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WO2024177066A1 - Plasma processing device - Google Patents

Plasma processing device Download PDF

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Publication number
WO2024177066A1
WO2024177066A1 PCT/JP2024/006032 JP2024006032W WO2024177066A1 WO 2024177066 A1 WO2024177066 A1 WO 2024177066A1 JP 2024006032 W JP2024006032 W JP 2024006032W WO 2024177066 A1 WO2024177066 A1 WO 2024177066A1
Authority
WO
WIPO (PCT)
Prior art keywords
slit
antenna
mask
mask member
longitudinal direction
Prior art date
Application number
PCT/JP2024/006032
Other languages
French (fr)
Japanese (ja)
Inventor
大輔 松尾
靖典 安東
Original Assignee
日新電機株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日新電機株式会社 filed Critical 日新電機株式会社
Publication of WO2024177066A1 publication Critical patent/WO2024177066A1/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/50Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
    • C23C16/505Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using radio frequency discharges
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/46Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy

Definitions

  • the present invention relates to a plasma processing device that uses plasma to process a workpiece.
  • Patent Document 1 discloses such a plasma processing apparatus in which an antenna is placed outside a vacuum vessel, and a high-frequency magnetic field generated from the antenna is transmitted into the vacuum vessel through a magnetic field transmission window that is provided to cover an opening in the side wall of the vacuum vessel, thereby generating plasma within the vacuum vessel.
  • the plasma processing apparatus of Patent Document 1 includes a metal slit plate that covers the opening of the vacuum vessel, and a dielectric plate that covers the slits formed in the slit plate from the outside of the vacuum vessel.
  • the metal slit plate and the dielectric plate superimposed on the slit plate function as a magnetic field transmission window, so the thickness of the magnetic field transmission window can be made smaller than when only the dielectric plate functions as the magnetic field transmission window. This makes it possible to shorten the distance from the antenna to the inside of the vacuum vessel, and to efficiently supply the high-frequency magnetic field generated by the antenna into the vacuum vessel.
  • the thickness of the mask plate is as thin as possible so as not to reduce the transmittance of the high-frequency magnetic field generated by the antenna.
  • the mask plate described above is a single flat plate, making it thinner will cause the mask plate to warp and become deformed.
  • the mask plate is heated by the heat of the generated plasma or by radiation from the workpiece by the plasma, so to prevent the mask plate from deforming due to heating, it is desirable for the mask plate to be made of a heavy metal such as Mo or W, which has a small thermal expansion coefficient.
  • the mask plate in addition to the beam-shaped regions that cover the slits formed in the slit plate, the mask plate also has slits between the beam-shaped regions that allow a magnetic field to pass through. Since Mo or W is difficult to cut, it is difficult to cut the mask plate to form slits, and cutting the mask plate in this way is also costly.
  • the present invention was made to solve all of these problems at once, and its main objective is to reduce the thickness of the mask member that covers the slits formed in the slit plate and to use a material with a low thermal expansion coefficient for the mask member in a plasma processing apparatus in which an antenna is placed outside the vacuum vessel and a magnetic field transmission window is formed by overlapping a dielectric plate and a slit plate.
  • the plasma processing apparatus is a plasma processing apparatus that generates plasma within a vacuum vessel by passing a high-frequency current through an antenna provided outside the vacuum vessel, and is characterized by comprising a slit plate that covers an opening formed in the vacuum vessel at a position facing the antenna, a dielectric plate that covers multiple slit openings formed in the slit plate from the outside of the vacuum vessel, multiple mask members that are provided for each of the slit openings and cover the slit openings from the inside of the vacuum vessel with gaps, and a fixing mechanism that fixes the multiple mask members in correspondence with each of the slit openings.
  • each mask member is provided for each slit opening, the size of each mask member is smaller than that of a mask plate in which the slit plate is covered with a single flat plate. Therefore, the mask member is less likely to warp during processing, and the thickness of the mask member can be made thinner. As a result, it is possible to suppress a decrease in the transmittance of the high-frequency magnetic field generated by the antenna.
  • heavy metals such as Mo or W, which have a small thermal expansion coefficient, can be used as the material for the mask member, and deformation of the mask member due to heating can be suppressed.
  • the slit opening is rectangular in shape with its longitudinal direction intersecting the antenna
  • the mask member is elongated and extends from one end of the slit opening to the other end in the longitudinal direction
  • the fixing mechanism includes a pressing member that presses the mask member against the slit plate, and a fitting portion formed on the pressing member or the slit plate and that fits into the longitudinal end of the mask member.
  • a plurality of the mask members are provided for each of the slit openings, and the plurality of mask members provided for each of the slit openings are provided with gaps between each other to cover the slit openings.
  • the mask members are provided in multiple numbers for each slit opening along the longitudinal direction of the antenna, and are elongated with different longitudinal lengths. In the thickness direction of the slit plate, the mask members longer in the longitudinal direction are arranged toward the inside of the vacuum vessel.
  • the fitting portion is provided along the longitudinal direction of the antenna and further includes a plurality of recesses that fit into the respective ends of the mask members, and is arranged so as to sandwich the end of the mask member that is longer in the longitudinal direction between a communicating wall formed by communicating adjacent portions of the plurality of recesses and an opposing wall provided opposite the communicating wall.
  • each mask member is fixed in the longitudinal direction of the antenna by the communicating wall and the opposing wall, so that it is possible to prevent each mask member from shifting in the longitudinal direction of the antenna.
  • the mask member longer in the longitudinal direction is attached to the slit plate, it is possible to prevent the mask member from falling off the slit plate.
  • the multiple mask members provided for each slit opening are provided without gaps when viewed from inside the vacuum vessel, and therefore the multiple mask members provided for each slit opening cover the dielectric plate without gaps when viewed from inside the vacuum vessel, preventing conductive flying objects and the like from adhering to and contaminating the dielectric plate.
  • the plasma processing apparatus may have a shielding wall disposed in the gap between the slit plate and the mask member for blocking charged particles moving along the longitudinal direction of the antenna.
  • the thickness of the mask member covering the slits formed in the slit plate can be reduced, and a material with a low thermal expansion coefficient can be used for the mask member.
  • FIG. 4 is a perspective view of the configuration near the magnetic field transmission window in the embodiment, as viewed from inside the vacuum vessel.
  • FIG. 4 is an exploded perspective view showing a configuration near a magnetic field transmission window in the embodiment.
  • FIG. 4 is a plan view of the configuration near the magnetic field transmission window in the embodiment, as viewed from inside the vacuum vessel.
  • 5A is a cross-sectional view taken along line AA in FIG. 4, and
  • FIG. 5B is a partially enlarged view of part B in the cross-sectional view taken along line AA.
  • 5 is a cross-sectional view taken along line BB in FIG. 4 .
  • FIG. 11 is a plan view of a configuration in the vicinity of a magnetic field transmission window in another embodiment, as viewed from inside the vacuum vessel.
  • 8A is a cross-sectional view taken along line AA in FIG. 7
  • FIG. 8B is a partially enlarged view of part B in the cross-sectional view taken along line AA.
  • FIG. 11 is a plan view of a configuration in the vicinity of a magnetic field transmission window in another embodiment, as viewed from inside the vacuum vessel.
  • 11A is a cross-sectional view taken along line AA in FIG. 10
  • FIG. 11B is a partially enlarged perspective view of part B in FIG. 10 when the pressing member is removed.
  • FIG. 11 is a cross-sectional view showing a configuration in the vicinity of a magnetic field transmission window when cutting between the antenna and the fixing mechanism along the longitudinal direction of the antenna in another embodiment.
  • the plasma processing apparatus 100 of this embodiment processes a substrate O by using an inductively coupled plasma P.
  • the substrate O is, for example, a substrate for a flat panel display (FPD) such as a liquid crystal display or an organic electroluminescence display, a flexible substrate for a flexible display, etc.
  • the processing performed on the substrate O is, for example, film formation by a plasma CVD method, etching, ashing, sputtering, etc.
  • the plasma processing apparatus 100 is also called a plasma CVD apparatus when film formation is performed by plasma CVD, a plasma etching apparatus when etching is performed, a plasma ashing apparatus when ashing is performed, and a plasma sputtering apparatus when sputtering is performed.
  • the plasma processing apparatus 100 comprises a vacuum vessel 1 which is evacuated and into which a gas is introduced, an antenna 2 provided outside the vacuum vessel 1, and a high frequency power supply 3 which applies a high frequency to the antenna 2.
  • a high frequency current IR flows through the antenna 2, generating an induced electric field within the vacuum vessel 1 and generating an inductively coupled plasma P.
  • the vacuum vessel 1 is, for example, a metal vessel, and an opening 1x is formed in its wall (here, the upper wall 1a) that penetrates in the thickness direction.
  • the vacuum vessel 1 is electrically grounded here, and its interior is evacuated to a vacuum by a vacuum exhaust device 4.
  • Gas is introduced into the vacuum vessel 1 via, for example, a flow rate regulator (not shown) or one or more gas inlets 11 provided in the vacuum vessel 1.
  • the gas may be selected according to the processing contents to be performed on the substrate O.
  • the gas is a raw material gas or a gas obtained by diluting the raw material gas with a dilution gas (for example, H 2 ).
  • a Si film can be formed on the substrate, when the raw material gas is SiH 4 +NH 3 , a SiN film can be formed, when the raw material gas is SiH 4 +O 2 , a SiO 2 film can be formed, and when the raw material gas is SiF 4 +N 2 , a SiN:F film (fluorinated silicon nitride film) can be formed.
  • a bias voltage may be applied to the substrate holder 5 from a bias power supply 12.
  • the bias voltage may be, for example, a negative DC voltage, a negative bias voltage, etc., but is not limited to these.
  • a heater 51 for heating the substrate O may be provided inside the substrate holder 5.
  • the antenna 2 is arranged to face the opening 1x formed in the vacuum vessel 1. Note that the number of antennas 2 is not limited to one, and multiple antennas 2 may be provided.
  • the high-frequency power supply 3 can pass a high-frequency current IR through the antenna 2 via a matching circuit 31.
  • the frequency of the high-frequency current is, for example, a typical 13.56 MHz, but is not limited to this and may be changed as appropriate.
  • This plasma processing apparatus 100 further includes a slit plate 6 that blocks the openings 1x formed in the wall (upper wall 1a) of the vacuum vessel 1 from outside the vacuum vessel 1, a dielectric plate 7 that blocks the slit openings 6x formed in the slit plate 6 from outside the vacuum vessel 1, a plurality of mask members 8 that are provided for each slit opening 6x and cover each slit opening 6x from inside the vacuum vessel 1 with a gap G therebetween, and a fixing mechanism 9 that fixes the plurality of mask members 8 corresponding to each slit opening.
  • the slit plate 6 allows the high-frequency magnetic field generated by the antenna 2 to pass through the vacuum vessel 1, and prevents the electric field from entering the vacuum vessel 1 from the outside.
  • the slit plate 6 is flat, and multiple slit openings 6x are formed through it in the thickness direction.
  • the slit openings 6x are rectangular with their longitudinal direction intersecting the antenna 2.
  • the slit plate 6 preferably has a higher mechanical strength than the dielectric plate 7 described later, and preferably has a larger thickness dimension than the dielectric plate 7.
  • the multiple slit openings 6x are formed parallel to each other when viewed from the thickness direction, and intersect with the antenna 2 (specifically, perpendicular to each other).
  • a beam-shaped region 6z is formed parallel to each slit opening 6x.
  • the multiple slit openings 6x all have the same shape (specifically, rectangular in plan view), and the length (width) along the longitudinal direction of the antenna 2 is, for example, 5 mm to 30 mm, but is not limited thereto.
  • the slit plate 6 is manufactured by rolling (e.g., cold rolling or hot rolling) a metal material such as one metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.), and has a thickness of, for example, about 5 mm.
  • a metal material such as one metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.)
  • the manufacturing method and thickness are not limited to this and may be changed as appropriate depending on the specifications.
  • the slit plate 6 is larger than the opening 1x of the vacuum vessel in a plan view, and is supported by the upper wall 1a to close the opening 1x.
  • a sealing member S (see FIG. 1), such as an O-ring or gasket, is interposed between the slit plate 6 and the upper wall 1a, creating a vacuum seal between them.
  • the dielectric plate 7 is provided on the outward surface 61 of the slit plate 6 that faces the outside of the vacuum vessel 1 (the reverse side of the inward surface that faces the inside of the vacuum vessel 1) and covers the slit opening 6x of the slit plate 6.
  • the dielectric plate 7 is a flat plate made entirely of a dielectric material, and is made of, for example, ceramics such as alumina, silicon carbide, silicon nitride, etc., inorganic materials such as quartz glass and non-alkali glass, and resin materials such as fluororesin (e.g. Teflon). From the viewpoint of reducing dielectric loss, the material making up the dielectric plate 7 preferably has a dielectric tangent of 0.01 or less, and more preferably 0.005 or less.
  • the thickness of the dielectric plate 7 is made smaller than the thickness of the slit plate 6, but this is not limiting.
  • the thickness needs to be strong enough to withstand the pressure difference between the inside and outside of the vacuum vessel 1 received through the slit openings 6x, and may be set appropriately according to the specifications such as the number and length of the slit openings 6x.
  • a thinner thickness is preferable.
  • the slit plate 6 and the dielectric plate 7 function as a magnetic field transmission window W that allows the magnetic field generated by the antenna 2 to pass through.
  • the high frequency magnetic field generated by the antenna 2 passes through the magnetic field transmission window W consisting of the slit plate 6 and the dielectric plate 7 and is formed (supplied) inside the vacuum vessel 1.
  • an induced electric field is generated in the space inside the vacuum vessel 1, and an inductively coupled plasma P is generated.
  • the mask member 8 is provided on the inward surface 62 of the slit plate 6 that faces the inside of the vacuum vessel 1, and covers the slit opening 6x of the slit plate 6.
  • the mask member 8 is elongated and extends from one end 6x1 to the other end 6x2 in the longitudinal direction of the slit opening 6x, and in this embodiment, the mask member 8 is a rectangular flat plate having a longitudinal direction intersecting the antenna 2. More specifically, the longitudinal length of the mask member 8 is longer than the longitudinal length of the slit opening 6x, and the length (width) of the mask member 8 along the longitudinal direction of the antenna 2 is approximately the same as the width of the slit opening 6x along the longitudinal direction of the antenna 2.
  • the mask member 8 is disposed parallel to the slit opening 6x when viewed from the thickness direction of the slit plate 6, and covers substantially the entire slit opening 6x.
  • the mask member 8 may be formed so as to cover only a portion of the slit opening 6x. From the viewpoint of improving the transmittance of the magnetic field, the narrower the width of the mask member 8, the more preferable it is, e.g., 10 mm or less, and more preferably 5 mm or less.
  • each mask member 8 is arranged parallel to each other when viewed from the longitudinal direction of the antenna 2.
  • each mask member 8 is arranged so as to intersect with the antenna 2 (specifically, so as to be perpendicular to it), and each has the same flat plate shape.
  • each mask member 8 is arranged parallel to each slit opening 6x when viewed from the thickness direction of the slit plate 6, and each mask member 8 covers almost the entirety of each slit opening 6x.
  • the mask member 8 is made of a metal material such as a heavy metal with a small thermal expansion coefficient, such as Mo or W, or an alloy of these.
  • the thickness of the mask member 8 is preferably smaller than the thickness of the slit plate 6, for example, about 5 mm or less.
  • the thickness of the mask member 8 is not limited to this and may be changed as appropriate depending on the specifications.
  • the fixing mechanism 9 positions and fixes each mask member 8 so that each mask member 8 covers each slit opening 6x.
  • the fixing mechanism 9 is formed on the slit plate 6 and includes a fitting portion 91 that fits with the longitudinal end of the mask member 8, and a pressing member 92 that presses the mask member 8 against the slit plate 6.
  • the fitting portion 91 is formed on the inward surface 62 of the slit plate 6 and is provided to correspond to both ends 6x1, 6x2 of the slit opening 6x.
  • the fitting portion 91 is formed as a recess forming a part of a rectangular parallelepiped, and the recess forming the fitting portion 91 has a longitudinal direction along the longitudinal direction of the antenna 2.
  • the longitudinal length of the fitting portion 91 is approximately the same as the length (width) of the mask member 8 along the longitudinal direction of the antenna 2.
  • one side forming the longitudinal direction of the recess approximately coincides with the inner side of the vacuum vessel 1 at both ends 6x1, 6x2 of the slit opening 6x.
  • the multiple fitting portions 91 are provided along the longitudinal direction of the antenna 2 and are provided parallel to each other and spaced apart by the length (width) of the beam-shaped region 6z along the longitudinal direction of the antenna 2.
  • the fitting portion 91 is formed with a mounting surface 91a on which the mask member 8 is placed.
  • the mounting surface 91a is provided inside the vacuum vessel 1 relative to the inward surface 62, and each mask member 8 covers each slit opening 6x from the inside of the vacuum vessel 1 with a gap G. This reduces the induced current generated in the mask member 8 and the slit plate along the antenna 2, and efficiently suppresses the decrease in the transmittance of the high frequency magnetic field.
  • the dimension of the gap G between the outward surface of the mask member 8 and the inward surface 62 of the slit plate 6 is preferably set to a value of 5 mm or less.
  • the fitting portion 91 is made of the same material as the slit plate 6, and is manufactured by rolling (e.g., cold rolling or hot rolling) a metal material such as a metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.).
  • a metal material such as a metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.).
  • the fitting portion 91 does not have to be made of the same material as the slit plate 6.
  • the pressing member 92 is elongated along the longitudinal direction of the antenna 2, and fits into the fitting portion 91 when the mask member 8 is pressed.
  • the pressing member 92 has a plurality of convex portions 921 formed along the longitudinal direction of the pressing member 92, which fit into the concave portions constituting the fitting portion 91, and are arranged parallel to each other and spaced apart by the length (width) of the beam-shaped region 6z along the longitudinal direction of the antenna 2.
  • the convex portions 921 are rectangular parallelepiped extending along the longitudinal direction of the antenna 2, and the length of the convex portions 921 along the longitudinal direction of the antenna 2 and the length in the direction intersecting the antenna 2 are approximately the same as the longitudinal and lateral lengths of the concave portions of the fitting portion 91, respectively.
  • a flow path 6c through which a cooling medium such as water flows is formed (or provided) in the slit plate 6.
  • This flow path 6c is formed along the longitudinal direction of the antenna 2 near the fixing mechanism 9.
  • the flow path 6c is formed so as to be located directly above the fixing mechanism 9 along the thickness direction of the slit plate 6.
  • ⁇ Effects of this embodiment> According to the plasma processing apparatus 100 of the present embodiment configured as described above, since a mask member 8 is provided for each of the slit openings 6x, the size of each mask member 8 is smaller than that of a mask plate in which the slit plate 6 is covered with a single flat plate. Therefore, the mask member 8 is less likely to warp, and the mask member 8 can be processed to have a thin thickness. As a result, it is possible to suppress a decrease in the transmittance of the high frequency magnetic field generated from the antenna 2.
  • each mask member 8 is provided for each slit opening 6x and there is no need to cut the mask members 8 to form slits, heavy metals such as Mo or W, which have a small thermal expansion coefficient, can be used as the material for the mask members 8, and deformation of the mask members 8 due to heating can be suppressed.
  • the mask member 8 is positioned by the fitting portion 91, so that the mask member 8 can be prevented from shifting when the pressing member 92 is pressing the mask member 8.
  • the mask member 8 since the mask member 8 is provided along the longitudinal direction of the slit opening 6x, the mask member 8 can be fixed in correspondence with the slit opening 6x, and conductive flying objects and the like can be prevented from adhering to and contaminating the dielectric plate.
  • the shape of the mask member 8 is a rectangular flat plate, but the shape of the mask member 8 may be other elongated shapes, such as a column shape.
  • the fitting portion 91 is formed on the slit plate 6, but the fitting portion 91 may also be formed on the pressing member 92.
  • a plurality of mask members 8 may be provided for each slit opening 6x, and the mask members 8 provided for each slit opening 6x may be offset from each other to cover the slit opening 6x.
  • the fixing mechanism 9 allows each mask member 8 to be offset from each other along the longitudinal direction of the antenna 2, and also to be provided with a gap G' between each mask member when viewed from the thickness direction of the slit plate 6.
  • each mask member 8 may or may not overlap each other when viewed from the longitudinal direction of the antenna 2 or the thickness direction of the slit plate 6.
  • the size of the gap G' between each mask member 8 is not particularly limited.
  • the number of mask members 8 provided for each slit opening 6x may be three or more.
  • each mask member 8 along the longitudinal direction of the antenna 2 is smaller than when the slit opening 6x is covered with one mask member 8, so the induced current generated in each mask member 8 can be reduced and the decrease in the transmittance of the high frequency magnetic field can be further suppressed.
  • the multiple mask members 8 are provided with a gap G' between them, it is possible to suppress unevenness in plasma density that can occur along the antenna 2 due to the multiple mask members 8 coming into contact with each other.
  • a plurality of mask members 8 are provided for each slit opening 6x along the longitudinal direction of the antenna 2, and are elongated with different longitudinal lengths, and the mask members 8' that are longer in the longitudinal direction may be arranged toward the inside of the vacuum vessel 1 in the thickness direction of the slit plate 6.
  • the fitting portion 91 may be provided along the longitudinal direction of the antenna 2, and further include a plurality of recesses that fit into the ends of each mask member 8, and may be provided so as to sandwich the end of the mask member 8' that is longer in the longitudinal direction between a communication wall w1 formed by communication between adjacent parts of the plurality of recesses and an opposing wall w2 provided opposite the communication wall w1.
  • the fitting portion 91 includes a first recess 911 that fits with the mask member 8 that is shorter in the longitudinal direction, and a second recess 912 that fits with the mask member 8' that is longer in the longitudinal direction.
  • the first recess 911 is provided closer to the ends 6x1 and 6x2 of the slit opening 6x than the second recess 912, and the mounting surface of the first recess 911 on which the mask member 8 is placed is formed between the inward surface 62 of the slit plate 6 and the mounting surface of the second recess 912 on which the mask member 8' is placed, as viewed from the thickness direction of the slit plate 6.
  • first recess 911 and the second recess 912 are provided adjacent to each other to form a communicating wall w1
  • the second recess 912 has an opposing wall w2 that faces the communicating wall w1.
  • the communicating wall w1 and the opposing wall w2 are provided parallel to each other and spaced apart by approximately the same distance as the short-side length of the mask member 8'.
  • each mask member 8 when each mask member 8 is attached to the slit plate 6, since each mask member 8, 8' is fixed by the communicating wall w1 and the opposing wall w2, it is possible to prevent each mask member 8, 8' from shifting in the longitudinal direction of the antenna 2. In particular, when the mask member 8' which is longer in the longitudinal direction is attached to the slit plate 6, it is possible to prevent the mask member 8' from falling off the slit plate 6. Furthermore, since adjacent portions of the first recess 911 and the second recess 912 are connected to each other, the mask members 8, 8' provided for each slit opening 6x are provided without any gaps when viewed from inside the vacuum vessel 1. Therefore, the mask members 8, 8' provided for each slit opening 6x cover the dielectric plate 7 without any gaps when viewed from inside the vacuum vessel 1, so that it is possible to prevent conductive flying objects and the like from adhering to and contaminating the dielectric plate 7.
  • a shielding wall SW for shielding charged particles moving along the longitudinal direction of the antenna 2 may be provided in the gap G between the slit plate 6 and the mask member 8.
  • This shielding wall SW may have a wall surface formed to intersect (specifically, perpendicular to) the longitudinal direction of the antenna 2.
  • the shielding wall SW may be formed to shield all or part of the gap G.
  • a plurality of shielding walls SW may be provided along the longitudinal direction of the antenna 2.
  • the plurality of shielding walls SW are preferably parallel to each other and provided at a constant interval (pitch) along the longitudinal direction of the antenna 2.
  • the interval (pitch) between the plurality of shielding walls SW along the longitudinal direction of the antenna 2 may be equal to or different from the interval between the slit openings 6x of the slit plate 6.
  • a protrusion 6p that protrudes into the gap G toward the outward surface 81 of the mask member 8 may be formed on the inward surface of the beam-shaped region 6z of the slit plate 6, and this protrusion 6p may form the shielding wall SW.
  • a protrusion that protrudes into the gap G toward the inward surface 62 of the slit plate 6 may be formed on the outward surface 81 of the mask member 8, and this protrusion may form the shielding wall SW.
  • the thickness of the mask member covering the slits formed in the slit plate can be reduced, and a material with a low thermal expansion coefficient can be used for the mask member.
  • REFERENCE SIGNS LIST 100 Plasma processing apparatus O: Substrate P: Inductively coupled plasma 2: Antenna 3: High frequency power supply 6: Slit plate 6x: Slit opening 7: Dielectric plate 8: Mask member 9: Fixing mechanism 91: Fitting portion 92: Pressing member W: Magnetic field transmission window S: Seal member

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
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  • Materials Engineering (AREA)
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  • Organic Chemistry (AREA)
  • Plasma Technology (AREA)
  • Drying Of Semiconductors (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

A plasma processing device (100) for generating plasma in a vacuum container (1) by applying a high-frequency current to an antenna (2) provided outside the vacuum container (1), the plasma processing device comprising: a slit plate (6) that closes an opening (1x), of the vacuum container (1), formed at a position facing the antenna (2); a dielectric plate (7) that closes, from the outside of the vacuum container (1), a plurality of slit openings (6x) formed in the slit plate (6); a plurality of mask members (8) that are provided for the respective slit openings (6x) and that cover the slit openings (6x) from the inside of the vacuum container (1) by being spaced apart from the openings; and a fixation mechanism (9) that fixes the plurality of mask members (8) in correspondence with the respective slit openings (6x).

Description

プラズマ処理装置Plasma Processing Equipment
 本発明は、プラズマを用いて被処理物を処理するプラズマ処理装置に関するものである。 The present invention relates to a plasma processing device that uses plasma to process a workpiece.
 アンテナに高周波電流を流し、それによって生じる誘導電界によって誘導結合型のプラズマ(略称ICP)を発生させ、この誘導結合型のプラズマを用いて基板等の被処理物に処理を施すプラズマ処理装置が従来から提案されている。このようなプラズマ処理装置として、特許文献1には、アンテナを真空容器の外部に配置し、真空容器の側壁の開口を塞ぐように設けた磁場透過窓を通じてアンテナから生じた高周波磁場を真空容器内に透過させることで、真空容器内にプラズマを発生させるものが開示されている。 Plasma processing apparatuses have been proposed that generate inductively coupled plasma (abbreviated ICP) by passing a high-frequency current through an antenna, and use the resulting induced electric field to process a substrate or other workpiece. Patent Document 1 discloses such a plasma processing apparatus in which an antenna is placed outside a vacuum vessel, and a high-frequency magnetic field generated from the antenna is transmitted into the vacuum vessel through a magnetic field transmission window that is provided to cover an opening in the side wall of the vacuum vessel, thereby generating plasma within the vacuum vessel.
 この特許文献1のプラズマ処理装置は、真空容器の開口を塞ぐ金属製のスリット板と、スリット板に形成されたスリットを真空容器の外側から塞ぐ誘電体板とを備えるようにしている。このプラズマ処理装置では、金属製のスリット板と、このスリット板に重ね合わせた誘電体板とに磁場透過窓としての機能を担わせているので、誘電体板のみに磁場透過窓としての機能を担わせる場合に比べて磁場透過窓の厚みを小さくすることができる。これにより、アンテナから真空容器内までの距離を短くすることができ、アンテナから生じた高周波磁場を効率良く真空容器内に供給することができる。 The plasma processing apparatus of Patent Document 1 includes a metal slit plate that covers the opening of the vacuum vessel, and a dielectric plate that covers the slits formed in the slit plate from the outside of the vacuum vessel. In this plasma processing apparatus, the metal slit plate and the dielectric plate superimposed on the slit plate function as a magnetic field transmission window, so the thickness of the magnetic field transmission window can be made smaller than when only the dielectric plate functions as the magnetic field transmission window. This makes it possible to shorten the distance from the antenna to the inside of the vacuum vessel, and to efficiently supply the high-frequency magnetic field generated by the antenna into the vacuum vessel.
国際公開2020-188809号公報International Publication No. 2020-188809
 しかしながら、上記特許文献1のプラズマ処理装置の構成では、スリット近傍に生成されたプラズマによる堆積物やスパッタ等による粒子の回り込みによる堆積物が誘電体板に堆積してしまい、そうした堆積物が導電性であると、スリットを形成する内側面が堆積物を介して導電してしまう。そうすると、アンテナから生じる高周波磁場により、スリット板にもアンテナの長手方向に沿った高周波電流が流れてしまい、スリット板や堆積物の発熱により誘電体板が加熱される。その結果、誘電体板の熱歪みが生じたり、誘電体板と堆積物との化学反応による強度低下が生じたりして、誘電体板が破損する恐れなどが生じる。 However, in the configuration of the plasma processing apparatus of Patent Document 1, deposits due to plasma generated near the slits and deposits due to particles wrapped around by sputtering, etc., accumulate on the dielectric plate. If such deposits are conductive, the inner surface forming the slit becomes conductive through the deposits. This causes a high-frequency magnetic field generated by the antenna to cause a high-frequency current to flow in the slit plate along the longitudinal direction of the antenna, and the dielectric plate is heated by the heat generated by the slit plate and the deposits. This results in thermal distortion of the dielectric plate and a decrease in strength due to a chemical reaction between the dielectric plate and the deposits, which may cause the dielectric plate to be damaged.
 このような問題に対処するため、上記特許文献1のプラズマ処理装置では、例えば、1枚の平板で構成されるマスク板によって、スリットを真空容器の内側から間隙を空けて覆うことが考えられる。このような構成であれば、スリット板に形成されたスリットをマスク板によって真空容器の内側から覆うことで、真空容器の内側から視て誘電体板が隠れるようにしているので、導電性の飛来物等が誘電体板に付着して汚染するのを防止できる。 In order to address such problems, in the plasma processing apparatus of Patent Document 1, for example, it is conceivable to cover the slits from the inside of the vacuum vessel with a mask plate consisting of a single flat plate, leaving a gap. With such a configuration, the slits formed in the slit plate are covered from the inside of the vacuum vessel with the mask plate, so that the dielectric plate is hidden when viewed from inside the vacuum vessel, and it is possible to prevent conductive flying objects, etc. from adhering to and contaminating the dielectric plate.
 一方、上記のようなマスク板を備える場合、アンテナから発生した高周波磁場の透過率を低下させないように、マスク板の厚みはより薄い方が好ましい。しかしながら、上記のマスク板は1枚の平板であるので、薄く作製しようとするとマスク板にそりが発生して、マスク板が変形してしまう。 On the other hand, when a mask plate as described above is provided, it is preferable that the thickness of the mask plate is as thin as possible so as not to reduce the transmittance of the high-frequency magnetic field generated by the antenna. However, since the mask plate described above is a single flat plate, making it thinner will cause the mask plate to warp and become deformed.
 また、生成したプラズマの熱又はプラズマによる被処理物からの輻射によって、マスク板が加熱されるので、マスク板が加熱によって変形することを防ぐために、マスク板の材質は、熱膨張率が小さいMo又はW等の重金属で形成されることが望ましい。一方、マスク板には、スリット板に形成されたスリットを覆う梁状領域の他に、磁場を透過させるスリットが梁状領域の間に形成されている。Mo又はWは切削加工することが難しいので、スリットを形成するようにマスク板を切削加工することは困難であり、また、そのようにマスク板を切削加工するにはコストもかかる。 The mask plate is heated by the heat of the generated plasma or by radiation from the workpiece by the plasma, so to prevent the mask plate from deforming due to heating, it is desirable for the mask plate to be made of a heavy metal such as Mo or W, which has a small thermal expansion coefficient. On the other hand, in addition to the beam-shaped regions that cover the slits formed in the slit plate, the mask plate also has slits between the beam-shaped regions that allow a magnetic field to pass through. Since Mo or W is difficult to cut, it is difficult to cut the mask plate to form slits, and cutting the mask plate in this way is also costly.
 本発明は、かかる問題を一挙に解決するべくなされたものであり、真空容器の外部にアンテナを配置し、誘電体板とスリット板とを重ねて磁場透過窓を構成したプラズマ処理装置において、スリット板に形成されたスリットを覆うマスク部材の厚みを薄くし、かつ、熱膨張率が小さい材質をマスク部材に用いることをその主たる課題とするものである。 The present invention was made to solve all of these problems at once, and its main objective is to reduce the thickness of the mask member that covers the slits formed in the slit plate and to use a material with a low thermal expansion coefficient for the mask member in a plasma processing apparatus in which an antenna is placed outside the vacuum vessel and a magnetic field transmission window is formed by overlapping a dielectric plate and a slit plate.
 すなわち本発明に係るプラズマ処理装置は、真空容器の外部に設けられたアンテナに高周波電流を流して前記真空容器内にプラズマを発生させるプラズマ処理装置であって、前記真空容器の前記アンテナに臨む位置に形成された開口を塞ぐスリット板と、前記スリット板に形成された複数のスリット開口を前記真空容器の外側から塞ぐ誘電体板と、前記スリット開口毎に設けられ、前記スリット開口を前記真空容器の内側から間隙を開けて覆う複数のマスク部材と、前記複数のマスク部材を前記スリット開口毎に対応して固定する固定機構とを備えることを特徴とする。 In other words, the plasma processing apparatus according to the present invention is a plasma processing apparatus that generates plasma within a vacuum vessel by passing a high-frequency current through an antenna provided outside the vacuum vessel, and is characterized by comprising a slit plate that covers an opening formed in the vacuum vessel at a position facing the antenna, a dielectric plate that covers multiple slit openings formed in the slit plate from the outside of the vacuum vessel, multiple mask members that are provided for each of the slit openings and cover the slit openings from the inside of the vacuum vessel with gaps, and a fixing mechanism that fixes the multiple mask members in correspondence with each of the slit openings.
 このような構成であれば、スリット開口それぞれにマスク部材が設けられるので、スリット板を1枚の平板で覆うマスク板と比較して、各マスク部材の大きさが小さくなる。したがって、加工時にマスク部材にそりが発生しにくくなり、マスク部材の厚みを薄くすることができる。その結果、アンテナから発生した高周波磁場の透過率が低下することを抑制することができる。
 また、マスク部材がスリット開口毎に設けられており、スリットを形成するようにマスク部材を切削加工する必要がないので、熱膨張率が小さいMo又はW等の重金属をマスク部材の材質に用いることができ、加熱によるマスク部材の変形を抑制することができる。
With this configuration, since a mask member is provided for each slit opening, the size of each mask member is smaller than that of a mask plate in which the slit plate is covered with a single flat plate. Therefore, the mask member is less likely to warp during processing, and the thickness of the mask member can be made thinner. As a result, it is possible to suppress a decrease in the transmittance of the high-frequency magnetic field generated by the antenna.
In addition, since a mask member is provided for each slit opening and there is no need to cut the mask member to form the slits, heavy metals such as Mo or W, which have a small thermal expansion coefficient, can be used as the material for the mask member, and deformation of the mask member due to heating can be suppressed.
 前記スリット開口は、前記アンテナに交差する方向に長手方向を有する矩形状をなしており、前記マスク部材は、前記スリット開口の長手方向における一方の端部から他方の端部に亘って設けられる長尺状をなすものであり、前記固定機構は、前記マスク部材を前記スリット板へ押さえる押え部材と、前記押え部材又は前記スリット板に形成され、前記マスク部材の長手方向の端部と嵌り合う嵌合部とを備えるものが好ましい。
 このような構成であれば、嵌合部によってマスク部材が位置決めされるので、押え部材がマスク部材を押さえた状態において、マスク部材がずれることを抑制することができる。また、マスク部材は、スリット開口の長手方向に亘って設けられるので、マスク部材をスリット開口に対応して固定することができ、導電性の飛来物等が誘電体板に付着して汚染することを防止できる。
It is preferable that the slit opening is rectangular in shape with its longitudinal direction intersecting the antenna, the mask member is elongated and extends from one end of the slit opening to the other end in the longitudinal direction, and the fixing mechanism includes a pressing member that presses the mask member against the slit plate, and a fitting portion formed on the pressing member or the slit plate and that fits into the longitudinal end of the mask member.
With this configuration, the mask member is positioned by the fitting portion, so that it is possible to prevent the mask member from shifting when the pressing member presses the mask member. Also, since the mask member is provided across the longitudinal direction of the slit opening, the mask member can be fixed in correspondence with the slit opening, and it is possible to prevent conductive flying objects and the like from adhering to and contaminating the dielectric plate.
 前記マスク部材は、前記スリット開口毎に複数備えられ、前記スリット開口に複数備えられたマスク部材は、互いに間隙を空けて設けられて前記スリット開口を覆うものが挙げられる。
 このような構成であれば、スリット開口を1つのマスク部材で覆う場合と比較して、アンテナの長手方向に沿った各マスク部材の幅が小さくなるので、各マスク部材に生じる誘導電流を小さくでき、高周波磁場の透過率の低下をより抑えることができる。
 また、複数のマスク部材は互いに間隙を空けて設けられるので、複数のマスク部材が互いに接触することによりアンテナに沿って生じ得るプラズマ密度のムラを抑制することができる。
A plurality of the mask members are provided for each of the slit openings, and the plurality of mask members provided for each of the slit openings are provided with gaps between each other to cover the slit openings.
With this configuration, the width of each mask member along the longitudinal direction of the antenna is smaller than when the slit opening is covered with a single mask member, thereby reducing the induced current generated in each mask member and further suppressing the decrease in the transmittance of the high-frequency magnetic field.
Furthermore, since the multiple mask members are provided with gaps between them, it is possible to suppress unevenness in plasma density that may occur along the antenna due to the multiple mask members coming into contact with each other.
 前記マスク部材は、前記アンテナの長手方向に沿って前記スリット開口毎に複数備えられ、長手方向の長さが互いに異なる長尺状をなしており、前記スリット板の厚み方向において、前記真空容器の内側に向かうにつれて、長手方向に長い方のマスク部材が配置され、前記嵌合部は、前記アンテナの長手方向に沿って設けられ、各マスク部材の端部それぞれに嵌り合う複数の凹部をさらに備え、前記複数の凹部の隣り合う部分が連通することによって形成される連通壁と、前記連通壁に対向して設けられる対向壁とによって、長手方向に長い方のマスク部材の端部を挟むように設けられるものが挙げられる。
 このような構成であれば、各マスク部材は、連通壁及び対向壁によってアンテナの長手方向に対して固定されるので、各マスク部材がアンテナの長手方向にずれることを防止することができる。特に長手方向に長い方のマスク部材をスリット板に取り付ける場合、当該マスク部材がスリット板から脱落することを防ぐことができる。
 また、複数の凹部の隣り合う部分が連通しているので、スリット開口毎に複数備えられたマスク部材は、真空容器の内側から視て、隙間なく設けられることとなる。したがって、スリット開口毎に複数備えられたマスク部材が、真空容器の内側から視て、誘電体板を隙間なく覆うので、導電性の飛来物等が誘電体板に付着して汚染するのを防止できる。
The mask members are provided in multiple numbers for each slit opening along the longitudinal direction of the antenna, and are elongated with different longitudinal lengths. In the thickness direction of the slit plate, the mask members longer in the longitudinal direction are arranged toward the inside of the vacuum vessel. The fitting portion is provided along the longitudinal direction of the antenna and further includes a plurality of recesses that fit into the respective ends of the mask members, and is arranged so as to sandwich the end of the mask member that is longer in the longitudinal direction between a communicating wall formed by communicating adjacent portions of the plurality of recesses and an opposing wall provided opposite the communicating wall.
With this configuration, each mask member is fixed in the longitudinal direction of the antenna by the communicating wall and the opposing wall, so that it is possible to prevent each mask member from shifting in the longitudinal direction of the antenna. In particular, when the mask member longer in the longitudinal direction is attached to the slit plate, it is possible to prevent the mask member from falling off the slit plate.
In addition, since adjacent portions of the multiple recesses are connected, the multiple mask members provided for each slit opening are provided without gaps when viewed from inside the vacuum vessel, and therefore the multiple mask members provided for each slit opening cover the dielectric plate without gaps when viewed from inside the vacuum vessel, preventing conductive flying objects and the like from adhering to and contaminating the dielectric plate.
 前記プラズマ処理装置は、前記スリット板と前記マスク部材との間隙内に、前記アンテナの長手方向に沿って移動する荷電粒子を遮蔽する遮蔽壁が設けられているものが挙げられる。
 このような構成であれば、間隙内におけるアンテナの長手方向に沿った荷電粒子の移動を遮蔽壁により抑制できるので、マスク部材とスリット板との間におけるプラズマの発生を防止することができる。
The plasma processing apparatus may have a shielding wall disposed in the gap between the slit plate and the mask member for blocking charged particles moving along the longitudinal direction of the antenna.
With this configuration, the movement of charged particles along the longitudinal direction of the antenna within the gap can be suppressed by the shielding wall, so that generation of plasma between the mask member and the slit plate can be prevented.
 このように構成した本発明によれば、真空容器の外部にアンテナを配置し、誘電体板とスリット板とを重ねて磁場透過窓を構成したプラズマ処理装置において、スリット板に形成されたスリットを覆うマスク部材の厚みを薄くし、かつ、熱膨張率が小さい材質をマスク部材に用いることができる。 In accordance with the present invention, which is configured in this manner, in a plasma processing apparatus in which an antenna is placed outside a vacuum vessel and a magnetic field transmission window is formed by overlapping a dielectric plate and a slit plate, the thickness of the mask member covering the slits formed in the slit plate can be reduced, and a material with a low thermal expansion coefficient can be used for the mask member.
一実施形態のプラズマ処理装置の構成を模式的に示す断面図。1 is a cross-sectional view illustrating a schematic configuration of a plasma processing apparatus according to an embodiment. 同実施形態における磁場透過窓付近の構成を真空容器の内側から見た斜視図。FIG. 4 is a perspective view of the configuration near the magnetic field transmission window in the embodiment, as viewed from inside the vacuum vessel. 同実施形態における磁場透過窓付近の構成を示す分解斜視図。FIG. 4 is an exploded perspective view showing a configuration near a magnetic field transmission window in the embodiment. 同実施形態における磁場透過窓付近の構成を真空容器の内側から視た平面図。FIG. 4 is a plan view of the configuration near the magnetic field transmission window in the embodiment, as viewed from inside the vacuum vessel. (a)図4におけるA-A線断面図、(b)A-A線断面図におけるB部を拡大した部分拡大図。5A is a cross-sectional view taken along line AA in FIG. 4, and FIG. 5B is a partially enlarged view of part B in the cross-sectional view taken along line AA. 図4におけるB-B線断面図。5 is a cross-sectional view taken along line BB in FIG. 4 . その他の実施形態における磁場透過窓付近の構成を真空容器の内側から視た平面図。FIG. 11 is a plan view of a configuration in the vicinity of a magnetic field transmission window in another embodiment, as viewed from inside the vacuum vessel. (a)図7におけるA-A線断面図、(b)A-A線断面図におけるB部を拡大した部分拡大図。8A is a cross-sectional view taken along line AA in FIG. 7, and FIG. 8B is a partially enlarged view of part B in the cross-sectional view taken along line AA. 図7におけるB-B線断面図。Cross-sectional view taken along line BB in FIG. その他の実施形態における磁場透過窓付近の構成を真空容器の内側から視た平面図。FIG. 11 is a plan view of a configuration in the vicinity of a magnetic field transmission window in another embodiment, as viewed from inside the vacuum vessel. (a)図10におけるA-A線断面図、(b)押え部材を外した場合における、図10のB部を拡大した部分拡大斜視図。11A is a cross-sectional view taken along line AA in FIG. 10 , and FIG. 11B is a partially enlarged perspective view of part B in FIG. 10 when the pressing member is removed. その他の実施形態における、アンテナと固定機構との間をアンテナの長手方向に沿って切った場合の磁場透過窓付近の構成を示す断面図。FIG. 11 is a cross-sectional view showing a configuration in the vicinity of a magnetic field transmission window when cutting between the antenna and the fixing mechanism along the longitudinal direction of the antenna in another embodiment.
 以下に、本発明に係るプラズマ処理装置の一実施形態について、図面を参照して説明する。なお、以下に示すいずれの図についても、わかりやすくするために、適宜省略し又は誇張して模式的に描かれている場合がある。同一の構成要素については、同一の符号を付して説明を適宜省略する。 Below, an embodiment of a plasma processing apparatus according to the present invention will be described with reference to the drawings. Note that in all of the drawings shown below, some parts may be omitted or exaggerated as appropriate for ease of understanding. Identical components will be given the same reference numerals and descriptions thereof will be omitted as appropriate.
<装置構成>
 本実施形態のプラズマ処理装置100は、誘導結合型のプラズマPを用いて基板Oに処理を施すものである。ここで、基板Oは、例えば、液晶ディスプレイや有機ELディスプレイ等のフラットパネルディスプレイ(FPD)用の基板、フレキシブルディスプレイ用のフレキシブル基板等である。また、基板Oに施す処理は、例えば、プラズマCVD法による膜形成、エッチング、アッシング、スパッタリング等である。
<Device Configuration>
The plasma processing apparatus 100 of this embodiment processes a substrate O by using an inductively coupled plasma P. Here, the substrate O is, for example, a substrate for a flat panel display (FPD) such as a liquid crystal display or an organic electroluminescence display, a flexible substrate for a flexible display, etc. The processing performed on the substrate O is, for example, film formation by a plasma CVD method, etching, ashing, sputtering, etc.
 なお、このプラズマ処理装置100は、プラズマCVD法によって膜形成を行う場合はプラズマCVD装置、エッチングを行う場合はプラズマエッチング装置、アッシングを行う場合はプラズマアッシング装置、スパッタリングを行う場合はプラズマスパッタリング装置とも呼ばれる。 The plasma processing apparatus 100 is also called a plasma CVD apparatus when film formation is performed by plasma CVD, a plasma etching apparatus when etching is performed, a plasma ashing apparatus when ashing is performed, and a plasma sputtering apparatus when sputtering is performed.
 具体的にプラズマ処理装置100は、図1に示すように、真空排気され且つガスが導入される真空容器1と、真空容器1の外部に設けられたアンテナ2と、アンテナ2に高周波を印加する高周波電源3とを備えたものである。かかる構成において、アンテナ2に高周波電源3から高周波を印加することによりアンテナ2には高周波電流IRが流れて、真空容器1内に誘導電界が発生して誘導結合型のプラズマPが生成される。 Specifically, as shown in FIG. 1, the plasma processing apparatus 100 comprises a vacuum vessel 1 which is evacuated and into which a gas is introduced, an antenna 2 provided outside the vacuum vessel 1, and a high frequency power supply 3 which applies a high frequency to the antenna 2. In this configuration, by applying a high frequency from the high frequency power supply 3 to the antenna 2, a high frequency current IR flows through the antenna 2, generating an induced electric field within the vacuum vessel 1 and generating an inductively coupled plasma P.
 真空容器1は、例えば金属製の容器であり、その壁(ここでは上壁1a)には、厚さ方向に貫通する開口1xが形成されている。この真空容器1は、ここでは電気的に接地されており、その内部は真空排気装置4によって真空排気される。 The vacuum vessel 1 is, for example, a metal vessel, and an opening 1x is formed in its wall (here, the upper wall 1a) that penetrates in the thickness direction. The vacuum vessel 1 is electrically grounded here, and its interior is evacuated to a vacuum by a vacuum exhaust device 4.
 また、真空容器1内には、例えば流量調整器(図示省略)や真空容器1に設けられた1又は複数のガス導入口11を経由して、ガスが導入される。ガスは、基板Oに施す処理内容に応じたものにすれば良い。例えば、プラズマCVD法によって基板に膜形成を行う場合には、ガスは、原料ガス又はそれを希釈ガス(例えばH)で希釈したガスである。より具体例を挙げると、原料ガスがSiHの場合はSi膜を、SiH+NHの場合はSiN膜を、SiH+Oの場合はSiO膜を、SiF+Nの場合はSiN:F膜(フッ素化シリコン窒化膜)を、それぞれ基板上に形成することができる。 Gas is introduced into the vacuum vessel 1 via, for example, a flow rate regulator (not shown) or one or more gas inlets 11 provided in the vacuum vessel 1. The gas may be selected according to the processing contents to be performed on the substrate O. For example, when a film is formed on the substrate by plasma CVD, the gas is a raw material gas or a gas obtained by diluting the raw material gas with a dilution gas (for example, H 2 ). To give a more specific example, when the raw material gas is SiH 4 , a Si film can be formed on the substrate, when the raw material gas is SiH 4 +NH 3 , a SiN film can be formed, when the raw material gas is SiH 4 +O 2 , a SiO 2 film can be formed, and when the raw material gas is SiF 4 +N 2 , a SiN:F film (fluorinated silicon nitride film) can be formed.
 この真空容器1の内部には、基板Oを保持する基板ホルダ5が設けられている。この例のように、基板ホルダ5にバイアス電源12からバイアス電圧を印加するようにしても良い。バイアス電圧は、例えば負の直流電圧、負のバイアス電圧等であるが、これに限られるものではない。このようなバイアス電圧によって、例えば、プラズマP中の正イオンが基板Oに入射する時のエネルギーを制御して、基板Oの表面に形成される膜の結晶化度の制御等を行うことができる。基板ホルダ5内に、基板Oを加熱するヒータ51を設けておいても良い。 Inside this vacuum vessel 1, there is provided a substrate holder 5 for holding a substrate O. As in this example, a bias voltage may be applied to the substrate holder 5 from a bias power supply 12. The bias voltage may be, for example, a negative DC voltage, a negative bias voltage, etc., but is not limited to these. By using such a bias voltage, for example, it is possible to control the energy when positive ions in the plasma P are incident on the substrate O, thereby controlling the crystallinity of the film formed on the surface of the substrate O. A heater 51 for heating the substrate O may be provided inside the substrate holder 5.
 アンテナ2は、図1に示すように、真空容器1に形成された開口1xに臨むように配置されている。なお、アンテナ2の本数は1本に限らず、複数本のアンテナ2を設けても良い。 As shown in FIG. 1, the antenna 2 is arranged to face the opening 1x formed in the vacuum vessel 1. Note that the number of antennas 2 is not limited to one, and multiple antennas 2 may be provided.
 高周波電源3は、整合回路31を介してアンテナ2に高周波電流IRを流すことができる。高周波の周波数は例えば一般的な13.56MHzであるが、これに限られるものではなく適宜変更してもよい。 The high-frequency power supply 3 can pass a high-frequency current IR through the antenna 2 via a matching circuit 31. The frequency of the high-frequency current is, for example, a typical 13.56 MHz, but is not limited to this and may be changed as appropriate.
 このプラズマ処理装置100は、真空容器1の壁(上壁1a)に形成された開口1xを真空容器1の外側から塞ぐスリット板6と、スリット板6に形成されたスリット開口6xを真空容器1の外側から塞ぐ誘電体板7と、スリット開口6x毎に設けられ、各スリット開口6xを真空容器1の内側から間隙Gを空けて覆う複数のマスク部材8と、複数のマスク部材8をスリット開口毎に対応して固定する固定機構9とをさらに備える。 This plasma processing apparatus 100 further includes a slit plate 6 that blocks the openings 1x formed in the wall (upper wall 1a) of the vacuum vessel 1 from outside the vacuum vessel 1, a dielectric plate 7 that blocks the slit openings 6x formed in the slit plate 6 from outside the vacuum vessel 1, a plurality of mask members 8 that are provided for each slit opening 6x and cover each slit opening 6x from inside the vacuum vessel 1 with a gap G therebetween, and a fixing mechanism 9 that fixes the plurality of mask members 8 corresponding to each slit opening.
 スリット板6は、アンテナ2から生じた高周波磁場を真空容器1内に透過させるとともに、真空容器1の外部から真空容器1の内部への電界の入り込みを防ぐものである。具体的にこのスリット板6は平板状をなしており、その厚さ方向に貫通してなるスリット開口6xが複数形成される。スリット開口6xは、アンテナ2に交差する方向に長手方向を有する矩形状をなすものである。このスリット板6は、後述する誘電体板7よりも機械強度が高いことが好ましく、誘電体板7よりも厚み寸法が大きいことが好ましい。複数のスリット開口6xは、厚さ方向から視て、互いに平行であって、かつ、アンテナ2に交差するように(具体的には直交するように)形成されている。すなわち、複数のスリット開口6xの間には、各スリット開口6xに平行な梁状領域6zが形成されている。複数のスリット開口6xはいずれも同形状(具体的には平面視矩形状)であり、アンテナ2の長手方向に沿った長さ(幅)は、例えば5mm以上30mm以下であるがこれに限らない。 The slit plate 6 allows the high-frequency magnetic field generated by the antenna 2 to pass through the vacuum vessel 1, and prevents the electric field from entering the vacuum vessel 1 from the outside. Specifically, the slit plate 6 is flat, and multiple slit openings 6x are formed through it in the thickness direction. The slit openings 6x are rectangular with their longitudinal direction intersecting the antenna 2. The slit plate 6 preferably has a higher mechanical strength than the dielectric plate 7 described later, and preferably has a larger thickness dimension than the dielectric plate 7. The multiple slit openings 6x are formed parallel to each other when viewed from the thickness direction, and intersect with the antenna 2 (specifically, perpendicular to each other). That is, between the multiple slit openings 6x, a beam-shaped region 6z is formed parallel to each slit opening 6x. The multiple slit openings 6x all have the same shape (specifically, rectangular in plan view), and the length (width) along the longitudinal direction of the antenna 2 is, for example, 5 mm to 30 mm, but is not limited thereto.
 より具体的に説明すると、スリット板6は、例えばCu、Al、Zn、Ni、Sn、Si、Ti、Fe、Cr、Nb、C、Mo、W又はCoを含む群から選択される1種の金属又はそれらの合金(例えばステンレス合金、アルミニウム合金等)等の金属材料を圧延加工(例えば冷間圧延や熱間圧延)などにより製造したものであり、例えば厚みが約5mmのものである。ただし、製造方法や厚みはこれに限らず仕様に応じて適宜変更して構わない。 To be more specific, the slit plate 6 is manufactured by rolling (e.g., cold rolling or hot rolling) a metal material such as one metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.), and has a thickness of, for example, about 5 mm. However, the manufacturing method and thickness are not limited to this and may be changed as appropriate depending on the specifications.
 このスリット板6は、平面視において真空容器の開口1xよりも大きいものであり、上壁1aに支持された状態で開口1xを塞いでいる。スリット板6と上壁1aとの間には、Oリングやガスケット等のシール部材S(図1参照)が介在しており、これらの間は真空シールされている。 The slit plate 6 is larger than the opening 1x of the vacuum vessel in a plan view, and is supported by the upper wall 1a to close the opening 1x. A sealing member S (see FIG. 1), such as an O-ring or gasket, is interposed between the slit plate 6 and the upper wall 1a, creating a vacuum seal between them.
 誘電体板7は、スリット板6において真空容器1の外側を向く外向き面61(真空容器1の内部を向く内向き面の裏面)に設けられて、スリット板6のスリット開口6xを塞ぐものである。 The dielectric plate 7 is provided on the outward surface 61 of the slit plate 6 that faces the outside of the vacuum vessel 1 (the reverse side of the inward surface that faces the inside of the vacuum vessel 1) and covers the slit opening 6x of the slit plate 6.
 誘電体板7は、全体が誘電体物質で構成された平板状をなすものであり、例えばアルミナ、炭化ケイ素、窒化ケイ素等のセラミックス、石英ガラス、無アルカリガラス等の無機材料、フッ素樹脂(例えばテフロン)等の樹脂材料等からなる。なお、誘電損を低減する観点から、誘電体板7を構成する材料は、誘電正接が0.01以下のものが好ましく、0.005以下のものがより好ましい。 The dielectric plate 7 is a flat plate made entirely of a dielectric material, and is made of, for example, ceramics such as alumina, silicon carbide, silicon nitride, etc., inorganic materials such as quartz glass and non-alkali glass, and resin materials such as fluororesin (e.g. Teflon). From the viewpoint of reducing dielectric loss, the material making up the dielectric plate 7 preferably has a dielectric tangent of 0.01 or less, and more preferably 0.005 or less.
 ここでは誘電体板7の板厚をスリット板6の板厚よりも小さくしているが、これに限定されず、例えば真空容器1を真空排気した状態において、スリット開口6xから受ける真空容器1の内外の差圧に耐え得る強度を備えれば良く、スリット開口6xの数や長さ等の仕様に応じて適宜設定されてよい。ただし、アンテナ2と真空容器1との間の距離を短くする観点からは薄い方が好ましい。 Here, the thickness of the dielectric plate 7 is made smaller than the thickness of the slit plate 6, but this is not limiting. For example, when the vacuum vessel 1 is evacuated, the thickness needs to be strong enough to withstand the pressure difference between the inside and outside of the vacuum vessel 1 received through the slit openings 6x, and may be set appropriately according to the specifications such as the number and length of the slit openings 6x. However, from the viewpoint of shortening the distance between the antenna 2 and the vacuum vessel 1, a thinner thickness is preferable.
 かかる構成により、スリット板6及び誘電体板7は、アンテナ2から発生した磁場を透過させる磁場透過窓Wとして機能を担う。すなわち、高周波電源3からアンテナ2に高周波を印加すると、アンテナ2から発生した高周波磁場が、スリット板6及び誘電体板7からなる磁場透過窓Wを透過して真空容器1内に形成(供給)される。これにより、真空容器1内の空間に誘導電界が発生し、誘導結合型のプラズマPが生成される。 With this configuration, the slit plate 6 and the dielectric plate 7 function as a magnetic field transmission window W that allows the magnetic field generated by the antenna 2 to pass through. In other words, when a high frequency is applied to the antenna 2 from the high frequency power supply 3, the high frequency magnetic field generated by the antenna 2 passes through the magnetic field transmission window W consisting of the slit plate 6 and the dielectric plate 7 and is formed (supplied) inside the vacuum vessel 1. As a result, an induced electric field is generated in the space inside the vacuum vessel 1, and an inductively coupled plasma P is generated.
 然して、マスク部材8は、スリット板6において真空容器1の内側を向く内向き面62に設けられて、スリット板6のスリット開口6xを覆うものである。 The mask member 8 is provided on the inward surface 62 of the slit plate 6 that faces the inside of the vacuum vessel 1, and covers the slit opening 6x of the slit plate 6.
 具体的には、図2~図6に示すように、マスク部材8は、スリット開口6xの長手方向における一方の端部6x1から他方の端部6x2に亘って設けられる長尺状をなしており、本実施形態において、マスク部材8は、アンテナ2に交差する方向に長手方向を有する矩形平板状をなす。より詳細には、マスク部材8の長手方向の長さは、スリット開口6xの長手方向の長さよりも長く、アンテナ2の長手方向に沿ったマスク部材8の長さ(幅)は、アンテナ2の長手方向に沿ったスリット開口6xの幅と略同一である。 Specifically, as shown in Figures 2 to 6, the mask member 8 is elongated and extends from one end 6x1 to the other end 6x2 in the longitudinal direction of the slit opening 6x, and in this embodiment, the mask member 8 is a rectangular flat plate having a longitudinal direction intersecting the antenna 2. More specifically, the longitudinal length of the mask member 8 is longer than the longitudinal length of the slit opening 6x, and the length (width) of the mask member 8 along the longitudinal direction of the antenna 2 is approximately the same as the width of the slit opening 6x along the longitudinal direction of the antenna 2.
 また、マスク部材8は、スリット板6の厚さ方向から見てスリット開口6xと平行に設けられて、スリット開口6xの略全体を覆っている。なお、マスク部材8は、スリット開口6xの一部を覆うように形成されていてもよい。また、磁場の透過率を向上させる観点からマスク部材8の幅は狭い程好ましく、例えば10mm以下が好ましく、5mm以下がより好ましい。 The mask member 8 is disposed parallel to the slit opening 6x when viewed from the thickness direction of the slit plate 6, and covers substantially the entire slit opening 6x. The mask member 8 may be formed so as to cover only a portion of the slit opening 6x. From the viewpoint of improving the transmittance of the magnetic field, the narrower the width of the mask member 8, the more preferable it is, e.g., 10 mm or less, and more preferably 5 mm or less.
 さらに、複数のマスク部材8は、アンテナ2の長手方向から視て互いに平行に設けられる。ここでは、各マスク部材8は、アンテナ2に交差するように(具体的には直交するように)設けられ、互いに同一の平板状をなしている。また、各マスク部材8は、スリット板6の厚み方向から視て各スリット開口6xと平行に設けられて、各マスク部材8が各スリット開口6xの略全部を覆っている。 Furthermore, the multiple mask members 8 are arranged parallel to each other when viewed from the longitudinal direction of the antenna 2. Here, each mask member 8 is arranged so as to intersect with the antenna 2 (specifically, so as to be perpendicular to it), and each has the same flat plate shape. Also, each mask member 8 is arranged parallel to each slit opening 6x when viewed from the thickness direction of the slit plate 6, and each mask member 8 covers almost the entirety of each slit opening 6x.
 その上、マスク部材8は、例えばMo又はWといった熱膨張率が小さい重金属又はそれらの合金等の金属材料により構成されている。マスク部材8の厚みは、スリット板6の厚みより小さいことが好ましく、例えば約5mm以下のものである。ただし、マスク部材8の厚みはこれに限らず仕様に応じて適宜変更して構わない。 Moreover, the mask member 8 is made of a metal material such as a heavy metal with a small thermal expansion coefficient, such as Mo or W, or an alloy of these. The thickness of the mask member 8 is preferably smaller than the thickness of the slit plate 6, for example, about 5 mm or less. However, the thickness of the mask member 8 is not limited to this and may be changed as appropriate depending on the specifications.
 固定機構9は、各マスク部材8が各スリット開口6xを覆うように、各マスク部材8を位置決めして固定するものである。具体的には、図2~図6に示すように、固定機構9は、スリット板6に形成され、マスク部材8の長手方向の端部と嵌り合う嵌合部91と、マスク部材8をスリット板6へ押さえる押え部材92とを備える。 The fixing mechanism 9 positions and fixes each mask member 8 so that each mask member 8 covers each slit opening 6x. Specifically, as shown in Figures 2 to 6, the fixing mechanism 9 is formed on the slit plate 6 and includes a fitting portion 91 that fits with the longitudinal end of the mask member 8, and a pressing member 92 that presses the mask member 8 against the slit plate 6.
 嵌合部91は、スリット板6の内向き面62に形成され、スリット開口6xの両端部6x1、6x2に対応して設けられる。本実施形態において、嵌合部91は、直方体の一部をなす凹部で構成され、嵌合部91を構成する凹部は、アンテナ2の長手方向に沿った長手方向を有している。具体的には、嵌合部91の長手方向の長さは、アンテナ2の長手方向に沿ったマスク部材8の長さ(幅)と略同一である。また、凹部の長手方向を構成する一辺は、スリット開口6xの両端部6x1、6x2の真空容器1の内側の辺と略一致している。さらに、複数の嵌合部91は、アンテナ2の長手方向に沿って設けられ、アンテナ2の長手方向に沿った梁状領域6zの長さ(幅)だけ互いに平行に離れて設けられる。 The fitting portion 91 is formed on the inward surface 62 of the slit plate 6 and is provided to correspond to both ends 6x1, 6x2 of the slit opening 6x. In this embodiment, the fitting portion 91 is formed as a recess forming a part of a rectangular parallelepiped, and the recess forming the fitting portion 91 has a longitudinal direction along the longitudinal direction of the antenna 2. Specifically, the longitudinal length of the fitting portion 91 is approximately the same as the length (width) of the mask member 8 along the longitudinal direction of the antenna 2. In addition, one side forming the longitudinal direction of the recess approximately coincides with the inner side of the vacuum vessel 1 at both ends 6x1, 6x2 of the slit opening 6x. Furthermore, the multiple fitting portions 91 are provided along the longitudinal direction of the antenna 2 and are provided parallel to each other and spaced apart by the length (width) of the beam-shaped region 6z along the longitudinal direction of the antenna 2.
 また、本実施形態において、嵌合部91には、マスク部材8が載置される載置面91aが形成される。具体的には、載置面91aが内向き面62よりも真空容器1の内側に設けられることによって、各マスク部材8は、各スリット開口6xを真空容器1の内側から間隙Gを開けて覆っている。これにより、アンテナ2に沿ってマスク部材8及びスリット板に生じる誘導電流を小さくでき、高周波磁場の透過率の低下を効率よく抑制できる。なお、マスク部材8の外向き面とスリット板6の内向き面62との間隙Gの寸法は、5mm以下の値に設定されているのが好ましい。 In this embodiment, the fitting portion 91 is formed with a mounting surface 91a on which the mask member 8 is placed. Specifically, the mounting surface 91a is provided inside the vacuum vessel 1 relative to the inward surface 62, and each mask member 8 covers each slit opening 6x from the inside of the vacuum vessel 1 with a gap G. This reduces the induced current generated in the mask member 8 and the slit plate along the antenna 2, and efficiently suppresses the decrease in the transmittance of the high frequency magnetic field. The dimension of the gap G between the outward surface of the mask member 8 and the inward surface 62 of the slit plate 6 is preferably set to a value of 5 mm or less.
 より具体的に説明すると、嵌合部91は、スリット板6と同種の材質で構成されており、例えばCu、Al、Zn、Ni、Sn、Si、Ti、Fe、Cr、Nb、C、Mo、W又はCoを含む群から選択される1種の金属又はそれらの合金(例えばステンレス合金、アルミニウム合金等)等の金属材料を圧延加工(例えば冷間圧延や熱間圧延)などにより製造したものである。ただし、嵌合部91は、スリット板6と同種の材質で構成されていなくともよい。 More specifically, the fitting portion 91 is made of the same material as the slit plate 6, and is manufactured by rolling (e.g., cold rolling or hot rolling) a metal material such as a metal selected from the group including Cu, Al, Zn, Ni, Sn, Si, Ti, Fe, Cr, Nb, C, Mo, W, or Co, or an alloy thereof (e.g., stainless steel alloy, aluminum alloy, etc.). However, the fitting portion 91 does not have to be made of the same material as the slit plate 6.
 押え部材92は、アンテナ2の長手方向に沿った長尺状をなし、マスク部材8を押さえた状態において嵌合部91と嵌り合うものである。具体的に押え部材92には、嵌合部91を構成する凹部と嵌り合う凸部921が、押え部材92の長手方向に沿って複数形成され、アンテナ2の長手方向に沿った梁状領域6zの長さ(幅)だけ互いに平行に離れて設けられる。本実施形態において、凸部921は、アンテナ2の長手方向に沿って延びる直方体状をなしており、凸部921において、アンテナ2の長手方向に沿った長さ及びアンテナ2と交差する方向の長さは、それぞれ嵌合部91の凹部の長手方向及び短手方向の長さと略同一である。 The pressing member 92 is elongated along the longitudinal direction of the antenna 2, and fits into the fitting portion 91 when the mask member 8 is pressed. Specifically, the pressing member 92 has a plurality of convex portions 921 formed along the longitudinal direction of the pressing member 92, which fit into the concave portions constituting the fitting portion 91, and are arranged parallel to each other and spaced apart by the length (width) of the beam-shaped region 6z along the longitudinal direction of the antenna 2. In this embodiment, the convex portions 921 are rectangular parallelepiped extending along the longitudinal direction of the antenna 2, and the length of the convex portions 921 along the longitudinal direction of the antenna 2 and the length in the direction intersecting the antenna 2 are approximately the same as the longitudinal and lateral lengths of the concave portions of the fitting portion 91, respectively.
 なおこの実施形態では、スリット板6には水等の冷却媒体が流れる流路6cが形成されている(又は設けられている。)。この流路6cは、固定機構9の近傍にアンテナ2の長手方向に沿って形成されている。ここでは、流路6cは、スリット板6の厚み方向に沿って固定機構9の直上に位置するように形成されている。 In this embodiment, a flow path 6c through which a cooling medium such as water flows is formed (or provided) in the slit plate 6. This flow path 6c is formed along the longitudinal direction of the antenna 2 near the fixing mechanism 9. Here, the flow path 6c is formed so as to be located directly above the fixing mechanism 9 along the thickness direction of the slit plate 6.
<本実施形態の効果>
 このように構成した本実施形態のプラズマ処理装置100によれば、スリット板6を1枚の平板で覆うマスク板と比較して、スリット開口6xそれぞれにマスク部材8が設けられるので、各マスク部材8の大きさが小さくなる。したがって、マスク部材8にそりが発生しにくくなり、マスク部材8の厚みを薄く加工することができる。その結果、アンテナ2から発生した高周波磁場の透過率が低下することを抑制することができる。
 また、各マスク部材8がスリット開口6x毎に設けられており、スリットを形成するようにマスク部材8を切削加工する必要がないので、熱膨張率が小さいMo又はW等の重金属をマスク部材8の材質に用いることができ、加熱によるマスク部材8の変形を抑制することができる。
<Effects of this embodiment>
According to the plasma processing apparatus 100 of the present embodiment configured as described above, since a mask member 8 is provided for each of the slit openings 6x, the size of each mask member 8 is smaller than that of a mask plate in which the slit plate 6 is covered with a single flat plate. Therefore, the mask member 8 is less likely to warp, and the mask member 8 can be processed to have a thin thickness. As a result, it is possible to suppress a decrease in the transmittance of the high frequency magnetic field generated from the antenna 2.
In addition, since each mask member 8 is provided for each slit opening 6x and there is no need to cut the mask members 8 to form slits, heavy metals such as Mo or W, which have a small thermal expansion coefficient, can be used as the material for the mask members 8, and deformation of the mask members 8 due to heating can be suppressed.
 さらに、本実施形態のプラズマ処理装置100によれば、嵌合部91によってマスク部材8が位置決めされるので、押え部材92がマスク部材8を押さえた状態において、マスク部材8がずれることを抑制することができる。また、マスク部材8は、スリット開口6xの長手方向に亘って設けられるので、マスク部材8をスリット開口6xに対応して固定することができ、導電性の飛来物等が誘電体板に付着して汚染することを防止できる。 Furthermore, according to the plasma processing apparatus 100 of this embodiment, the mask member 8 is positioned by the fitting portion 91, so that the mask member 8 can be prevented from shifting when the pressing member 92 is pressing the mask member 8. In addition, since the mask member 8 is provided along the longitudinal direction of the slit opening 6x, the mask member 8 can be fixed in correspondence with the slit opening 6x, and conductive flying objects and the like can be prevented from adhering to and contaminating the dielectric plate.
<その他の変形実施形態>
 なお、本発明は前記実施形態に限られるものではない。
<Other Modified Embodiments>
The present invention is not limited to the above-described embodiment.
 本実施形態において、マスク部材8の形状は矩形平板状であったが、マスク部材8の形状は、柱状などその他の長尺状であってもよい。 In this embodiment, the shape of the mask member 8 is a rectangular flat plate, but the shape of the mask member 8 may be other elongated shapes, such as a column shape.
 本実施形態において、嵌合部91は、スリット板6に形成されるものであったが、嵌合部91は、押え部材92に形成されていてもよい。 In this embodiment, the fitting portion 91 is formed on the slit plate 6, but the fitting portion 91 may also be formed on the pressing member 92.
 他の実施形態のプラズマ処理装置100では、図7~図9に示すように、マスク部材8がスリット開口6x毎に複数備えられ、スリット開口6xに複数備えられたマスク部材8は、互いにずれて設けられてスリット開口6xを覆うようにしてもよい。この場合、固定機構9によって、各マスク部材8は、アンテナ2の長手方向に沿って互いにずれて設けられるとともに、スリット板6の厚み方向から視ても互いに間隙G‘を空けて設けられる。なお、各マスク部材8は、アンテナ2の長手方向又はスリット板6の厚さ方向から視て互いに重複していてもよく、重複してなくてもよい。また各マスク部材8間の間隙G’の大きさは特に限定されない。さらに、図7~図9では、スリット開口6xごとに2つのマスク部材8が設けられているが、スリット開口6xごとに設けられるマスク部材8の個数は3つ以上であってもよい。 In another embodiment of the plasma processing apparatus 100, as shown in Figs. 7 to 9, a plurality of mask members 8 may be provided for each slit opening 6x, and the mask members 8 provided for each slit opening 6x may be offset from each other to cover the slit opening 6x. In this case, the fixing mechanism 9 allows each mask member 8 to be offset from each other along the longitudinal direction of the antenna 2, and also to be provided with a gap G' between each mask member when viewed from the thickness direction of the slit plate 6. Note that each mask member 8 may or may not overlap each other when viewed from the longitudinal direction of the antenna 2 or the thickness direction of the slit plate 6. The size of the gap G' between each mask member 8 is not particularly limited. Furthermore, although two mask members 8 are provided for each slit opening 6x in Figs. 7 to 9, the number of mask members 8 provided for each slit opening 6x may be three or more.
 この構成により、スリット開口6xを1つのマスク部材8で覆う場合と比較して、アンテナ2の長手方向に沿った各マスク部材8の幅が小さくなるので、各マスク部材8に生じる誘導電流を小さくでき、高周波磁場の透過率の低下をより抑えることができる。また、複数のマスク部材8が互いに間隙G’を空けて設けられるので、複数のマスク部材8が互いに接触することによりアンテナ2に沿って生じ得るプラズマ密度のムラを抑制することができる。 With this configuration, the width of each mask member 8 along the longitudinal direction of the antenna 2 is smaller than when the slit opening 6x is covered with one mask member 8, so the induced current generated in each mask member 8 can be reduced and the decrease in the transmittance of the high frequency magnetic field can be further suppressed. In addition, since the multiple mask members 8 are provided with a gap G' between them, it is possible to suppress unevenness in plasma density that can occur along the antenna 2 due to the multiple mask members 8 coming into contact with each other.
 また、他の実施形態のプラズマ処理装置100では、図10及び図11に示すように、マスク部材8が、アンテナ2の長手方向に沿ってスリット開口6x毎に複数備えられ、長手方向の長さが互いに異なる長尺状をなしており、スリット板6の厚み方向において、真空容器1の内側に向かうにつれて、長手方向に長い方のマスク部材8’が配置されるようにしてもよい。この場合、嵌合部91は、アンテナ2の長手方向に沿って設けられ、各マスク部材8の端部それぞれに嵌り合う複数の凹部をさらに備え、複数の凹部の隣り合う部分が連通することによって形成される連通壁w1と、連通壁w1に対向して設けられる対向壁w2とによって、長手方向に長い方のマスク部材8’の端部を挟むように設けられるようにしてもよい。 Also, in another embodiment of the plasma processing apparatus 100, as shown in Figs. 10 and 11, a plurality of mask members 8 are provided for each slit opening 6x along the longitudinal direction of the antenna 2, and are elongated with different longitudinal lengths, and the mask members 8' that are longer in the longitudinal direction may be arranged toward the inside of the vacuum vessel 1 in the thickness direction of the slit plate 6. In this case, the fitting portion 91 may be provided along the longitudinal direction of the antenna 2, and further include a plurality of recesses that fit into the ends of each mask member 8, and may be provided so as to sandwich the end of the mask member 8' that is longer in the longitudinal direction between a communication wall w1 formed by communication between adjacent parts of the plurality of recesses and an opposing wall w2 provided opposite the communication wall w1.
 この実施形態において、嵌合部91は、長手方向に短い方のマスク部材8と嵌り合う第1凹部911と、長手方向に長い方のマスク部材8’と嵌り合う第2凹部912とを備える。第1凹部911は、第2凹部912よりもスリット開口6xの端部6x1、6x2の近くに設けられ、マスク部材8が載置される第1凹部911の載置面は、スリット板6の厚み方向から視て、スリット板6の内向き面62とマスク部材8’が載置される第2凹部912の載置面との間に形成される。また、第1凹部911及び第2凹部912は互いに隣接して設けられることによって連通壁w1が形成され、第2凹部912には、連通壁w1と対向する対向壁w2が形成される。連通壁w1及び対向壁w2は、マスク部材8’の短手方向の長さと略同一だけ互いに平行に離れて設けられる。 In this embodiment, the fitting portion 91 includes a first recess 911 that fits with the mask member 8 that is shorter in the longitudinal direction, and a second recess 912 that fits with the mask member 8' that is longer in the longitudinal direction. The first recess 911 is provided closer to the ends 6x1 and 6x2 of the slit opening 6x than the second recess 912, and the mounting surface of the first recess 911 on which the mask member 8 is placed is formed between the inward surface 62 of the slit plate 6 and the mounting surface of the second recess 912 on which the mask member 8' is placed, as viewed from the thickness direction of the slit plate 6. In addition, the first recess 911 and the second recess 912 are provided adjacent to each other to form a communicating wall w1, and the second recess 912 has an opposing wall w2 that faces the communicating wall w1. The communicating wall w1 and the opposing wall w2 are provided parallel to each other and spaced apart by approximately the same distance as the short-side length of the mask member 8'.
 この構成により、各マスク部材8をスリット板6に取り付ける場合、各マスク部材8、8’は、連通壁w1及び対向壁w2によって固定されるので、各マスク部材8、8’がアンテナ2の長手方向にずれることを防止することができる。特に、長手方向に長い方のマスク部材8’をスリット板6に取り付ける場合に、当該マスク部材8’がスリット板6から脱落することを防ぐことができる。
 また、第1凹部911及び第2凹部912の隣り合う部分が連通しているので、スリット開口6x毎に複数備えられたマスク部材8、8’は、真空容器1の内側から視て、隙間なく設けられることとなる。したがって、スリット開口6x毎に複数備えられたマスク部材8、8’が、真空容器1の内側から視て、誘電体板7を隙間なく覆うので、導電性の飛来物等が誘電体板7に付着して汚染するのを防止できる。
With this configuration, when each mask member 8 is attached to the slit plate 6, since each mask member 8, 8' is fixed by the communicating wall w1 and the opposing wall w2, it is possible to prevent each mask member 8, 8' from shifting in the longitudinal direction of the antenna 2. In particular, when the mask member 8' which is longer in the longitudinal direction is attached to the slit plate 6, it is possible to prevent the mask member 8' from falling off the slit plate 6.
Furthermore, since adjacent portions of the first recess 911 and the second recess 912 are connected to each other, the mask members 8, 8' provided for each slit opening 6x are provided without any gaps when viewed from inside the vacuum vessel 1. Therefore, the mask members 8, 8' provided for each slit opening 6x cover the dielectric plate 7 without any gaps when viewed from inside the vacuum vessel 1, so that it is possible to prevent conductive flying objects and the like from adhering to and contaminating the dielectric plate 7.
 また他の実施形態のプラズマ処理装置100では、スリット板6とマスク部材8との間隙G内に、アンテナ2の長手方向に沿って移動する荷電粒子を遮蔽する遮蔽壁SWが設けられていてもよい。この遮蔽壁SWは、アンテナ2の長手方向に対して交差する(具体的には直交する)ように形成された壁面を有してよい。アンテナ2の長手方向から視て、遮蔽壁SWは間隙Gの全部又は一部を遮蔽するように形成されてよい。そしてこの遮蔽壁SWは、アンテナ2の長手方向に沿って複数設けられてもよい。複数の遮蔽壁SWは互いに平行であり、アンテナ2の長手方向に沿って一定の間隔(ピッチ)で設けられているのが好ましい。アンテナ2の長手方向に沿った複数の遮蔽壁SW間の間隔(ピッチ)は、スリット板6のスリット開口6x間の間隔と等しくてもよく、異なっていてもよい。 In another embodiment of the plasma processing apparatus 100, a shielding wall SW for shielding charged particles moving along the longitudinal direction of the antenna 2 may be provided in the gap G between the slit plate 6 and the mask member 8. This shielding wall SW may have a wall surface formed to intersect (specifically, perpendicular to) the longitudinal direction of the antenna 2. When viewed from the longitudinal direction of the antenna 2, the shielding wall SW may be formed to shield all or part of the gap G. A plurality of shielding walls SW may be provided along the longitudinal direction of the antenna 2. The plurality of shielding walls SW are preferably parallel to each other and provided at a constant interval (pitch) along the longitudinal direction of the antenna 2. The interval (pitch) between the plurality of shielding walls SW along the longitudinal direction of the antenna 2 may be equal to or different from the interval between the slit openings 6x of the slit plate 6.
 具体的には、例えば図12に示すように、スリット板6の梁状領域6zの内向き面に、マスク部材8の外向き面81に向かって間隙G内に突き出す突出部6pが形成されており、この突出部6pにより遮蔽壁SWが構成されてもよい。または、マスク部材8の外向き面81に、スリット板6の内向き面62に向かって間隙G内に突き出す突出部が形成されており、この突出部により遮蔽壁SWが構成されてもよい。 Specifically, as shown in FIG. 12, for example, a protrusion 6p that protrudes into the gap G toward the outward surface 81 of the mask member 8 may be formed on the inward surface of the beam-shaped region 6z of the slit plate 6, and this protrusion 6p may form the shielding wall SW. Alternatively, a protrusion that protrudes into the gap G toward the inward surface 62 of the slit plate 6 may be formed on the outward surface 81 of the mask member 8, and this protrusion may form the shielding wall SW.
 その他、本発明は前記実施形態に限られず、その趣旨を逸脱しない範囲で種々の変形が可能であるのは言うまでもない。 It goes without saying that the present invention is not limited to the above-described embodiment, and various modifications are possible without departing from the spirit of the invention.
 本発明によれば、真空容器の外部にアンテナを配置し、誘電体板とスリット板とを重ねて磁場透過窓を構成したプラズマ処理装置において、スリット板に形成されたスリットを覆うマスク部材の厚みを薄くし、かつ、熱膨張率が小さい材質をマスク部材に用いることができる。 In accordance with the present invention, in a plasma processing apparatus in which an antenna is placed outside a vacuum vessel and a magnetic field transmission window is formed by overlapping a dielectric plate and a slit plate, the thickness of the mask member covering the slits formed in the slit plate can be reduced, and a material with a low thermal expansion coefficient can be used for the mask member.
100・・・プラズマ処理装置
O  ・・・基板
P  ・・・誘導結合プラズマ
2  ・・・アンテナ
3  ・・・高周波電源
6  ・・・スリット板
6x ・・・スリット開口
7  ・・・誘電体板
8  ・・・マスク部材
9  ・・・固定機構
91 ・・・嵌合部
92 ・・・押え部材
W  ・・・磁場透過窓
S  ・・・シール部材
REFERENCE SIGNS LIST 100: Plasma processing apparatus O: Substrate P: Inductively coupled plasma 2: Antenna 3: High frequency power supply 6: Slit plate 6x: Slit opening 7: Dielectric plate 8: Mask member 9: Fixing mechanism 91: Fitting portion 92: Pressing member W: Magnetic field transmission window S: Seal member

Claims (5)

  1.  真空容器の外部に設けられたアンテナに高周波電流を流して前記真空容器内にプラズマを発生させるプラズマ処理装置であって、
     前記真空容器の前記アンテナに臨む位置に形成された開口を塞ぐスリット板と、
     前記スリット板に形成された複数のスリット開口を前記真空容器の外側から塞ぐ誘電体板と、
     前記スリット開口毎に設けられ、前記スリット開口を前記真空容器の内側から間隙を開けて覆う複数のマスク部材と、
     前記複数のマスク部材を前記スリット開口毎に対応して固定する固定機構とを備えるプラズマ処理装置。
    A plasma processing apparatus that generates plasma in a vacuum chamber by passing a high-frequency current through an antenna provided outside the vacuum chamber,
    a slit plate for closing an opening formed in the vacuum vessel at a position facing the antenna;
    a dielectric plate that covers the plurality of slit openings formed in the slit plate from outside the vacuum vessel;
    a plurality of mask members provided for each of the slit openings and covering the slit openings from the inside of the vacuum vessel with gaps;
    a fixing mechanism for fixing the plurality of mask members to correspond to each of the slit openings.
  2.  前記スリット開口は、前記アンテナに交差する方向に長手方向を有する矩形状をなしており、
     前記マスク部材は、前記スリット開口の長手方向における一方の端部から他方の端部に亘って設けられる長尺状をなすものであり、
     前記固定機構は、
      前記マスク部材を前記スリット板へ押さえる押え部材と、
      前記押え部材又は前記スリット板に形成され、前記マスク部材の長手方向の端部と嵌り合う嵌合部とを備える請求項1記載のプラズマ処理装置。
    The slit opening has a rectangular shape having a longitudinal direction intersecting with the antenna,
    the mask member is elongated and extends from one end to the other end in a longitudinal direction of the slit opening,
    The fixing mechanism includes:
    a pressing member for pressing the mask member against the slit plate;
    2. The plasma processing apparatus according to claim 1, further comprising a fitting portion formed on the pressing member or the slit plate, the fitting portion fitting with an end portion of the mask member in the longitudinal direction.
  3.  前記マスク部材は、前記スリット開口毎に複数備えられ、
     前記スリット開口に複数備えられたマスク部材は、互いに間隙を空けて設けられて前記スリット開口を覆う請求項1記載のプラズマ処理装置。
    The mask member is provided in plurality for each of the slit openings,
    2. The plasma processing apparatus according to claim 1, wherein the mask members provided on the slit opening are spaced apart from one another to cover the slit opening.
  4.  前記マスク部材は、前記アンテナの長手方向に沿って前記スリット開口毎に複数備えられ、長手方向の長さが互いに異なる長尺状をなしており、
     前記スリット板の厚み方向において、前記真空容器の内側に向かうにつれて、長手方向に長い方のマスク部材が配置され、
     前記嵌合部は、前記アンテナの長手方向に沿って設けられ、各マスク部材の端部それぞれに嵌り合う複数の凹部をさらに備え、
     前記複数の凹部の隣り合う部分が連通することによって形成される連通壁と、前記連通壁に対向して前記複数の凹部にそれぞれ設けられる対向壁とによって、前記スリット開口に複数備えられたマスク部材が挟まれる請求項2記載のプラズマ処理装置。
    The mask member is provided in a plurality of positions for each of the slit openings along the longitudinal direction of the antenna, and has an elongated shape with different longitudinal lengths,
    In a thickness direction of the slit plate, a mask member that is longer in a longitudinal direction is disposed toward an inner side of the vacuum vessel,
    the fitting portion is provided along a longitudinal direction of the antenna and further includes a plurality of recesses that fit into the ends of the mask members,
    3. The plasma processing apparatus of claim 2, wherein the mask members provided in the slit openings are sandwiched between a communication wall formed by communication between adjacent portions of the plurality of recesses and an opposing wall provided in each of the plurality of recesses opposite the communication wall.
  5.  前記スリット板と前記マスク部材との間隙内に、前記アンテナの長手方向に沿って移動する荷電粒子を遮蔽する遮蔽壁が設けられている請求項1乃至4のいずれか一項に記載のプラズマ処理装置。 The plasma processing apparatus according to any one of claims 1 to 4, wherein a shielding wall is provided in the gap between the slit plate and the mask member to block charged particles moving along the longitudinal direction of the antenna.
PCT/JP2024/006032 2023-02-24 2024-02-20 Plasma processing device WO2024177066A1 (en)

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JP2012138411A (en) * 2010-12-24 2012-07-19 Canon Anelva Corp Plasma processing apparatus
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JP2021118114A (en) * 2020-01-27 2021-08-10 日新電機株式会社 Plasma source and plasma processing device
JP2021168276A (en) * 2020-04-13 2021-10-21 日新電機株式会社 Plasma source and plasma processing apparatus
JP2023023176A (en) * 2021-08-04 2023-02-16 日新電機株式会社 Plasma processing apparatus

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Publication number Priority date Publication date Assignee Title
JP2012138411A (en) * 2010-12-24 2012-07-19 Canon Anelva Corp Plasma processing apparatus
JP2014093226A (en) * 2012-11-05 2014-05-19 Tokyo Electron Ltd Plasma processing apparatus, and plasma generating device
JP2021118114A (en) * 2020-01-27 2021-08-10 日新電機株式会社 Plasma source and plasma processing device
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JP2023023176A (en) * 2021-08-04 2023-02-16 日新電機株式会社 Plasma processing apparatus

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