CN100584307C - Attapulgite chinese angelica shampoo - Google Patents
Attapulgite chinese angelica shampoo Download PDFInfo
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- CN100584307C CN100584307C CN200810021832A CN200810021832A CN100584307C CN 100584307 C CN100584307 C CN 100584307C CN 200810021832 A CN200810021832 A CN 200810021832A CN 200810021832 A CN200810021832 A CN 200810021832A CN 100584307 C CN100584307 C CN 100584307C
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Abstract
The invention discloses attapulgite angelical shampoo, which has the technical proposal that the attapulgite angelical shampoo is composed of modified pasty attapulgite clay, angelical mixed solution, dodecyl dimethyl betaine, lauryl diethanol amide, citric acid, nipagin methyl ester, nipagine propyl ester and deionized water. The attapulgite angelical shampoo has the manufacturing method of purification, sodium modification, acidification, feed proportioning, pulverization, stirring and mixing, grinding, high-speed stirring, emulsification, vacuum degassing and can pack for obtaining the finished product of the attapulgite angelical shampoo. The attapulgite angelical shampoo has exquisite and rich foam, can facilitate hair to absorb the nutrition in the attapulgite angelical shampoo as well as can absorb and eliminate the sweat scale, the dust, the microorganism, the scurf, the abnormal smell, etc. of the hair to keep scalp clear and hair beauty. The attapulgite angelical shampoo is suitable for hairdressing and nursing.
Description
Technical field
The present invention relates to shampoo, be specifically related to a kind of concave-convex stick Chinese angelica shampoo.
Background technology
Shampoo is a kind of oil-in-water type product, is opaque emulsion form, and it is with its strong detergency, and has the effect of hair care hair care concurrently and very popular.
In recent years, the inherent quality of people's pay attention to day by day shampoo, particularly the zest to eyes and skin is little, and require the oils and fats of shampoo removal skin within reason and hair, relatively gentleer to skin and mucosa, shampoo can impel hair soft and high resilience, and can increase the gloss of hair and be easy to rinsing.
Gong Ying shampoo is synthetic with industrial chemicals mostly in the market, is difficult to satisfy the demands of consumers, and improper use also can cause bad phenomenon generations such as the dry bifurcated of hair, easily broken, curling and scalp allergy.
Chinese patent Granted publication CN 1046087, Granted publication day is on November 3rd, 1999, name is called " Chinese medicine shampoo ", discloses " a kind of Chinese medicine shampoo.The various shampoos of prior art have scrubbing, make the bright and clean effect of hair, but all do not have the effect of preventing and curing diseases, people wish a kind of melt prevent and cure diseases, health care comes out in the shampoo of one.The present invention is made up of shampoo substrate and traditional Chinese medicine liquid.The Chinese medicine of producing medicinal liquid has Herba speranskiae tuberculatae: Cacumen Platycladi: Radix Sophorae Flavescentis: Semen Vaccariae: Fructus Gleditsia: Herba Ecliptae: the Radix Angelicae Dahuricae: western rhizome of chuanxiong: Galla Turcica (Galla Helepensis): Flos Caryophylli: Aloe: Calyx Kaki=6: 6: 4: 6: 6: 4: 3: 3: 4: 2: 4: 5.People use the hair washing of this Chinese medicine shampoo, can make the bright and clean softness of hair, elegant graceful, be easy to the combing molding, can also prevent and treat the various skin disease.”
The weak point of above-mentioned patent is this technology just simple " proportionally, traditional Chinese medicine liquid is mixed with shampoo substrate, the bottling of cooling back promptly obtains this Chinese medicine shampoo ", can not fully play the effect of shampoo substrate and Chinese medicine.
Chinese patent publication number CN1021385, open day is on October 12nd, 1988, name is called " a kind of highly effective liquid detergent and production method ", discloses " a kind of high-efficient washing spirit that is used for the sanitary purpose washing aspect of being made special auxiliary agent by inorganic mineral raw material bentonite and attapulgite.It is to make anion surfactant by preparing a certain amount of sodium lauryl sulphate, and CMC makes thickening, stabilizing agent, and lanoline is made conditioner and a certain amount of bentonite and attapulgite and made special auxiliary agent, spice, pigment and mix through heated and stirred.The present invention is cheap, and its cost of material only is about 75% of general shampoo and a shampoo paste.Strong detergency, consumption are few, nontoxic.”
The weak point of above-mentioned patent is not select for use in this technology to make special auxiliary agent through the inorganic mineral raw material bentonite and the attapulgite of purifying and modification is handled, and its dispersibility and suspendability are all poor, therefore can have influence on the product quality of highly effective liquid detergent.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of concave-convex stick Chinese angelica shampoo is provided.
Concave-convex stick Chinese angelica shampoo is made up of modified cream attapulgite clay, Radix Angelicae Sinensis mixed liquor, dodecyldimethylammonium hydroxide inner salt, lauroyl diethanolamine, citric acid, methyl hydroxybenzoate, propylparaben and deionized water.
The production method of concave-convex stick Chinese angelica shampoo is purification, sodium, acidify, batching, pulverize, mix, grinding, high-speed stirred, emulsifying, vacuum outgas, cannedly be the finished product of concave-convex stick Chinese angelica shampoo.
Attapulgite clay is a kind of nanometer porous fibrous silicate clay mineral of Shuifu County's magnesium that contains, and when attapulgite content 〉=80% in the attapulgite clay was above, its specific surface area was bigger, can reach 500m
2More than/the g.Use " wet beneficiation craft of attapulgite " and " attapulgite ore pul making production technology ", the screening of mineral such as the hydromica in the attapulgite clay, quartz, opal and carbonate is got rid of, obtain a kind of attapulgite sludge slurry; Through the lip lipstick attapulgite clay after sodium processing and the acidification, it is the special good natural magnesium aluminium silicate gel of a kind of thixotropy and gumminess, it is neutral that pH value is, and the viscosity of attapulgite clay, expansion capacity, colloid index, whiteness, specific surface area, absorption property, suspensibility and dirt-removing power all are greatly improved.
Radix Angelicae Sinensis can be expanded blood capillary, the blood circulation promoting of scalp and skin, and vitamin antagonist E lacks, and is anti-loss, the skin care hair, and make hair pitch-black shinny.
Radix Salviae Miltiorrhizae contains abundant vitamin and trace element zinc, copper, ferrum etc., can promote the melanic generation of hair, also can improve because of diseases such as poliosis that trace element deficiency causes, yellow hair, hair dryings.
Rhizoma Chuanxiong energy enlarged head blood capillary, blood circulation promoting increases hair nutrition, and makes hair that good pliability and the function that is difficult for becoming fragile be arranged, and can delay the poliosis growth, keeps hair to lubricate gloss.
The Cortex Eucommiae contains abundant vitamin E and carotene, the various trace elements such as ferrum, calcium, phosphorus, boron, zinc that also have vitamin B1, B2 and needed by human body, have resisting fatigue, defying age, promotion body metabolism and improve the particular utility of comprehensive immunity, can increase the hair melanocyte, improve the activity of hair melanocyte, prevent poliosis.
Flos Carthami can be regulated the blood circulation of scalp blood capillary, replenishes hair follicle nutrition, improves the natural on-off cycles of hair growth environment.
The Radix Glycyrrhizae invigorating the spleen and replenishing QI, heat-clearing and toxic substances removing, cushion toxicity.
Radix Ginseng contains ginsenoside, tannin, nitrilo acid, vitamin, monosaccharide and polysaccharide, alkaloid, the ginsenoside helps blood circulation of skin, increase the supply of skin-nourishing, trichogenous effect, make hair bright and clean moist and soft simultaneously, the effect that also has antioxidation and repair the damaged hair molecule.
Dodecyldimethylammonium hydroxide inner salt all has advantages of excellent stability under acidity and alkali condition, the detergency of its aqueous solution, foaming characteristic and permeability are all fine, anti-hard water, biological degradability is good, little to skin irritation, the performance gentleness, compatibility is good, also has good stain removal bactericidal, flexibility and antistatic behaviour.
Lauroyl diethanolamine has good foaming characteristic, stability, thickening property, permeability and washing performance, and is good with other active matter compatibilities, is a kind of foam stabiliser preferably.
Citric acid has gentle frank tart flavour, can improve and adjust the pH value of shampoo, improves the performance of surfactant.
Methyl hydroxybenzoate has the broad-spectrum antibacterial effect, to Gram-positive, and negative bacteria, yeast and mycete have very strong inhibitory action, and the low and safety economy of working concentration uses effect duration long.Methyl hydroxybenzoate is compatible with various chemical substances easily, and the composite use of methyl hydroxybenzoate and propylparaben is to reach better antiseptic effect.
The present invention is achieved by following technical proposals:
1, the batching of concave-convex stick Chinese angelica shampoo is made up of following component by weight percentage: modified cream attapulgite clay 30～60%, Radix Angelicae Sinensis mixed liquor 10～55%, dodecyldimethylammonium hydroxide inner salt 0.5～8%, lauroyl diethanolamine 0.5～10%, citric acid 0.01～1%, methyl hydroxybenzoate 0.05～0.5%, propylparaben 0.05～0.5% and deionized water 2～40%.
Described modified cream attapulgite clay is on attapulgite ore pul making production technology basis, attapulgite sludge slurry is carried out sodium processing, acidification, washing and sieve decontamination, mud through post precipitation is modified cream attapulgite clay, modified cream attapulgite clay is through powerful stirring at a high speed, become the special good natural gelinite of a kind of thixotropy and gumminess, viscosity is up to more than the 10000mPas.
Attapulgite ore pul making production technology is: will stir in the attapulgite ore deposit input blender, after extruder is squeezed into lamellar, import once more in the blender and stir, natural drying after extruder is squeezed into lamellar, air dried attapulgite ore deposit is transported in the feed reservoir soaks, dash with air pump and to turn over, post precipitation is emitted immersion water, the sieve decontamination in the input semi-finished product pond, is soaked again, dash with air pump and to turn over, post precipitation is emitted immersion water, and the slurry transportation of post precipitation is arrived in the finished product pond, is attapulgite sludge slurry finished product.
Above-mentioned production technology is to adopt " the attapulgite ore pul making production technology " in application on January 6th, 2004 by the inventor, and the Chinese patent Granted publication number is: CN1287965C, Granted publication day: on December 6th, 2006.
The production technology of modified cream attapulgite clay is: (1) selects for use attapulgite sludge slurry to be body material of the present invention, and attapulgite sludge slurry is made up of following component by weight percentage: attapulgite clay 15～35% and water 65～85%; (2) sodium is handled: attapulgite sludge slurry is transported in the blender, stirs after adding sodium carbonate, be transported in the sodium pond ageing 1～7 day through the attapulgite sludge slurry after stirring; The sodium batching is made up of following component by weight percentage: attapulgite sludge slurry 95～99.5% and sodium carbonate 0.5～5%; (3) acidification: attapulgite sludge slurry after the sodium is transported in the blender, stirs after adding concentration and be 98% sulphuric acid, be transported in the acidification pool ageing 1～3 day through the attapulgite sludge slurry after stirring; The acidify batching is made up of following component by weight percentage: attapulgite sludge slurry 92～99.5% after the sodium and concentration are 98% sulphuric acid 0.5～8%; (4) washing and sieve decontamination: the slurry of the attapulgite sludge after the acidify is transported in the sedimentation tank, soaks again, dash with air pump and turn over, the sieve decontamination, post precipitation is emitted immersion water, and the slurry transportation of post precipitation is arrived in the finished product pond, and the mud of post precipitation is lip lipstick attapulgite clay; The washing batching is made up of following component by weight percentage: attapulgite sludge slurry 25～65% and water 35～75% after the acidify; Lip lipstick attapulgite clay is made up of following component by weight percentage: attapulgite clay 5～40% and water 60～95%.
The pH value of the immersion water of emitting is neutral meta-acid, can be used to produce the raw material of transparent shampoo.
The batching of described Radix Angelicae Sinensis mixed liquor is made up of following component by weight percentage: Radix Angelicae Sinensis 2.0～15.0%, Radix Salviae Miltiorrhizae 2.0～12.0%, Rhizoma Chuanxiong 1.0～10.0%, the Cortex Eucommiae 1.0～8.0%, Flos Carthami 1.0～6.0%, Radix Glycyrrhizae 0.5～5.0%, Radix Ginseng 0.1～1.0% and water 75.0～90.0%; The preparation method of Radix Angelicae Sinensis mixed liquor: pulverize after the batch mixes with the Radix Angelicae Sinensis mixed liquor, add then and carry out steaming and decocting in the rustless steel container, digestion time was controlled at 2～4 hours, and the clarifying liquid in cooling back is the Radix Angelicae Sinensis mixed liquor.
2, the production method of concave-convex stick Chinese angelica shampoo: 1. carry out stirring at low speed in the batching adding blender with concave-convex stick Chinese angelica shampoo, mix the back and be the mixture of concave-convex stick Chinese angelica shampoo; 2. the mixture that 1. step is obtained is imported to grind in the multi-functional colloid mill and is pasty mixture, and fineness of the particles is less than 0.015 millimeter; 3. the pasty mixture after the grinding that 2. step is obtained carries out powerful stirring of high speed and is the paste semi-finished product in the input ultrahigh speed blender; 4. the paste semi-finished product that 3. step obtained carry out vacuum degassing process to be handled, and canned is the finished product of concave-convex stick Chinese angelica shampoo.
Concave-convex stick Chinese angelica shampoo uses modified cream attapulgite clay to be primary raw material, does not need to add in addition thickening agent and wetting agent, not only can improve the quality of shampoo, can also reduce production costs greatly.
Behind the processing of attapulgite sludge slurry process sodium, acidification, washing and the sieve decontamination, lip lipstick attapulgite clay becomes a kind of thixotropy and the special good natural magnesium aluminium silicate gel of gumminess, it is neutral that pH value is, and the viscosity of attapulgite clay, expansion capacity, colloid index, whiteness, specific surface area, absorption property, suspensibility and dirt-removing power all are greatly improved.
Concave-convex stick Chinese angelica shampoo is the auxotype shampoo, the energy blood circulation promoting, and vitamin antagonist E lacks, and is anti-loss, the skin care hair, and make hair pitch-black shinny.People are in the hair washing process, concave-convex stick Chinese angelica shampoo has exquisiteness and abundant foam, not only can make hair well absorb nutrition in the concave-convex stick Chinese angelica shampoo, relatively gentleer to eyes, hair and skin, nonirritant, and concave-convex stick Chinese angelica shampoo can also adsorb and remove foreign material such as sweat mixed with dirt on the hair, dust, microorganism, dandruff, abnormal flavour, the cleaning of maintenance scalp and hair and attractive in appearance, be easy to carry out rinsing after using the concave-convex stick Chinese angelica shampoo hair washing, more satin is beautiful to impel hair.
Concave-convex stick Chinese angelica shampoo is applicable to the hair caring nursing, is specially adapted to anemia of pregnant woman and puerpera's hair caring nursing.
The specific embodiment
The invention will be further described below in conjunction with embodiment:
1, the batching of concave-convex stick Chinese angelica shampoo is made up of following component by weight percentage: modified cream attapulgite clay 40%, Radix Angelicae Sinensis mixed liquor 45%, dodecyldimethylammonium hydroxide inner salt 4%, lauroyl diethanolamine 3.4%, citric acid 0.4%, methyl hydroxybenzoate 0.15%, propylparaben 0.05% and deionized water 7%.
The production technology of modified cream attapulgite clay is: (1) selects for use attapulgite sludge slurry to be body material of the present invention, and attapulgite sludge slurry is made up of following component by weight percentage: attapulgite clay 30% and water 70%; (2) sodium is handled: attapulgite sludge slurry is transported in the blender, stirs after adding sodium carbonate, be transported in the sodium pond ageing 3 days through the attapulgite sludge slurry after stirring; The sodium batching is made up of following component by weight percentage: attapulgite sludge slurry 98% and sodium carbonate 2%; (3) acidification: attapulgite sludge slurry after the sodium is transported in the blender, stirs after adding concentration and be 98% sulphuric acid, be transported in the acidification pool ageing 2 days through the attapulgite sludge slurry after stirring; The acidify batching is made up of following component by weight percentage: attapulgite sludge slurry 97% after the sodium and concentration are 98% sulphuric acid 3%; (4) washing and sieve decontamination: the slurry of the attapulgite sludge after the acidify is transported in the sedimentation tank, soaks again, dash with air pump and turn over, the sieve decontamination, post precipitation is emitted immersion water, and the slurry transportation of post precipitation is arrived in the finished product pond, and the mud of post precipitation is lip lipstick attapulgite clay; The washing batching is made up of following component by weight percentage: attapulgite sludge slurry 40 and water 60% after the acidify; Lip lipstick attapulgite clay is made up of following component by weight percentage: attapulgite clay 30% and water 70%.
The batching of described Radix Angelicae Sinensis mixed liquor is made up of following component by weight percentage: Radix Angelicae Sinensis 10%, Radix Salviae Miltiorrhizae 8%, Rhizoma Chuanxiong 5%, the Cortex Eucommiae 5%, Flos Carthami 4%, Radix Glycyrrhizae 2.8%, Radix Ginseng 0.2% and water 65%;
The preparation method of Radix Angelicae Sinensis mixed liquor: pulverize after the batch mixes with the Radix Angelicae Sinensis mixed liquor, add then and carry out steaming and decocting in the rustless steel container, digestion time was controlled at 2 hours, and the clarifying liquid in cooling back is the Radix Angelicae Sinensis mixed liquor.
2, the production method of concave-convex stick Chinese angelica shampoo: 1. carry out stirring at low speed in the batching adding blender with concave-convex stick Chinese angelica shampoo, mix the back and be the mixture of concave-convex stick Chinese angelica shampoo; 2. the mixture that 1. step is obtained is imported to grind in the multi-functional colloid mill and is pasty mixture, and fineness of the particles is less than 0.015 millimeter; 3. the pasty mixture after the grinding that 2. step is obtained carries out powerful stirring of high speed and is the paste semi-finished product in the input ultrahigh speed blender; 4. the paste semi-finished product that 3. step obtained carry out vacuum degassing process to be handled, and canned is the finished product of concave-convex stick Chinese angelica shampoo.
Claims (1)
1, a kind of concave-convex stick Chinese angelica shampoo, it is characterized in that the batching of concave-convex stick Chinese angelica shampoo is made up of following component by weight percentage: modified cream attapulgite clay 30～60%, Radix Angelicae Sinensis mixed liquor 10～55%, dodecyldimethylammonium hydroxide inner salt 0.5～8%, lauroyl diethanolamine 0.5～10%, citric acid 0.01～1%, methyl hydroxybenzoate 0.05～0.5%, propylparaben 0.05～0.5% and deionized water 2～40%;
The preparation method of described modified cream attapulgite clay: (1) selects for use attapulgite sludge slurry to be body material of the present invention, and attapulgite sludge slurry is made up of following component by weight percentage: attapulgite clay 15～55%, water 65～85%; (2) sodium is handled: attapulgite sludge slurry is transported in the blender, stirs after adding sodium carbonate, be transported in the sodium pond ageing 1～7 day through the attapulgite sludge slurry after stirring; The sodium batching is made up of following component by weight percentage: attapulgite sludge slurry 95～99.5%, sodium carbonate 0.5～5%; (3) acidification: attapulgite sludge slurry after the sodium is transported in the blender, stirs after adding concentration and be 98% sulphuric acid, be transported in the acidification pool ageing 1～3 day through the attapulgite sludge slurry after stirring; The acidify batching is made up of following component by weight percentage: the attapulgite sludge slurry 92～99.5% after the sodium, and concentration is 98% sulphuric acid 0.5～8%; (4) washing and sieve decontamination: the slurry of the attapulgite sludge after the acidify is transported in the sedimentation tank, soaks again, dash with air pump and turn over, the sieve decontamination, post precipitation is emitted immersion water, and the slurry transportation of post precipitation is arrived in the finished product pond, and the mud of post precipitation is lip lipstick attapulgite clay; The washing batching is made up of following component by weight percentage: the attapulgite sludge slurry 25～65% after the acidify, water 35～75%; Lip lipstick attapulgite clay is made up of following component by weight percentage: attapulgite clay 5～40%, water 60～95%;
The batching of described Radix Angelicae Sinensis mixed liquor is made up of following component by weight percentage: Radix Angelicae Sinensis 2.0～15.0%, Radix Salviae Miltiorrhizae 2.0～12.0%, Rhizoma Chuanxiong 1.0～10.0%, the Cortex Eucommiae 1.0～8.0%, Flos Carthami 1.0～6.0%, Radix Glycyrrhizae 0.5～5.0%, Radix Ginseng 0.1～1.0% and water 75.0～90.0%; The preparation method of Radix Angelicae Sinensis mixed liquor: pulverize after the batch mixes with the Radix Angelicae Sinensis mixed liquor, add then and carry out steaming and decocting in the rustless steel container, digestion time was controlled at 2～4 hours, and the clarifying liquid in cooling back is the Radix Angelicae Sinensis mixed liquor.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200810021832A CN100584307C (en) | 2008-08-25 | 2008-08-25 | Attapulgite chinese angelica shampoo |
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| CN200810021832A CN100584307C (en) | 2008-08-25 | 2008-08-25 | Attapulgite chinese angelica shampoo |
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| CN101342128A CN101342128A (en) | 2009-01-14 |
| CN100584307C true CN100584307C (en) | 2010-01-27 |
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| CN200810021832A Expired - Fee Related CN100584307C (en) | 2008-08-25 | 2008-08-25 | Attapulgite chinese angelica shampoo |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101700217B (en) * | 2009-09-16 | 2011-05-18 | 许庆华 | Attapulgite Chinese medicinal herb sun protection cream |
| CN104478365B (en) * | 2014-12-25 | 2017-09-22 | 苏州中材非金属矿工业设计研究院有限公司 | A kind of method for improving the hard water resistance performance of aluminium magnesium silicate inorganic gel |
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Granted publication date: 20100127 Termination date: 20100825 |