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US20030040622A1 - Method for the preparation of modified cellulose ethers - Google Patents

Method for the preparation of modified cellulose ethers Download PDF

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Publication number
US20030040622A1
US20030040622A1 US09/463,498 US46349800A US2003040622A1 US 20030040622 A1 US20030040622 A1 US 20030040622A1 US 46349800 A US46349800 A US 46349800A US 2003040622 A1 US2003040622 A1 US 2003040622A1
Authority
US
United States
Prior art keywords
cellulose
cellulose ether
akd
alkyl
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US09/463,498
Other languages
English (en)
Inventor
Mikko Lahteenmaki
Heidi Kahkonen
Goran Kloow
Oliver Ruppert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Metsa Specialty Chemicals Oy
Original Assignee
Metsa Specialty Chemicals Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metsa Specialty Chemicals Oy filed Critical Metsa Specialty Chemicals Oy
Assigned to METSA SPECIALTY CHEMICALS OY reassignment METSA SPECIALTY CHEMICALS OY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KLOOW, GOERAN, KAEHKOENEN, HEIDI, LAEHTEENMAEKI, MIKKO, RUPPERT, OLIVER
Publication of US20030040622A1 publication Critical patent/US20030040622A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B13/00—Preparation of cellulose ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B11/00—Preparation of cellulose ethers
    • C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified

Definitions

  • the invention relates to the preparation of hydrophobically modified cellulose ethers.
  • Cellulose ethers such as carboxymethyl cellulose
  • Objects of use include, for example, foods, medicines, cosmetic preparations, detergents, agricultural chemicals, textiles, printing inks, paper coating agents, construction materials, adhesives, paints, ceramic materials, and additives of polymerisation.
  • Cellulose ethers can be modified by attaching different substituents to hydroxyl groups in cellulose. In this way, the solubility or the hydrophobicity of cellulose ether in particular can be affected.
  • U.S. Pat. No. 4,228,277 describes the modification of non-ionic cellulose ethers, such as methyl cellulose, methyl hydroxypropyl cellulose, hydroxypropyl cellulose, and particularly hydroxyethyl cellulose, by using epoxyalkanes having a length of the alkyl group of 10 to 24 carbons.
  • one advantage of the modification is that even small amounts of hydrophobically modified cellulose ether make the viscosity of an aqueous solution increase so that the dosage of the cellulose ether can be decreased.
  • the cellulose ether thus modified can be used in paints.
  • the modification is carried out by using a cellulose ether as a starting material, and the reaction times are long, 2 to 5 hours. However, it is uncomfortable to use epoxy compounds because they are detrimental to health.
  • carboxymethyl hydroxyethyl cellulose is modified by an alkyl group having 8 to 25 carbons in an amount of 0.1 to 4% by weight.
  • the alkyl reagent can be halide, halohydride, or epoxide, all of which are hazardous to environment and health. Hydroxyethylation, hydrophobic modification and carboxymethylation are carried out in sequence, therefore the reaction time is long, more than 4 hours.
  • U.S. Pat. No. 5,302,196 describes cellulose ethers which are modified by a fluorine-containing alkyl group having 3 to 24 carbon atoms, the fluorine content being 0.05 to 5% by weight.
  • the cellulose ether is especially hydroxyethyl cellulose, hydroxyethyl carboxymethyl cellulose or methyl hydroxyethyl cellulose.
  • the fluorine-containing alkyl reagent is preferably epoxide, bromide or perfluoroolefin. This product is also developed for paints. The reaction is long, the modification requires a reaction time of 6 hours.
  • cellulose ether especially hydroxyethyl cellulose
  • an aromatic alkyl group having at least 10 carbons, the content being 0.001 to 0.1 moles per one mole of a glucose repeat unit of the cellulose ether.
  • the alkyl reagent can be, for example, halide, oxirane, acid, (thio)isocyanate or halohydrin.
  • the product can be used in latex paints. This manufacturing process also has a long reaction time, 6 or up to 12 hours.
  • This invention introduces a new type of hydrophobically modified cellulose ether in which the modifying agent is alkylketene dimer.
  • the cellulose ether is preferably carboxymethyl cellulose or sodium carboxymethyl cellulose (CMC, NaCMC).
  • Cellulose ether modified with alkylketene dimer is easy to manufacture. The process is safe, simple, and quick. The modification can also improve the dispersability of cellulose ether in water.
  • the product is suitable to be used in any water-based application.
  • the hydrophobic group renders the substance properties that are advantageous to, for example, detergents, paper coating mixtures, paints, dispersing agents, and oil drilling muds.
  • alkylketene dimer is used to modify the cellulose ether.
  • the general formula of AKD is
  • R 1 and R 2 are alkyl or alkenyl chains having 5 to 22, preferably 13 to 20 carbons.
  • R 1 or R 2 can also be substituted or they can contain heteroatoms in a chain.
  • R 1 and R 2 can in particular have a straight chain and contain 14 to 18 carbons.
  • AKD may react with the hydroxyl group of cellulose or cellulose ether, forming the following formula:
  • Elevated reaction temperatures are preferable, such as 30-120° C., preferably 50-90° C., and most preferably 60-85° C., so that at elevated temperatures AKD is melted first.
  • High temperature and alkaline pH improve the reactivity of AKD with cellulose lose ether.
  • AKD can react with substituents, for example carboxymethyl groups in cellulose ether.
  • AKD can also react with other compounds which contain an OH group. These include water, alcohol, and sodium glycolate which are generated in the preparation of CMC. The thus generated compounds also have an effect on the hydrophobicity of the product.
  • the reacted AKD concentration in the cellulose ether can be analysed by using gas chromatography.
  • the unreacted AKD or AKD reacted with other OH containing compounds are extracted with a suitable solvent.
  • the sample is hydrolysed causing the cleavage of alkyl ketene group.
  • the reacted AKD is extracted with a suitable solvent and analysed with gas chromatograph.
  • the AKD can be in a solid state or dispersed in water or other solvents.
  • the content of AKD in the cellulose ether can be 0.001-10% by weight.
  • the content is preferably 0.01-2% by weight.
  • the molecular weight (Mw) of the cellulose ether can be 10 000 -1 000 000, preferably 20 000 -700 000.
  • the cellulose ether can be, for example, alkyl, hydroxyalkyl or carboxyalkyl substituted or a mixed ether of these.
  • cellulose ether that is modified by AKD can be used in any water-based application. It can be used, for example, in paper or board coating mixtures, in the wet end in paper or board manufacturing, paints, construction materials, adhesives, oil drilling mud, detergents, cosmetic products, and as a dispersion agent.
  • the cellulose ether is preferably carboxymethyl cellulose (CMC).
  • CMC carboxymethyl cellulose
  • Its degree of substitution i.e., the average number of substituted hydroxyl groups in a glucose ring
  • DS degree of substitution
  • Its molecular weight is preferably 40 000 -500 000. It can be applied to all the above-mentioned objects.
  • the cellulose ether can also be, e.g., hydroxyethyl cellulose (HEC). Its molecular weight can be, for example, 90 000 -1 300 000 and the molar substitution (MS) 1.5-4. HEC can be used in coating, construction materials, and cosmetic preparations in particular.
  • HEC hydroxyethyl cellulose
  • the cellulose ether can also be, e.g., hydroxypropyl cellulose (HPC). Its molecular weight can be, for example, 80 000 -1 150 000 and the molar substitution (MS) 1.5-4. HPC can be used in foods, medical preparations, and coating in particular.
  • HPC hydroxypropyl cellulose
  • cellulose ethers are prepared by mixing wood-based or cotton wool-based raw material with a reaction medium, such as alcohol or acetone, and by mercerising it with an alkalic substance, such as sodium hydroxide, to activate the cellulose.
  • a reaction medium such as alcohol or acetone
  • an alkalic substance such as sodium hydroxide
  • An etherifying chemical is added and it is allowed to react.
  • the complete product is neutralised.
  • the viscosity can be reduced if needed.
  • By-products, such as salts generated in the reaction are washed out with alcohol, for example, when purified cellulose ether is manufactured. but they can also be left in the product or only remove partly (technical or crude cellulose ether).
  • the solvent used is separated and the product is dried.
  • the particle size and the bulk density can be adjusted by grinding the product into powder or by granulating it.
  • the product can also be screened.
  • Cellulose ether can be modified with AKD by various methods.
  • AKD can be added to the cellulose ether at any stage of the production, for example, in mercerisation, etherification, or drying.
  • AKD can be added in a solid form or as a dispersion. High temperature and alkaline pH improve the reactivity of AKD with cellulose ether.
  • AKD can also be added to the cellulose ether as such.
  • the cellulose ether can be coated, for example, with solid AKD or an AKD dispersion. In that case, a suitable amount of AKD is sprayed onto the surface of the cellulose ether or mixed with it. The product is treated with high temperature to initiate the reaction.
  • AKD is a safe chemical. It is neither combustible nor explosive; therefore, it neither causes a danger in a process nor is it dangerous to the environment. AKD is not hazardous or irritating and it does not cause allergies; therefore, it does not present any danger to the process personnel or the end-user.
  • alkylketene dimer the length of the alkyl group being 16 to 18 carbons (Raisio Chemicals).
  • CMC Metal Organic Chemicals
  • alkylketene dimer dispersion having an AKD content of 10% by weight, diluted with 50 g of water, was sprayed on CMC, agitating the powder at the same time.
  • the product was dried at 80° C. to a moisture content of less than 8%.
  • the AKD content of the end product was 0.1% by weight.
  • Hydrophobically modified CMC having an average molecular weight of 400 000 and a degree of substitution of 0.86, and an AKD content of 10.0% by weight, was prepared according to the procedure described in example 7.
  • Ethanol was recovered and the product was dried at 80° C. to a moisture content of less than 8%.
  • the AKD content of the end product was 0.3% by weight, the average molecular weight 150 000, and the DS of the carboxymethyl group 0.57.
  • the sample contained 0.02% by weight of AKD reacted with cellulose.
  • Samples 10-15 were prepared according to the procedure described in example 9.
  • the product was neutralised after etherification with hydrochloric acid.
  • AKD was added after neutralisation and allowed to react 5 minutes at 70° C.
  • TABLE 2 Molecular Degree of AKD content weight substitution in CMC, Example of CMC of CMC % by weight 10 180 000 0.46 0.6 11 120 000 0.48 0.6 12 140 000 0.52 0.06 13 150 000 0.55 1.1 14 140 000 0.56 2.7 15 270 000 0.52 0.06
  • CMC was neutralised with hydrochloric acid.
  • Samples 17-19 were prepared according to the procedure described in example 16. In example 19 AKD was added during mercerisation. TABLE 3 AKD Molecular Degree of content in weight substitution CMC, % Example Raw material of CMC of CMC by weight 17 wood pulp 60 000 0.77 0.07 (Metsa-Botnia) 18 wood pulp 240 000 0.89 0.07 (Borregaard) 19 cotton linter 380 000 0.80 0.7 (Buckeye, Temming)

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Detergent Compositions (AREA)
  • Paper (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
US09/463,498 1998-05-25 1999-04-08 Method for the preparation of modified cellulose ethers Abandoned US20030040622A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI981149 1998-05-25
FI981149A FI107385B (fi) 1998-05-25 1998-05-25 Modifioitujen selluloosaeetterien valmistus

Publications (1)

Publication Number Publication Date
US20030040622A1 true US20030040622A1 (en) 2003-02-27

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US09/463,498 Abandoned US20030040622A1 (en) 1998-05-25 1999-04-08 Method for the preparation of modified cellulose ethers
US09/463,499 Expired - Fee Related US6600033B1 (en) 1998-05-25 1999-04-08 Modified cellulose ethers

Family Applications After (1)

Application Number Title Priority Date Filing Date
US09/463,499 Expired - Fee Related US6600033B1 (en) 1998-05-25 1999-04-08 Modified cellulose ethers

Country Status (21)

Country Link
US (2) US20030040622A1 (fi)
EP (2) EP0998498B9 (fi)
JP (1) JP4468579B2 (fi)
KR (1) KR100362421B1 (fi)
CN (1) CN1191278C (fi)
AR (1) AR016721A1 (fi)
AT (1) ATE444312T1 (fi)
AU (1) AU3422399A (fi)
BR (1) BR9906504B1 (fi)
CA (1) CA2297904C (fi)
CO (1) CO5050321A1 (fi)
DE (1) DE69941472D1 (fi)
ES (1) ES2333186T3 (fi)
FI (1) FI107385B (fi)
HK (1) HK1027823A1 (fi)
HU (1) HUP0100160A3 (fi)
PL (1) PL200907B1 (fi)
TR (1) TR200000242T1 (fi)
TW (1) TW500728B (fi)
WO (2) WO1999061479A1 (fi)
ZA (1) ZA200000301B (fi)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070105985A1 (en) * 2005-11-04 2007-05-10 Gillette Paul C Ether derivatives of raw cotton linters for water-borne coatings
CN108048236A (zh) * 2017-12-01 2018-05-18 纳爱斯浙江科技有限公司 一种含有羧甲基纤维素的液体洗涤剂及其制备方法

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Publication number Priority date Publication date Assignee Title
FI19992519A (fi) * 1999-11-25 2001-05-26 Neste Chemicals Oy Menetelmä nukleofiilisten yhdisteiden asetoasetyloimiseksi
US6528643B1 (en) * 2000-05-05 2003-03-04 Hercules Incorporated Esterified polysaccharide products and B-lactone ring opened ketene dimer products containing the compositions, and process of making the same
US6677427B1 (en) 2000-06-13 2004-01-13 Hercules Incorporated Enzyme-catalyzed polyamides and compositions and processes of preparing and using the same
US6528644B1 (en) 2001-09-26 2003-03-04 Hercules Incorporated Acetoacetylated saccharides and process of making the same
GB0227242D0 (en) * 2002-11-21 2002-12-31 Unilever Plc Improvements relating to fabric laundering
JP5007985B2 (ja) * 2004-06-25 2012-08-22 国立大学法人 東京大学 ポリマーブラシ化合物及びその調製方法
GB0419689D0 (en) 2004-09-04 2004-10-06 Unilever Plc Improvements relating to fabric laundering
EP2085070A1 (en) * 2008-01-11 2009-08-05 Procter & Gamble International Operations SA. Cleaning and/or treatment compositions
EP2302025B1 (en) * 2009-09-08 2016-04-13 The Procter & Gamble Company A laundry detergent composition comprising a highly water-soluble carboxmethyl cellulose particle
CN102443067B (zh) * 2011-10-28 2013-03-20 东北林业大学 一种羰基化改性纳米纤维素的制备方法
CN104629508B (zh) * 2015-03-11 2018-03-06 马清浩 一种耐水耐擦洗内外墙乳胶漆
DE17784205T1 (de) 2016-09-28 2019-11-28 Cp Kelco Oy Waschmittelzusammensetzungen mit polysacchariden mit extrem niedrigem molekulargewicht
WO2019111937A1 (ja) * 2017-12-06 2019-06-13 花王株式会社 繊維製品用洗浄剤組成物
US11872711B2 (en) 2019-05-10 2024-01-16 The Gillette Company Llc Lubricating member for razor cartridges
CN110563855A (zh) * 2019-10-12 2019-12-13 山东省食品发酵工业研究设计院 一种自组装纳米粒子材料——十八烷酰十八烷酸普鲁兰多糖酯的合成方法
CN111995691A (zh) * 2020-08-21 2020-11-27 南京林业大学 纤维素醚类衍生物、制备方法及用途
EP4269548A1 (en) 2022-04-27 2023-11-01 Dalli-Werke GmbH & Co. KG Detergent composition with antiscalants

Family Cites Families (8)

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US2627477A (en) 1949-10-06 1953-02-03 Hercules Powder Co Ltd Higher alkyl ketene dimer emulsion
SE361908B (fi) * 1972-07-14 1973-11-19 Kema Nord Ab
JPS50120836A (fi) * 1974-03-08 1975-09-22
US4228277A (en) 1979-02-12 1980-10-14 Hercules Incorporated Modified nonionic cellulose ethers
GB8621680D0 (en) * 1986-09-09 1986-10-15 Du Pont Filler compositions
US4826970A (en) 1987-09-17 1989-05-02 Hercules Incorporated Carboxymethyl hydrophobically modified hydroxyethylcellulose
ATE108190T1 (de) 1989-01-31 1994-07-15 Union Carbide Chem Plastic Polysaccharide mit alkaryl- oder aralkyl- hydrophoben und latexzusammensetzungen, die die polysaccharide enthalten.
DE4028746A1 (de) 1990-09-11 1992-03-12 Hoechst Ag Modifizierte celluloseether und ihre verwendung in dispersionsfarben

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070105985A1 (en) * 2005-11-04 2007-05-10 Gillette Paul C Ether derivatives of raw cotton linters for water-borne coatings
US7932309B2 (en) * 2005-11-04 2011-04-26 Hercules Incorporated Ether derivatives of raw cotton linters for water-borne coatings
CN108048236A (zh) * 2017-12-01 2018-05-18 纳爱斯浙江科技有限公司 一种含有羧甲基纤维素的液体洗涤剂及其制备方法

Also Published As

Publication number Publication date
KR100362421B1 (ko) 2002-11-25
EP0998498B9 (en) 2010-03-03
HK1027823A1 (en) 2001-01-23
ATE444312T1 (de) 2009-10-15
US6600033B1 (en) 2003-07-29
HUP0100160A2 (hu) 2001-06-28
TW500728B (en) 2002-09-01
EP0998498B1 (en) 2009-09-30
KR20010022029A (ko) 2001-03-15
JP2002516353A (ja) 2002-06-04
BR9906504A (pt) 2000-09-26
PL200907B1 (pl) 2009-02-27
CA2297904A1 (en) 1999-12-02
AU3334499A (en) 1999-12-13
DE69941472D1 (de) 2009-11-12
TR200000242T1 (tr) 2001-02-21
FI107385B (fi) 2001-07-31
PL339291A1 (en) 2000-12-04
WO1999061478A1 (en) 1999-12-02
FI981149A0 (fi) 1998-05-25
BR9906504B1 (pt) 2008-11-18
ES2333186T3 (es) 2010-02-17
CN1191278C (zh) 2005-03-02
AR016721A1 (es) 2001-07-25
JP4468579B2 (ja) 2010-05-26
ZA200000301B (en) 2001-02-26
AU3422399A (en) 1999-12-13
EP2078733A1 (en) 2009-07-15
FI981149A (fi) 1999-11-26
CO5050321A1 (es) 2001-06-27
HUP0100160A3 (en) 2002-10-28
CN1272116A (zh) 2000-11-01
AU747262B2 (en) 2002-05-09
EP0998498A1 (en) 2000-05-10
WO1999061479A1 (en) 1999-12-02
CA2297904C (en) 2007-07-31

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