Air pollution is influenced by a combination of pollutant emissions and meteorological conditions. Anthropogenic emissions and meteorological conditions are the two main causes of atmospheric pollution, and the contribution of meteorology and emissions to the reduction of PM
2.5 concentrations across the country has not yet been comprehensively examined. This study used the Kolmogorov–Zurbenko (KZ) filter and random forest (RF) model to decompose and reconstruct PM
2.5 time series in five major urban agglomerations in China, analyzing the impact of meteorological factors on PM
2.5 concentrations. From 2015 to 2021, PM
2.5 concentrations significantly decreased in all urban agglomerations, with annual averages dropping by approximately 50% in Beijing–Tianjin–Hebei (BTH), Yangtze River Delta (YRD), Pearl River Delta (PRD), Central Plain (CP), and Chengdu–Chongqing (CC). This reduction was due to both favorable meteorological conditions and emission reductions. The KZ filter effectively separated the PM
2.5 time series, and the RF model achieved high squared correlation coefficient (
R2) values between predicted and observed values, ranging from 0.94 to 0.98. Initially, meteorological factors had a positive contribution to PM
2.5 reduction, indicating unfavorable conditions, but this gradually turned negative, indicating favorable conditions. By 2021, the rates of meteorological contribution to PM
2.5 reduction in BTH, YRD, PRD, CP, and CC changed from 14.3%, 16.9%, 7.2%, 12.2%, and 11.5% to −36.5%, −31.5%, −26.9%, −30.3%, and −23.5%, respectively. Temperature and atmospheric pressure had the most significant effects on PM
2.5 concentrations. The significant decline in PM
2.5 concentrations in BTH and CP after 2017 indicated that emission control measures were gradually taking effect. This study confirms that effective pollution control measures combined with favorable meteorological conditions jointly contributed to the improvement in air quality.
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