MXPA01003978A - Metalocenos puenteados para copolimerizacion de olefinas-. - Google Patents
Metalocenos puenteados para copolimerizacion de olefinas-.Info
- Publication number
- MXPA01003978A MXPA01003978A MXPA01003978A MXPA01003978A MXPA01003978A MX PA01003978 A MXPA01003978 A MX PA01003978A MX PA01003978 A MXPA01003978 A MX PA01003978A MX PA01003978 A MXPA01003978 A MX PA01003978A MX PA01003978 A MXPA01003978 A MX PA01003978A
- Authority
- MX
- Mexico
- Prior art keywords
- polymerization
- atom
- bridged metallocene
- metallocene catalyst
- olefin
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La invencion esta dirigida a complejos catalizadores de metaloceno puenteados que son suficientemente solubles en solventes alifaticos para ser particularmente adecuados para procesos de polimerizacion de olefinas en solucion, tal que puedan prepararse copolimeros de olefina con altos pesos moleculares y altas actividades de catalizador, particularmente a elevadas temperaturas de reaccion de polimerizacion. Mas especificamente, la invencion se refiere particularmente a un proceso de polimerizacion para copolimeros de etileno que tienen una densidad de alrededor de 0.850 a alrededor de 0.940, que comprende poner en contacto, bajo condiciones de polimerizacion en solucion a una temperatura de reaccion a o mayor de 60 a 250oC, etileno y uno o mas co-monomeros capaces de polimerizacion por insercion con un complejo catalizador de metaloceno puenteado derivado a partir de dos ligandos auxiliares, cada uno de los cuales, independientemente, puede ser sustituido o sin sustituir, donde los ligandos son enlazados mediante un puente covalente que contiene un solo atomo del grupo 14 sustituido, la sustitucion en dicho atomo del grupo 14 comprendiendo grupos arilo, al menos uno de los cuales contiene un sustituyente hidrocarbilsililo, y B) un co-catalizador de activacion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10532998P | 1998-10-23 | 1998-10-23 | |
| US13106799P | 1999-04-26 | 1999-04-26 | |
| PCT/US1999/024944 WO2000024793A1 (en) | 1998-10-23 | 1999-10-22 | Bridged metallocenes for olefin copolymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA01003978A true MXPA01003978A (es) | 2003-06-06 |
Family
ID=26802468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA01003978A MXPA01003978A (es) | 1998-10-23 | 1999-10-22 | Metalocenos puenteados para copolimerizacion de olefinas-. |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US6528670B1 (es) |
| EP (1) | EP1196464B9 (es) |
| JP (1) | JP4689829B2 (es) |
| KR (1) | KR100568839B1 (es) |
| CN (1) | CN1138796C (es) |
| AT (1) | ATE284422T1 (es) |
| AU (1) | AU757241B2 (es) |
| BR (1) | BR9914717A (es) |
| CA (1) | CA2345628C (es) |
| DE (1) | DE69922548T2 (es) |
| ES (1) | ES2233109T3 (es) |
| HK (1) | HK1041705A1 (es) |
| MX (1) | MXPA01003978A (es) |
| RU (1) | RU2232766C2 (es) |
| WO (1) | WO2000024793A1 (es) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
| US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
| BR0014798A (pt) * | 1999-10-22 | 2002-06-11 | Exxonmobil Chem Patents Inc | Complexos catiÈnicos carbênio adequados para catalisadores de polimerização |
| AU2003211542B8 (en) | 2002-09-27 | 2009-08-13 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
| JP4610859B2 (ja) * | 2002-09-27 | 2011-01-12 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| EP1589043A3 (en) | 2003-08-11 | 2006-02-15 | ExxonMobil Chemical Patents Inc. | Polymers of ethylene and, optionally, copolymerizable esters, films using such polymers and stretch hood packaging processes using such films |
| EP1727838B1 (en) * | 2004-03-24 | 2013-04-17 | ExxonMobil Chemical Patents Inc. | Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers |
| US7947786B2 (en) * | 2004-10-13 | 2011-05-24 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
| EP1734059A1 (en) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Carbon-bridged cyclopentadienyl-fluorenyl ligands |
| JP5252714B2 (ja) * | 2006-03-02 | 2013-07-31 | エクソンモービル・ケミカル・パテンツ・インク | プロピレンコポリマーを生産する方法 |
| AR060641A1 (es) | 2006-05-17 | 2008-07-02 | Dow Global Technologies Inc | Proceso de polimerizacion de solucion de polietileno de alta temperatura |
| EP1903061A1 (en) * | 2006-09-25 | 2008-03-26 | Total Petrochemicals Research Feluy | Preparation of diphenyl-bridged substituted cyclopentadienyl-fluorenyl ligands |
| EP2083046A1 (en) | 2008-01-25 | 2009-07-29 | ExxonMobil Chemical Patents Inc. | Thermoplastic elastomer compositions |
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| FR2934599B1 (fr) * | 2008-07-29 | 2012-12-21 | Arkema France | Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations |
| US8378042B2 (en) | 2009-04-28 | 2013-02-19 | Exxonmobil Chemical Patents Inc. | Finishing process for amorphous polymers |
| JP6177526B2 (ja) | 2009-12-23 | 2017-08-09 | インヴィスタ テクノロジーズ エスアエルエルＩＮＶＩＳＴＡ ＴＥＣＨＮＯＬＯＧＩＥＳ Ｓ．ａ．ｒ．ｌ． | 伸縮性ポリオレフィン繊維を含有する布 |
| KR101851409B1 (ko) | 2009-12-23 | 2018-05-31 | 인비스타 테크놀러지스 에스.에이 알.엘. | 폴리올레핀 탄성 섬유 |
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| MX2012007401A (es) | 2009-12-23 | 2012-07-17 | Invista Tech Sarl | Articulos elasticos que incluyen fibra elastica de poliolefina. |
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| US5631202A (en) * | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
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-
1999
- 1999-10-22 AT AT99974265T patent/ATE284422T1/de not_active IP Right Cessation
- 1999-10-22 KR KR1020017004930A patent/KR100568839B1/ko not_active IP Right Cessation
- 1999-10-22 ES ES99974265T patent/ES2233109T3/es not_active Expired - Lifetime
- 1999-10-22 BR BR9914717-3A patent/BR9914717A/pt not_active IP Right Cessation
- 1999-10-22 AU AU13212/00A patent/AU757241B2/en not_active Ceased
- 1999-10-22 DE DE69922548T patent/DE69922548T2/de not_active Expired - Lifetime
- 1999-10-22 MX MXPA01003978A patent/MXPA01003978A/es not_active IP Right Cessation
- 1999-10-22 CN CNB998123811A patent/CN1138796C/zh not_active Expired - Lifetime
- 1999-10-22 US US09/426,099 patent/US6528670B1/en not_active Expired - Lifetime
- 1999-10-22 WO PCT/US1999/024944 patent/WO2000024793A1/en active IP Right Grant
- 1999-10-22 EP EP99974265A patent/EP1196464B9/en not_active Expired - Lifetime
- 1999-10-22 RU RU2001113445/04A patent/RU2232766C2/ru not_active IP Right Cessation
- 1999-10-22 JP JP2000578362A patent/JP4689829B2/ja not_active Expired - Lifetime
- 1999-10-22 CA CA2345628A patent/CA2345628C/en not_active Expired - Fee Related
-
2002
- 2002-03-07 US US10/092,660 patent/US6506857B2/en not_active Expired - Lifetime
- 2002-05-03 HK HK02103341.8A patent/HK1041705A1/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR9914717A (pt) | 2001-07-10 |
| CN1138796C (zh) | 2004-02-18 |
| EP1196464B9 (en) | 2005-03-23 |
| RU2232766C2 (ru) | 2004-07-20 |
| CA2345628A1 (en) | 2000-05-04 |
| ATE284422T1 (de) | 2004-12-15 |
| WO2000024793A8 (en) | 2001-10-11 |
| DE69922548T2 (de) | 2006-01-05 |
| CN1328580A (zh) | 2001-12-26 |
| EP1196464A1 (en) | 2002-04-17 |
| JP4689829B2 (ja) | 2011-05-25 |
| DE69922548D1 (de) | 2005-01-13 |
| US6528670B1 (en) | 2003-03-04 |
| AU757241B2 (en) | 2003-02-06 |
| AU1321200A (en) | 2000-05-15 |
| US6506857B2 (en) | 2003-01-14 |
| HK1041705A1 (zh) | 2002-07-19 |
| US20020137959A1 (en) | 2002-09-26 |
| JP2002528463A (ja) | 2002-09-03 |
| KR20010099705A (ko) | 2001-11-09 |
| WO2000024793A1 (en) | 2000-05-04 |
| KR100568839B1 (ko) | 2006-04-10 |
| ES2233109T3 (es) | 2005-06-01 |
| EP1196464B1 (en) | 2004-12-08 |
| CA2345628C (en) | 2010-02-16 |
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