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11 pages, 4300 KiB  
Article
Polarimeter Optical Spectrum Analyzer
by Eyal Buks
Photonics 2024, 11(6), 486; https://doi.org/10.3390/photonics11060486 - 21 May 2024
Viewed by 800
Abstract
A coherent optical spectrum analyzer is integrated with a rotating quarter wave plate polarimeter. The combined polarimeter optical spectrum analyzer (POSA) allows the extraction of the state of polarization with high spectral resolution. The POSA is used in this work to study two [...] Read more.
A coherent optical spectrum analyzer is integrated with a rotating quarter wave plate polarimeter. The combined polarimeter optical spectrum analyzer (POSA) allows the extraction of the state of polarization with high spectral resolution. The POSA is used in this work to study two optical systems. The first is an optical modulator based on a ferrimagnetic sphere resonator. The POSA is employed to explore the underlying magneto–optical mechanism responsible for modulation sideband asymmetry. The second system under study is a cryogenic fiber loop laser, which produces an unequally spaced optical comb. The polarization measurements provide insights into the nonlinear processes responsible for comb creation. Characterizations extracted from the POSA data provide guidelines for the performance optimization of applications based on the systems under study. Full article
(This article belongs to the Special Issue High-Power Fiber Lasers)
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Figure 1

Figure 1
<p>SOP. (<b>a</b>) The Poincaré sphere. (<b>b</b>) The POSA setup.</p>
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<p>Experimental setup. Optical components and fibers are in red, whereas blue is used to label the MW components and coaxial cables. (<b>a</b>) Optical fibers are installed on both sides of the FMSR for transmission of light through the sphere (see Ref. [<a href="#B35-photonics-11-00486" class="html-bibr">35</a>] for more details on the experimental setup). (<b>b</b>) The cryogenic fiber loop laser (see Ref. [<a href="#B52-photonics-11-00486" class="html-bibr">52</a>] for more details).</p>
Full article ">Figure 3
<p>FMSR. Normalized sideband intensities <math display="inline"><semantics> <mrow> <msub> <mi>I</mi> <mi mathvariant="normal">L</mi> </msub> <mo>/</mo> <msub> <mi>I</mi> <mi mathvariant="normal">P</mi> </msub> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <msub> <mi>I</mi> <mi mathvariant="normal">R</mi> </msub> <mo>/</mo> <msub> <mi>I</mi> <mi mathvariant="normal">P</mi> </msub> </mrow> </semantics></math> are shown in (<b>1</b>) and (<b>3</b>), respectively (<math display="inline"><semantics> <msub> <mi>I</mi> <mi mathvariant="normal">P</mi> </msub> </semantics></math> is the central peak intensity). The letters a, b, and c in the Poincaré plots’ labels refer to the values of <math display="inline"><semantics> <mi>υ</mi> </semantics></math> indicated in (<b>1</b>) and (<b>3</b>). The numbers 1, 2, and 3 in the Poincaré plots’ labels refer to the left sideband, central peak, and right sideband, respectively. The Poincaré vectors are shown in red.</p>
Full article ">Figure 4
<p>USOC intensity (<b>a</b>) and DOP (<b>b</b>). The diode current is <math display="inline"><semantics> <mrow> <mn>0.2</mn> <mo form="prefix">A</mo> </mrow> </semantics></math>, and the EDF temperature is <math display="inline"><semantics> <mrow> <mn>3.2</mn> <mo form="prefix">K</mo> </mrow> </semantics></math>.</p>
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14 pages, 6346 KiB  
Article
Odd Magneto-Optical Linear Dichroism in a Magnetophotonic Crystal
by Tatiana V. Mikhailova, Daria O. Ignatyeva, Sergey D. Lyashko, Vladimir N. Berzhansky and Vladimir I. Belotelov
Photonics 2023, 10(11), 1237; https://doi.org/10.3390/photonics10111237 - 6 Nov 2023
Cited by 2 | Viewed by 1222
Abstract
The phenomena of magneto-optical polarization rotation and circular magnetic dichroism are well known in the Faraday configuration. We present another effect, an odd magneto-optical linear dichroism, arising in nanostructures with polarization-dependent mode Q-factors and magneto-optical components. It reveals itself as the magneto-optical [...] Read more.
The phenomena of magneto-optical polarization rotation and circular magnetic dichroism are well known in the Faraday configuration. We present another effect, an odd magneto-optical linear dichroism, arising in nanostructures with polarization-dependent mode Q-factors and magneto-optical components. It reveals itself as the magneto-optical modulation of light intensity for the two opposite magnetization directions in the Faraday configuration. The effect was demonstrated on a magnetophotonic crystal with a cavity mode, the polarization-dependent Q-factor of which is due to oblique incidence. For a polarization angle of 60° (or 120°) and an angle of incidence around 60°, the magneto-optical intensity modulation maximizes and reaches 6%. Full article
(This article belongs to the Section Optoelectronics and Optical Materials)
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Figure 1

Figure 1
<p>Configuration for observation of the odd magneto-optical linear dichroism. Red arrows indicate magnetization directions.</p>
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<p>A color plot for the transmittance calculated for different wavelengths and polarization angles <span class="html-italic">Ψ</span><sub>0</sub> of the arbitrary linearly (s + p) polarized light (<b>a</b>). Measured transmittance of MPC with positive orientation of magnetization <math display="inline"><semantics> <mrow> <mi>T</mi> <mo stretchy="false">(</mo> <mo>+</mo> <msub> <mi>M</mi> <mrow> <msub> <mi>z</mi> <mi>i</mi> </msub> </mrow> </msub> <mo stretchy="false">)</mo> </mrow> </semantics></math> versus initial state of polarization <span class="html-italic">Ψ</span><sub>0</sub> (<b>b</b>). Measured (symbol) and simulated (lines) transmittance of MPC at resonance wavelength <span class="html-italic">λ</span><sub>R</sub> = 721 nm in configurations with opposite orientations of magnetization <math display="inline"><semantics> <mrow> <mi>T</mi> <mo stretchy="false">(</mo> <mo>+</mo> <msub> <mi>M</mi> <mrow> <msub> <mi>z</mi> <mi>i</mi> </msub> </mrow> </msub> <mo stretchy="false">)</mo> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi>T</mi> <mo stretchy="false">(</mo> <mo>−</mo> <msub> <mi>M</mi> <mrow> <msub> <mi>z</mi> <mi>i</mi> </msub> </mrow> </msub> <mo stretchy="false">)</mo> </mrow> </semantics></math> versus initial state of polarization <span class="html-italic">Ψ</span><sub>0</sub> (<b>c</b>). The arrows indicate the values of <span class="html-italic">Ψ</span><sub>0</sub> corresponding to the configurations in <a href="#photonics-10-01237-f004" class="html-fig">Figure 4</a>b.</p>
Full article ">Figure 3
<p>Simulated distribution of electric field intensity of p- and s-polarized light inside MPC (<b>a</b>) and measured (symbol) and simulated (lines) dependences of the <span class="html-italic">Q</span>-factor and its derivative <math display="inline"><semantics> <mrow> <msub> <msup> <mi>Q</mi> <mo>′</mo> </msup> <mrow> <msub> <mi>Ψ</mi> <mn>0</mn> </msub> </mrow> </msub> </mrow> </semantics></math> on the initial state of polarization <span class="html-italic">Ψ</span><sub>0</sub> at <span class="html-italic">λ</span><sub>R</sub> = 721 nm (<b>b</b>). The angle of incidence is <span class="html-italic">θ</span> = 60°.</p>
Full article ">Figure 4
<p>Measured (symbols) and simulated (lines) values of the odd magneto-optical linear dichroism <span class="html-italic">δ<sub>T</sub></span> of MPC: (<b>a</b>) at resonance wavelength <span class="html-italic">λ</span><sub>R</sub> = 721 nm versus initial state of polarization <span class="html-italic">Ψ</span><sub>0</sub>, (<b>b</b>) in the vicinity of resonance for different <span class="html-italic">Ψ</span><sub>0</sub>: 60° and 120°. The angle of incidence is <span class="html-italic">θ</span> = 60°.</p>
Full article ">Figure A1
<p>Spectra of transmittance of MPC at normal incidence <span class="html-italic">θ</span> = 0° for p- and s-polarized light and different scales: (<b>a</b>) in a wide spectral range showing a photonic bandgap, from 575 nm to 925 nm, and (<b>b</b>) in the vicinity of the resonant wavelength, from 760 nm to 790 nm. (<b>c</b>) Spectra of Faraday rotation angle of MPC for p- or s-polarized light at normal incidence <span class="html-italic">θ</span> = 0°.</p>
Full article ">
11 pages, 3841 KiB  
Article
A Polarimetric Fiber Ring Laser Incorporating a Coupled Optoelectronic Oscillator and Its Application to Magnetic Field Sensing
by Danqi Feng, Yangxu Tang, Run Lei, Ziqing Feng and Ming Deng
Photonics 2023, 10(6), 662; https://doi.org/10.3390/photonics10060662 - 7 Jun 2023
Cited by 2 | Viewed by 1358
Abstract
A novel configuration for a polarimetric fiber ring laser incorporating a coupled optoelectronic oscillator (COEO) is proposed and experimentally demonstrated, and its application to magnetic field sensing is studied. The COEO-based polarimetric fiber ring laser has two mutually coupled loops: the fiber ring [...] Read more.
A novel configuration for a polarimetric fiber ring laser incorporating a coupled optoelectronic oscillator (COEO) is proposed and experimentally demonstrated, and its application to magnetic field sensing is studied. The COEO-based polarimetric fiber ring laser has two mutually coupled loops: the fiber ring laser loop and the OEO loop. In the fiber ring laser loop, longitudinal modes break up into orthogonal polarization modes because of birefringence. The frequency of the polarization mode beat (PMB) signals is determined by the cavity birefringence. In the OEO loop, a microwave signal with its frequency equal to the PMB signal is generated. By feeding the oscillation mode to modulate the optical loop, mode-locking can be achieved, rendering the mode spacing of the laser equal to the frequency of the oscillating OEO mode. We can estimate the birefringence variation by measuring the oscillating frequency of the COEO. To validate the proposed sensing system, a circular birefringence change is introduced in a magneto-optic crystal via the Faraday rotation effect. Then, the magnetic field sensing is implemented. Such configuration can achieve single longitudinal oscillation and realize high-speed and high-precision measurements. Full article
(This article belongs to the Special Issue Photonic Sensors)
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Figure 1

Figure 1
<p>Schematic diagram of the magnetic sensor based on the COEO.</p>
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<p>(<b>a</b>) Two eigenpolarization modes of linear polarization of the same longitudinal mode. (<b>b</b>) The longitudinal modes (<span class="html-italic">E<sub>f</sub></span>) and (<b>c</b>) the longitudinal modes (<span class="html-italic">E<sub>s</sub></span>) after transmission through the magneto-optic crystal.</p>
Full article ">Figure 3
<p>The principal axis of the Pol is oriented at an angle of <math display="inline"><semantics><mrow><mi>ϕ</mi><mo>=</mo><mi>θ</mi><mo>−</mo><mrow><mi>π</mi><mo>/</mo><mn>4</mn></mrow></mrow></semantics></math> with respect to the principal axis of the MZM.</p>
Full article ">Figure 4
<p>(<b>a</b>) Two eigenpolarization modes of linear polarization. (<b>b</b>) Modes of the polarimetric multi-longitudinal mode fiber laser. (<b>c</b>) The oscillating modes that existed in the OEO loop. (<b>d</b>) The existed laser modes with a mode spacing of <span class="html-italic">f<sub>PMB</sub></span>, which is in phase after mode-locking. (<b>e</b>) The final existed mode in the OEO loop.</p>
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<p>The measured modes of the laser (<b>a</b>) without Pol; (<b>b</b>) with Pol.</p>
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<p>(<b>a</b>) The measured optical pulses. (<b>b</b>) the measured optical spectra.</p>
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<p>The electrical spectra of the RF signal (<b>a</b>) of the optical pulses and (<b>b</b>) from the OEO loop.</p>
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<p>(<b>a</b>) The measured frequency responses under different magnetic field strengths. (<b>b</b>) The relationship between the frequency shift and the magnetic field strength. (<b>c</b>) The measured magnetic field strength as a function of the applied magnetic field strength and the measured errors.</p>
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<p>Stability of the COEO at temporal duration of 120 min.</p>
Full article ">
16 pages, 3984 KiB  
Article
Microstructural and Morphological Characterization of the Cobalt-Nickel Thin Films Deposited by the Laser-Induced Thermionic Vacuum Arc Method
by Virginia Dinca, Aurelia Mandes, Rodica Vladoiu, Gabriel Prodan, Victor Ciupina and Silviu Polosan
Coatings 2023, 13(6), 984; https://doi.org/10.3390/coatings13060984 - 25 May 2023
Cited by 1 | Viewed by 1866
Abstract
Laser Induced-Thermionic Vacuum Arc (LTVA) technology was used for depositing uniform intermetallic CoNi thin films of 100 nm thickness. LTVA is an original deposition method using a combination of the typical Thermionic Vacuum Arc (TVA) system and a laser beam provided by a [...] Read more.
Laser Induced-Thermionic Vacuum Arc (LTVA) technology was used for depositing uniform intermetallic CoNi thin films of 100 nm thickness. LTVA is an original deposition method using a combination of the typical Thermionic Vacuum Arc (TVA) system and a laser beam provided by a QUANTEL Q-Smart 850 Nd:YAG compact Q-switched laser with a second harmonic module. The novelty is related to the simultaneous deposition of a bi-component metallic thin film using photonic processes of the laser over the plasma deposition, which improves the roughness but also triggers the composition of the deposited thin film. Structural analysis of the deposited thin films confirms the formation of face-centered cubic (fcc) as the main phase CoNi and hexagonal Co3Ni as the minority phase, observed mainly using high-resolution transmission electron microscopy. The magneto-optical measurements suggest an isotropic distribution of the CoNi alloy thin films for the in-plan angular rotation. From the low coercive field of Hc = 40 Oe and a saturation field at 900 Oe, the CoNi thin films obtained by LTVA are considered semi-hard magnetic materials. Magnetic force microscopy reveals spherical magnetic nanoparticles with mean size of about 40–50 nm. The resistivity was estimated at ρ = 34.16 μΩ cm, which is higher than the values for bulk Co and Ni. Full article
(This article belongs to the Special Issue Nanostructured Materials Deposition Techniques and Characterization)
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Figure 1
<p>Schematic of the experimental LTVA system for CoNi thin film deposition.</p>
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<p>X-ray diffraction patterns of the CoNi thin film (<b>a</b>) and details of the (111) peak (<b>b</b>).</p>
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<p>HRTEM image (<b>a</b>) with SAED determination (<b>b</b>) and estimation of nanocrystal dimension based on LogNormal analysis (<b>c</b>).</p>
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<p>X-ray reflectometry of CoNi thin film.</p>
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<p>SEM micrographs recorded on CoNi sample-2D image (<b>a</b>) and 3D image (<b>b</b>).</p>
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<p>EDX patterns of CoNi thin films.</p>
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<p>AFM image of the CoNi thin films: (<b>a</b>) 20 × 20 μm and (<b>b</b>) 1 × 1 μm. MFM images of the CoNi thin films: (<b>c</b>) 20 × 20 μm and (<b>d</b>) 1 × 1 μm.</p>
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<p>MOKE curves for three in-plan orientations (<b>a</b>) and the angle dependence of the coercive field (<b>b</b>).</p>
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<p>Current-voltage measurements at T = 295 K.</p>
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<p>Resistivity versus temperature.</p>
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20 pages, 5942 KiB  
Article
A New Generation of OPM for High Dynamic and Large Bandwidth MEG: The 4He OPMs—First Applications in Healthy Volunteers
by Tjerk P. Gutteling, Mathilde Bonnefond, Tommy Clausner, Sébastien Daligault, Rudy Romain, Sergey Mitryukovskiy, William Fourcault, Vincent Josselin, Matthieu Le Prado, Agustin Palacios-Laloy, Etienne Labyt, Julien Jung and Denis Schwartz
Sensors 2023, 23(5), 2801; https://doi.org/10.3390/s23052801 - 3 Mar 2023
Cited by 16 | Viewed by 5295
Abstract
MagnetoEncephaloGraphy (MEG) provides a measure of electrical activity in the brain at a millisecond time scale. From these signals, one can non-invasively derive the dynamics of brain activity. Conventional MEG systems (SQUID-MEG) use very low temperatures to achieve the necessary sensitivity. This leads [...] Read more.
MagnetoEncephaloGraphy (MEG) provides a measure of electrical activity in the brain at a millisecond time scale. From these signals, one can non-invasively derive the dynamics of brain activity. Conventional MEG systems (SQUID-MEG) use very low temperatures to achieve the necessary sensitivity. This leads to severe experimental and economical limitations. A new generation of MEG sensors is emerging: the optically pumped magnetometers (OPM). In OPM, an atomic gas enclosed in a glass cell is traversed by a laser beam whose modulation depends on the local magnetic field. MAG4Health is developing OPMs using Helium gas (4He-OPM). They operate at room temperature with a large dynamic range and a large frequency bandwidth and output natively a 3D vectorial measure of the magnetic field. In this study, five 4He-OPMs were compared to a classical SQUID-MEG system in a group of 18 volunteers to evaluate their experimental performances. Considering that the 4He-OPMs operate at real room temperature and can be placed directly on the head, our assumption was that 4He-OPMs would provide a reliable recording of physiological magnetic brain activity. Indeed, the results showed that the 4He-OPMs showed very similar results to the classical SQUID-MEG system by taking advantage of a shorter distance to the brain, despite having a lower sensitivity. Full article
(This article belongs to the Section Physical Sensors)
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Figure 1
<p>Experimental setup. (<b>A</b>) SQUID-MEG system used in this study with the subject in a typical seated position. (<b>B</b>): Top left: Subject setup with the five <sup>4</sup>He-OPMs used in the somatosensory task. One of them serving as a reference sensor (green label) is placed over the top of the head, and the four other ones are located on the left side of the subject. The cables are supported by a wooden frame. Top right: Same setup on a phantom head without the wooden frame. Bottom right: zoomed view of one of the <sup>4</sup>He-OPMs used and zoomed view of the sensors installed in the headset. The sensor has a 2 cm by 2 cm by 5 cm footprint. The glass cell containing the sensitive helium gas and the associated Helmholtz coils are visible. (<b>C</b>) SQUID-MEG sensors layout with the sensors closest to the OPMs location in red for the somatosensory task and in blue for the visual task. (<b>D</b>) <sup>4</sup>He-OPMs sensors layout in red for the somatosensory task and in blue for the visual task.</p>
Full article ">Figure 2
<p>Empty room and visual task baseline average PSDs for SQUID-MEG and <sup>4</sup>He-OPMs. Mean PSDs obtained after averaging PSDs over sessions and over all the sensors used in this study: SQUID-MEG: MLO31, MLO11, MRO21, MRO11, MLC11, MLC13, MLC33, MLC31 and <sup>4</sup>He-OPMs: All 4 sensors except the reference with the two directions (radial and a tangential one) used in this study. No notch filters were applied for this figure. Top: Empty room full spectrum up to 300 Hz. Middle: Empty room spectrum zoomed up to 100 Hz. Bottom: Visual task baseline (500 ms) spectrum up to 100 Hz.</p>
Full article ">Figure 3
<p>Event-related fields for SQUID-MEG (<b>A</b>), <sup>4</sup>He-OPMs in the radial (<b>B</b>) and tangential axis (<b>C</b>). Gray-filled lines at the bottom of each panel represent the RMS of the combined signal. Gray vertical area denotes the suppressed stimulation artifact. Note that the scales for SQUID-MEG and <sup>4</sup>He-OPMs are not the same.</p>
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<p>Individual time-courses of best SNR sensors following somatosensory stimulation for SQUID-MEG, radial <sup>4</sup>He-OPMs and tangential <sup>4</sup>He-OPMs. For visualization only, a multiplication factor and polarity alignment are applied to the SQUID-MEG and tangential axis of the <sup>4</sup>He-OPMs sensors with reference to the radial axis <sup>4</sup>He-OPMs. The top three panels depict three representative subjects with varying degrees of correlation between SQUID-MEG and <sup>4</sup>He-OPMs. The bottom panel shows the group average (<span class="html-italic">n</span> = 17).</p>
Full article ">Figure 5
<p>Average signal-to-noise ratio per modality, sensor type and axis. Black horizontal bars denote the group means. Plots span the entire data range.</p>
Full article ">Figure 6
<p>Group averaged event-related fields for conventional SQUID-MEG (<b>A</b>), <sup>4</sup>He-OPMs in the radial (<b>B</b>) and tangential direction (<b>C</b>). Gray-filled lines at the bottom of each panel represent the RMS of the combined signal. Note that the scales for SQUID-MEG and <sup>4</sup>He-OPMs are not the same.</p>
Full article ">Figure 7
<p>Individual time-courses of best SNR sensors following visual stimulation for SQUID, <sup>4</sup>He-OPMs radial and <sup>4</sup>He-OPMs tangential sensors. For visualization only, a multiplication factor and polarity alignment are applied to the SQUID-MEG and tangential <sup>4</sup>He-OPMs with reference to the radial <sup>4</sup>He-OPM sensor. The top three panels depict three representative subjects with varying degrees of correspondence between SQUID-MEG and <sup>4</sup>He-OPMs. The bottom panel shows the group average (<span class="html-italic">n</span> = 18).</p>
Full article ">Figure 8
<p>Average signal-to-noise ratio per modality, sensor type and axis, calculated as the maximum absolute post-stimulus onset deflection [0 s, 0.3 s] divided by the standard error of the baseline [−0.2 s, 0 s]. Black horizontal bars denote the group means. Plots span the entire data range.</p>
Full article ">Figure 9
<p>Group-average time-frequency representation of the visual experiment MEG data for the SQUID-MEG and <sup>4</sup>He-OPM in the radial and tangential axes (<b>A</b>). Values denote the percent change relative to baseline [−0.4 s, 0 s]. Note that the scale is different between SQUID and <sup>4</sup>He-OPMs sensors. Significant clusters (<span class="html-italic">p</span> &lt; 0.05, two-tailed) are contained within areas marked in black. The onset of the visual stimulus was at t = 0. (<b>B</b>,<b>C</b>) depict time-frequency representations of two selected participants, one with a high individual gamma frequency (<b>B</b>) and a low to average frequency (<b>C</b>), in the gamma range for SQUID-MEG (<b>left</b>) and <sup>4</sup>He-OPMs (radial axis, (<b>middle</b>)). Post-stimulus percent signal change [0.1 s, 0.4 s] is depicted on the (<b>right</b>) (scaling is adjusted for comparison).</p>
Full article ">Figure A1
<p>Individual averages of the somatosensory stimulation experiment, comparing SQUID-MEG and <sup>4</sup>He-OPMs in radial and tangential direction for the sensors with the best SNR. Pearson product-moment correlations between SQUID-MEG and either radial <sup>4</sup>He-OPMs (r<sub>radial</sub>) or tangential <sup>4</sup>He-OPMs (r<sub>tangential</sub>). Amplification factors for SQUID-MEG and tangential <sup>4</sup>He-OPM relative to radial <sup>4</sup>He-OPM are indicated in the individual figure legends.</p>
Full article ">Figure A2
<p>Individual averages of the visual stimulation experiment, comparing SQUID-MEG and <sup>4</sup>He-OPMs in radial and tangential direction for the sensor with the best SNR. Pearson product-moment correlations between SQUID-MEG and either radial <sup>4</sup>He-OPMs (r<sub>radial</sub>) or tangential <sup>4</sup>He-OPMs (r<sub>tangential</sub>). Amplification factors for SQUID-MEG and tangential <sup>4</sup>He-OPMs relative to radial <sup>4</sup>He-OPMs are indicated in the individual figure legends.</p>
Full article ">
14 pages, 4437 KiB  
Article
Modeling of Enhanced Polar Magneto-Optic Kerr Effect by Surface Plasmons in Au Bowtie Arrays
by Jingyi Liu, Lianchun Long and Yang Yang
Nanomaterials 2023, 13(2), 253; https://doi.org/10.3390/nano13020253 - 6 Jan 2023
Viewed by 2173
Abstract
The weak magneto-optical (MO) signal of traditional MO materials is indeed an important issue for their further practical applications. Although many strategies have been proposed to improve the MO effect, hybridization with noble metal nanostructures is a promising route in recent years due [...] Read more.
The weak magneto-optical (MO) signal of traditional MO materials is indeed an important issue for their further practical applications. Although many strategies have been proposed to improve the MO effect, hybridization with noble metal nanostructures is a promising route in recent years due to the high localized-surface plasmon resonances (LSPR) effect. A new magneto-optical surface plasmon resonance (MOSPR) structure hybrid with Au bowtie arrays is proposed to increase the measuring range of the polar magneto-optical Kerr effect (PMOKE) and the quality factor through the LSPR effect. It is verified by a numerical simulation of the finite element method (FEM). The optimized parameters were found by modulating the shape and geometric dimensions. Owing to the significant LSPR from the Au bowties, a PMOKE amplification signal spectrum with narrow linewidth, and a high amplitude with high-sensing performance was achieved. Compared with the bare magnetic film alone, by optimizing the relevant parameters of the LSPR structure, the maximum signal increases 3255 times, and the quality factor can be greatly improved, which would provide important guidance and help for the practical application of MO devices. Full article
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Figure 1
<p>Schematic of the periodic model geometry for calculation of the PMOKE. (<b>a</b>) General schematic showing the Au nanostructure, magnetic region, air region, and p-polarized light incidence mode (the polarized light is incident vertically, and the polarization angle is 0°). (<b>b</b>) The parameters that affect the PMOKE discussed in this paper. (<b>c</b>) The X directional component of the electric field, which is the result of the MO rotation induced by the PMOKE.</p>
Full article ">Figure 2
<p>Wavelength-dependent PMOKE response for Au bowties of different height (heights are indicated in the legend). The bowties were located centered within the unit cell of the periodic model. The color subgraph represents the reflected electric field. (<b>a</b>) Kerr rotation and (<b>b</b>) normalized amplitude of the X component of the reflected electric field.</p>
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<p>Kerr rotation, Kerr ellipticity, and absolute Kerr signal (the sum of the rotation and ellipticity in quadrature) of PMOKE response for Au bowties of different gap distance <span class="html-italic">δ</span>.</p>
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<p>Wavelength dependence of PMOKE response for the Au bowties of different side length. (<b>a</b>) shows the absolute Kerr signal with difference in side length from 100 nm to 230 nm, (<b>b</b>) the maximum absolute Kerr signal and resonant wavelength, (<b>c</b>) the normalized amplitude of the X component (<span class="html-italic">Ex</span>) of the electric field in the XZ plane, and (<b>d</b>) the normalized amplitude of the X component (<span class="html-italic">Ex</span>) of the electric field in the YZ plane.</p>
Full article ">Figure 5
<p>Wavelength dependence of PMOKE response for the Au bowties of different <span class="html-italic">θ</span> and side length placed at center of the magnetic layer (the side length is indicated in the legend). (<b>a</b>,<b>c</b>,<b>e</b>,<b>g</b>,<b>i</b>) indicate the change rule in PMOKE with <span class="html-italic">θ</span> under 400–1000 nm incident wave when the side length changes from 100 nm to 200 nm every 25 nm. (<b>b</b>,<b>d</b>,<b>f</b>,<b>h</b>,<b>j</b>) denote the change rule in PMOKE of the structure with <span class="html-italic">θ</span> under three resonant wavelengths (565 nm, 665 nm, and 815 nm).</p>
Full article ">Figure 5 Cont.
<p>Wavelength dependence of PMOKE response for the Au bowties of different <span class="html-italic">θ</span> and side length placed at center of the magnetic layer (the side length is indicated in the legend). (<b>a</b>,<b>c</b>,<b>e</b>,<b>g</b>,<b>i</b>) indicate the change rule in PMOKE with <span class="html-italic">θ</span> under 400–1000 nm incident wave when the side length changes from 100 nm to 200 nm every 25 nm. (<b>b</b>,<b>d</b>,<b>f</b>,<b>h</b>,<b>j</b>) denote the change rule in PMOKE of the structure with <span class="html-italic">θ</span> under three resonant wavelengths (565 nm, 665 nm, and 815 nm).</p>
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<p>Electric field distribution of 175 nm side length Au bowties placed at rotations of 1°, 5°, 9°, 13°, and 17° under 565 nm incident wavelength. The cross-sections show the X component of the local field, normalized by the incident field amplitude, plotted at one instance in phase. Field distribution for a cross-section through the center of the YZ plane. The field appears to penetrate further into the reflect air layer in the case of a 9° rotation.</p>
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<p>Comparison of quality factors amongst different structures. (Klopfer, E. 2020 [<a href="#B45-nanomaterials-13-00253" class="html-bibr">45</a>]; Alipour-Banaei, H. 2014 [<a href="#B46-nanomaterials-13-00253" class="html-bibr">46</a>]; Seifouri, M. 2017 [<a href="#B47-nanomaterials-13-00253" class="html-bibr">47</a>]; Rebhi, S. 2018 [<a href="#B48-nanomaterials-13-00253" class="html-bibr">48</a>]).</p>
Full article ">Figure A1
<p>Variation in Kerr rotation and ellipticity with the incident wavelength (<b>a</b>) and side length of Au nanotriangle (<b>b</b>).</p>
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26 pages, 4898 KiB  
Review
Magnetic Semiconductors as Materials for Spintronics
by Andrei Telegin and Yurii Sukhorukov
Magnetochemistry 2022, 8(12), 173; https://doi.org/10.3390/magnetochemistry8120173 - 29 Nov 2022
Cited by 16 | Viewed by 5024
Abstract
From the various aspects of spintronics the review highlights the area devoted to the creation of new functional materials based on magnetic semiconductors and demonstrates both the main physical phenomena involved and the technical possibilities of creating various devices: maser, p-n diode with [...] Read more.
From the various aspects of spintronics the review highlights the area devoted to the creation of new functional materials based on magnetic semiconductors and demonstrates both the main physical phenomena involved and the technical possibilities of creating various devices: maser, p-n diode with colossal magnetoresistance, spin valve, magnetic lens, optical modulators, spin wave amplifier, etc. Particular attention is paid to promising research directions such as ultrafast spin transport and THz spectroscopy of magnetic semiconductors. Special care has been taken to include a brief theoretical background and experimental results for the new spintronics approach employing magnetostrictive semiconductors—strain-magnetooptics. Finally, it presents top-down approaches for magnetic semiconductors. The mechano-physical methods of obtaining and features of the physical properties of high-density nanoceramics based on complex magnetic oxides are considered. The potential possibility of using these nanoceramics as an absorber of solar energy, as well as in modulators of electromagnetic radiation, is shown. Full article
(This article belongs to the Special Issue Spintronics, Magnetic Semiconductors and Devices)
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Figure 1
<p>Schematic representation of changes in the band structure of a magnetic SCs depending on the orientation of the electron spin (<b>right</b>), which are absent in the band structure of a non-magnetic semiconductor (<b>left</b>).</p>
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<p>Schematic representation of the FM/SC heterostructure with spin-polarized electron transport from the ferromagnetic SC (<b>a</b>) for the case of an inverse population of the upper Zeeman level (E<sub>2</sub>) of the non-magnetic SC with g &lt; 0 by conduction electrons and subsequent radiative recombination; (<b>b</b>) for the case of the population of the lower Zeeman level (E<sub>1</sub>) of the SC with g &gt; 0 by conduction electrons and subsequent photoexcitation to the upper Zeeman level. Symbols H and I denote the magnetic field and current direction, respectively, while LS—spin-orbital coupling. Red and blue arrows are assigned to the direction of the spin and the magnetic moment of electrons.</p>
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<p>Schematic of an electrical spin-injection source for the paramagnetic medium. An electrical current is driven across the interface between a ferromagnetic layer and the paramagnetic layer (separated by an oxide tunnel barrier), which causes a spin current Is to flow into the paramagnet. It is assumed that the static field B is sufficiently strong to saturate the magnetization M of the ferromagnetic layer normal to the film plane [<a href="#B54-magnetochemistry-08-00173" class="html-bibr">54</a>].</p>
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<p>(<b>a</b>) Photo of the spin-injection maser with a control unit. Inset: the contact structure of p-HgCr<sub>2</sub>Se<sub>4</sub>/n-InSb, (<b>b</b>) dependence of radiation power P of the maser on temperature for various contact structures: 1—Co<sub>2</sub>MnSb/n-InSb in the field of 6 kOe and current I = 2 A; 2—Co<sub>2</sub>MnSn/n-InSb at H = 6.6 kOe and I = 3 A; 3—p-HgCr<sub>2</sub>Se<sub>4</sub>/n-InSb at H = 7.5 kOe and I = 3 A; 4—n-Eu<sub>0.98</sub>Gd<sub>0.02</sub>O/n-InSb at H = 6.2 kOe and I = 2 A.</p>
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<p>Spin-wave attenuation versus electric field for wavevector k = 9.2 × 10<sup>5</sup> cm<sup>−1</sup> (1), k = 6.3 × 10<sup>5</sup> cm<sup>−1</sup> (2) taken at temperatures below 80 K. Dots are experimental results; solid lines are modelling.</p>
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<p>Magnetoelectric element based on a layered structure: FM material (e.g., CoFe, NiFe) and a piezoelectric layer (e.g., PZT) [<a href="#B73-magnetochemistry-08-00173" class="html-bibr">73</a>].</p>
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<p>Schematic of structures based on a p-n junction in ferromagnetic SCs. The depleted layers are shaded. A four-fold contact scheme for measuring electrical and MR in magnetic field H is applied.</p>
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<p>Field dependences of magnetoresistance MR for p-n structure of HgCr<sub>2</sub>Se<sub>4</sub> at T = 125 K ≈ T<sub>C</sub>. The inset shows the field dependences of the MR of the initial crystals of n-HgCr<sub>2</sub>Se<sub>4</sub> and p-HgCr<sub>2</sub>Se<sub>4</sub>.</p>
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<p>Temperature dependences of the magnetoresistance MR (left axis, square symbols) and the magnetotransmission MT (right axis, circle symbols,) at wavelength of 6 µm for La<sub>0.8</sub>Ag<sub>0.1</sub>MnO<sub>3</sub> films in the magnetic field of 8 kOe. The dashed red line is the result of the fitting by function f = a + b/sqrt(T). Inset: field dependences of MR (left axis) at T = 295 K (1) and T = 80 K (2) and MT (right axis) at T = 295 K (3) and wavelength of 6 µm.</p>
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<p>Temperature dependences of the absolute value of (<b>a</b>) the colossal MR and (<b>b</b>) magnetotransmission MT at wavelength of 3 μm for the Sm<sub>0.55</sub>Sr<sub>0.45</sub>MnO<sub>3</sub>–Nd<sub>0.55</sub>Sr<sub>0.45</sub>MnO<sub>3</sub> thin-film heterostructure in the magnetic field of 8 kOe. The dashed lines are the Gaussian fitting for each thin-film layer and the interface, the solid red line is the result of the fitting; (<b>c</b>) temperature dependences of the absolute value of MT for the single-layer La<sub>0.7</sub>Sr<sub>0.3</sub>MnO<sub>3</sub> film (1) and thin-film CoFe<sub>2</sub>O<sub>4</sub>/La<sub>0.7</sub>Sr<sub>0.3</sub>MnO<sub>3</sub> heterostructure (2) at wavelength of 6 μm in the magnetic field of 8 kOe.</p>
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<p>Schematic representation of the spin valve: (<b>a</b>) top view, (<b>b</b>) cross-sectional view, (<b>c</b>) field dependence of the magnetoresistance MR of the spin valve [<a href="#B89-magnetochemistry-08-00173" class="html-bibr">89</a>].</p>
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<p>A schematic model of a spin switch.</p>
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<p>Temperature dependencies of the absolute value of magnetotransmission MT (left axis, red symbols) and modulation depth m (right axis, blue symbols) of a modulator based on La<sub>0.82</sub>Na<sub>0.18</sub>MnO<sub>3</sub> film in a magnetic field of 8 kOe and wavelength of 8.8 μm. The inset shows the field dependence of m at T = 303 K in a constant field (solid line) and in an alternating magnetic field (circles).</p>
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<p>(<b>a</b>) The principal scheme of the modulator of IR radiation: 1—a MO element, 2—a source of permanent or alternating magnetic field H. Arrows indicate an incident light upon the sample, reflected and transmitted modulated radiation; (<b>b</b>) a prototype of the IR radiation modulator based on the effect of MT in a manganite film: black cylinder with center hole is a magnetic field source with MO element inside, blue plate with electrical contacts is a thermal stabilization system with controller.</p>
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<p>Magnetic field dependences of (<b>a</b>) linear magnetostriction (Δ<span class="html-italic">l</span>/<span class="html-italic">l</span>)<sub>100</sub>; (<b>b</b>) magnetoreflection <span class="html-italic">MRf</span>; (<b>c</b>) magnetotransmission MT and (<b>d</b>) magnetoabsorption of light MAbs of the CoFe<sub>2</sub>O<sub>4</sub> single crystal for orientation of magnetic field H||[100] at wavelength of 2.7 µm and <span class="html-italic">T</span> = 295 K.</p>
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<p>Field dependence of magnetotransmission MT at wavelength of 3.4 μm and T = 67 K for SL—(La<sub>0.25</sub>Pr<sub>0.75</sub>)<sub>0.7</sub>Ca<sub>0.3</sub>MnO<sub>3</sub> single layer film; Het—heterostructure (La<sub>0.25</sub>Pr<sub>0.75</sub>)<sub>0.7</sub>Ca<sub>0.3</sub>MnO<sub>3</sub>/YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−y</sub>. Inset: schematic representation of the prototype of magnetic lens based on the (La<sub>0.25</sub>Pr<sub>0.75</sub>)<sub>0.7</sub>Ca<sub>0.3</sub>MnO<sub>3</sub>/YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7−y</sub> heterostructure. The arrow shows the direction of the external magnetic field H.</p>
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<p>High-density nanoceramics obtained (1) by the method of spherically converging shock waves (CuO); (2) by the method of cylindrical explosive loading (LaMnO<sub>3+y</sub>); (3) by the method of static pressure with shear (Y<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub>).</p>
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<p>Specific Faraday rotation of nanostructured YIG samples with different crystallite sizes, SC–YIG single crystal.</p>
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<p>Optical density spectra of CuO samples at T = 295 K: SC—single crystal, NP—nanopowder, NC—nanoceramics.</p>
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<p>(<b>a</b>) Spectra of the magnetization-induced rotation and ellipticity of the transmitted THz radiation for Hg<sub>0.92</sub>Cd<sub>0.02</sub>Cr<sub>2</sub>Se<sub>4</sub> single crystal at T = 40 K and 1 kOe applied field. The solid lines are linear fits used for guiding the eye [<a href="#B152-magnetochemistry-08-00173" class="html-bibr">152</a>]. (<b>b</b>)The temporal profile of the absorption of light in HgCr<sub>2</sub>Se<sub>4</sub> single crystal at energy 0.23 eV (5.4 μm) and T = 10 K with and without an external magnetic field.</p>
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11 pages, 3377 KiB  
Article
Magnetically Tunable Micro-Ring Resonators for Massive Magneto-Optical Modulation in Dense Wavelength Division Multiplexing Systems
by Josino Villela S. Neto, William O. F. Carvalho and Jorge Ricardo Mejía-Salazar
Sensors 2022, 22(21), 8163; https://doi.org/10.3390/s22218163 - 25 Oct 2022
Cited by 6 | Viewed by 2189
Abstract
We demonstrate, numerically, a new concept for on-chip magneto-optical (MO) modulation in dense wavelength division multiplexing (DWDM) applications. Our idea uses materials and mechanisms that are compatible with current silicon-on-insulator fabrication and CMOS technologies for monolithic integration. The physics behind our idea stems [...] Read more.
We demonstrate, numerically, a new concept for on-chip magneto-optical (MO) modulation in dense wavelength division multiplexing (DWDM) applications. Our idea uses materials and mechanisms that are compatible with current silicon-on-insulator fabrication and CMOS technologies for monolithic integration. The physics behind our idea stems in the exploitation of the enhanced MO activity of a micro-ring, made of cerium substituted yttrium iron garnet (Ce:YIG) material, to actively manipulate the resonance wavelengths of an adjacent micro-ring resonator (MRR) of silicon (Si). This active manipulation of the latter MO-MRR structure is used to modulate the optical signal traveling through a side-coupled Si bus waveguide. Moreover, by proper tailoring multiple MO-MRRs (side-coupled to the single Si bus waveguide) to match wavelength channels in DWDM across the entire C-band optical communications spectrum, we extend our proposal to massive and dynamic MO modulation in DWDM applications. Significantly, we noticed that the active MO shifting of the resonant wavelength (used for MO modulation here) can be used for improvements in the spectrum utilization efficiency in future elastic optical networks (EONs). Full article
(This article belongs to the Section Communications)
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Figure 1
<p>(<b>a</b>) Schematic 3D of the MO-MRR and (<b>b</b>) a zoom-in of the highlighted region in (<b>a</b>).</p>
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<p>Transmittances in the MO-MRR for non-magnetized (black dashed curve) and magnetized to <math display="inline"><semantics> <mrow> <mo>−</mo> <mi mathvariant="bold">M</mi> </mrow> </semantics></math> (blue solid curve) and <math display="inline"><semantics> <mrow> <mo>+</mo> <mi mathvariant="bold">M</mi> </mrow> </semantics></math> (red solid curve). The points I and III symbolize a possible coding for bit 1, whilst the points II and IV may coding the bit 0, as depicted in the inset.</p>
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<p>Normalized <span class="html-italic">H</span>-field in the MO-MRR. (<b>a</b>) The system in non-resonance condition (I &amp; III) and (<b>b</b>) in resonance condition (II &amp; IV). In (<b>c</b>), an inset from (<b>a</b>) at the straight MRR section, where one can see the guided wave and the evanescent field along the MO ring. (<b>d</b>) the cross-section view of the MO-MRR for TM mode.</p>
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<p>Resonances for <math display="inline"><semantics> <mrow> <mo>±</mo> <mi mathvariant="bold">M</mi> </mrow> </semantics></math> with small differences between the widths <math display="inline"><semantics> <msub> <mi>W</mi> <mn>2</mn> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>W</mi> <mn>1</mn> </msub> </semantics></math>. (<b>a</b>) Variations with steps of <math display="inline"><semantics> <mrow> <mo>±</mo> <mn>5</mn> </mrow> </semantics></math>% from 0% to <math display="inline"><semantics> <mrow> <mo>±</mo> <mn>10</mn> </mrow> </semantics></math>% and (<b>b</b>) variation from <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>4</mn> </mrow> </semantics></math> to <math display="inline"><semantics> <mrow> <mo>+</mo> <mn>4</mn> </mrow> </semantics></math>% with steps of 1%. (<b>c</b>) A linear fitting of <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>λ</mi> </mrow> </semantics></math> as function of <math display="inline"><semantics> <mrow> <msub> <mi>W</mi> <mn>2</mn> </msub> <mo>/</mo> <msub> <mi>W</mi> <mn>1</mn> </msub> </mrow> </semantics></math>.</p>
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<p>(<b>a</b>) Schematic representation of multiple MO-MRRs side-coupled to a single Si-waveguide for massive MO modulation in DWDM applications. (<b>b</b>–<b>i</b>) MO modulation in DWDM for different combinations of <math display="inline"><semantics> <mrow> <mo>(</mo> <msubsup> <mi>λ</mi> <mrow> <mn>1</mn> </mrow> <mrow> <mo>±</mo> <mi mathvariant="bold">M</mi> </mrow> </msubsup> <mo>,</mo> <msubsup> <mi>λ</mi> <mrow> <mn>2</mn> </mrow> <mrow> <mo>±</mo> <mi mathvariant="bold">M</mi> </mrow> </msubsup> <mo>,</mo> <msubsup> <mi>λ</mi> <mrow> <mn>3</mn> </mrow> <mrow> <mo>±</mo> <mi mathvariant="bold">M</mi> </mrow> </msubsup> <mo>)</mo> </mrow> </semantics></math>.</p>
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18 pages, 3847 KiB  
Review
Bi-Substituted Ferrite Garnet Type Magneto-Optic Materials Studied at ESRI Nano-Fabrication Laboratories, ECU, Australia
by Mohammad Nur-E-Alam, Mikhail Vasiliev and Kamal Alameh
Coatings 2022, 12(10), 1471; https://doi.org/10.3390/coatings12101471 - 5 Oct 2022
Cited by 4 | Viewed by 2588
Abstract
Since 2007, at the Electron Science Research Institute (ESRI) nano-fabrication laboratories, Edith Cowan University, Australia, we have devoted research efforts to the synthesis and characterization of bismuth-containing ferrite-garnet-type thin-film magneto-optic (MO) materials of different compositions. We report on the growth and characteristics of [...] Read more.
Since 2007, at the Electron Science Research Institute (ESRI) nano-fabrication laboratories, Edith Cowan University, Australia, we have devoted research efforts to the synthesis and characterization of bismuth-containing ferrite-garnet-type thin-film magneto-optic (MO) materials of different compositions. We report on the growth and characteristics of radio frequency (RF) magnetron sputtered bismuth-substituted iron-garnet thin films. We study the process parameters associated with the RF magnetron sputter deposition technique and investigate the results of optimizing process parameters. To achieve the best MO properties, we employ a few unique techniques, such as co-sputtered nanocomposite films and all-garnet multilayer structures, as well as the application of oxygen plasma treatment to amorphous garnet layers immediately following the deposition process. We demonstrated a remarkable enhancement in the MO properties of Bi-containing ferrite-type garnet thin-film materials, including record-high MO figures of merit and improved conventional and unconventional hysteresis loops of Faraday rotation. Previously unpublished research results on the forward-looking applications of magnetic garnet coatings applied to microparticles of advanced luminescent materials are reported. In the context of developing the next-generation ultra-fast optoelectronic devices, such as light intensity switches and modulators, high-speed flat panel displays, and high-sensitivity sensors, it is important to consider the desirable optical, magnetic, and magneto-optic properties that are found in highly bismuth-substituted iron garnet thin-film materials of various composition types. Full article
(This article belongs to the Special Issue New Advances in Novel Optical Materials and Devices)
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Figure 1
<p>Schematic diagram of RF magnetron sputtering and co-sputtering techniques used for garnet and composite layers fabrication.</p>
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<p>Schematic diagram of the sequential sputtering technique used to deposit the all-garnet multilayer structures.</p>
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<p>Schematic diagram of a multistep sputtering technique used for garnet/oxide multilayer (garnet layer under protective layer) structures deposition.</p>
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<p>Schematic diagram of the flow chart of oxygen plasma treatment process applied to as-deposited garnet layers.</p>
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<p>Schematic representation of magnetic fluorescent micro/nanoparticles preparation process.</p>
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<p>Schematic diagram of the annealing crystallization process of garnet layer (<b>a</b>), measurement of optical transmission spectra to derive the film thickness and absorption coefficient (<b>b</b>), and specific Faraday rotation and hysteresis loop of Faraday rotation characterization methodologies (<b>c</b>) [<a href="#B13-coatings-12-01471" class="html-bibr">13</a>].</p>
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<p>Optimized (best achieved by our group so far) optical and MO properties observed on garnet layers prepared by different development approaches. The best obtained specific Faraday rotation of garnet films (Bi<sub>2</sub>Dy<sub>1</sub>Fe<sub>4</sub>Ga<sub>1</sub>O<sub>12</sub>), presented with the measured specific Faraday rotation data points achieved in Bi<sub>2</sub>Dy<sub>1</sub>Fe<sub>4.3</sub>Ga<sub>0.7</sub>O<sub>12</sub> garnet films and the best performing garnet-Bi<sub>2</sub>O<sub>3</sub> composite films (<b>a</b>), measured MO quality factor in terms of the figure of merit of typical Bi<sub>1.8</sub>Lu<sub>1.2</sub>Fe<sub>3.6</sub>Al<sub>1.4</sub>O<sub>12</sub> garnet layer and deposited at 250 °C and 680 °C substrate temperature and several best annealed composite Bi<sub>1.8</sub>Lu<sub>1.2</sub>Fe<sub>3.6</sub>Al<sub>1.4</sub>O<sub>12</sub>: (4.5 vol. % Bi<sub>2</sub>O<sub>3</sub> ) films (<b>b</b>), improved optical and MO properties observed in oxygen plasma treated garnet films, and the garnet layers deposited using various substrate stage rotation rates (rpm) [<a href="#B13-coatings-12-01471" class="html-bibr">13</a>,<a href="#B33-coatings-12-01471" class="html-bibr">33</a>,<a href="#B37-coatings-12-01471" class="html-bibr">37</a>,<a href="#B38-coatings-12-01471" class="html-bibr">38</a>].</p>
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<p>Measured hysteresis loop of Faraday rotation in different types of garnet-oxides composite layers and multilayer structures. The effects of excess oxide content added to the base garnet layers were observed. Measured hysteresis loops of ((Bi,Dy)<sub>3</sub>(Fe,Ga)<sub>5</sub>O<sub>12</sub>: Bi<sub>2</sub>O<sub>3</sub>) composite films having different volumetric fractions of extra Bi<sub>2</sub>O<sub>3</sub> (<b>a</b>), Bi<sub>3</sub>Fe<sub>5</sub>O<sub>12</sub>: Dy<sub>2</sub>O<sub>3</sub>) (2.7-15 Vol. %) composite thin films prepared on GGG substrates (<b>b</b>), obtained hysteresis loops from an optimally annealed all-garnet multilayer structure prepared on a GGG (111) substrate with an external magnetic field applied both in perpendicular direction (out-of-plane, green color curve) and parallel (in-plane, red color curve) with respect to the film plane of the multilayer structure (<b>c</b>), and an unconventional magnetic hysteresis loop measured in a modified all-garnet multilayer structure [<a href="#B12-coatings-12-01471" class="html-bibr">12</a>,<a href="#B31-coatings-12-01471" class="html-bibr">31</a>,<a href="#B32-coatings-12-01471" class="html-bibr">32</a>,<a href="#B34-coatings-12-01471" class="html-bibr">34</a>].</p>
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<p>Observed MCD signals from garnet layers prepared under protective layers (<b>a</b>), microstructural properties of garnet-oxide composite (<b>b</b>,<b>c</b>), XRD data, and RMS roughness properties of post-deposition oxygen plasma treated garnet layers followed by optimized annealing crystallization (<b>d</b>,<b>e</b>) [<a href="#B13-coatings-12-01471" class="html-bibr">13</a>,<a href="#B38-coatings-12-01471" class="html-bibr">38</a>].</p>
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17 pages, 16265 KiB  
Review
Magneto-Optics Effects: New Trends and Future Prospects for Technological Developments
by Conrad Rizal, Hiromasa Shimizu and Jorge Ricardo Mejía-Salazar
Magnetochemistry 2022, 8(9), 94; https://doi.org/10.3390/magnetochemistry8090094 - 24 Aug 2022
Cited by 20 | Viewed by 6529
Abstract
Magneto-optics (MO) is an effervescent research field, with a wide range of potential industrial applications including sensing, theranostics, pharmaceutics, magnetometry, and spectroscopy, among others. This review discusses the historical development, from the discovery of MO effects up to the most recent application trends. [...] Read more.
Magneto-optics (MO) is an effervescent research field, with a wide range of potential industrial applications including sensing, theranostics, pharmaceutics, magnetometry, and spectroscopy, among others. This review discusses the historical development, from the discovery of MO effects up to the most recent application trends. In addition to the consolidated fields of magnetoplasmonic sensing and modulation of optical signals, we describe novel MO materials, phenomena, and applications. We also identified the emerging field of all-dielectric magnetophotonics, which hold promise to overcome dissipation from metallic inclusions in plasmonic nanostructures. Moreover, we identified some challenges, such as the need to merge magneto-chiroptical effects with microfluidics technology, for chiral sensing and enantioseparation of drugs in the pharmaceutical industry. Other potential industrial applications are discussed in light of recent research achievements in the available literature. Full article
(This article belongs to the Special Issue Advanced Plasmonics and Magneto-Optical Technologies)
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<p>(<b>a</b>) Localized surface plasmon resonances (SPRs) and (<b>b</b>) propagating SPRs. (<b>c</b>) Magnetoplasmonics: merging of optics, magnetism and spectroscopy. Figures (<b>a</b>,<b>b</b>) were adapted from the American Institute of Physics, 2021 [<a href="#B70-magnetochemistry-08-00094" class="html-bibr">70</a>]. Copyright 2021 American Institute of Physics.</p>
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<p>(<b>a</b>) A schematic diagram of the fabricated Au/Co/Au MOSPR sensor. A quartz glass prism is mounted on top of the glass substrate, and the light is coupled with an incident angle <math display="inline"><semantics> <msub> <mi>θ</mi> <mi>inc</mi> </msub> </semantics></math>. (<b>b</b>) The reflectivity measured in air without magnetic field (left axis), and <math display="inline"><semantics> <mrow> <mi>TMOKE</mi> <mo>=</mo> <mo>Δ</mo> <mi>R</mi> <mo>/</mo> <mi>R</mi> </mrow> </semantics></math> (right axis). Time transient of (<b>c</b>) the reflected light intensity and (<b>d</b>) TMOKE upon ethanol gas injection at concentrations of 1, 2, 3, and 4%. In the inset is a photo of the MOSPR sensor chip that was mounted on a quartz prism and positioned between a pair of coils. This chip was part of the Au/Co/Au construction.</p>
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<p>Illustrative representation for the active tuning of insertion losses in a magnetoplasmonic waveguide.</p>
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<p>(<b>a</b>) A cross-sectional SEM image of the TE mode semiconductor optical isolator. (<b>b</b>) A schematic diagram of the experimental setup for measuring the characteristics of semiconductor optical isolators. (<b>c</b>) Forward and backward propagation loss as a function of the length of the semiconductor optical isolators.</p>
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<p>(<b>a</b>) Schematic of the magnetoplasmonic multilayer nanostructure for switching the extrinsic optical chirality by using the magneto-chiroptical effect. The applied magnetic field can be alternated between the <math display="inline"><semantics> <mrow> <mo>+</mo> <mi>z</mi> </mrow> </semantics></math> (H+) and <math display="inline"><semantics> <mrow> <mo>−</mo> <mi>z</mi> </mrow> </semantics></math> (H−) directions, as indicated, and the incident CPL can be RCP (<math display="inline"><semantics> <mrow> <mi>σ</mi> <mo>+</mo> </mrow> </semantics></math>) or LCP (<math display="inline"><semantics> <mrow> <mi>σ</mi> <mo>−</mo> </mrow> </semantics></math>). (<b>b</b>) Different material layer thicknesses are highlighted by using a cross-sectional TEM micrograph. (<b>c</b>) Results of magneto-chiroptical effect are comparatively shown with the extrinsic chiroptical activity (without W/O H, see the green line) through CD measurements, for an angle of incidence <math display="inline"><semantics> <mrow> <mi>θ</mi> <mo>=</mo> <msup> <mn>45</mn> <mo>∘</mo> </msup> </mrow> </semantics></math>, by using magnetic field amplitudes varying from <math display="inline"><semantics> <mrow> <mo>−</mo> <mn>3.1</mn> </mrow> </semantics></math> kOe to <math display="inline"><semantics> <mrow> <mo>+</mo> <mn>3.1</mn> </mrow> </semantics></math> kOe (applied along the <span class="html-italic">z</span> axis, as illustrated). Reprinted with permission from Qin et al., ACS Nano <b>14</b>, 2808 (2020) [<a href="#B31-magnetochemistry-08-00094" class="html-bibr">31</a>]. Copyright 2020 American Chemical Society. (<b>d</b>) Magnetoplasmonic chiral arrange of Au and Ni nanoantennas on a substrate. Green and orange arrows are used to indicate longitudinal resonances of bimetallic nanoparticles, excited with quarter-period phase delay. (<b>e</b>) Experimental results for the CDT associated to H+ and H- are comparatively shown with the case without H. Reprinted with permission from Zubritskaya et al., Nano Lett. <b>18</b>, 302–307 (2018) [<a href="#B105-magnetochemistry-08-00094" class="html-bibr">105</a>]. Copyright 2018 American Chemical Society.</p>
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<p>The real and imaginary parts of the off-diagonal permittivity component (<math display="inline"><semantics> <msub> <mi>ε</mi> <mn>2</mn> </msub> </semantics></math>) and the extinction coefficient (<span class="html-italic">k</span>) are shown as a function of the incident wavelength in (<b>a</b>,<b>b</b>), respectively, for three Ce:YIG samples on GGG substrates. Adapted with permission from ref. [<a href="#B116-magnetochemistry-08-00094" class="html-bibr">116</a>]. Copyright 2016 Springer Nature.</p>
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<p>(<b>a</b>) Schematic of the metasurface and mode excitation. (<b>b</b>) SEM picture of the fabricated microstructure. Adapted with permission from ref. [<a href="#B33-magnetochemistry-08-00094" class="html-bibr">33</a>]. Copyright 2020 Springer Nature.</p>
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<p>Real part of the electric field component <math display="inline"><semantics> <msub> <mi>E</mi> <mi>x</mi> </msub> </semantics></math> associated with the resonant electromagnetic field distributions for the (<b>a</b>,<b>c</b>) TE<math display="inline"><semantics> <msub> <mrow/> <mrow> <mn>0</mn> <mo>,</mo> <mn>1</mn> </mrow> </msub> </semantics></math> (propagating along the <span class="html-italic">y</span>-axis) and (<b>b</b>,<b>d</b>) TM<math display="inline"><semantics> <msub> <mrow/> <mrow> <mn>1</mn> <mo>,</mo> <mn>0</mn> </mrow> </msub> </semantics></math> (propagating along the <span class="html-italic">x</span>-axis) modes. Numerical results, shown inside one period of the metasurface (the cross-sections are taken at the center of the nanopillar), were calculated for a TM incident wave under normal incidence. Adapted with permission from ref. [<a href="#B33-magnetochemistry-08-00094" class="html-bibr">33</a>]. Copyright 2020 Springer Nature.</p>
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<p>The origin of magneto-optics and emerging trends. 1800–1850: Early-Stage Discovery [<a href="#B1-magnetochemistry-08-00094" class="html-bibr">1</a>,<a href="#B145-magnetochemistry-08-00094" class="html-bibr">145</a>,<a href="#B146-magnetochemistry-08-00094" class="html-bibr">146</a>]: Faraday Effect; 1850–1900: Experimental Observation of the Kerr Effect [<a href="#B147-magnetochemistry-08-00094" class="html-bibr">147</a>]; 1900–1950: Synchrotron &amp; X-ray Magneto-Optics [<a href="#B148-magnetochemistry-08-00094" class="html-bibr">148</a>]; 1950–2000: Laser, Non-linear and Ultra-fast Magneto-Optics [<a href="#B149-magnetochemistry-08-00094" class="html-bibr">149</a>]; and 2000–Present: Magnetoplasmonics [<a href="#B15-magnetochemistry-08-00094" class="html-bibr">15</a>,<a href="#B53-magnetochemistry-08-00094" class="html-bibr">53</a>,<a href="#B74-magnetochemistry-08-00094" class="html-bibr">74</a>,<a href="#B129-magnetochemistry-08-00094" class="html-bibr">129</a>,<a href="#B150-magnetochemistry-08-00094" class="html-bibr">150</a>,<a href="#B151-magnetochemistry-08-00094" class="html-bibr">151</a>], all-dielectric magnetophotonics [<a href="#B24-magnetochemistry-08-00094" class="html-bibr">24</a>,<a href="#B25-magnetochemistry-08-00094" class="html-bibr">25</a>,<a href="#B32-magnetochemistry-08-00094" class="html-bibr">32</a>,<a href="#B33-magnetochemistry-08-00094" class="html-bibr">33</a>,<a href="#B35-magnetochemistry-08-00094" class="html-bibr">35</a>,<a href="#B42-magnetochemistry-08-00094" class="html-bibr">42</a>,<a href="#B124-magnetochemistry-08-00094" class="html-bibr">124</a>], and industrial Applications [<a href="#B70-magnetochemistry-08-00094" class="html-bibr">70</a>].</p>
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<p>Potential applications of MO-SPR sensors in industry (e.g., nanostructure characterization, and label-free chemical and biological sensing) including but not limited to the following sectors: agriculture [<a href="#B154-magnetochemistry-08-00094" class="html-bibr">154</a>,<a href="#B155-magnetochemistry-08-00094" class="html-bibr">155</a>], marine [<a href="#B156-magnetochemistry-08-00094" class="html-bibr">156</a>], medical science [<a href="#B32-magnetochemistry-08-00094" class="html-bibr">32</a>,<a href="#B157-magnetochemistry-08-00094" class="html-bibr">157</a>], bio-chemistry [<a href="#B158-magnetochemistry-08-00094" class="html-bibr">158</a>], meteorology [<a href="#B159-magnetochemistry-08-00094" class="html-bibr">159</a>], nanoscopy [<a href="#B7-magnetochemistry-08-00094" class="html-bibr">7</a>,<a href="#B8-magnetochemistry-08-00094" class="html-bibr">8</a>,<a href="#B9-magnetochemistry-08-00094" class="html-bibr">9</a>,<a href="#B10-magnetochemistry-08-00094" class="html-bibr">10</a>,<a href="#B160-magnetochemistry-08-00094" class="html-bibr">160</a>], and pharmacy [<a href="#B70-magnetochemistry-08-00094" class="html-bibr">70</a>,<a href="#B106-magnetochemistry-08-00094" class="html-bibr">106</a>,<a href="#B161-magnetochemistry-08-00094" class="html-bibr">161</a>,<a href="#B162-magnetochemistry-08-00094" class="html-bibr">162</a>].</p>
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12 pages, 5046 KiB  
Article
Reversible Conversion of Odd/Even One-Way Modes in Magneto-Optical Photonic Crystal Double-Channel Waveguides
by Xinyue Yu, Suna Zhuang, Jianfeng Chen, Zhi-Yuan Li and Wenyao Liang
Nanomaterials 2022, 12(14), 2448; https://doi.org/10.3390/nano12142448 - 17 Jul 2022
Cited by 4 | Viewed by 2042
Abstract
We have studied the transmission properties of odd/even one-way modes and their reversible conversion in a double-channel waveguide consisting of two magneto-optical photonic crystals (MOPCs) sandwiched with Al2O3 PC. There exist two pairs of even and odd modes, i.e., M1(even)/M2(odd) [...] Read more.
We have studied the transmission properties of odd/even one-way modes and their reversible conversion in a double-channel waveguide consisting of two magneto-optical photonic crystals (MOPCs) sandwiched with Al2O3 PC. There exist two pairs of even and odd modes, i.e., M1(even)/M2(odd) or M3(odd)/M4(even) modes, for the double-channel waveguides with one- or two-stranded coupling layer of Al2O3 rods, respectively. Among them, the M1, M2, and M3 modes are caused by the weak coupling strength of two sub-waveguides, while the M4 mode results from the strong coupling effect and supports dispersionless slow-light propagation. Furthermore, we realize the reversible conversion between odd and even modes (i.e., between M1 and M2 modes, or M3 and M4 modes) in the one- or two-stranded structure, respectively, by adjusting the length and position of the perfect electric conductor (PEC) defect properly to cause the desired significant phase delay along the upper and lower equivalent transmission paths. Additionally, we find that the robustness of the M1 even mode is poor because of extra excitations of counter-propagation modes near the right Brillouin boundary, while the other three modes have extremely strong robustness against PEC defects and their one-way transmittances are nearly 100%. These results hold promise for many fields, such as slow-light modulation and the design of topological devices. Full article
(This article belongs to the Topic Advances and Applications of 2D Materials, 2nd Volume)
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<p>(Color online). (<b>a1</b>,<b>b1</b>) The supercells of the double-channel MOPCs A and B created by introducing a one- and two-stranded Al<sub>2</sub>O<sub>3</sub> PC coupling layer into the MOPC structures; (<b>a2</b>,<b>b2</b>) The band structures for TM polarization corresponding to structures A and B, respectively. The red, blue, green, and yellow lines present four waveguide modes supported in the double-channel MOPCs; (<b>a3,b3</b>). The eigenmodal field distributions (<span class="html-italic">E<sub>z</sub></span>) corresponding to M1, M2, M3, and M4, respectively.</p>
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<p>The green and yellow curves represent <span class="html-italic">v<sub>g</sub></span> and GVD for the M3 and M4 modes, respectively.</p>
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<p>The <span class="html-italic">E<sub>z</sub></span> field distributions for (<b>a</b>) M1 even mode, (<b>b</b>) M2 odd mode, (<b>c</b>) M4 even mode, (<b>d</b>) M3 odd mode in double-channel waveguide. The white stars represent the two point sources.</p>
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<p>The <span class="html-italic">E<sub>z</sub></span> field distributions when a PEC defect of 5<span class="html-italic">a</span> is vertically and symmetrically inserted in the double-channel waveguide for (<b>a</b>) M1 mode, (<b>b</b>) M2 mode, (<b>c</b>) M4 mode, (<b>d</b>) M3 mode. The white block inset in (<b>d</b>) is the Poynting vector distribution for the M3 mode. The size and direction of the red arrow characterize the strength and propagation direction of EM wave.</p>
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<p>The simulation results for the M2 mode: (<b>a</b>) without a PEC defect; (<b>b</b>) with a PEC defect (<math display="inline"><semantics> <mrow> <mn>5</mn> <mi>a</mi> <mo>×</mo> <mn>0.1</mn> <mi>a</mi> </mrow> </semantics></math>) vertically and symmetrically inserted in the waveguide. <span class="html-italic">x</span><sub>0</sub> = 0 is set at the position of the two point sources as denoted by the dashed purple line, while <span class="html-italic">x</span><sub>1</sub> and <span class="html-italic">x</span><sub>2</sub> denote the chosen minimum amplitude positions of the two cases.</p>
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<p>The <span class="html-italic">E<sub>z</sub></span> field distributions with a PEC defect of 6.25<span class="html-italic">a</span> vertically and asymmetrically inserted in the double-channel MOPCs waveguide for excited (<b>a</b>) M1 mode, (<b>b</b>) M2 mode, (<b>c</b>) M4 mode, (<b>d</b>) M3 mode.</p>
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<p>The <span class="html-italic">E<sub>z</sub></span> field distributions with different lengths of PEC defect asymmetrically inserted in the waveguide. (<b>a</b>,<b>c</b>) 7.5<span class="html-italic">a</span>; (<b>b</b>,<b>d</b>) 8.75<span class="html-italic">a</span>.</p>
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<p>The <span class="html-italic">E<sub>z</sub></span> field distributions with two PEC defects of 6.25<span class="html-italic">a</span> inserted into the one- and two-stranded waveguides for excited (<b>a</b>) M1 mode, (<b>b</b>) M2 mode, (<b>c</b>) M4 mode, (<b>d</b>) M3 mode.</p>
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<p>The transmission spectra for (<b>a</b>) M1 mode, (<b>b</b>) M2 mode, (<b>c</b>) M3 mode, and (<b>d</b>) M4 mode in three cases of without PEC, symmetric PEC and asymmetric PEC defect.</p>
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8 pages, 1875 KiB  
Article
Interfacial Effect on Photo-Modulated Magnetic Properties of Core/Shell-Structured NiFe/NiFe2O4 Nanoparticles
by Wenda Zhou, Mingyue Chen, He Huang, Guyue Wang, Xingfang Luo, Cailei Yuan, Jingyan Zhang, Yanfei Wu, Xinqi Zheng, Jianxin Shen, Shouguo Wang and Baogen Shen
Materials 2022, 15(4), 1347; https://doi.org/10.3390/ma15041347 - 11 Feb 2022
Cited by 1 | Viewed by 1645
Abstract
Photo-modulated magnetism has become an emerging method for technological applications, such as magneto-optical devices. In this work, by introducing oxygen during rapid thermal annealing, NiFe/NiFe2O4 core/shell nanoparticles were successfully fabricated by pulsed laser deposition. Obvious photo-modulated ferromagnetism was observed in [...] Read more.
Photo-modulated magnetism has become an emerging method for technological applications, such as magneto-optical devices. In this work, by introducing oxygen during rapid thermal annealing, NiFe/NiFe2O4 core/shell nanoparticles were successfully fabricated by pulsed laser deposition. Obvious photo-modulated ferromagnetism was observed in core/shell nanoparticles confined in Al2O3 film. Theoretical and experimental investigations indicate much more photogenerated electrons are captured at the interface of NiFe/NiFe2O4 compared with NiFe nanoparticles due to interfacial effect, resulting in the improved ferromagnetism under light irradiation. This work provides a promising strategy for optical engineering design of optical information storage, high-speed wireless communication, and magneto-optical semiconductor devices. Full article
(This article belongs to the Special Issue Recent Progress in Semiconductor Spintronics)
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<p>(<b>a</b>,<b>e</b>) lanar low magnitude TEM images, (<b>b</b>,<b>f</b>) electron diffraction patterns, (<b>c</b>,<b>g</b>) HRTEM images, (<b>d</b>,<b>h</b>) unit cell schematic diagrams of NiFe nanoparticles and NiFe/NiFe<sub>2</sub>O<sub>4</sub> core/shell nanoparticles in amorphous Al<sub>2</sub>O<sub>3</sub> matrix, respectively.</p>
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<p>XPS spectra of (<b>a</b>,<b>e</b>) Ni 2p, (<b>b</b>,<b>f</b>) Fe 2p, (<b>c</b>,<b>g</b>) Al 2p, (<b>d</b>,<b>h</b>) O 1s of NiFe nanoparticles and NiFe/NiFe<sub>2</sub>O<sub>4</sub> core/shell nanoparticles, respectively.</p>
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<p>M–T curves (<b>a</b>,<b>d</b>), M–H curves (<b>b</b>,<b>c</b>,<b>e</b>,<b>f</b>) for NiFe nanoparticles and NiFe/NiFe<sub>2</sub>O<sub>4</sub> core/shell nanoparticles with and without light, respectively. Inset of (<b>a</b>,<b>d</b>): corresponding magnified images of M-T curve at low-temperature range.</p>
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<p>(<b>a</b>) Side and (<b>b</b>) top view of calculated charge density difference at the interface of NiFe and NiFe<sub>2</sub>O<sub>4</sub>. The blue and yellow regions represent electron depletion and accumulation, respectively.</p>
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11 pages, 2514 KiB  
Article
Spectrally Selective Detection of Short Spin Waves in Magnetoplasmonic Nanostructures via the Magneto-Optical Intensity Effect
by Olga V. Borovkova, Saveliy V. Lutsenko, Mikhail A. Kozhaev, Andrey N. Kalish and Vladimir I. Belotelov
Nanomaterials 2022, 12(3), 405; https://doi.org/10.3390/nano12030405 - 26 Jan 2022
Cited by 5 | Viewed by 2529
Abstract
A method of spectrally selective detection of short spin waves (or magnons) by means of the transverse magneto-optical (MO) intensity effect in transmission in the magnetoplasmonic nanostructure is proposed. We considered the spin waves with a wavelength equal to or less than (by [...] Read more.
A method of spectrally selective detection of short spin waves (or magnons) by means of the transverse magneto-optical (MO) intensity effect in transmission in the magnetoplasmonic nanostructure is proposed. We considered the spin waves with a wavelength equal to or less than (by an integer number of times) the period of the plasmonic structure, that is, of the order of hundreds of nanometers or 1–2 μm. The method is based on the analysis of the MO effect spectrum versus the modulation of the sample magnetization (created by the spin wave) and related spatial symmetry breaking in the magnetic layer. The spatial symmetry breaking leads to the appearance of the MO effect modulation at the normal incidence of light in the spectral range of the optical states (the SPP and the waveguide modes) and the breaking of the antisymmetry of the effect with respect to the sign of the incidence angle of light. We reveal that the magnitude of the MO effect varies periodically depending on the spatial shift of the spin wave with respect to the plasmonic grating. The period of this modulation is equal to the period of the spin wave. All these facts allow for the detection of spin waves of a certain wavelength propagating in a nanostructure by measuring the MO response. Full article
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<p>The scheme of the magnetization precession and the spatial dependence of the oscillating component of the magnetization <math display="inline"><semantics> <msub> <mi>m</mi> <mi>x</mi> </msub> </semantics></math>.</p>
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<p>The scheme of the addressed magnetoplasmonic nanostructure. Gold grating is fabricated above the ferrimagnetic layer magnetized by the external magnetic field <math display="inline"><semantics> <msub> <mi mathvariant="bold">H</mi> <mn mathvariant="bold">0</mn> </msub> </semantics></math> directed along the <span class="html-italic">y</span>-axis. The spin wave also propagating along the <span class="html-italic">y</span>-axis creates a modulation of the magnetization inside the magnetic layer shown by the green line. This leads to modulation of the gyration value <math display="inline"><semantics> <msub> <mi>g</mi> <mi>x</mi> </msub> </semantics></math> along the <span class="html-italic">y</span>-axis (green curve). The nanostructure is illuminated by linearly <span class="html-italic">p</span>-polarized light (shown by the red oblique arrow) with the plane wavefront. The electric vector <math display="inline"><semantics> <mi mathvariant="bold">E</mi> </semantics></math> of the input light lies in the plane <math display="inline"><semantics> <mrow> <mi>z</mi> <mi>O</mi> <mi>y</mi> </mrow> </semantics></math>. The spatial distribution of the intensity of the optical field inside the ferrimagnetic layer related to the excitation of the SPP wave is shown by a yellow-red-black color plot. One can see that the period of the magnetization modulation is equal to double the period of the SPP wave. Parameter <math display="inline"><semantics> <mrow> <mo>Δ</mo> <mi>y</mi> </mrow> </semantics></math> is a spatial shift between the left edge of the nearest gold stripe (the start of the plasmonic grating period) and ‘zero’ of the gyration modulation. This parameter plays a role in the phase shift between the optical mode and the magnetization modulation. The parameters <math display="inline"><semantics> <msub> <mi>h</mi> <mrow> <mi>A</mi> <mi>u</mi> </mrow> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>h</mi> <mrow> <mi>B</mi> <mi>I</mi> <mi>G</mi> </mrow> </msub> </semantics></math> refer to the thickness of gold and ferrimagnetic layers, correspondingly.</p>
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<p>Angular and wavelength-resolved transmission (<b>a</b>–<b>c</b>) <math display="inline"><semantics> <msub> <mi>δ</mi> <mi>T</mi> </msub> </semantics></math> (<b>d</b>–<b>f</b>) spectra of the addressed nanostructure with the uniform spatial distribution of the magnetization in the ferrimagnetic layer (left column), magnetization modulation with <math display="inline"><semantics> <mrow> <msub> <mi>λ</mi> <mrow> <mi>S</mi> <mi>W</mi> </mrow> </msub> <mo>=</mo> <mi>P</mi> </mrow> </semantics></math> (center column), and <math display="inline"><semantics> <mrow> <mn>2</mn> <msub> <mi>λ</mi> <mrow> <mi>S</mi> <mi>W</mi> </mrow> </msub> <mo>=</mo> <mi>P</mi> </mrow> </semantics></math> (right column). The orders of the SPP modes in the left column are denoted by <span class="html-italic">m</span>. The phase shift between the plasmonic grating and the magnetization modulation is 0.</p>
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<p>The spatial distributions of the <math display="inline"><semantics> <mrow> <mrow> <mo>|</mo> </mrow> <msub> <mi>H</mi> <mi>x</mi> </msub> <msup> <mrow> <mo>|</mo> </mrow> <mn>2</mn> </msup> </mrow> </semantics></math> of the SPP wave and the magnetization modulation (green line) for two different values of phase shift between the plasmonic grating and the magnetization modulation (<b>a</b>) <math display="inline"><semantics> <mrow> <mi>ϕ</mi> <mo>=</mo> <mn>1.9</mn> </mrow> </semantics></math> rad (<math display="inline"><semantics> <mrow> <msub> <mi>δ</mi> <mi>T</mi> </msub> <mo>=</mo> <mn>0</mn> </mrow> </semantics></math>) and (<b>b</b>) <math display="inline"><semantics> <mrow> <mi>ϕ</mi> <mo>=</mo> <mn>2.7</mn> </mrow> </semantics></math> rad (<math display="inline"><semantics> <mrow> <msub> <mi>δ</mi> <mi>T</mi> </msub> <mo>=</mo> <mn>0.15</mn> </mrow> </semantics></math>). The magnon wavelength is half of the plasmonic grating period. White dashed lines denote the cross sections of the gold stripes of the plasmonic grating.</p>
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<p>The magneto-optical effect <math display="inline"><semantics> <msub> <mi>δ</mi> <mi>T</mi> </msub> </semantics></math> versus the phase shift <math display="inline"><semantics> <mi>ϕ</mi> </semantics></math> between the plasmonic grating and the spin wave for two periods of the magnetization modulation. (<b>a</b>) The magnetization modulation period is equal to the period of the plasmonic grating. (<b>b</b>) The magnetization modulation period is equal to the half of the period of the plasmonic grating. (<b>c</b>) The spectral dependence of the maximum value of <math display="inline"><semantics> <msub> <mi>δ</mi> <mi>T</mi> </msub> </semantics></math> for two different periods of magnetization modulation.</p>
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<p>Angular and wavelength-resolved transmission (<b>a</b>,<b>b</b>) and <math display="inline"><semantics> <msub> <mi>δ</mi> <mi>T</mi> </msub> </semantics></math> (<b>c</b>,<b>d</b>) spectra of the nanostructure near the waveguide modes excitation area with (right column) and without (left column) the spatial modulation of the magnetization in the ferrimagnetic layer. The phase shift between the plasmonic grating and the magnetization modulation is 0.</p>
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10 pages, 33527 KiB  
Article
Silicon-Based All-Dielectric Metasurface on an Iron Garnet Film for Efficient Magneto-Optical Light Modulation in Near IR Range
by Denis M. Krichevsky, Shuang Xia, Mikhail P. Mandrik, Daria O. Ignatyeva, Lei Bi and Vladimir I. Belotelov
Nanomaterials 2021, 11(11), 2926; https://doi.org/10.3390/nano11112926 - 1 Nov 2021
Cited by 9 | Viewed by 2704
Abstract
All-dielectric nanostructures provide a unique low-loss platform for efficiently increasing light-matter interaction via excitation of the localized or propagating optical modes. Here, we report on the transverse magneto-optical Kerr effect enhancement in an all-dielectric metasurface based on a two-dimensional array of Si nanodisks [...] Read more.
All-dielectric nanostructures provide a unique low-loss platform for efficiently increasing light-matter interaction via excitation of the localized or propagating optical modes. Here, we report on the transverse magneto-optical Kerr effect enhancement in an all-dielectric metasurface based on a two-dimensional array of Si nanodisks on a cerium substituted dysprosium iron garnet thin film. We observed up to 15% light intensity modulation under TM modes excitation. The observed magneto-optical effect is nearly independent of the rotation of the light incidence plane with respect to the metasurface. Being compatible with conventional semiconductor technology, our structure holds promise for device applications, such as light modulators, magnetic and chemical sensors. Full article
(This article belongs to the Special Issue Nanophotonic and Optical Nanomaterials)
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<p>Schematic representation of the magneto-optical metasurface of Si nanodisk array on a Ce:DyIG (<b>a</b>) and SEM image of the sample (<b>b</b>).</p>
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<p>Angle resolved transmission spectra of the sample under p-polarized light excitation. (<b>a</b>) Experimental, (<b>b</b>) numerical, (<b>c</b>) calculated modes dispersion.</p>
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<p>Electromagnetic field distribution of the TM0<sub>(±1, 0)</sub> (<b>a</b>,<b>c</b>) and TE0<sub>(0, ±1)</sub> (<b>b</b>,<b>d</b>) modes.</p>
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<p>Experimental TMOKE spectra as a function of <span class="html-italic">θ</span> (<b>a</b>) and for a fixed polar incident angle <span class="html-italic">θ</span> = 10° as a function of the azimuth incident angle <span class="html-italic">φ</span> (<b>b</b>). All curves in (<b>b</b>) have offsets to clarify the representation.</p>
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<p>Dielectric permittivity (<b>a</b>) and gyration (<b>b</b>) of Ce:DyIG.</p>
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<p>Electromagnetic field distribution of the TM1<sub>(±1, 0)</sub> (<b>a</b>,<b>c</b>) and TE1<sub>(0, ±1)</sub> (<b>b</b>,<b>d</b>) modes.</p>
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<p>Numerically simulated TMOKE spectra as a function of θ (<b>a</b>) and for fixed θ = 10° as a function of the sample rotation angle φ (<b>b</b>). All curves in (<b>b</b>) have offsets to clarify representation.</p>
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<p>Schematic of TMOKE setup used in the experiment.</p>
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13 pages, 5229 KiB  
Article
MagnetoPlasmonic Waves/HOMO-LUMO Free π-Electron Transitions Coupling in Organic Macrocycles and Their Effect in Sensing Applications
by Maria Grazia Manera, Gabriele Giancane, Simona Bettini, Ludovico Valli, Victor Borovkov, Adriano Colombelli, Daniela Lospinoso and Roberto Rella
Chemosensors 2021, 9(10), 272; https://doi.org/10.3390/chemosensors9100272 - 22 Sep 2021
Cited by 1 | Viewed by 2244
Abstract
Optical and magneto-optical surface plasmon resonance (MOSPR) characterization and preliminary sensing test onto single- and multi-layers of two organic macrocycles have been performed; TbPc2(OC11H21)8 phthalocyanine and CoCoPo2 porphyrin were deposited by the Langmuir-Schäfer (LS) technique [...] Read more.
Optical and magneto-optical surface plasmon resonance (MOSPR) characterization and preliminary sensing test onto single- and multi-layers of two organic macrocycles have been performed; TbPc2(OC11H21)8 phthalocyanine and CoCoPo2 porphyrin were deposited by the Langmuir-Schäfer (LS) technique onto proper Au/Co/Au magneto-optical transducers. Investigations of the MOSPR properties in Kretschmann configuration by angular modulation, gives us an indication about the potential discrimination of two organic macrocycles with absorption electronic transition in and out of the propagating plasmon energy spectral range. An improved molecular vapors sensitivity increase by the MOSPR sensing probe can be demonstrated depending on the overlap between the plasmonic probe energy and the absorption electronic transitions of the macrocycles under investigation. If the interaction between the plasmon energy and molecular HOMO-LUMO transition is preserved, a variation in the complex refractive index takes place. Under this condition, the magneto-plasmonic effect reported as 1/|MOSPR| signal allows us to increase the detection of molecules deposited onto the plasmonic transducer and their gas sensing capacity. The detection mechanism appears strongly enhanced if the Plasmon Wave/HOMO-LUMO transitions energy are in resonance. Under coupling conditions, a different volatile organic compounds (VOC) sensing capability has been demonstrated using n-butylamine as the trial molecule. Full article
(This article belongs to the Section Materials for Chemical Sensing)
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Figure 1

Figure 1
<p>Molecular structures of (<b>a</b>) TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> terbium phthalocyanine derivative and (<b>b</b>) bis porphyrin derivative CoCoPo<sub>2</sub> used as active molecules.</p>
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<p>Π-area per molecule isotherm curves for the floating film of TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> (panel <b>a</b>) and CoCoPo<sub>2</sub> (panel <b>b</b>).</p>
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<p>BAM images of TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> recorded at different surface pressure values, 4 mN·m<sup>−1</sup> (box <b>a</b>), 7.5, 18 and 29 mN·m<sup>−1</sup> (boxes <b>b</b>–<b>d</b>). Width of images is 430 μm.</p>
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<p>BAM images of CoCoPo2 recorded at different surface pressure values, 5 mN·m<sup>−1</sup> (box <b>a</b>), 12, 26 and 34 mN·m<sup>−1</sup> (boxes <b>b</b>–<b>d</b>). Width of images is 430 μm.</p>
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<p>(<b>a</b>) AFM image of the CoCoPo<sub>2</sub> and (<b>b</b>) TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> L-S layers deposited onto MOSPR transducers.</p>
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<p>UV-VIS electronic absorption spectra of the TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> macrocycle as floating film, in chloroform solution and in L-S thin film form deposited onto silica glass substrate.</p>
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<p>UV-VIS electronic absorption spectra of the CoCoPo<sub>2</sub> macrocycle as floating film, in chloroform solution and in L-S thin film form deposited onto silica glass substrate.</p>
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<p>UV-VIS electronic absorption spectra comparison of TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> and CoCoPo<sub>2</sub> monolayer deposited onto silica glass substrate. The position of the transducers surface plasmon resonance energy coupling with electronic transition of the TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> is evidenced.</p>
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<p>(<b>a</b>,<b>b</b>) Experimental reflectivity curves (SPR) vs. angle of incidence of TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> and CoCoPo<sub>2</sub> macrocycles. (<b>c</b>) Magneto-plasmonic curves (TMOKE signal) of Au/Co/Au transducers covered by 5 monolayers (5ML) of TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> and CoCoPo<sub>2</sub>, respectivley.</p>
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<p>(<b>a</b>) 1/|TMOKE| signal vs. incidence angle of the Au/Co/Au transducer alone compared with the same signals acquired in the presence of a single monolayer of CoCoPo<sub>2</sub> and TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> macrocycles. The coloured circles represent the investigating laser size (&lt;0.5 mm). (<b>b</b>) 1/|TMOKE| signals vs. incidence angle in Kretschmann configuration for CoCoPo<sub>2</sub> and TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> monolayers interacting with butylamine vapours, respectively.</p>
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<p>(<b>a</b>) 1/|TMOKE| signal vs. incidence angle of the Au/Co/Au transducer alone compared with the same signals acquired in the presence of a single monolayer of CoCoPo<sub>2</sub> and TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> macrocycles. The coloured circles represent the investigating laser size (&lt;0.5 mm). (<b>b</b>) 1/|TMOKE| signals vs. incidence angle in Kretschmann configuration for CoCoPo<sub>2</sub> and TbPc<sub>2</sub>(OC<sub>11</sub>H<sub>21</sub>)<sub>8</sub> monolayers interacting with butylamine vapours, respectively.</p>
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