WO2016163118A1 - シート製造装置及びシート製造方法 - Google Patents
シート製造装置及びシート製造方法 Download PDFInfo
- Publication number
- WO2016163118A1 WO2016163118A1 PCT/JP2016/001919 JP2016001919W WO2016163118A1 WO 2016163118 A1 WO2016163118 A1 WO 2016163118A1 JP 2016001919 W JP2016001919 W JP 2016001919W WO 2016163118 A1 WO2016163118 A1 WO 2016163118A1
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- WIPO (PCT)
- Prior art keywords
- unit
- sheet
- moisture
- defibrating
- mixing
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/02—Patterned paper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F13/00—Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F9/00—Complete machines for making continuous webs of paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
- D21G1/00—Calenders; Smoothing apparatus
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
Definitions
- the present invention relates to a sheet manufacturing apparatus and a sheet manufacturing method.
- paper making paper making
- paper produced by a papermaking method is entangled with cellulose fibers derived from, for example, wood, and partially bound to each other by a binder (paper strength enhancer (starch glue, water-soluble resin, etc.)).
- paper strength enhancer starch glue, water-soluble resin, etc.
- the paper making method is wet, it is necessary to use a large amount of water, and after the paper is formed, there is a need for dehydration / drying, etc., and energy and time spent therefor are very large. Moreover, the used water needs to be appropriately treated as waste water. Therefore, it has become difficult to meet the recent demands for energy saving and environmental protection. In addition, the equipment used for the papermaking method often requires large utilities such as water, electric power, and drainage facilities, and it is difficult to reduce the size. From these viewpoints, as a paper manufacturing method replacing the papermaking method, a method called a dry method that uses no or little water is expected.
- Patent Document 1 discloses a used paper board obtained by applying heat and pressure by laminating a resin-impregnated sheet on a layered molded body obtained by dry defibrating waste paper and mixing with an adhesive.
- a watermark may be formed on a sheet of paper or the like.
- a watermark is formed by using a metal stamp or dandy roll in the paper manufacturing process. Since a watermark is formed using a mold or a roll, a watermark having the same design is often formed on a large amount of paper.
- One of the objects according to some aspects of the present invention is to provide a sheet manufacturing apparatus and a sheet manufacturing method capable of forming a watermark with a free design on a sheet and easily changing the design of the watermark. It is in.
- the present invention has been made to solve at least a part of the above problems, and can be realized as the following aspects or application examples.
- a defibrating unit for defibrating a raw material containing fibers in air, and a defibrated material and a resin defibrated by the defibrating unit are mixed in the air.
- the mixing unit, a depositing unit for depositing the mixture mixed by the mixing unit, a moisture applying unit for applying moisture to a part of the deposit deposited by the depositing unit, and the moisture applying unit provide the moisture.
- a sheet forming unit that pressurizes and heats the applied deposit to form a sheet having portions having different light transmittances.
- a watermark on a portion to which moisture has been imparted simply by imparting moisture to the deposit and pressurizing and heating it. Therefore, a watermark can be formed on the sheet with a free design, and the watermark design can be easily changed.
- the sheet manufacturing apparatus may include a pressurizing unit that pressurizes the deposit, and the moisture applying unit may apply the moisture to the deposit pressurized by the pressurizing unit.
- a defibrating unit for defibrating a raw material containing fibers in air, and a defibrated material and a resin defibrated by the defibrating unit are mixed in the air.
- a pressure heating unit that pressurizes and heats the first sheet to which the moisture is imparted by the moisture imparting unit to form a second sheet having a portion having a different light transmittance.
- a watermark can be formed only by pressurizing and heating the first sheet to which moisture has been applied. Therefore, it is possible to form a watermark with a free design on the second sheet, and it is easy to change the watermark design.
- the moisture applying unit may apply the moisture by an inkjet method.
- Such a sheet manufacturing apparatus can form a high-definition watermark with high accuracy.
- the moisture imparting unit may impart moisture including nanofibers.
- a defibrating step of defibrating a raw material containing fibers in the air, and a defibrated material and a resin defibrated in the defibrating step are mixed in the air.
- a sheet manufacturing method it is possible to form a watermark on a portion to which moisture has been imparted simply by imparting moisture to the deposit and heating under pressure. Therefore, a sheet on which a watermark with a free design is formed can be easily manufactured, and a sheet can be easily manufactured even if the watermark design is changed.
- a defibrating step of defibrating a raw material containing fibers in the air, and a defibrated material and a resin defibrated in the defibrating step are mixed in the air.
- a mixing step, a deposition step of depositing the mixture mixed in the mixing step, a sheet forming step of forming the first sheet by heating the deposit deposited in the deposition step, and a part of the first sheet A moisture applying step for applying moisture, and a pressure heating step for forming the second sheet having portions having different light transmittances by pressurizing and heating the first sheet to which the moisture has been applied by the moisture applying step.
- a sheet manufacturing method is a sheet manufacturing method.
- a watermark can be formed only by pressurizing and heating the first sheet to which moisture has been applied. Therefore, the second sheet on which a watermark with a free design is formed can be easily manufactured, and the second sheet can be easily manufactured even if the watermark design is changed.
- symbol A of FIG. The expansion schematic diagram of the part enclosed with the broken line shown with the code
- the sheet manufacturing apparatus of the present embodiment includes a defibrating unit that defibrates a raw material containing fibers in the air, a defibrated material and resin defibrated by the defibrating unit, and a mixing unit that mixes in air.
- the depositing part for depositing the mixture mixed by the mixing part, the moisture imparting part for imparting moisture to a part of the deposit deposited by the depositing part, for example, by an ink jet method, and the moisture imparting part by the moisture imparting part.
- a sheet forming section for forming a sheet having portions having different light transmittances by pressurizing and heating the deposited material.
- FIG. 1 is a diagram schematically illustrating a sheet manufacturing apparatus 100 according to the present embodiment.
- the sheet manufacturing apparatus 100 includes a supply unit 10, a manufacturing unit 102, and a control unit 140, as shown in FIG.
- the manufacturing unit 102 manufactures a sheet.
- the manufacturing unit 102 includes a crushing unit 12, a defibrating unit 20, a classifying unit 30, a sorting unit 40, a first web forming unit 45, a mixing unit 50, a depositing unit 60, and a second web forming unit. 70, a sheet forming unit 80, and a cutting unit 90.
- the supply unit 10 supplies raw materials to the crushing unit 12.
- the supply unit 10 is, for example, an automatic input unit for continuously supplying raw materials to the crushing unit 12.
- the raw material supplied by the supply part 10 contains fibers, such as a used paper and a pulp sheet, for example.
- the crushing unit 12 cuts the raw material supplied by the supply unit 10 in the air (in the air) or the like into pieces.
- the shape and size of the strip is, for example, a strip of several cm square.
- the crushing unit 12 has a crushing blade 14, and the charged raw material can be cut by the crushing blade 14.
- a shredder is used, for example.
- the raw material cut by the crushing unit 12 is received by the hopper 1 and then transferred (conveyed) to the defibrating unit 20 through the pipe 2.
- the defibrating unit 20 defibrates the raw material cut by the crushing unit 12.
- “defibration” means unraveling a raw material (a material to be defibrated) formed by binding a plurality of fibers into individual fibers.
- the defibrating unit 20 also has a function of separating substances such as resin particles, ink, toner, and a bleeding inhibitor adhering to the raw material from the fibers.
- the “defibrated material” includes resin particles (resins that bind multiple fibers together), ink, toner, etc. In some cases, additives such as colorants, anti-bleeding materials, and paper strength enhancing agents are included.
- the shape of the defibrated material that has been unraveled is a string shape or a ribbon shape.
- the unraveled defibrated material may exist in an unentangled state (independent state) with other undisentangled fibers, or entangled with other undisentangled defibrated material to form a lump. It may exist in a state (a state forming a so-called “dama”).
- the defibrating unit 20 defibrates in a dry manner in the air (in the air) or the like. Specifically, an impeller mill is used as the defibrating unit 20.
- the defibrating unit 20 has a function of generating an air flow that sucks the raw material and discharges the defibrated material. As a result, the defibrating unit 20 can suck the raw material together with the airflow from the introduction port 22 with the airflow generated by itself, defibrate, and transport the defibrated material to the discharge port 24.
- the defibrated material that has passed through the defibrating unit 20 is transferred to the classifying unit 30 via the tube 3.
- the classifying unit 30 classifies the defibrated material that has passed through the defibrating unit 20. Specifically, the classifying unit 30 separates and removes relatively small ones or low density ones (resin particles, colorants, additives, etc.) among the defibrated materials. Thereby, the ratio for which the fiber which is a comparatively large or high density thing among defibrated materials can be raised.
- an airflow classifier is used as the classification unit 30.
- the airflow classifier generates a swirling airflow and separates it according to the difference in centrifugal force depending on the size and density of what is classified, and the classification point can be adjusted by adjusting the speed and centrifugal force of the airflow.
- a cyclone, an elbow jet, an eddy classifier, or the like is used as the classification unit 30.
- a cyclone as shown in the figure can be suitably used as the classifying unit 30 because of its simple structure.
- the classification unit 30 includes, for example, an inlet 31, a cylindrical part 32 to which the inlet 31 is connected, an inverted conical part 33 that is located below the cylindrical part 32 and continues to the cylindrical part 32, and an inverted conical part 33.
- the lower discharge port 34 provided in the lower center of the upper portion and the upper discharge port 35 provided in the upper center of the cylindrical portion 32 are provided.
- the classification unit 30 includes fibers (first classified material) larger than the resin particles and ink particles in the defibrated material, and the defibrated material. Among them, it can be separated into resin particles, colorants, additives, etc. (second classified product) that are smaller than the fibers and have a low density.
- the first classified product is discharged from the lower discharge port 34 and is introduced into the sorting unit 40 through the pipe 4.
- the second classified product is discharged from the upper discharge port 35 to the receiving portion 36 through the pipe 5.
- the sorting unit 40 introduces the first classified product (defibrated material defibrated by the defibrating unit 20) that has passed through the classifying unit 30 from the introduction port 42, and sorts the first classified product according to the length of the fiber.
- the selection unit 40 for example, a sieve is used.
- the sorting unit 40 has a net (filter, screen), and includes fibers or particles (those that pass through the net, the first sort) that are smaller than the mesh size included in the first classification, Fibers that are larger than the size of the mesh, undefibrated pieces, and lumps (those that do not pass through the net, second selection) can be separated.
- the first selection is received by the hopper 6 and then transferred to the mixing unit 50 via the pipe 7.
- the second selected item is returned to the defibrating unit 20 from the discharge port 44 through the pipe 8.
- the sorting unit 40 is a cylindrical sieve that can be rotated by a motor.
- a metal net for example, an expanded metal obtained by extending a cut metal plate, or a punching metal in which a hole is formed in the metal plate by a press machine or the like is used.
- the first web forming unit 45 conveys the first sorted product that has passed through the sorting unit 40 to the mixing unit 50.
- the first web forming unit 45 includes a mesh belt 46, a stretching roller 47, and a suction unit (suction mechanism) 48.
- the suction unit 48 can suck the first sorted material dispersed in the air through the opening (opening of the mesh) of the sorting unit 40 onto the mesh belt 46.
- the first selection is deposited on the moving mesh belt 46 to form the web V.
- the basic configurations of the mesh belt 46, the stretching roller 47, and the suction unit 48 are the same as the mesh belt 72, the stretching roller 74, and the suction mechanism 76 of the second web forming unit 70 described later.
- the web V is formed in a soft and swelled state containing a lot of air by passing through the sorting unit 40 and the first web forming unit 45.
- the web V deposited on the mesh belt 46 is put into the tube 7 and conveyed to the mixing unit 50.
- the mixing unit 50 mixes the first sorted product that has passed through the sorting unit 40 (the first sorted product conveyed by the first web forming unit 45) and the additive containing resin.
- the mixing unit 50 includes an additive supply unit 52 that supplies the additive, a pipe 54 that conveys the first selected product and the additive, and a blower 56.
- the additive is supplied from the additive supply unit 52 to the pipe 54 via the hopper 9.
- the tube 54 is continuous with the tube 7.
- the mechanism which mixes a 1st selection material and an additive is not specifically limited, It may stir with the blade
- the additive supply unit 52 As the additive supply unit 52, a screw feeder as shown in FIG. 1 or a disk feeder (not shown) is used.
- the additive supplied from the additive supply unit 52 includes a resin for binding a plurality of fibers. At the time when the resin is supplied, the plurality of fibers are not bound. The resin melts when passing through the sheet forming portion 80 and binds a plurality of fibers.
- the resin supplied from the additive supply unit 52 is a thermoplastic resin or a thermosetting resin.
- a thermoplastic resin or a thermosetting resin for example, AS resin, ABS resin, polypropylene, polyethylene, polyvinyl chloride, polystyrene, acrylic resin, polyester resin, polyethylene terephthalate, Polyphenylene ether, polybutylene terephthalate, nylon, polyamide, polycarbonate, polyacetal, polyphenylene sulfide, polyether ether ketone, and the like. These resins may be used alone or in combination.
- the additive supplied from the additive supply unit 52 may be fibrous or powdery.
- the additive supplied from the additive supply unit 52 prevents coloring of the fibers and the aggregation of the fibers depending on the type of sheet to be produced.
- An anti-agglomeration material, a flame retardant for making the fiber and the like difficult to burn may be included.
- the mixture (mixture of the first selection product and the additive) that has passed through the mixing unit 50 is transferred to the deposition unit 60 via the pipe 54.
- the depositing unit 60 introduces the mixture that has passed through the mixing unit 50 from the introduction port 62, loosens the entangled defibrated material (fibers), and drops the mixture while dispersing it in the air (in the air) or the like. Furthermore, when the additive resin supplied from the additive supply unit 52 is fibrous, the deposition unit 60 loosens the entangled resin. Thereby, the deposition unit 60 can deposit the mixture on the second web forming unit 70 with good uniformity.
- Rotating cylindrical sieve is used as the accumulation unit 60.
- the deposition unit 60 has a net, and drops fibers or particles (those that pass through the net) included in the mixture that has passed through the mixing unit 50 that are smaller than the mesh opening size.
- the configuration of the deposition unit 60 is the same as the configuration of the sorting unit 40, for example.
- the “sieving” of the accumulation unit 60 may not have a function of selecting a specific object. That is, the “sieving” used as the depositing unit 60 means that the net is provided, and the depositing unit 60 may drop all of the mixture introduced into the depositing unit 60.
- the second web forming unit 70 deposits the passing material that has passed through the depositing unit 60 to form the web W.
- the second web forming unit 70 includes, for example, a mesh belt 72, a tension roller 74, and a suction mechanism 76.
- the mesh belt 72 accumulates the passing material that has passed through the opening (opening of the mesh) of the accumulation unit 60 while moving.
- the mesh belt 72 is stretched by a stretching roller 74, and is configured to allow air to pass therethrough.
- the mesh belt 72 moves as the stretching roller 74 rotates. While the mesh belt 72 continuously moves, the passing material that has passed through the accumulation portion 60 is continuously piled up, whereby the web W is formed on the mesh belt 72.
- the mesh belt 72 is made of, for example, metal, resin, cloth, or non-woven fabric.
- the suction mechanism 76 is provided below the mesh belt 72 (on the side opposite to the accumulation unit 60 side).
- the suction mechanism 76 can generate an air flow directed downward (air flow directed from the accumulation unit 60 toward the mesh belt 72).
- the suction mechanism 76 By the suction mechanism 76, the mixture dispersed in the air by the deposition unit 60 can be sucked onto the mesh belt 72. Thereby, the discharge speed from the deposition part 60 can be increased.
- the suction mechanism 76 can form a downflow in the dropping path of the mixture, and can prevent the defibrated material and additives from being entangled during the dropping.
- the web W in a soft and swelled state containing a large amount of air is formed.
- the web W deposited on the mesh belt 72 is conveyed to the sheet forming unit 80.
- a humidity control unit 78 that adjusts the humidity of the web W is provided.
- the humidity control unit 78 can adjust the amount ratio of the web W and water by adding water or water vapor to the web W.
- the sheet forming unit 80 forms the sheet S by pressurizing and heating the web W deposited on the mesh belt 72.
- the sheet forming unit 80 by heating the mixture of the defibrated material and the additive mixed in the web W, the plurality of fibers in the mixture are bound to each other via the additive (resin). Can do.
- the sheet forming unit 80 for example, a heating roller (heater roller), a hot press molding machine, a hot plate, a hot air blower, an infrared heater, or a flash fixing device is used.
- the sheet forming unit 80 includes a first binding unit 82 and a second binding unit 84, and the binding units 82 and 84 each include a pair of heating rollers 86. Since the binding portions 82 and 84 are configured as the heating roller 86, the web W is continuously conveyed as compared with the case where the binding portions 82 and 84 are configured as a plate-like press device (flat plate press device). Sheet S can be formed.
- the number of heating rollers 86 is not particularly limited.
- the cutting unit 90 cuts the sheet S formed by the sheet forming unit 80.
- the cutting unit 90 includes a first cutting unit 92 that cuts the sheet S in a direction that intersects the conveyance direction of the sheet S, and a second cutting unit 94 that cuts the sheet S in a direction parallel to the conveyance direction. ,have.
- the second cutting unit 94 cuts the sheet S that has passed through the first cutting unit 92, for example.
- a single-sheet sheet S having a predetermined size is formed.
- the cut sheet S is discharged to the discharge unit 96.
- fiber is used as part of the raw material.
- fibers include natural fibers (animal fibers, plant fibers), chemical fibers (organic fibers, inorganic fibers, organic-inorganic composite fibers), and the like, as long as the fibers form hydrogen bonds between the fibers.
- examples of the fiber include fibers made of cellulose, silk, wool, cotton, cannabis, kenaf, flax, ramie, jute, manila hemp, sisal hemp, conifer, hardwood, etc., and these may be used alone.
- they may be used by appropriately mixing them, or may be used as regenerated fibers that have been purified.
- the fiber may be dried, and liquids, such as water and an organic solvent, may be contained or impregnated.
- the fiber may be subjected to various surface treatments.
- the average diameter (if the cross section is not a circle, the largest one among the lengths in the direction perpendicular to the longitudinal direction) Or, when a circle having an area equal to the area of the cross section is assumed, the diameter of the circle (equivalent circle diameter) is 1 ⁇ m or more and 1000 ⁇ m or less on average.
- the length of the fiber included in the sheet of the present embodiment is not particularly limited, but as an independent single fiber, the length along the longitudinal direction of the fiber is 1 ⁇ m or more and 5 mm or less. Further, the average length of the fibers is 20 ⁇ m or more and 3600 ⁇ m or less as a length weighted average fiber length. Furthermore, the length of the fiber may have variation (distribution).
- the term “fiber” may refer to a single fiber and may refer to an aggregate of a plurality of fibers (for example, a cotton-like state).
- the fiber may be a fiber (defibrated material) that has been disentangled into a fibrous shape by defibrating the material to be defibrated.
- the material to be defibrated for example, fibers such as pulp sheet, paper, waste paper, tissue paper, kitchen paper, cleaner, filter, liquid absorbent material, sound absorber, cushioning material, mat, cardboard are entangled or bound. It points to what was done.
- the material to be defibrated may be the sheet of the present embodiment or the sheet after use (old sheet).
- rayon, lyocell, cupra, vinylon, acrylic, nylon, aramid, polyester, polyethylene, polypropylene, polyurethane, polyimide, carbon, glass, metal fibers (organic fiber, inorganic fiber, organic fiber, etc.) Inorganic composite fibers) may be included.
- an additive containing a resin is supplied from the additive supply unit 52. That is, the additive supplied from the additive supply unit 52 includes a resin for binding a plurality of fibers. At the time when the additive is supplied, the plurality of fibers are not bound. The additive resin melts or softens when passing through the sheet forming portion 80 to bind a plurality of fibers.
- the additive supplied from the additive supply unit 52 may be, for example, a composite (particle) in which at least a part of the surface of the resin particle is covered with inorganic fine particles. Further, the complex may be used alone or appropriately mixed with other substances. Furthermore, the additive may include nanofibers. Examples of nanofibers include cellulose nanofibers. Cellulose nanofibers are finely pulverized plant fibers (cellulose fibers), and have a thickness of, for example, several nm to several tens of nm. When nanofibers are blended with the additive, moisture is imparted between the fibers, and when this evaporates (drys), hydrogen bonds between the fibers of the material to be defibrated can be strengthened by the nanofibers.
- the resin is supplied from the additive supply unit 52 and receives a frictional charging action when passing through the mixing unit 50 and the deposition unit 60.
- the charged resin adheres to the fibers and is also deposited on the mesh belt 72 together with the fibers, and adheres (electrostatically attracts) to the fibers even in the state of the web W.
- the type of resin may be either a natural resin or a synthetic resin, and may be either a thermoplastic resin or a thermosetting resin.
- the resin is preferably solid at normal temperature, and a thermoplastic resin is more preferable in view of binding fibers by heat in the sheet forming unit 80.
- Examples of natural resins include rosin, dammar, mastic, copal, phlegm, shellac, phlebotomy, sandalac, colophonium, etc., and those that are used alone or as appropriate mixed, and these are appropriately modified. Also good.
- thermosetting resin examples include thermosetting resins such as phenol resin, epoxy resin, melamine resin, urea resin, unsaturated polyester resin, alkyd resin, polyurethane, and thermosetting polyimide resin.
- thermoplastic resins include AS resin, ABS resin, polypropylene, polyethylene, polyvinyl chloride, polystyrene, acrylic resin, polyester resin, polyethylene terephthalate, polyphenylene ether, polybutylene terephthalate, nylon, polyamide, polycarbonate, Examples include polyacetal, polyphenylene sulfide, polyether ether ketone, and the like.
- the resin may be a copolymerized or modified type.
- resin systems include styrene resins, acrylic resins, styrene-acrylic copolymer resins, olefin resins, chlorinated resins.
- vinyl resins examples include vinyl resins, polyester resins, polyamide resins, polyurethane resins, polyvinyl alcohol resins, vinyl ether resins, N-vinyl resins, and styrene-butadiene resins.
- the resin may contain a colorant for coloring the fiber and a flame retardant for making the fiber difficult to burn. When at least one of these is included, it can be easily obtained by blending them into the resin by melt kneading.
- the mixing unit 50 the above-described fibers and the resin are mixed, and the mixing ratio thereof can be appropriately adjusted depending on the strength, use, and the like of the sheet S to be manufactured.
- the ratio of the resin to the fibers is 5% by mass or more and 70% by mass or less, and in view of obtaining good mixing in the mixing unit 50, and the mixture in sheet form From the viewpoint of making it difficult for the resin to be detached due to the air current generated by gravity and the suction mechanism 76, it is preferably 5% by mass or more and 50% by mass or less.
- the sheet manufacturing apparatus 100 includes a moisture imparting unit 150. 2 and 3 correspond to a portion surrounded by a broken line indicated by reference numeral A in FIG. 1, and show a configuration including a pressurizing unit 160, a moisture applying unit 150, and a part of the sheet forming unit 80.
- the moisture applying unit 150 is provided in the sheet manufacturing apparatus 100 on the downstream side of the configuration in which the web W is formed (deposition unit 60). Further, the moisture applying unit 150 is provided on the upstream side of the configuration in which the web W is heated to form the sheet S (sheet forming unit 80). In the sheet manufacturing apparatus 100 of this embodiment, the sheet forming unit 80 is provided upstream of the first binding unit 82 (sheet forming unit).
- the moisture application unit 150 applies moisture to a part of the deposit (web W) deposited by the deposition unit 60.
- the moisture imparting unit 150 does not impart moisture to the entire deposit, and is different from the humidity conditioning unit 78 described above that regulates the web W at least in this respect.
- moisture-content provision part 150 provides a water
- the mass of moisture per unit area of the web W given to the web W by the moisture applying unit 150 is, for example, per unit area of the web W of moisture given as mist in the humidity control unit 78. It is several to several tens of times the mass.
- the amount of moisture imparted to the web W by the moisture imparting unit 150 is the type and amount of fibers and resin in the web W, the heat of evaporation of moisture, the amount of heat imparted by the heating unit (sheet forming unit 80), and the sheet S. It is set as appropriate in consideration of the mechanical strength of the given area.
- the moisture applying unit 150 is configured by, for example, an ink jet recording type recording head 152.
- the recording head 152 is depicted.
- the recording head 152 may be a so-called line type head or a serial type head. In the case where the recording head 152 is a line-type head, a configuration for performing scanning of the recording head 152 is unnecessary, and the apparatus can be downsized.
- the recording method of the recording head 152 is not particularly limited as long as moisture can be ejected as droplets from the nozzle holes of the recording head 152 to adhere the droplets to the web W.
- a method of the recording head 152 an electrostatic suction method, a method of ejecting liquid droplets by pump pressure, a method of using a piezoelectric element, a method of heating and foaming liquid with a microelectrode, and ejecting liquid droplets, etc. Can do.
- the moisture applying unit 150 can appropriately include configurations of a housing, a carriage mechanism of the recording head 152, various driving units, various control units, sensors, a tray, an operation panel, and the like.
- the moisture applying unit 150 includes the on-demand type recording head 152, an arbitrary amount of moisture can be applied to an arbitrary position of the web W very accurately.
- the moisture applying unit 150 may be configured by a dispenser (not shown) or the like. It is preferable that the moisture applying unit 150 is configured to be able to apply moisture with a free design like the recording head 152 or the dispenser. In the sheet manufacturing apparatus 100 of the present embodiment, the moisture application unit 150 is configured by the recording head 152, so that it is possible to apply moisture to the web W with high positional accuracy.
- the moisture imparted to the web W by the moisture imparting unit 150 may be water, an aqueous solution, or a dispersion using water as a medium. That is, water is preferably water, an aqueous solution, an aqueous dispersion, or the like. Furthermore, the above-mentioned cellulose nanofiber may be dispersed as an aqueous dispersion. By applying cellulose nanofibers to the web W together with water, hydrogen bonding between the fibers of the web W can be strengthened. As water, it is preferable to use pure water or ultrapure water such as ion exchange water, ultrafiltration water, reverse osmosis water, and distilled water. In particular, water obtained by sterilizing these waters by ultraviolet irradiation or addition of hydrogen peroxide is preferable because generation of mold and bacteria can be suppressed over a long period of time.
- the moisture applying unit 150 is configured by the recording head 152 that applies moisture only from one surface of the web W.
- the recording head 152 may be provided so that moisture can be applied to both surfaces of the web W.
- the moisture applying unit 150 may include a plurality of recording heads 152, and may be used in combination with other configurations (such as liquid nozzles) without being limited to the recording head 152.
- the sheet manufacturing apparatus 100 of the present embodiment includes a pressurizing unit 160.
- the pressurizing unit 160 is provided on the downstream side of the configuration in which the web W is formed (deposition unit 60).
- the pressurizing unit 160 is provided on the upstream side of the configuration in which the web W is heated to form the sheet S (sheet forming unit 80).
- the pressurizing unit 160 is provided on the downstream side of the deposition unit 60 and on the upstream side of the moisture applying unit 150.
- the pressurizing unit 160 may be provided downstream of the moisture applying unit 150 and upstream of the heating unit (first binding unit 82).
- the pressurizing unit 160 is a pair of calendar rollers 162 and applies pressure to the web W. By applying pressure to the web W, the thickness of the web W is reduced, and the density of the web W is increased.
- the pressure unit 160 can apply a pressure higher than the pressure applied to the web W by the first binding unit 82 (sheet forming unit 80).
- the pressurization part 160 is not an essential structure, when the pressurization part 160 is provided in the upstream rather than the moisture provision part 150, the density of the web W is raised and the space
- the web W is pressurized and heated in the sheet forming unit 80 to bind the fibers and the resin.
- the resin is softened and bound to the fiber, and the moisture imparted by the moisture imparting unit 150 is evaporated. As water evaporates, hydrogen bonds are induced between the fibers.
- the fibers are bound by the resin.
- the thickness of the sheet S increases due to the elasticity of the fibers when the pressure is lost after passing through the sheet forming unit 80. .
- hydrogen bonding occurs in addition to the binding by the resin, and therefore the degree of restoration of the thickness of the sheet S is smaller than that in the region to which moisture has not been applied.
- seat S becomes high in the area
- the amount of voids in the sheet S is smaller in the region to which moisture is applied than in the region to which moisture is not applied.
- a relatively high density part and a relatively low density part in the sheet S can be formed.
- a sheet S having a high density portion can be formed.
- a relatively high density portion (region) is referred to as a “high density portion (region)”
- a relatively low density portion (region) is referred to as a “low density portion. (Region) ".
- the high density portion (region) of the sheet S has a small number of voids and / or a small size of the voids. Therefore, light scattering is less likely to occur in the high density portion than in the low density portion. Therefore, the high-density portion has higher light transmittance and lower light reflectance than the relatively low-density portion. For this reason, a watermark pattern can be formed on the sheet S by the high density portion (the portion to which moisture is applied) and the low density portion.
- FIG. 4 is a schematic diagram illustrating an example of a mode in which the sheet S is manufactured by the sheet manufacturing apparatus 100 of the present embodiment.
- moisture is imparted to the web W by the moisture imparting unit 150, a moisture imparting region 154 is formed, and the web W passes through the sheet forming unit 80 (pressure heating unit) to become a sheet S.
- region 156 is formed in the position corresponding to the moisture provision area
- the region to which moisture is applied becomes a high-density region 156 when the sheet S is formed, and the light transmittance can be increased.
- region 158 can be formed in the sheet
- such a watermark can be easily formed when the sheet S is manufactured.
- the moisture applying unit 150 (recording head 152) is an ink jet method, the portion to which moisture is applied can be freely changed at an arbitrary timing. Therefore, a watermark can be formed on the sheet S with a free design, and the watermark design can be easily changed.
- FIG. 5 is a schematic view showing a part of a sheet manufacturing apparatus 200 according to a modified embodiment.
- a sheet manufacturing apparatus according to a modified embodiment includes a defibrating unit that defibrates a raw material containing fibers in air, and a mixing unit that mixes the defibrated material and resin defibrated by the defibrating unit in air.
- the sheet manufacturing apparatus 200 includes a supply unit, a manufacturing unit, and a control unit, and the manufacturing unit includes a crushing unit 12 and a defibrating unit.
- Unit 20 classifying unit 30, sorting unit 40, first web forming unit 45, mixing unit 50, stacking unit 60, second web forming unit 70, sheet forming unit 80, cutting unit 90, , And a discharge unit 96. Since these configurations in the sheet manufacturing apparatus 200 according to the modified embodiment are the same as those in the sheet manufacturing apparatus 100 according to the above-described embodiment, detailed description will be omitted by attaching the same reference numerals. In FIG. 5, the configuration upstream of the sheet forming unit 80 is omitted.
- a single sheet S that passes through the sheet forming unit 80 (heating unit) and the cutting unit 90 and is received by the discharge unit 96 is transferred by the feed roller 202, and the recording head 152 (moisture application) Part 150) provides moisture to a part of the sheet S. Then, the sheet S to which moisture has been applied is pressurized and heated by the hot press 204 (pressure heating unit) to form the high density region 156 in the sheet S (sheet S ′).
- FIG. 6 is a schematic diagram illustrating an example of a mode in which the sheet S is manufactured by the sheet manufacturing apparatus 200 according to the modified embodiment.
- moisture is applied to the sheet S (first sheet) by the moisture application unit 150 to form a moisture application region 154, and the first sheet is pressurized and heated by the pressure heating unit (heat press 204).
- the pressure heating unit heat press 204
- the moisture imparting region 154 to which moisture has been imparted by the moisture imparting unit 150 (recording head 152) becomes a high density region 156 when it becomes the sheet S ′ (second sheet) and transmits light.
- the rate can be increased.
- the high density region 156 and the low density region 158 can be formed on the sheet S ′ (second sheet), and a watermark can be formed.
- the sheet manufacturing apparatus 200 of the modified embodiment since the moisture applying unit 150 (recording head 152) is an ink jet system, a portion to which moisture is applied can be freely changed. Therefore, a watermark can be formed on the sheet S (first sheet) with a free design, and the watermark design can be easily changed.
- the sheet S (first sheet) to which moisture is applied by the sheet manufacturing apparatus 200 of the modified embodiment may be a sheet having a uniform density, or a sheet in which the high density region 156 has already been formed. May be. That is, the sheet manufacturing apparatus 200 according to the modified embodiment can form the high density region 156 by applying moisture to the low density region 158. Therefore, in the sheet manufacturing apparatus 200 according to the modified embodiment, the moisture applying unit 150 may not be provided on the upstream side of the sheet forming unit 80. Further, in the sheet manufacturing apparatus 200 according to the modified embodiment, the configuration upstream of the sheet forming unit 80 can be the same as that of the sheet manufacturing apparatus 100 according to the above-described embodiment, and the moisture applying unit 150 and the pressure heating unit. You may make it have two sets of.
- the sheet manufacturing method of the present embodiment includes a defibrating process, a mixing process, a deposition process, a moisture application process, and a sheet forming process. More specifically, in the defibrating process, the raw material containing fibers is defibrated in the air, and in the mixing process, the defibrated material and resin defibrated in the defibrating process are mixed in the air, and the deposition process Deposits the mixture mixed in the mixing step, the moisture applying step applies moisture to a part of the deposit deposited in the depositing step, for example, by an ink jet method, and the sheet forming step is a moisture applying step. The deposit to which moisture has been applied is heated under pressure to form a sheet having portions with different light transmittances.
- the sheet manufacturing method of the present embodiment can be performed using, for example, the sheet manufacturing apparatus 100 described above.
- the defibrating step can be performed by the defibrating unit 20 described above.
- the mixing step can be performed by the mixing unit 50 described above.
- the deposition process can be performed by the deposition unit 60 described above.
- the moisture application step can be performed by the above-described moisture application unit 150.
- the sheet forming step can be performed by the above-described sheet forming unit 80 (pressure heating unit).
- the fiber and resin used in the sheet manufacturing method of the present embodiment are the same as those described in the section of the sheet manufacturing apparatus described above, detailed description is omitted.
- the sheet manufacturing method of the present embodiment light scattering can be reduced in the high density region 156 in the sheet S corresponding to the moisture application region 154 of the web W.
- the light transmittance and / or the light reflectance of the high density region 156 and the low density region 158 can be made different, and the sheet S on which the watermark is formed can be easily manufactured.
- the sheet manufacturing method of the modified embodiment includes a defibrating step, a mixing step, a deposition step, a sheet forming step, a moisture applying step, and a pressure heating step. More specifically, in the defibrating process, the raw material containing fibers is defibrated in the air, and in the mixing process, the defibrated material and resin defibrated in the defibrating process are mixed in the air, and the deposition process Deposits the mixture mixed in the mixing step, the sheet forming step heats the deposit deposited in the deposition step to form the first sheet, and the moisture applying step forms part of the first sheet, For example, moisture is imparted by an ink jet method, and in the pressure heating step, the first sheet to which moisture has been imparted by the moisture imparting step is pressurized and heated to form a second sheet having portions having different light transmittances.
- the sheet manufacturing method of the modified embodiment can be performed using the above-described sheet manufacturing apparatus 200, for example.
- the defibrating step can be performed by the defibrating unit 20 described above.
- the mixing step can be performed by the mixing unit 50 described above.
- the deposition process can be performed by the deposition unit 60 described above.
- the sheet forming step can be performed by the sheet forming unit 80 described above.
- the moisture application step can be performed by the above-described moisture application unit 150.
- the pressurizing and heating step can be performed by the above-described sheet forming unit 80 or hot press 204 (pressurizing and heating unit).
- light scattering can be reduced in the high density region 156 of the second sheet corresponding to the moisture application region 154 of the first sheet.
- the light transmittance and / or the light reflectance of the high density region 156 and the low density region 158 can be made different, and the second sheet on which the watermark is formed can be easily manufactured.
- Sheet The sheet manufactured by the sheet manufacturing apparatus or the sheet manufacturing method of the above embodiment has a high density region and a low density region as described above. Such a sheet has a high-definition watermark as a result of moisture being applied, for example, by an inkjet method.
- the sheet is formed from at least the above-described fibers and resin as a raw material and formed into a sheet shape, a board shape, a web shape, or an uneven shape.
- the sheet in this specification can be classified into paper and non-woven fabric.
- the paper includes, for example, a mode in which pulp or waste paper is used as a raw material and is formed into a sheet shape, and includes recording paper for writing and printing, wallpaper, wrapping paper, colored paper, drawing paper, Kent paper, and the like.
- Non-woven fabrics are thicker than paper or have low strength. General nonwoven fabrics, fiber boards, tissue papers (cleaning tissue papers), kitchen papers, cleaners, filters, liquid (waste ink and oil) absorbents, sound absorption Materials, cushioning materials, mats, etc.
- the raw material may be plant fibers such as cellulose, chemical fibers such as PET (polyethylene terephthalate) and polyester, and animal fibers such as wool and silk.
- the term “homogeneous” means that, in the case of uniform dispersion or mixing, in an object that can define two or more components or two or more components, one component is relative to another component. This means that the existing positions are uniform throughout the system, or the same or substantially equal to each other in each part of the system. Further, the uniformity of coloration and the uniformity of color tone indicate that there is no color shading when the sheet is viewed in plan, and the density is uniform.
- a part of the configuration may be omitted within a range having the characteristics and effects described in the present application, or each embodiment or modification may be combined.
- the present invention includes configurations that are substantially the same as the configurations described in the embodiments (configurations that have the same functions, methods, and results, or configurations that have the same objects and effects).
- the invention includes a configuration in which a non-essential part of the configuration described in the embodiment is replaced.
- the present invention includes a configuration that exhibits the same operational effects as the configuration described in the embodiment or a configuration that can achieve the same object.
- the invention includes a configuration in which a known technique is added to the configuration described in the embodiment.
- additive supply Part 54 ... pipe, 56 ... blower, 60 ... deposition part, 62 ... introduction port, 70 ... second web forming part, 72 ... mesh belt, 74 ... tension roller, 76 ... suction mechanism, 78 ... humidity control part, 80 ... sheet forming part, 82 ... first binding part, 84 ... second binding part, 86 ... heating roller, 90 ... cutting , 92 ... 1st cutting part, 94 ... 2nd cutting part, 96 ... Discharging part, 100 ... Sheet manufacturing apparatus, 102 ... Manufacturing part, 140 ... Control part, 150 ... Moisture applying part, 152 ... Recording head, 154 ... Moisture application region, 156 ... high density region, 158 ... low density region, 160 ... pressurizing unit, 162 ... calender roller, 200 ... sheet manufacturing apparatus, 202 ... roller, 204 ... heat press, 206 ... tray, V ... web, W ... Web, S ... Sheet
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Abstract
Description
1.1. 構成
まず、本実施形態に係るシート製造装置について、図面を参照しながら説明する。図1は、本実施形態に係るシート製造装置100を模式的に示す図である。
本実施形態のシート製造装置100において、繊維は原料の一部として使用される。係る繊維としては、天然繊維(動物繊維、植物繊維)、化学繊維(有機繊維、無機繊維、有機無機複合繊維)などが挙げられるが、繊維間に水素結合が形成される繊維であればよい。更に詳しくは、繊維としては、セルロース、絹、羊毛、綿、大麻、ケナフ、亜麻、ラミー、黄麻、マニラ麻、サイザル麻、針葉樹、広葉樹等からなる繊維が挙げられ、これらを単独で用いてもよいし、適宜混合して用いてもよいし、精製などを行った再生繊維として用いてもよい。また、繊維は、乾燥されていてもよいし、水、有機溶剤等の液体が含有又は含浸されていてもよい。さらに繊維は、各種の表面処理が施されていてもよい。
本実施形態のシート製造装置100では、添加物供給部52から樹脂を含む添加物が供給される。すなわち添加物供給部52から供給される添加物は、複数の繊維を結着させるための樹脂を含む。添加物が供給された時点では、複数の繊維は結着されていない。添加物の樹脂は、シート形成部80を通過する際に溶融又は軟化して、複数の繊維を結着させる。
本実施形態のシート製造装置100は、水分付与部150を有する。図2及び図3は、図1の符号Aで示した破線で囲まれた部分に相当し、加圧部160、水分付与部150及びシート形成部80の一部を含む構成を示している。
図2及び図3に示すように、本実施形態のシート製造装置100は、加圧部160を有している。加圧部160は、シート製造装置100において、ウェブWが形成される構成(堆積部60)よりも下流側に設けられる。また、加圧部160は、ウェブWが加熱されてシートSとされる構成(シート形成部80)よりも上流側に設けられる。図2に示すシート製造装置100では、加圧部160は、堆積部60よりも下流側であって水分付与部150よりも上流側に設けられている。なお、図3に示すように、加圧部160は、水分付与部150よりも下流側であって加熱部(第1結着部82)よりも上流側に設けられてもよい。
水分は、ウェブWに付与された際に、ウェブWを構成する繊維や樹脂を濡らす。ウェブWの水分が付与された部分では、加熱部(シート形成部80)によって加圧加熱されて水分が蒸発する際に、繊維間の水素結合を誘発する。これにより、ウェブWの水分が付与された部分は、水分が付与されない部分よりも高密度化される。
図5は、変形実施形態に係るシート製造装置200の一部を示す模式図である。変形実施形態に係るシート製造装置は、繊維を含む原料を気中で解繊する解繊部と、解繊部により解繊された解繊物と樹脂とを、気中で混合する混合部と、混合部により混合された混合物を堆積させる堆積部と、堆積部により堆積された堆積物を加熱して第1シートを成形するシート形成部と、第1シートの一部に、例えばインクジェット法により、水分を付与する水分付与部と、水分付与部により前記水分が付与された第1シートを加圧加熱して、光透過率の異なる部分を有する第2シートを成形する加圧加熱部と、を備える。
本実施形態のシート製造方法は、解繊工程と、混合工程と、堆積工程と、水分付与工程と、シート形成工程と、を含む。より詳細には、解繊工程は、繊維を含む原料を気中で解繊し、混合工程は、解繊工程で解繊された解繊物と樹脂とを、気中で混合し、堆積工程は、混合工程で混合された混合物を堆積させ、水分付与工程は、堆積工程で堆積された堆積物の一部に、例えばインクジェット法により、水分を付与し、シート形成工程は、水分付与工程で水分が付与された堆積物を加圧加熱して、光透過率の異なる部分を有するシートを成形する。
上記実施形態のシート製造装置、又はシート製造方法によって製造されるシートは、上述の通り、高密度領域と低密度領域とを有する。係るシートは、例えばインクジェット法によって水分が付与される結果、高精細な透かしを有する。
本明細書において、「均一」との文言は、均一な分散や混合という場合には、2種以上又は2相以上の成分を定義できる物体において、1つの成分の他の成分に対する相対的な存在位置が、系全体において一様、又は系の各部分において互いに同一若しくは実質的に等しいことを指す。また、着色の均一性や色調の均一性は、シートを平面視したときに色の濃淡がなく、一様な濃度であることを指す。
Claims (7)
- 繊維を含む原料を気中で解繊する解繊部と、
前記解繊部により解繊された解繊物と樹脂とを、気中で混合する混合部と、
前記混合部により混合された混合物を堆積させる堆積部と、
前記堆積部により堆積された堆積物の一部に、水分を付与する水分付与部と、
前記水分付与部により前記水分が付与された堆積物を加圧加熱して、光透過率の異なる部分を有するシートを成形するシート形成部と、を備えることを特徴とする、シート製造装置。 - 前記堆積物を加圧する加圧部を備え、
前記水分付与部は、前記加圧部により加圧された堆積物に、前記水分を付与することを特徴とする、請求項1に記載のシート製造装置。 - 繊維を含む原料を気中で解繊する解繊部と、
前記解繊部により解繊された解繊物と樹脂とを、気中で混合する混合部と、
前記混合部により混合された混合物を堆積させる堆積部と、
前記堆積部により堆積された堆積物を加熱して第1シートを成形するシート形成部と、
前記第1シートの一部に、水分を付与する水分付与部と、
前記水分付与部により前記水分が付与された第1シートを加圧加熱して、光透過率の異なる部分を有する第2シートを成形する加圧加熱部と、を備えることを特徴とする、シート製造装置。 - 前記水分付与部は、インクジェット法により前記水分を付与することを特徴とする、請求項1ないし請求項3のいずれか一項に記載のシート製造装置。
- 前記水分付与部は、ナノ繊維を含む水分を付与することを特徴とする、請求項1ないし請求項4のいずれか一項に記載のシート製造装置。
- 繊維を含む原料を気中で解繊する解繊工程と、
前記解繊工程で解繊された解繊物と樹脂とを、気中で混合する混合工程と、
前記混合工程で混合された混合物を堆積させる堆積工程と、
前記堆積工程で堆積された堆積物の一部に、水分を付与する水分付与工程と、
前記水分付与工程で前記水分が付与された堆積物を加圧加熱して、光透過率の異なる部分を有するシートを成形するシート形成工程と、を含むことを特徴とする、シート製造方法。 - 繊維を含む原料を気中で解繊する解繊工程と、
前記解繊工程で解繊された解繊物と樹脂とを、気中で混合する混合工程と、
前記混合工程で混合された混合物を堆積させる堆積工程と、
前記堆積工程で堆積された堆積物を加熱して第1シートを成形するシート形成工程と、
前記第1シートの一部に、水分を付与する水分付与工程と、
前記水分付与工程により前記水分が付与された第1シートを加圧加熱して、光透過率の異なる部分を有する第2シートを成形する加圧加熱工程と、を含むことを特徴とする、シート製造方法。
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US15/561,377 US10428466B2 (en) | 2015-04-06 | 2016-04-05 | Sheet manufacturing apparatus and sheet manufacturing method |
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Also Published As
Publication number | Publication date |
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EP3281756A1 (en) | 2018-02-14 |
TW201700831A (zh) | 2017-01-01 |
JPWO2016163118A1 (ja) | 2018-02-01 |
US20180080176A1 (en) | 2018-03-22 |
CN107428024A (zh) | 2017-12-01 |
EP3281756A4 (en) | 2018-12-12 |
JP6743808B2 (ja) | 2020-08-19 |
US10428466B2 (en) | 2019-10-01 |
EP3281756B1 (en) | 2022-06-01 |
CN107428024B (zh) | 2020-07-28 |
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