ATE284422T1 - Verbrückte metallocene zur olefincopolymerisation - Google Patents
Verbrückte metallocene zur olefincopolymerisationInfo
- Publication number
- ATE284422T1 ATE284422T1 AT99974265T AT99974265T ATE284422T1 AT E284422 T1 ATE284422 T1 AT E284422T1 AT 99974265 T AT99974265 T AT 99974265T AT 99974265 T AT99974265 T AT 99974265T AT E284422 T1 ATE284422 T1 AT E284422T1
- Authority
- AT
- Austria
- Prior art keywords
- polymerization
- atom
- bridged metallocene
- metallocene catalyst
- olefin
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000003446 ligand Substances 0.000 abstract 2
- 239000012968 metallocene catalyst Substances 0.000 abstract 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 238000003780 insertion Methods 0.000 abstract 1
- 230000037431 insertion Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10532998P | 1998-10-23 | 1998-10-23 | |
| US13106799P | 1999-04-26 | 1999-04-26 | |
| PCT/US1999/024944 WO2000024793A1 (en) | 1998-10-23 | 1999-10-22 | Bridged metallocenes for olefin copolymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE284422T1 true ATE284422T1 (de) | 2004-12-15 |
Family
ID=26802468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99974265T ATE284422T1 (de) | 1998-10-23 | 1999-10-22 | Verbrückte metallocene zur olefincopolymerisation |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6528670B1 (de) |
| EP (1) | EP1196464B9 (de) |
| JP (1) | JP4689829B2 (de) |
| KR (1) | KR100568839B1 (de) |
| CN (1) | CN1138796C (de) |
| AT (1) | ATE284422T1 (de) |
| AU (1) | AU757241B2 (de) |
| BR (1) | BR9914717A (de) |
| CA (1) | CA2345628C (de) |
| DE (1) | DE69922548T2 (de) |
| ES (1) | ES2233109T3 (de) |
| HK (1) | HK1041705A1 (de) |
| MX (1) | MXPA01003978A (de) |
| RU (1) | RU2232766C2 (de) |
| WO (1) | WO2000024793A1 (de) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0014798A (pt) * | 1999-10-22 | 2002-06-11 | Exxonmobil Chem Patents Inc | Complexos catiÈnicos carbênio adequados para catalisadores de polimerização |
| US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
| US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
| KR100785840B1 (ko) * | 2002-09-27 | 2007-12-13 | 미쓰이 가가쿠 가부시키가이샤 | 가교 메탈로센 화합물, 올레핀 중합 촉매 및 올레핀의 중합방법 |
| JP4610859B2 (ja) * | 2002-09-27 | 2011-01-12 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| EP1589044A3 (de) | 2003-08-11 | 2006-02-15 | ExxonMobil Chemical Patents Inc. | Polymere, bestehend aus Ethylen und gegebenenfalls copolymerisierbaren Estern, Filme aus diesen Polymeren und dieses Filme verwendendes Stretchfolienhaubenverpackungsverfahren |
| EP1727838B1 (de) * | 2004-03-24 | 2013-04-17 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von ethylen-mischpolymeren und danach hergestellte mischpolymere; zusammensetzungen und elektrische vorrichtungen, die derartige mischpolymere enthalten |
| US7947786B2 (en) * | 2004-10-13 | 2011-05-24 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
| ATE411330T1 (de) * | 2005-03-18 | 2008-10-15 | Basell Polyolefine Gmbh | Metallocenverbindungen |
| EP1734059A1 (de) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Kohlenstoffverbrückte Cyclopentadienyl-Fluorenyl-Liganden |
| JP5252714B2 (ja) * | 2006-03-02 | 2013-07-31 | エクソンモービル・ケミカル・パテンツ・インク | プロピレンコポリマーを生産する方法 |
| CN101490096B (zh) | 2006-05-17 | 2012-06-13 | 陶氏环球技术有限责任公司 | 聚丙烯溶液聚合法 |
| EP1903061A1 (de) * | 2006-09-25 | 2008-03-26 | Total Petrochemicals Research Feluy | Verfahren zur Herstellung eines Biphenyl verbrückten Cyclopentadienyl-Fluorenyl Liganden |
| EP2083046A1 (de) | 2008-01-25 | 2009-07-29 | ExxonMobil Chemical Patents Inc. | Thermoplastische Elastomerzusammensetzungen |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| FR2934599B1 (fr) * | 2008-07-29 | 2012-12-21 | Arkema France | Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations |
| US8378042B2 (en) * | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
| CN102762782A (zh) | 2009-12-23 | 2012-10-31 | 英威达技术有限公司 | 包含抗粘添加剂的弹性纤维 |
| CN102770590B (zh) | 2009-12-23 | 2015-04-29 | 英威达技术有限公司 | 包含聚烯烃弹性纤维的织物的制备方法 |
| CN102762785A (zh) | 2009-12-23 | 2012-10-31 | 英威达技术有限公司 | 聚烯烃弹性纤维 |
| JP5951502B2 (ja) | 2009-12-23 | 2016-07-13 | インヴィスタ テクノロジーズ エスアエルエル | 伸縮性ポリオレフィン繊維を含有する伸縮性製品 |
| US8425847B2 (en) | 2010-01-14 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
| WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
| CN102190749B (zh) * | 2010-03-05 | 2013-02-20 | 中国石油天然气股份有限公司 | 一种乙烯/α-烯烃共聚合的方法 |
| CN106103507B (zh) | 2014-03-21 | 2019-04-05 | 埃克森美孚化学专利公司 | 乙烯丙烯共聚物的制备方法 |
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Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
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-
1999
- 1999-10-22 DE DE69922548T patent/DE69922548T2/de not_active Expired - Lifetime
- 1999-10-22 AT AT99974265T patent/ATE284422T1/de not_active IP Right Cessation
- 1999-10-22 HK HK02103341.8A patent/HK1041705A1/zh unknown
- 1999-10-22 BR BR9914717-3A patent/BR9914717A/pt not_active IP Right Cessation
- 1999-10-22 ES ES99974265T patent/ES2233109T3/es not_active Expired - Lifetime
- 1999-10-22 WO PCT/US1999/024944 patent/WO2000024793A1/en active IP Right Grant
- 1999-10-22 AU AU13212/00A patent/AU757241B2/en not_active Ceased
- 1999-10-22 EP EP99974265A patent/EP1196464B9/de not_active Expired - Lifetime
- 1999-10-22 JP JP2000578362A patent/JP4689829B2/ja not_active Expired - Lifetime
- 1999-10-22 CA CA2345628A patent/CA2345628C/en not_active Expired - Fee Related
- 1999-10-22 KR KR1020017004930A patent/KR100568839B1/ko not_active Expired - Fee Related
- 1999-10-22 RU RU2001113445/04A patent/RU2232766C2/ru not_active IP Right Cessation
- 1999-10-22 CN CNB998123811A patent/CN1138796C/zh not_active Expired - Lifetime
- 1999-10-22 MX MXPA01003978A patent/MXPA01003978A/es not_active IP Right Cessation
- 1999-10-22 US US09/426,099 patent/US6528670B1/en not_active Expired - Lifetime
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2002
- 2002-03-07 US US10/092,660 patent/US6506857B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2232766C2 (ru) | 2004-07-20 |
| WO2000024793A8 (en) | 2001-10-11 |
| DE69922548D1 (de) | 2005-01-13 |
| WO2000024793A1 (en) | 2000-05-04 |
| HK1041705A1 (zh) | 2002-07-19 |
| EP1196464B1 (de) | 2004-12-08 |
| KR100568839B1 (ko) | 2006-04-10 |
| US20020137959A1 (en) | 2002-09-26 |
| BR9914717A (pt) | 2001-07-10 |
| DE69922548T2 (de) | 2006-01-05 |
| MXPA01003978A (es) | 2003-06-06 |
| EP1196464B9 (de) | 2005-03-23 |
| CA2345628A1 (en) | 2000-05-04 |
| AU1321200A (en) | 2000-05-15 |
| US6506857B2 (en) | 2003-01-14 |
| JP2002528463A (ja) | 2002-09-03 |
| ES2233109T3 (es) | 2005-06-01 |
| CA2345628C (en) | 2010-02-16 |
| US6528670B1 (en) | 2003-03-04 |
| KR20010099705A (ko) | 2001-11-09 |
| AU757241B2 (en) | 2003-02-06 |
| CN1328580A (zh) | 2001-12-26 |
| EP1196464A1 (de) | 2002-04-17 |
| JP4689829B2 (ja) | 2011-05-25 |
| CN1138796C (zh) | 2004-02-18 |
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