TWI745636B - Layered body for forming container, forming container and packaging body, and manufacturing method of forming container and packaging body - Google Patents
Layered body for forming container, forming container and packaging body, and manufacturing method of forming container and packaging body Download PDFInfo
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- TWI745636B TWI745636B TW107140327A TW107140327A TWI745636B TW I745636 B TWI745636 B TW I745636B TW 107140327 A TW107140327 A TW 107140327A TW 107140327 A TW107140327 A TW 107140327A TW I745636 B TWI745636 B TW I745636B
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- 238000004806 packaging method and process Methods 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 229920005989 resin Polymers 0.000 claims abstract description 124
- 239000011347 resin Substances 0.000 claims abstract description 124
- 239000011888 foil Substances 0.000 claims abstract description 45
- 229910052751 metal Inorganic materials 0.000 claims abstract description 34
- 239000002184 metal Substances 0.000 claims abstract description 34
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 9
- 239000011342 resin composition Substances 0.000 claims abstract description 7
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims description 19
- 230000001954 sterilising effect Effects 0.000 claims description 12
- 238000004659 sterilization and disinfection Methods 0.000 claims description 12
- 238000007639 printing Methods 0.000 claims description 9
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- 238000004821 distillation Methods 0.000 claims description 3
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- 239000002365 multiple layer Substances 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 description 21
- -1 polypropylene Polymers 0.000 description 21
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- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
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- 238000000465 moulding Methods 0.000 description 8
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- 229920002803 thermoplastic polyurethane Polymers 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
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- 238000000034 method Methods 0.000 description 6
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- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical class [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 4
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- 150000001875 compounds Chemical class 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
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- 239000000314 lubricant Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
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- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000002087 whitening effect Effects 0.000 description 4
- 229920001661 Chitosan Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
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- 150000001336 alkenes Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 3
- 238000009820 dry lamination Methods 0.000 description 3
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
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- 238000007789 sealing Methods 0.000 description 3
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
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- 239000011651 chromium Substances 0.000 description 2
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical class [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 239000011112 polyethylene naphthalate Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000590428 Panacea Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052755 nonmetal Chemical class 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005633 polypropylene homopolymer resin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0036—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/12—Deep-drawing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/406—Bright, glossy, shiny surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/75—Printability
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
- Packages (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Abstract
本發明以低價提供一種由具備金屬箔層及外側樹脂膜層的積層體所成形的容器,其具有外觀良好的消光外表面。 The present invention provides a container formed from a laminate having a metal foil layer and an outer resin film layer at a low price, which has a matte outer surface with a good appearance.
本發明之用於成形容器的積層體10,具備金屬箔層11與積層於金屬箔層兩面中為容器外側面的單層或多層的外側樹脂膜層12。單層的外側樹脂膜層或多層的外側樹脂膜層之中的最外層,係由聚烯烴樹脂與烯烴系彈性體為主成分的樹脂組成物所構成。外側樹脂層的外表面的光澤度為0.5~30%。 The laminate 10 for forming a container of the present invention includes a metal foil layer 11 and a single-layer or multiple-layer outer resin film layer 12 laminated on both sides of the metal foil layer as the outer side of the container. The outermost layer of the single-layer outer resin film layer or the multilayer outer resin film layer is composed of a resin composition mainly composed of a polyolefin resin and an olefin-based elastomer. The glossiness of the outer surface of the outer resin layer is 0.5 to 30%.
Description
本發明係關於一種作為用以密封包裝食品等的成形容器之材料所使用的積層體、使相同積層體所成形的成形容器、以及對填充內容物的相同成形容器施予蓋體而成的包裝體,更詳細而言,係關於具有消光外表面的用於成形容器的積層體、成形容器及包裝體。又,本發明係關於具有消光外表面的成形容器及包裝體的製造方法。 The present invention relates to a laminated body used as a material for sealing and packaging shaped containers such as food, a shaped container formed by forming the same laminated body, and a package formed by applying a lid to the same shaped container filled with contents The body, in more detail, relates to a laminated body, a molded container, and a packaging body for forming a container having a matte outer surface. In addition, the present invention relates to a method of manufacturing a molded container and a packaging body having a matte outer surface.
積層體形成杯狀的成形容器作為能夠長期保存包裝如水羊羹、果凍、斷奶食品、照護用食品等的容器,已為人所知,而該積層體具備鋁箔等所構成的金屬箔層以及積層於金屬箔層兩面中為容器外側面的單層或多層外側樹脂膜層(參照下述專利文獻1等)。 The laminated body formed into a cup-shaped shaped container is known as a container that can store packages such as water yokan, jelly, weaning food, nursing food, etc. for a long time, and the laminated body has a metal foil layer composed of aluminum foil and the like On both sides of the metal foil layer, there are single or multiple outer resin film layers on the outer side of the container (refer to Patent Document 1 and the like below).
在包裝領域中,為了使外觀具有高級感,會有使用具消光(消艷)外表面的容器的情況。 In the packaging field, in order to provide a high-end appearance, there are cases where a container with a matte (glossy) outer surface is used.
例如下述專利文獻2中揭示,使用經壓印加工的聚丙烯樹脂膜,製作具有消光外表面的文具用資料夾等。
For example,
又,下述專利文獻3中揭示一種成型用硬塗膜,其係在最外層形成具有消光外表面的硬塗層。
In addition, the following
[專利文獻1]日本特開平6-345123號公報 [Patent Document 1] Japanese Patent Application Laid-Open No. 6-345123
[專利文獻2]日本特開平5-320376號公報 [Patent Document 2] Japanese Patent Application Laid-Open No. 5-320376
[專利文獻3]日本特開2011-148301號公報 [Patent Document 3] JP 2011-148301 A
然而,若以上述專利文獻2的壓印加工膜所構成的外側樹脂膜層的積層體成形為杯狀,成形時壓印加工膜會因成形時被拉伸而導致消光外表面產生斑紋,可能損及外觀。又,若使用壓印加工膜,則具有成本高漲的問題。
However, if the laminate of the outer resin film layer composed of the embossed film of
又,若以具有上述專利文獻3之消光塗布層的膜所構成的外側樹脂膜層的積層體成形為杯狀的情況中,具有在塗布層產生裂縫或塗布層剝離的問題。此外,形成消光塗布層的情況,也具有成本高漲這樣的問題。
In addition, when a laminate of an outer resin film layer composed of a film having a matte coating layer of
鑒於上述課題而完成本發明,其目的係以低價提供一種使具備金屬箔層及外側樹脂膜層的積層體所成形的容器,其具有良好的消光外表面的外觀。 The present invention was made in view of the above-mentioned problems, and its object is to provide a low-cost container formed of a laminate having a metal foil layer and an outer resin film layer, which has a good matte outer surface appearance.
本發明為了達成上述目的,而由以下的態樣所構成。 In order to achieve the above-mentioned object, the present invention is constituted by the following aspects.
1)一種用於成形容器的積層體,其係具備金屬箔層與積層於金屬箔層兩面中為容器外側面的單層或多層外側樹脂膜層的用於成形容器的積層體, 其中單層的外側樹脂膜層或多層的外側樹脂膜層中的最外層,係由以聚烯烴樹脂與烯烴系彈性體為主成分的樹脂組成物所構成,而外側樹脂膜層之外表面的光澤度為0.5~30%。 1) A laminate for forming a container, comprising a metal foil layer and a single layer or multiple outer resin film layers laminated on both sides of the metal foil layer as the outer side of the container for forming a container, Among them, the outermost layer of the single-layer outer resin film layer or the multi-layer outer resin film layer is composed of a resin composition mainly composed of polyolefin resin and olefin-based elastomer, and the outer surface of the outer resin film layer The gloss is 0.5~30%.
2)如上述1)之用於成形容器的積層體,其中在金屬箔層與外側樹脂膜層之間,全面或部分形成印刷層;或藉由對外側樹脂膜層添加上色成分,而將既定的標示或裝飾顯示於外側樹脂膜層的外表面。 2) The laminate for forming a container as described in 1) above, wherein a printed layer is formed entirely or partly between the metal foil layer and the outer resin film layer; or by adding a coloring component to the outer resin film layer, the The established logo or decoration is displayed on the outer surface of the outer resin film layer.
3)一種成形容器,其係使上述1)或2)之用於成形容器的積層體形成杯狀而成,其開口周緣具有凸緣。 3) A shaped container in which the laminated body for the shaped container of 1) or 2) is formed into a cup shape, and the opening periphery has a flange.
4)一種包裝體,其中,蓋體接合於填充有內容物的如上述3)之成形容器的凸緣上,以覆蓋成形容器的開口。 4) A packaging body, wherein a lid body is joined to the flange of the above-mentioned 3) shaped container filled with content to cover the opening of the shaped container.
5)一種成形容器的製造方法,其係製造如上述3)之成形容器的方法,包含:使上述1)或2)之用於成形容器的積層體形成杯狀的步驟;及以單層的外側樹脂膜層或多層的外側樹脂膜層中的最外層之樹脂的軟化點以上的溫度,對於由前述步驟所得之成形容器進行加熱處理的步驟。 5) A method of manufacturing a shaped container, which is a method of manufacturing a shaped container as described in 3) above, comprising: forming the laminated body of the above-mentioned 1) or 2) for the shaped container into a cup shape; and using a single layer The temperature of the outer resin film layer or the outermost resin film layer of the multi-layer outer resin film layer above the softening point of the resin is a step of heat-treating the molded container obtained in the foregoing step.
6)一種包裝體的製造方法,其係製造如上述4)之包裝體的方法,包含:將蓋體接合於填充有內容物的如上述3)之成形容器的凸緣以覆蓋成形容器之開口的步驟;及以單層的外側樹脂膜層或多層的外側樹脂膜層中的最外層之樹脂的軟化點以上的溫度,對於由前述步驟所得之包裝體進行加熱處理的步驟。 6) A method of manufacturing a packaging body, which is a method of manufacturing the packaging body as described in 4) above, comprising: joining a lid body to the flange of the shaped container as described in 3) above filled with content to cover the opening of the shaped container The step; and a single-layer outer resin film layer or a multi-layer outer resin film layer at a temperature above the softening point of the resin of the outermost layer to heat the package obtained by the foregoing steps.
7)如上述6)之包裝體的製造方法,其中該對包裝體實施加熱處理的步驟係藉由蒸餾殺菌處理進行。 7) The method of manufacturing a package as described in 6) above, wherein the step of applying heat treatment to the package is carried out by distillation and sterilization.
在上述1)之用於成形容器的積層體中,單層的外側樹脂膜層或多層的外側樹脂膜層中的最外層係由以聚烯烴樹脂與烯烴系彈性體為主成分的樹脂組成物所構成,外側樹脂膜層之外表面的光澤度為0.5~30%,因此使相同積層體所成形而成的成形容器,其外表面為消光。接著,上述1)之積層體的情況,不會如以壓印加工膜所構成的外側樹脂膜層外表面的積層體,會因在成形時被拉伸而導致外表面產生斑紋。又,以具有消光塗布層的膜所構成的外側樹脂膜層外表面的積層體,於塗布層不會產生裂縫,且塗布層亦不會剝離,故亦不會耗費成本。 In the above 1) laminate for forming containers, the outermost layer of the single-layer outer resin film layer or the multi-layer outer resin film layer is composed of a resin composition mainly composed of polyolefin resin and olefin-based elastomer It is constructed that the glossiness of the outer surface of the outer resin film layer is 0.5 to 30%, so the outer surface of the molded container formed by molding the same laminate is matte. Next, in the case of the laminate of 1) above, unlike the laminate on the outer surface of the outer resin film layer made of an imprinted film, the outer surface is not stretched due to stretching during molding. In addition, the laminate on the outer surface of the outer resin film layer composed of a film having a matte coating layer does not cause cracks in the coating layer, and the coating layer does not peel off, so it is not costly.
因此,根據上述1)之用於成形容器的積層體,可以低價得到具有外觀良好之消光外表面的成形容器。 Therefore, according to the laminate for a molded container of 1) above, a molded container having a matte outer surface with a good appearance can be obtained at a low price.
此處,「光澤度」係依據JIS Z8741-1997(鏡面光澤度-測量方法,方法3(入射角度60度))進行測量。 Here, "gloss" is measured in accordance with JIS Z8741-1997 (specular gloss-measuring method, method 3 (incident angle 60 degrees)).
根據上述2)之用於成形容器的積層體,藉由在金屬箔層與外側樹脂膜層之間全面或部分形成印刷層,或是在外側樹脂膜層中添加上色成分,可在外側樹脂膜層的外表面顯示既定的標示或裝飾,因此使相同積層體成形而成的成形容器具有更優良的外觀。 According to the laminate for forming a container in 2) above, by forming a printing layer on the whole or part of the metal foil layer and the outer resin film layer, or adding a coloring component to the outer resin film layer, the outer resin film can be The outer surface of the film layer shows a predetermined logo or decoration, so that the molded container formed by the same laminate has a better appearance.
根據上述3)之成形容器,因為具有外觀良好的消光外表面,因此具有高級感。 According to the above-mentioned 3) molded container, since it has a matte outer surface with a good appearance, it has a high-quality feeling.
根據上述4)之包裝體,藉由具有外觀良好之消光外表面的容器,而具有高級感。 According to the package of 4) above, a container with a matte outer surface with a good appearance provides a sense of luxury.
根據上述5)之成形容器的製造方法,可得到下述效果。 According to the method of manufacturing a molded container of 5) above, the following effects can be obtained.
亦即,在使上述1)或2)之用於成形容器的積層體形成杯狀的情況,所得之成形容器的外表面的一部分,具體而言,例如在相同外表面中的底壁與周壁邊界的轉角部分產生白濁,導致金屬箔層表面的金屬色或印刷層的標示被隱蔽而無法被看見,而可能損及外觀。其原因被認為是因為成形上述積層體時,在單層的外側樹脂膜層或多層的外側樹脂膜層之中的最外層中的於聚烯烴樹脂(例如嵌段聚丙烯樹脂)之基質與烯烴系彈性體(例如乙烯-丙烯共聚物所構成的彈性體)之界面產生孔洞(空隙),並因為樹脂部分與孔洞的折射率差,導致成形容器外表面的一部分,特別是成形容器外表面之中因為成形造成變形程度大的轉角部分,看起來呈現白濁的態樣。 That is, in the case of forming a cup shape of the laminated body for forming a container in the above 1) or 2), a part of the outer surface of the resulting formed container, specifically, for example, the bottom wall and the peripheral wall in the same outer surface The corners of the border are turbid, causing the metallic color on the surface of the metal foil layer or the markings of the printed layer to be concealed and cannot be seen, which may damage the appearance. The reason for this is considered to be that when the above-mentioned laminate is formed, the matrix of polyolefin resin (for example, block polypropylene resin) and the olefin in the outermost layer of the outer resin film layer of a single layer or the outer resin film layer of multiple layers Holes (voids) are formed at the interface of elastomers (for example, elastomers composed of ethylene-propylene copolymers), and because of the difference in refractive index between the resin part and the holes, a part of the outer surface of the shaped container, especially the outer surface of the shaped container In the middle, the corners where the degree of deformation is large due to forming, appear to be cloudy.
於是,如上所述,在以單層的外側樹脂膜層或多層的外側樹脂膜層之中的最外層之樹脂的軟化點以上的溫度對成形容器進行加熱處理時,同層內部所生成的孔洞消失,進而使白濁消失。 Therefore, as described above, when the molded container is heated at a temperature above the softening point of the resin in the outermost layer of the single-layer outer resin film layer or the multilayer outer resin film layer, the holes formed in the same layer Disappear, and then make the white turbidity disappear.
因此,根據上述5)之成形容器的製造方法,可確實得到具有整體外觀良好之消光外表面的成形容器。 Therefore, according to the method for manufacturing a shaped container in the above 5), a shaped container having a matte outer surface with a good overall appearance can be obtained reliably.
此處,「軟化點」係依據JIS-K7206:2016(測量條件A50)所測量的「維卡軟化點」。 Here, the "softening point" is the "Vicat softening point" measured in accordance with JIS-K7206:2016 (measurement condition A50).
根據上述6)之包裝體的製造方法,即使在成形容器的一部分外表面產生白濁的情況,藉由對包裝體進行的加熱處理採以單層的外側樹脂膜層或 多層的外側樹脂膜層之中的最外層之樹脂的軟化點以上的溫度,便可使白濁消失,因此可確實得到具備具有整體外觀良好之消光外表面的成形容器的包裝體。 According to the manufacturing method of the packaging body of 6) above, even if a part of the outer surface of the molded container is cloudy, a single outer resin film layer or a single outer resin film layer or The temperature above the softening point of the resin of the outermost layer of the multi-layered outer resin film layers can make the white turbidity disappear. Therefore, it is possible to reliably obtain a package having a molded container having a matte outer surface with a good overall appearance.
根據上述7)之包裝體的製造方法,因為對包裝體所實施的加熱處理的步驟係藉由蒸餾殺菌處理進行,可在不增加步驟數量的情況下,有效率地使在成形容器的外表面所生成的白濁消失。 According to the manufacturing method of the packaging body of 7) above, because the heat treatment steps applied to the packaging body are carried out by distillation and sterilization treatment, it is possible to efficiently make the outer surface of the formed container without increasing the number of steps. The generated white turbidity disappeared.
(2):成形容器 (2): forming container
(21):底壁 (21): bottom wall
(22):周壁 (22): Zhou Bi
(23):凸緣 (23): Flange
(3):蓋體 (3): Cover body
(31):開封用舌片 (31): Tongue for opening
(4):包裝體 (4): Package body
(5):蒸餾殺菌處理裝置 (5): Retort sterilization treatment device
(10):用於成形容器的積層體 (10): Laminated body for forming containers
(11):金屬箔層 (11): Metal foil layer
(12):外側樹脂膜層 (12): Outer resin film layer
(12a):外側樹脂膜層的外表面 (12a): The outer surface of the outer resin film layer
(13):內側樹脂層 (13): Inner resin layer
(14):黏著劑層 (14): Adhesive layer
(15):印刷層 (15): Printing layer
(16):黏著劑層 (16): Adhesive layer
(C):內容物 (C): contents
第一圖顯示本發明之實施態樣的用於成形容器的積層體的層結構部分放大的剖面圖。 The first figure shows an enlarged cross-sectional view of the layer structure of the laminated body for forming the container according to the embodiment of the present invention.
第二圖依照步驟順序顯示本發明之實施態樣的包裝體之製造方法的垂直剖面圖。 The second figure shows a vertical cross-sectional view of the manufacturing method of the packaging body according to the embodiment of the present invention according to the sequence of steps.
第三圖係以相同方法製造的包裝體的立體圖。 The third figure is a perspective view of a package manufactured by the same method.
以下參照第一圖至第三圖說明本發明的實施態樣。 Hereinafter, embodiments of the present invention will be described with reference to the first to third figures.
第一圖顯示本發明的實施態樣之用於成形容器的積層體的層結構。圖式的積層體(10)具備:金屬箔層(11);及外側樹脂膜層(12),其積層於金屬箔層(11)之兩面中為容器(2)之外側的面。又,本實施態樣的積層體(10),具備內側樹脂層(13),其積層於金屬箔層(11)之兩面中為容器(2)之內側的面。 The first figure shows the layer structure of the laminated body used for forming the container according to the embodiment of the present invention. The laminated body (10) of the figure includes: a metal foil layer (11); and an outer resin film layer (12) which is laminated on both surfaces of the metal foil layer (11) as the surface outside the container (2). In addition, the laminate (10) of this embodiment includes an inner resin layer (13), which is laminated on both surfaces of the metal foil layer (11) as the inner surface of the container (2).
作為構成金屬箔層(11)之金屬箔,可使用鋁箔、鐵箔、不銹鋼箔、銅箔等,但較佳係使用鋁箔。鋁箔的情況,可為純鋁箔、鋁合金箔任一者, 又可為軟質、硬質的任一者,例如,若為鐵含量0.3~1.5質量%的、以JIS H4160分類的A8000系(特別是A8079H及A8021H)之經退火處理的軟質材料(O材),因為成形性優良而適合使用。 As the metal foil constituting the metal foil layer (11), aluminum foil, iron foil, stainless steel foil, copper foil, etc. can be used, but aluminum foil is preferably used. In the case of aluminum foil, it can be either pure aluminum foil or aluminum alloy foil. It can be either soft or hard. For example, if it is an annealed soft material (O material) of the A8000 series (especially A8079H and A8021H) classified by JIS H4160 with an iron content of 0.3 to 1.5% by mass, It is suitable for use because of its excellent formability.
對於金屬箔層(11)之單面或兩面,因應需求進行化學轉化處理等的底層處理。具體而言,例如對於已進行脫脂處理的金屬箔表面塗布下述1)~3)之中任一水溶液後,藉由乾燥而實施化學轉化處理,以形成皮膜;1)包含磷酸、鉻酸、至少1種化合物選自氟化物之金屬鹽及氟化物之非金屬鹽所構成之群組的混合物之水溶液;2)包含磷酸、丙烯酸系樹脂、至少1種樹脂選自幾丁聚醣(chitosan)衍生物樹脂及酚系樹脂所構成之群組、至少1種化合物選自鉻酸及鉻(III)鹽所構成之群組的的混合物之水溶液;3)包含磷酸、丙烯酸系樹脂、至少1種樹脂選自幾丁聚醣衍生物樹脂及酚系樹脂所構成之群組、至少1種化合物選自鉻酸及鉻(III)鹽所構成之群組、至少1種化合物選自氟化物之金屬鹽及氟化物之非金屬鹽所構成之群組的混合物之水溶液。 For one side or both sides of the metal foil layer (11), the bottom layer treatment such as chemical conversion treatment is carried out according to the demand. Specifically, for example, after coating any one of the following 1) to 3) aqueous solutions on the surface of a metal foil that has been degreasing treatment, it is dried to perform a chemical conversion treatment to form a film; 1) Contains phosphoric acid, chromic acid, An aqueous solution of at least one compound selected from the group consisting of metal salts of fluoride and non-metal salts of fluoride; 2) containing phosphoric acid, acrylic resin, and at least one resin selected from chitosan (chitosan) An aqueous solution of a mixture of derivative resins and phenolic resins, at least one compound selected from the group consisting of chromic acid and chromium (III) salt; 3) Contains phosphoric acid, acrylic resin, and at least one The resin is selected from the group consisting of chitosan derivative resins and phenolic resins, at least one compound is selected from the group consisting of chromic acid and chromium (III) salt, and at least one compound is selected from fluoride metal An aqueous solution of a mixture of salt and non-metallic salt of fluoride.
藉由上述化學轉化處理而形成於金屬箔層(11)表面的皮膜中,鉻附著量(每一單面)較佳為0.1mg/m2~50mg/m2,特佳為2mg/m2~20mg/m2。 In the film formed on the surface of the metal foil layer (11) by the above-mentioned chemical conversion treatment, the chromium adhesion amount (per side) is preferably 0.1 mg/m 2 to 50 mg/m 2 , particularly preferably 2 mg/m 2 ~20mg/m 2 .
金屬箔層(11)之厚度較佳為30~200μm,更佳為50~150μm。藉由上述範圍,可得到充分的屏障性與成形加工性。 The thickness of the metal foil layer (11) is preferably 30-200 μm, more preferably 50-150 μm. With the above range, sufficient barrier properties and moldability can be obtained.
外側樹脂膜層(12)為單層或多層(第一圖中顯示為單層)。 The outer resin film layer (12) is a single layer or multiple layers (shown as a single layer in the first figure).
構成成形容器(2)外表面的層,亦即單層的外側樹脂膜層(12)或多層的外側樹脂膜層(12)之中的最外層,係由以聚烯烴樹脂與烯烴系彈性體為主成分 的樹脂組成物所構成。且由上述層所構成之外側樹脂膜層(12)之外表面(12a),其光澤度(光澤值)為0.5~30%。上述的樹脂組成物中,聚烯烴樹脂可列舉嵌段聚丙烯樹脂(PP-B)、均聚丙烯樹脂(PP-H)、無規聚丙烯樹脂(PP-R)、高密度聚乙烯樹脂(HDPE)、直鏈狀低密度聚乙烯樹脂(LLDPE)、低密度聚乙烯樹脂(LDPE)等。又,烯烴系彈性體可列舉乙烯-丙烯共聚物、乙烯-丁烯共聚物、乙烯-丙烯-1-丁烯共聚物等。關於乙烯以外的單體,含量為5~40質量%,熔點小於90℃。又,上述的層亦可包含熔點在135℃以上的聚烯烴成分。再者,為了調整成形容器(2)外表面的光澤度,亦可因應需求,於上述的層中添加有機、無機的微粒子填充劑。 The layer constituting the outer surface of the molded container (2), that is, the outermost layer of the single-layer outer resin film layer (12) or the multi-layer outer resin film layer (12), is composed of polyolefin resin and olefin elastomer Main ingredient The resin composition is composed. And the outer surface (12a) of the outer resin film layer (12) formed by the above-mentioned layer has a glossiness (gloss value) of 0.5-30%. Among the above resin compositions, polyolefin resins include block polypropylene resins (PP-B), homopolypropylene resins (PP-H), random polypropylene resins (PP-R), high-density polyethylene resins ( HDPE), linear low-density polyethylene resin (LLDPE), low-density polyethylene resin (LDPE), etc. In addition, examples of olefin-based elastomers include ethylene-propylene copolymers, ethylene-butene copolymers, and ethylene-propylene-1-butene copolymers. Regarding monomers other than ethylene, the content is 5-40% by mass, and the melting point is less than 90°C. In addition, the above-mentioned layer may contain a polyolefin component having a melting point of 135°C or higher. Furthermore, in order to adjust the glossiness of the outer surface of the molded container (2), organic and inorganic particulate fillers can also be added to the above-mentioned layer according to requirements.
當外側樹脂膜層(12)為多層的情況下,除最外層以外的層可由聚丙烯樹脂(PP)、聚乙烯樹脂(PE)等的聚烯烴樹脂、尼龍6(PA6)、尼龍66(PA66)、MXD尼龍等的聚醯胺樹脂(PA)、聚對苯二甲酸乙二酯樹脂(PET)、聚對苯二甲酸丁二酯樹脂(PBT)、聚萘二甲酸乙二酯樹脂(PEN)等的聚酯樹脂(PEs)等所形成。 When the outer resin film layer (12) is a multilayer, the layers other than the outermost layer can be made of polypropylene resin (PP), polyethylene resin (PE) and other polyolefin resins, nylon 6 (PA6), nylon 66 (PA66) ), MXD nylon and other polyamide resin (PA), polyethylene terephthalate resin (PET), polybutylene terephthalate resin (PBT), polyethylene naphthalate resin (PEN ) And other polyester resins (PEs).
外側樹脂膜層(12)之厚度較佳為5~100μm,更佳為15~80μm。 The thickness of the outer resin film layer (12) is preferably 5-100 μm, more preferably 15-80 μm.
外側樹脂膜層(12)中,為了得到適當深度的成形容器(2),亦可添加潤滑劑。又,作為潤滑劑的替代,或是在潤滑劑以外,亦可在成形時於積層體(10)表面塗布矽油、菜籽油等的潤滑油。 In the outer resin film layer (12), in order to obtain a molded container (2) of an appropriate depth, a lubricant may be added. In addition, as an alternative to the lubricant, or in addition to the lubricant, a lubricant such as silicone oil or rapeseed oil may be applied to the surface of the layered body (10) during forming.
金屬箔層(11)與外側樹脂膜層(12)之積層可透過黏著劑層(14)以乾式積層法來進行。黏著劑層(14),例如可使用雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑或聚醚-聚胺基甲酸酯樹脂系黏著劑。 The lamination of the metal foil layer (11) and the outer resin film layer (12) can be carried out by a dry lamination method through the adhesive layer (14). For the adhesive layer (14), for example, a two-component curing type polyester-urethane resin adhesive or a polyether-urethane resin adhesive can be used.
在外側樹脂膜層(12)之內表面,藉由凹版印刷等全面或部分地形成印刷層(15)。藉由該印刷層(15),可在成形容器(2)之外表面顯示既定的標示或裝飾。印刷層(15)雖未特別限定,但在強調消光外表面(12a)而具有高級感的意義上,較佳係使底色為黑色等的深色。 On the inner surface of the outer resin film layer (12), a printing layer (15) is fully or partially formed by gravure printing or the like. With the printing layer (15), a predetermined mark or decoration can be displayed on the outer surface of the shaped container (2). Although the printing layer (15) is not particularly limited, in the sense of emphasizing the matte outer surface (12a) to have a sense of luxury, it is preferable to make the background color a dark color such as black.
另外,亦可在外側樹脂膜層(12)中添加顏料等的上色成分來代替印刷層(15)。 In addition, a coloring component such as a pigment may be added to the outer resin film layer (12) instead of the printing layer (15).
因為內側樹脂層(13)構成容器(2)之內面(包含凸緣部(23)之上表面),因此係由例如具有熱熔接性的聚丙烯樹脂(PP)膜或聚乙烯樹脂(PE)膜等的通用膜、或將該等貼合的複合片所構成。 Because the inner resin layer (13) constitutes the inner surface of the container (2) (including the upper surface of the flange (23)), it is made of, for example, polypropylene resin (PP) film or polyethylene resin (PE ) It is composed of general-purpose films such as films, or composite sheets laminated with these.
構成內側樹脂層(13)之膜或複合片的厚度較佳為100~500μm,更佳為200~400μm。 The thickness of the film or composite sheet constituting the inner resin layer (13) is preferably 100 to 500 μm, more preferably 200 to 400 μm.
構成金屬箔層(11)與內側樹脂層(13)的膜或複合片的積層可透過黏著劑層(16),以乾式積層法進行。黏著劑層(16),可使用例如雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑或聚醚-聚胺基甲酸酯樹脂系黏著劑。 The lamination of the film or composite sheet constituting the metal foil layer (11) and the inner resin layer (13) can be carried out by a dry lamination method through the adhesive layer (16). For the adhesive layer (16), for example, a two-component curing type polyester-urethane resin adhesive or a polyether-urethane resin adhesive can be used.
又,亦可由環氧樹脂或蟲膠(shellac)樹脂等的塗布層來形成內側樹脂層(13),以代替上述膜或複合片。 In addition, the inner resin layer (13) may be formed of a coating layer of epoxy resin or shellac resin, etc., instead of the above-mentioned film or composite sheet.
第二圖中依照步驟顯示包裝體的製造方法,該包裝體係使用上述積層體所形成的成形容器與蓋體以將食品等的內容物密封包裝而成。 The second figure shows the manufacturing method of the packaging body in accordance with the steps. The packaging system uses the molded container and the lid formed by the above-mentioned laminate to seal and package the contents such as food.
首先,將上述的積層體(10)裁切為既定的形狀、尺寸,並使其形成杯狀。積層體(10)之成形,可藉由深抽成形或拉伸成形等的冷軋成形進行。如此,可得到第二(a)圖所示的成形容器(2)。 First, the above-mentioned laminated body (10) is cut into a predetermined shape and size, and is formed into a cup shape. The forming of the laminated body (10) can be performed by cold rolling forming such as deep drawing forming or stretch forming. In this way, the shaped container (2) shown in the second (a) figure can be obtained.
成形容器(2)具備:底壁(21);周壁(22),其從底壁(21)之周緣立起;及水平環狀的凸緣(23),其從周壁(22)之上端緣往徑向外側延伸。 The shaped container (2) is provided with: a bottom wall (21); a peripheral wall (22) which rises from the peripheral edge of the bottom wall (21); and a horizontal ring-shaped flange (23) which extends from the upper edge of the peripheral wall (22) Extend radially outward.
此處,成形後的成形容器(2)之外表面中的一部分,特別是底壁(21)與周壁(22)邊界的轉角部分生成白濁,可能導致金屬箔層(11)表面的顏色或印刷層(15)之標示被隱蔽而無法被看見。這被認為是因為成形積層體(10),在單層的外側樹脂膜層(12)或多層的外側樹脂膜層(12)之中的最外層中的聚烯烴樹脂的基質與烯烴系彈性體的界面產生孔洞(空隙),並因為樹脂部分與孔洞的折射率差,導致在成形容器(2)之外表面中,因成形而變形程度大的轉角部分看起來呈現白濁。 Here, a part of the outer surface of the molded container (2) after molding, especially the corner part of the boundary between the bottom wall (21) and the peripheral wall (22), may become cloudy, which may cause the color or printing on the surface of the metal foil layer (11) The markings on layer (15) are concealed and cannot be seen. This is considered to be due to the formation of the laminate (10), the polyolefin resin matrix and the olefin elastomer in the outermost layer of the single-layer outer resin film layer (12) or the multilayer outer resin film layer (12) Pores (voids) are generated at the interface of the resin, and because of the difference in refractive index between the resin part and the pores, the corner part of the outer surface of the molded container (2) that is deformed by molding appears to be cloudy.
接著,如第二(b)圖所示,在成形容器(2)中填充食品等的內容物(C)後,將蓋體(3)下表面的周緣部熔接於成形容器(2)之凸緣(23)的上表面。 Next, as shown in the second (b) figure, after filling the molded container (2) with the contents (C) such as food, the peripheral edge of the lower surface of the lid (3) is welded to the convex of the molded container (2) The upper surface of the rim (23).
蓋體(3)例如可具備:金屬箔層,其由鋁箔等所構成;熱熔接性樹脂膜層,由聚丙烯樹脂(PP)膜、其由聚乙烯樹脂(PE)膜等所形成,且積層於金屬箔層的下表面;及外側樹脂膜層,其由聚酯樹脂(PS)膜或聚醯胺樹脂(PA)膜等所形成,且積層於金屬箔層的上表面。又,蓋體(3)中的開封用舌片(31)以比成形容器(2)之凸緣(23)更向外側突出的方式一體成形於其外周緣的一部分(參照第三圖)。 The cover (3) may include, for example, a metal foil layer made of aluminum foil or the like; a heat-sealable resin film layer made of polypropylene resin (PP) film, polyethylene resin (PE) film, etc., and Laminated on the lower surface of the metal foil layer; and an outer resin film layer, which is formed of a polyester resin (PS) film or a polyamide resin (PA) film, etc., and is laminated on the upper surface of the metal foil layer. In addition, the opening tongue (31) in the lid (3) is integrally formed on a part of the outer peripheral edge thereof so as to protrude more outward than the flange (23) of the molded container (2) (refer to the third figure).
將蓋體(3)熱熔接於成形容器(2)之凸緣(23)的手段並無特別限定,例如可藉由使凸緣(23)之上表面與蓋體(3)之下表面周緣部重合,以加熱至既定溫度(例如180℃左右)之熱板,對該等重合部分一邊施加既定壓力、一邊加熱既定時間而進行。 The means for thermally welding the lid (3) to the flange (23) of the molded container (2) is not particularly limited. For example, the upper surface of the flange (23) can be connected to the periphery of the lower surface of the lid (3). The partial overlap is performed by a hot plate heated to a predetermined temperature (for example, about 180° C.), and the overlapped portions are heated for a predetermined time while applying a predetermined pressure.
接著,將上述步驟中所得之包裝體(4)導入蒸餾殺菌裝置(5)內,進行蒸餾殺菌處理。該蒸餾殺菌處理步驟,兼作加熱處理步驟,用來使在成形容器(2)外表面之一部分所生成的白濁消失。 Next, the package (4) obtained in the above steps is introduced into the retort sterilization device (5), and the retort sterilization treatment is performed. This retort sterilization treatment step also serves as a heat treatment step to eliminate the white turbidity generated on a part of the outer surface of the molded container (2).
該步驟中的包裝體(4)之加熱溫度為積層體(10)之單層的外側樹脂膜層(12)或多層的外側樹脂膜層(12)之中的最外層之樹脂的軟化點以上的溫度。加熱溫度更佳為該樹脂的軟化點以上且小於熔解點的溫度。藉由使加熱溫度為該樹脂的軟化點以上的溫度,可緩和成形所造成的積層體(10)之應變,而容易填埋孔洞。又,藉由使加熱溫度小於該樹脂的熔解點之溫度,可在加熱後仍保持成形容器(2)之形狀。具體而言約為80℃以上,較佳為約100~180℃。加熱時間為5分鐘~3小時左右。 The heating temperature of the packaging body (4) in this step is above the softening point of the outermost resin film layer (12) of the single-layer outer resin film layer (12) of the laminate (10) or the outermost resin film layer (12) of the multilayer body (10) temperature. The heating temperature is more preferably a temperature higher than the softening point of the resin and lower than the melting point. By setting the heating temperature to a temperature higher than the softening point of the resin, the strain of the laminated body (10) caused by molding can be alleviated, and the holes can be easily filled. In addition, by making the heating temperature lower than the melting point of the resin, the shape of the molded container (2) can be maintained after heating. Specifically, it is about 80°C or higher, preferably about 100 to 180°C. The heating time is about 5 minutes to 3 hours.
另外,除了蒸餾殺菌處理以外,當然可藉由例如烘箱進行加熱處理,或藉由浸漬於溫水的處理等來進行加熱處理步驟。蒸餾殺菌處理以外的加熱處理的情況,亦可在成為包裝體(4)之前的步驟中,僅對於成形容器(2)進行加熱處理。 In addition to the retort sterilization treatment, it is of course possible to perform the heat treatment step by, for example, an oven for heat treatment, or by a treatment such as immersion in warm water. In the case of heat treatment other than the retort sterilization treatment, the heat treatment may be performed only on the molded container (2) in the step before becoming the package (4).
第三圖顯示蒸餾殺菌處理後的包裝體(4)。在成形容器(2)之外表面之中,原先在轉角部分等生成的白濁消失。這被認為是因為以蒸餾殺菌處理充分加熱成形容器(2),緩和了成形所造成的積層體(10)之應變,並填埋了孔洞。 The third figure shows the package (4) after the retort sterilization treatment. In the outer surface of the molded container (2), the white turbidity originally generated in the corner portion and the like disappears. This is believed to be because the molded container (2) was sufficiently heated by the retort sterilization treatment to alleviate the strain of the laminated body (10) caused by the molding and fill the holes.
如此,包裝體(4)具備具有整體外觀良好之消光外表面的成形容器(2),可對於有需求的人帶來高級感。 In this way, the packaging body (4) is provided with a molded container (2) with a matte outer surface with a good overall appearance, which can bring a sense of luxury to people in need.
接著說明本發明的實施例。然而本發明並不限於以下的實施例。 Next, an embodiment of the present invention will be described. However, the present invention is not limited to the following examples.
<實施例1> <Example 1>
作為金屬箔層,係準備以JIS H4160分類的A8021H-O所形成的鋁箔,在其兩面上塗布由聚丙烯酸、三價鉻化合物、水及醇所構成的化學轉化處理液,於180℃下進行乾燥,以使鉻附著量為10mg/m2的方式實施化學轉化處理,其厚度為120μm。作為外側樹脂膜層,係準備厚度50μm的單層無延伸聚丙烯樹脂膜(CPP),使用凹版印刷機以黑色印墨(DIC GRAPHICS公司製,商品名稱:PANACEA CVL-SP特墨805)在其單面的整個面上形成素面印刷層。又,作為內側樹脂層,係準備厚度300μm的高密度聚乙烯樹脂膜(HDPE)與聚丙烯樹脂膜(PP)之複合片(層比:50μm/250μm)。 As the metal foil layer, an aluminum foil made of A8021H-O classified according to JIS H4160 is prepared, and a chemical conversion treatment solution composed of polyacrylic acid, trivalent chromium compound, water and alcohol is coated on both sides at 180°C After drying, chemical conversion treatment was performed so that the chromium adhesion amount was 10 mg/m 2 , and the thickness was 120 μm. As the outer resin film layer, a single-layer non-stretched polypropylene resin film (CPP) with a thickness of 50μm was prepared, and a black ink (manufactured by DIC GRAPHICS, product name: PANACEA CVL-SP special ink 805) was used on a gravure printing machine. A plain printed layer is formed on the entire surface of a single side. In addition, as the inner resin layer, a composite sheet (layer ratio: 50 μm/250 μm) of a high-density polyethylene resin film (HDPE) and a polypropylene resin film (PP) with a thickness of 300 μm was prepared.
上述無延伸聚丙烯樹脂膜(CPP)中,樹脂組成物係使用在嵌段聚丙烯樹脂(PP-B)中添加了10質量%的乙烯-丁烯-1共聚物橡膠者(軟化點=97℃)。 In the above-mentioned non-stretched polypropylene resin film (CPP), the resin composition uses a block polypropylene resin (PP-B) with 10% by mass of ethylene-butene-1 copolymer rubber added (softening point = 97 ℃).
接著,在鋁箔的單面上,以使印刷層為內側的方式,使用雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑,乾式積層無延伸聚丙烯樹脂膜(CPP),而在鋁箔的另一面上,以使聚丙烯樹脂膜側為內側的方式,使用雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑,乾式積層該複合片,於40℃的環境下養護5天,藉此製作用於成形容器的積層體。 Next, on one side of the aluminum foil, a two-component curing type polyester-urethane resin adhesive is used so that the printed layer is inside, and a non-stretched polypropylene resin film (CPP) is dry laminated. On the other side of the aluminum foil, with the polypropylene resin film side as the inner side, a two-component curing type polyester-urethane resin adhesive was used to dry-laminate the composite sheet. After curing for 5 days in an environment, a laminate for forming a container was produced.
接著,再將上述用於成形容器的積層體裁切為既定形狀而成的空白試樣的兩面塗布微量的矽氧烷後,使用公模具及母模具所構成的模具進行深抽加工,藉此形成具有凸緣的圓形杯狀容器(底徑52mmφ,開口徑65mmφ,高度30mm,凸緣寬度8mm)。 Next, the blank sample obtained by cutting the laminate for forming the container into a predetermined shape is coated with a small amount of silicone on both sides, and then deep drawing is performed using a mold composed of a male mold and a female mold to form a blank sample. Round cup-shaped container with flange (bottom diameter 52mmφ, opening diameter 65mmφ, height 30mm, flange width 8mm).
另一方面,在以JIS H4160分類的A1N30H-O所形成的厚度20μm之鋁箔的單面,使用雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑,乾式積層 厚度12μm的聚對苯二甲酸乙二酯樹脂(PET)膜以作為外側樹脂層,並且在鋁箔的另一面,使用雙液硬化型的聚酯-聚胺基甲酸酯樹脂系黏著劑,乾式積層厚度30μm的直鏈狀低密度聚乙烯樹脂(LLDPE)膜以作為熱熔接性樹脂層,藉由在40℃的環境下養護5天,以製作蓋體用積層體。 On the other hand, on one side of aluminum foil with a thickness of 20μm formed by A1N30H-O classified by JIS H4160, a two-component curing type polyester-urethane resin adhesive is used for dry lamination. A 12μm thick polyethylene terephthalate resin (PET) film is used as the outer resin layer, and on the other side of the aluminum foil, a two-component curing type polyester-urethane resin adhesive, dry type A linear low-density polyethylene resin (LLDPE) film with a thickness of 30 μm was laminated as a heat-sealable resin layer, and cured in an environment of 40° C. for 5 days to produce a laminated body for lids.
將所得之積層體配合凸緣來裁切成所需要的形狀及尺寸,以製作附有開封用舌片的蓋體。 The obtained laminated body is cut into the desired shape and size according to the flange to produce the lid body with the tongue for opening.
在上述容器中放入70ml的水以後,於容器之凸緣的上表面,以直鏈狀低密度聚乙烯樹脂(LLDPE)膜的一面與其相接的方式重疊上述蓋體,再藉由加熱至200℃的環狀加熱板(外徑90mmφ,內徑74mmφ)以150kgf的加壓力按壓該等的重合面3秒,以進行熱封合(熱熔接)。藉此得到實施例1的包裝體。 After putting 70ml of water in the container, on the upper surface of the flange of the container, overlap the cover with one side of the linear low-density polyethylene resin (LLDPE) film in contact with it, and then heat it to A 200°C ring-shaped heating plate (outer diameter 90 mmφ, inner diameter 74 mmφ) is pressed against the overlapping surfaces of the same with a pressure of 150 kgf for 3 seconds to perform heat sealing (heat welding). Thus, the package of Example 1 was obtained.
<比較例1> <Comparative Example 1>
使用依序積層無規聚丙烯樹脂(PP-R)膜、嵌段聚丙烯樹脂(PP-B)膜及無規聚丙烯樹脂(PP-R)膜而成的厚度30μm的3層結構的無延伸聚丙烯樹脂膜(CPP)作為用於成形容器的積層體的外側樹脂膜層,其他則是以與實施例1相同的要領製作包裝體,並將此作為比較例1。 A three-layer structure with a thickness of 30μm, which is composed of a random polypropylene resin (PP-R) film, a block polypropylene resin (PP-B) film, and a random polypropylene resin (PP-R) film, is laminated in sequence. The stretched polypropylene resin film (CPP) was used as the outer resin film layer of the laminate for forming the container, and the other package was produced in the same manner as in Example 1, and this was used as Comparative Example 1.
針對實施例1及比較例1的包裝體,以光澤度測量器(BYK Gardner公司製 微三光澤S)測量容器的外表面的光澤度時,實施例1中為6%,比較例1中為100%。 Regarding the packaging bodies of Example 1 and Comparative Example 1, when the glossiness of the outer surface of the container was measured with a gloss measuring instrument (Micro Trigloss S manufactured by BYK Gardner), it was 6% in Example 1, and it was in Comparative Example 1. 100%.
又,以目視觀察實施例1及比較例1之包裝體的成形容器的外觀。實施例1中,在成形容器的外表面之中,於底壁與周壁邊界的轉角部分發現嚴重白化。另一方面,比較例1中,在成形容器的外表面未發現白化。 In addition, the appearance of the molded container of the packaging bodies of Example 1 and Comparative Example 1 was visually observed. In Example 1, in the outer surface of the shaped container, severe whitening was found in the corner portion of the boundary between the bottom wall and the peripheral wall. On the other hand, in Comparative Example 1, whitening was not found on the outer surface of the molded container.
接著,藉由恆溫恆濕烘箱(ESPEC股份有限公司製PL-1J型),對於實施例1的包裝體在加熱溫度100℃下實施加熱處理60分鐘後,將其從烘箱取出,並以目視觀察成形容器的外表面時,雖在轉角部分留有些許白化,但大部分消失。 Next, the package of Example 1 was heat-treated at a heating temperature of 100°C for 60 minutes in a constant temperature and humidity oven (PL-1J type manufactured by ESPEC Co., Ltd.), then it was taken out from the oven and visually observed When forming the outer surface of the container, although a little whitening remains in the corners, most of it disappears.
又,藉由蒸餾殺菌處理裝置(日阪製作所製RCS-40RTGN),在加熱溫度120℃下對實施例1的包裝體實施加熱處理30分鐘後,將其從相同裝置取出,並以目視觀察成形容器的外表面時,轉角部分的白化完全消失。 In addition, the package of Example 1 was heat-treated at a heating temperature of 120°C for 30 minutes with a retort sterilization treatment device (RCS-40RTGN manufactured by Nisaka Manufacturing Co., Ltd.), then it was taken out from the same device, and the shape was visually observed. On the outer surface of the container, the whitening of the corners completely disappeared.
本發明係用於密封包裝食品等,其可較佳地用於具有外觀良好之消光外表面的成形容器。 The present invention is used for sealing and packaging foods, etc., and it can be preferably used for shaped containers with a matte outer surface with good appearance.
(10):用於成形容器的積層體 (10): Laminated body for forming containers
(11):金屬箔層 (11): Metal foil layer
(12):外側樹脂膜層 (12): Outer resin film layer
(12a):外側樹脂膜層的外表面 (12a): The outer surface of the outer resin film layer
(13):內側樹脂層 (13): Inner resin layer
(14):黏著劑層 (14): Adhesive layer
(15):印刷層 (15): Printing layer
(16):黏著劑層 (16): Adhesive layer
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JP2018212431A JP7250482B2 (en) | 2017-12-15 | 2018-11-12 | Laminate for molded container, molded container and package, and method for manufacturing molded container and package |
JP2018-212431 | 2018-11-12 |
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TW107140327A TWI745636B (en) | 2017-12-15 | 2018-11-14 | Layered body for forming container, forming container and packaging body, and manufacturing method of forming container and packaging body |
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KR (2) | KR20190073272A (en) |
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CN215362758U (en) * | 2020-07-29 | 2021-12-31 | 深圳市望盛科技有限公司 | Production equipment for composite packaging box and composite packaging box |
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JP2017206283A (en) * | 2016-05-18 | 2017-11-24 | 昭和電工パッケージング株式会社 | Laminated sheet for container and container |
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JP3175306B2 (en) | 1992-05-26 | 2001-06-11 | チッソ株式会社 | Matte polypropylene film |
JP2866916B2 (en) | 1993-06-11 | 1999-03-08 | 昭和アルミニウム株式会社 | High barrier molded container |
US6322894B1 (en) * | 1999-05-07 | 2001-11-27 | Exxonmobil Oil Corporation | Matte surface film with improved cuttability |
JP2002337282A (en) | 2001-05-22 | 2002-11-27 | Oji Paper Co Ltd | Satin-like film |
US20040142188A1 (en) * | 2003-01-17 | 2004-07-22 | Peet Robert G. | Colored film structure |
JP2011148301A (en) | 2009-12-22 | 2011-08-04 | Toyobo Co Ltd | Mat hard coat film for molding |
KR20230035456A (en) | 2011-03-29 | 2023-03-13 | 가부시키가이샤 레조낙·패키징 | Molding packaging material and battery case |
CN103524882A (en) * | 2013-10-29 | 2014-01-22 | 大韩道恩高分子材料(上海)有限公司 | Polyolefin resin composition with lusterless characteristic |
JP6279973B2 (en) | 2014-05-16 | 2018-02-14 | 昭和電工パッケージング株式会社 | Molding packaging material and molding case |
CN106184957B (en) * | 2015-06-01 | 2019-04-19 | 昭和电工包装株式会社 | Container and package body |
CN106739367B (en) * | 2016-11-08 | 2019-04-19 | 佛山杜邦鸿基薄膜有限公司 | A kind of single-face matt polyester film and preparation method thereof |
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JP2017206283A (en) * | 2016-05-18 | 2017-11-24 | 昭和電工パッケージング株式会社 | Laminated sheet for container and container |
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JP7493075B2 (en) | 2024-05-30 |
JP2023090705A (en) | 2023-06-29 |
CN109927367A (en) | 2019-06-25 |
TW201927554A (en) | 2019-07-16 |
KR20230153320A (en) | 2023-11-06 |
KR20190073272A (en) | 2019-06-26 |
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