely specific embodiment of the present invention, but design concept of the present invention is not limited thereto, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Claims (3)
1. shampoo, by weight, composed of the following components:
31~54 parts in surfactant;
0.3~1.0 part of conditioner;
1.0~2.0 parts of pearling agents;
0.5~1.8 part of dehumidifying freshener;
Antiseptic 0.05-0.1 part;
Bright agent 10-20 of hair color part;
Citric acid 0.1-0.5 part;
Spice 0.1-0.5 part; And
Pure water adds to 100 parts,
Adjust pH value to 5.5-6.5 with citric acid;
Wherein, described conditioner is a polyquaternary ammonium salt-10; Described pearling agent is an EGDS, and bright agent of described hair color is Radix Polygoni Multiflori extracting solution; By weight, described surfactant is grouped into by following one-tenth:
Sodium laureth sulfate 15-25 part;
Coconut oil diethanol amide 3-5 part;
Empgen BB 3-4 part; And
Thea saponin extracting solution 10-20 part.
2. a kind of shampoo as claimed in claim 1 is characterized in that, by weight, described dehumidifying freshener is:
Camphora 0.2-0.8 part;
Mentholum 0.3-1.0 part.
3. a kind of shampoo as claimed in claim 1 is characterized in that, described antiseptic is methyl hydroxybenzoate or propylparaben or methylchloroisothiazandnone.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010105198044A CN102008409B (en) | 2010-10-25 | 2010-10-25 | Liquid shampoo |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010105198044A CN102008409B (en) | 2010-10-25 | 2010-10-25 | Liquid shampoo |
Publications (2)
Publication Number | Publication Date |
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CN102008409A CN102008409A (en) | 2011-04-13 |
CN102008409B true CN102008409B (en) | 2012-05-02 |
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ID=43838886
Family Applications (1)
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CN2010105198044A Expired - Fee Related CN102008409B (en) | 2010-10-25 | 2010-10-25 | Liquid shampoo |
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CN1301533A (en) * | 1999-12-28 | 2001-07-04 | 丁民勤 | Shampoo containing Chinese herbal medicines and production process thereof |
CN1543925A (en) * | 2003-11-20 | 2004-11-10 | 李明劲 | Shampoo cream containing Yerbadetajo Herb and method for preparing the same |
CN1593374A (en) * | 2004-07-07 | 2005-03-16 | 徐建华 | pharmaceutical hair washing shampoo and its making method |
-
2010
- 2010-10-25 CN CN2010105198044A patent/CN102008409B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1301533A (en) * | 1999-12-28 | 2001-07-04 | 丁民勤 | Shampoo containing Chinese herbal medicines and production process thereof |
CN1543925A (en) * | 2003-11-20 | 2004-11-10 | 李明劲 | Shampoo cream containing Yerbadetajo Herb and method for preparing the same |
CN1593374A (en) * | 2004-07-07 | 2005-03-16 | 徐建华 | pharmaceutical hair washing shampoo and its making method |
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CN102008409A (en) | 2011-04-13 |
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