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SK285145B6 - Metalocénové zlúčeniny, medziprodukt na ich prípravu, spôsob ich prípravy a ich použitie ako polymerizačných katalyzátorových zložiek na polymerizáciu a kopolymerizáciu olefínov - Google Patents

Metalocénové zlúčeniny, medziprodukt na ich prípravu, spôsob ich prípravy a ich použitie ako polymerizačných katalyzátorových zložiek na polymerizáciu a kopolymerizáciu olefínov Download PDF

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Publication number
SK285145B6
SK285145B6 SK1008-98A SK100898A SK285145B6 SK 285145 B6 SK285145 B6 SK 285145B6 SK 100898 A SK100898 A SK 100898A SK 285145 B6 SK285145 B6 SK 285145B6
Authority
SK
Slovakia
Prior art keywords
group
tert
indenyl
alkyl
hydrogen
Prior art date
Application number
SK1008-98A
Other languages
English (en)
Slovak (sk)
Other versions
SK100898A3 (en
Inventor
Reko Leino
Hendrik Luttikhedde
Carl-Erik Wilen
Jan N�Sman
Original Assignee
Borealis A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis A/S filed Critical Borealis A/S
Publication of SK100898A3 publication Critical patent/SK100898A3/sk
Publication of SK285145B6 publication Critical patent/SK285145B6/sk

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
SK1008-98A 1996-01-30 1997-01-30 Metalocénové zlúčeniny, medziprodukt na ich prípravu, spôsob ich prípravy a ich použitie ako polymerizačných katalyzátorových zložiek na polymerizáciu a kopolymerizáciu olefínov SK285145B6 (sk)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI960437A FI104826B (fi) 1996-01-30 1996-01-30 Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
PCT/FI1997/000049 WO1997028170A1 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them

Publications (2)

Publication Number Publication Date
SK100898A3 SK100898A3 (en) 1999-03-12
SK285145B6 true SK285145B6 (sk) 2006-07-07

Family

ID=8545178

Family Applications (1)

Application Number Title Priority Date Filing Date
SK1008-98A SK285145B6 (sk) 1996-01-30 1997-01-30 Metalocénové zlúčeniny, medziprodukt na ich prípravu, spôsob ich prípravy a ich použitie ako polymerizačných katalyzátorových zložiek na polymerizáciu a kopolymerizáciu olefínov

Country Status (20)

Country Link
US (1) US6277778B1 (zh)
EP (1) EP0880534B1 (zh)
JP (1) JP4051089B2 (zh)
KR (1) KR19990082158A (zh)
CN (1) CN1089342C (zh)
AR (1) AR005612A1 (zh)
AT (1) ATE256691T1 (zh)
AU (1) AU722731B2 (zh)
BR (1) BR9707236A (zh)
CZ (1) CZ297674B6 (zh)
DE (1) DE69726841T2 (zh)
ES (1) ES2212070T3 (zh)
FI (1) FI104826B (zh)
HU (1) HUP9902106A3 (zh)
IL (1) IL125542A (zh)
MY (1) MY120110A (zh)
SK (1) SK285145B6 (zh)
TW (1) TW442509B (zh)
WO (1) WO1997028170A1 (zh)
ZA (1) ZA97766B (zh)

Families Citing this family (212)

* Cited by examiner, † Cited by third party
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IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
JP3955140B2 (ja) * 1996-10-31 2007-08-08 レプソル・ケミカ・ソシエダ・アノニマ アルフアオレフインの重合及び共重合用触媒系
FI971565A (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
EP0953581B1 (en) * 1998-04-27 2004-01-07 Repsol Quimica S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
FI981148A (fi) 1998-05-25 1999-11-26 Borealis As Uusia aktivaattorijärjestelmä metalloseeniyhdisteitä varten
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
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