KR101579804B1 - Manufacturing methode of liquid self waterproofing admixture, composition and methode of construction using the same - Google Patents
Manufacturing methode of liquid self waterproofing admixture, composition and methode of construction using the same Download PDFInfo
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- KR101579804B1 KR101579804B1 KR1020150053689A KR20150053689A KR101579804B1 KR 101579804 B1 KR101579804 B1 KR 101579804B1 KR 1020150053689 A KR1020150053689 A KR 1020150053689A KR 20150053689 A KR20150053689 A KR 20150053689A KR 101579804 B1 KR101579804 B1 KR 101579804B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
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Abstract
Description
More particularly, the present invention relates to a liquid type concrete waterproofing agent capable of imparting water resistance to a concrete structure itself by mixing concrete into a concrete mixer, a method for manufacturing the same, and a construction method using the same.
Concrete is composed of aggregates such as water, cement, sand, and gravel, and is used to form building structures such as buildings, bridges, and tunnels by using a hydration reaction that hardens by reacting cement and water.
The concrete structure is divided into the underground layer buried in the ground and the surface layer exposed to the air. The underground layer is always in contact with water and the durability may be lowered due to repeated shrinkage and expansion due to the temperature change. The durability of concrete is especially affected by moisture, and water acts as a medium to deteriorate concrete. Dissolved sulfate, nitrate, carbonate, and acid rain can accelerate the damage of concrete structure.
It is inevitable that voids are formed inside the concrete in the hydration reaction, which is the process of curing the concrete, and this internal void becomes the path through which the water penetrates into the concrete structure. Water penetration through the internal pores can cause microcracks, which can deteriorate the waterproofing performance of the concrete, and can also significantly affect the life of the concrete structure while corroding the rebar.
As concrete methods for imparting waterproofness to concrete, there are a method of forming a waterproof film on a concrete surface, a method of penetrating a waterproofing agent to a certain depth, a method of preventing pores and cracks in a concrete, and the like, Is called concrete waterproofing. Spherical waterproofing is implemented by a method of reducing the amount of water to reduce the generation of internal voids, a method of filling the internal voids with fine particles, a method of preventing moisture penetration by mixing water repellent materials, and the like.
A prior art document relating to a concrete ballast waterproofing agent is Korean Patent Publication No. 2009-100885. This prior art document discloses that 35 to 42% by weight of oleic acid, 30 to 32% by weight of butylcellosolve, 10 to 15% by weight of monoethanolamine, 3 to 5% by weight of phosphorus pentoxide, 5 to 10% by weight of fluidizing agent, % And water in an amount of 10 to 15% by weight based on the total weight of the concrete. However, the sphere water repellent agent disclosed in the above literature is limited only by the water-repellent performance by the water-repellent component, and thus has a limitation in improving the waterproof performance. Therefore, there is a great need for the development of a new liquid spherical water repellent agent that exhibits waterproof performance by various mechanisms and is excellent in workability.
SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a method for producing a water-repellent agent for liquid spheres, which is improved in workability while exhibiting waterproof performance by various mechanisms.
In order to attain the above object, the present invention provides a process for producing a sulfonated naphthalene formaldehyde condensate, which comprises mixing 100 parts by weight of water, 15 to 20 parts by weight of stearic acid amide, 15 to 20 parts by weight of oleic acid, 40 to 50 parts by weight of a sulfonated naphthalene formaldehyde condensate, 2 parts by weight of an aqueous ammonia solution, 5 to 10 parts by weight of an aqueous ammonia solution and 0.5 to 1 part by weight of a surfactant, and stirring the mixture at a temperature of 80 to 90 DEG C for 15 minutes to prepare a water- 2 to 3 parts by weight of silica fume, 20 to 30 parts by weight of active silica, 3 to 5 parts by weight of diatomaceous earth and 10 to 15 parts by weight of water-soluble latex were mixed and stirred at a temperature of 70 to 90 DEG C for 15 minutes, Mixing the water-repellency-imparting mixed solution and the inorganic particle-filled dispersion solution at a weight ratio of 1: 0.5 to 1: 0.8, stirring the mixture at a temperature of 70 to 80 DEG C for 10 minutes, A third step of preparing a base waterproof base solution, mixing 1 to 2 parts by weight of sodium lauryl sulfate and 1 to 2 parts by weight of sodium benzoate into 100 parts by weight of the base water-repellent base solution and heating at 70 to 80 캜 for 10 minutes And a fourth step of preparing a concrete waterproofing liquid by stirring.
According to an embodiment of the present invention, the method further comprises, after the fourth step, mixing 0.5 to 1 part by weight of the hydrogel particles into 100 parts by weight of the spherical waterproofing liquid and stirring the mixture at room temperature for 10 minutes while applying ultrasonic waves .
According to another embodiment of the present invention, it is preferable that the hydrogel particles have a diameter of 5 to 20 microns.
The method for producing a liquid-filled concrete waterproofing agent of the present invention has the following effects.
1. Water repellency In the manufacturing process of mixed solution, fatty acid metal salt is generated and water repellency is given to the inside of concrete, thereby improving the waterproof performance of concrete.
2. Inorganic Particle-Filled Dispersion Solution contains inorganic particles such as silica fume and activated silica. These inorganic particles fill the internal voids to make the internal structure of the concrete more dense, and in particular, inorganic particles of different diameters are used The watertightness can be further improved.
3. The inorganic particle-filled dispersion liquid is mixed with a water-soluble resin, so that the aggregation of the inorganic particles can be prevented and the dispersibility of the inorganic particles can be improved.
4. Since the fluidity agent and the air entraining agent are included as the components of the concrete waterproofing agent, the mixing ratio of water can be reduced while improving the workability, so that water tightness can be further improved.
5. Because the hydrogel particles are contained in the spherical water repellent agent, when the water penetrates into the inside, the water is effectively prevented from penetrating into the depth by the expansion action of the hydrogel particles.
6. Corrosion inhibitor is included to prevent corrosion of reinforcing bars and so on.
Fig. 1 is a view showing a process for producing the liquid-phase-containing water repellent agent of the present invention in order.
The method for producing a liquid-filled concrete waterproofing agent according to the present invention comprises 100 parts by weight of water, 15 to 20 parts by weight of stearic acid amide, 15 to 20 parts by weight of oleic acid, 40 to 50 parts by weight of sulfonated naphthalene formaldehyde condensate, 2 parts by weight of an aqueous ammonia solution, 5 to 10 parts by weight of an aqueous ammonia solution and 0.5 to 1 part by weight of a surfactant, and stirring the mixture at a temperature of 80 to 90 DEG C for 15 minutes to prepare a water- 2 to 3 parts by weight of silica fume, 20 to 30 parts by weight of active silica, 3 to 5 parts by weight of diatomaceous earth and 10 to 15 parts by weight of water-soluble latex were mixed and stirred at 70 to 90 ° C for 15 minutes to obtain inorganic particle- Mixing the water-repellency-imparting mixed solution and the inorganic particle-filled dispersion solution at a weight ratio of 1: 0.5 to 1: 0.8, stirring the mixture at a temperature of 70 to 80 DEG C for 10 minutes, A third step of preparing a base waterproof base solution, mixing 1 to 2 parts by weight of sodium lauryl sulfate and 1 to 2 parts by weight of sodium benzoate into 100 parts by weight of the base water-repellent base solution and heating at 70 to 80 캜 for 10 minutes And a fourth step of preparing a concrete waterproofing liquid by stirring.
Fig. 1 is a view showing a process for producing the liquid-phase-containing water repellent agent of the present invention in order. 1, the method for manufacturing a liquid-repellent water repellent agent of the present invention comprises the steps of preparing a water repellency-imparting mixed solution (S1), preparing an inorganic particle-filled dispersion solution (S2) A step S4 of producing a waterproofing liquid and a step S5 of mixing the hydrogel particles. It is preferable that the above-mentioned steps proceed sequentially, and each step functions to mix the components exhibiting waterproof performance into components of the concrete waterproofing agent by different mechanisms.
The first step is the preparation of the water repellent admixture solution. The water-repellent mixing solution contains a fatty acid salt as a basic water-repellent component, and contains a fluidizing agent and a surfactant. The water-repellent component may be produced by reacting stearic acid amide and oleic acid with an aqueous ammonia solution, and the stearic acid amide may specifically be N, N'-methylenebisstearic acid amide. Stearic acid amide and aqueous ammonia solution of oleic acid have the function of pushing the moisture penetrating into the concrete by including the hydrophobic group in the fatty acid salts such as stearate and olive phosphate. The stearic acid amide is preferably 15 to 20 parts by weight based on 100 parts by weight of water as a solvent and 15 to 20 parts by weight relative to 100 parts by weight of water. If the amounts of stearic acid amide and oleic acid are less than 15 parts by weight each, the water repellency is deteriorated excessively, and if it exceeds 20 parts by weight, the strength of the concrete may be lowered. The amount of the ammonia aqueous solution is preferably 5 to 10 parts by weight relative to 100 parts by weight of water as a solvent. If the amount of the aqueous ammonia solution is less than 5 parts by weight, unreacted stearic acid and oleic acid may be present. If the amount is more than 10 parts by weight, corrosion of aggregates and the like may occur due to ammonia.
The water repellent-imparting mixed solution may further contain a fluidizing agent and a surfactant. The fluidizing agent may be a sulphonated melamine formaldehyde condensate (SM), sodium naphthionate, or the like. The fluidizing agent is included in the concrete composition to lower the viscosity, and it is possible to reduce the mixing amount of the minimum amount of water for workability and thus to inhibit the formation of pores in the concrete. The sulfonated naphthalene formaldehyde condensate, which is a fluidizing agent, is preferably mixed at 40 to 50 parts by weight with respect to 100 parts by weight of water as a solvent. When the amount is less than 40 parts by weight, the effect of imparting fluidity is excessively small. Can be degraded. Another fluidizing agent, sodium naphthionate, has the function of functioning as a fluidizing agent and a function of forming a fatty acid salt by reacting a part of oleic acid with stearic acid amide. The addition of sodium naphthonate further improves water repellency. The amount of sodium naphthoate to be added is preferably 1 to 2 parts by weight relative to 100 parts by weight of water as a solvent. When the content of sodium naphthonate is less than 1 part by weight, the fatty acid salt forming effect is less likely to be produced, and when it exceeds 2 parts by weight, rebar corrosion due to the sodium component may occur. The surfactant is required for the dispersion of stearic acid amide and oleic acid. Specifically, the surfactant may be an alkyl benzene sulfonate. The amount thereof is preferably 0.5 to 1 part by weight based on 100 parts by weight of water as a solvent. The water-repellent mixing solution is preferably prepared at 80 to 90 ° C. for 10 to 20 minutes. This temperature condition is favorable for the dissolution of fatty acids such as stearic acid amide and oleic acid.
The second step is the step of preparing the inorganic particle-filled dispersion solution. The inorganic particle-filled dispersion solution contains fine particles such as silica fume, activated silica, diatomaceous earth. These inorganic particles are contained within the concrete structure to fill the internal voids created in the hydration reaction. It is preferable that silica fume, activated silica and diatomaceous earth have different particle sizes, and silica fume is preferably larger in particle size than active silica and diatomaceous earth. When inorganic particles of different particle sizes are mixed, it is more advantageous to fill voids of various sizes. The particle size of the silica fume is preferably in the range of 50 to 300 microns, and the particle size of the active silica and the diatomaceous earth is preferably in the range of 10 to 50 microns. The inorganic particle-filled dispersion solution further comprises a water-soluble latex. The water-soluble latex enhances the viscosity of the inorganic particle-filled dispersion solution, thereby helping the inorganic particles to be more uniformly dispersed in the inorganic particle-filled dispersion solution. As a polymer resin, the concrete forms a fine membrane So as to fundamentally prevent the movement path of the water. The amount of silica fume is preferably 2 to 3 parts by weight, more preferably 20 to 30 parts by weight, and the amount of diatomaceous earth is preferably 3 to 5 parts by weight relative to 100 parts by weight of water as a dispersion liquid. Silica, and diatomaceous earth in consideration of the desired particle size. The amount of the water-soluble latex is preferably 10 to 15 parts by weight. The inorganic particle-filled dispersion liquid is preferably prepared under stirring conditions at a temperature of 70 to 90 DEG C for 10 to 20 minutes.
In the third step, the water repellent-imparting mixed solution prepared in the first step and the inorganic particle-filled dispersing solution prepared in the second step are mixed to prepare a basic waterproof base solution. At this time, the mixing ratio of the water repellency-imparting mixed solution to the inorganic particle-filled dispersion solution is preferably 1: 0.5 to 1: 0.8 by weight. When the mixing ratio of the inorganic particle-filled dispersion solution is less than 1: 0.5, the void filling effect due to the inorganic particles is insufficient and large voids can be formed inside. When the mixing ratio is more than 1: 0.8, The waterproof effect may be insufficient due to the deterioration of the effect. The mixing of the water repellent-imparting mixed solution and the inorganic particle-filled dispersion solution is preferably performed at a temperature of 70 to 80 캜 for 5 to 15 minutes.
The fourth step is to mix the air-entraining agent and the corrosion inhibitor into the concrete waterproofing base solution prepared in the third step to prepare a concrete waterproofing solution. The air entraining agent functions to regulate the viscosity and the air distribution of the concrete mixture by generating fine bubbles. Specifically, sodium lauryl sulfate can be used. The corrosion inhibitor functions to prevent corrosion of reinforcing bars and the like inside the concrete, and sodium benzoate can be used specifically. The amount of the air entraining agent is preferably 1 to 2 parts by weight based on 100 parts by weight of the concrete waterproof base solution, and the amount of the corrosion inhibitor is preferably 1 to 2 parts by weight relative to 100 parts by weight of the specific waterproof base solution. The mixing of the air entraining agent and the anticorrosive agent is preferably carried out at a temperature of 70 to 80 캜 for 5 to 15 minutes.
The fifth step is to mix the hydrogel particles with the spherical water solution prepared in the fourth step. The hydrogel particles are preferably mixed at a ratio of 0.5 to 1 part by weight with respect to 100 parts by weight of the spherical waterproofing solution, and the mixing time of the hydrogel particles is preferably 5 to 15 minutes. When the mixing amount of the hydrogel particles is less than 0.5 part by weight, the waterproof effect by the hydrogel particles is excessively small, and if it exceeds 1 part by weight, the strength may be lowered. The hydrogel particle is a polymer resin particle having a property of absorbing water and expanding, and may be specifically poly-2-hydroxyethylmethacrylate (PHEMA). The hydrogel particles are dispersed in the concrete structure, and when moisture penetrates from the surface, the hydrogel particles expand while absorbing moisture. The hydrogel particles located in the pores of the concrete fill the voids while expanding and function to prevent moisture from penetrating into the interior. Hydrogel particles basically absorb water and expand. However, water absorbed in water is discharged to the outside depending on the concentration of the salt contained in the water. Since there are many kinds of salts in the liquid spherical water repellent agent, the hydrogel particles are present in a state in which the liquid gel precursor is present in the waterproofing agent or concrete composition in a relatively unexpanded state. The hydrogel, which was dispersed in the cured concrete spherical state, functions to prevent water from penetrating any more because it absorbs moisture while filling underground water or rainwater from the outside. The particle size of the hydrogel particles is preferably 5 to 20 microns. If the particle size of the hydrogel particles is less than 5 microns, the preparation is difficult, while if the particle size exceeds 20 microns, dispersion becomes difficult.
The liquid spherical water repellent prepared by the above method can be used to produce concrete or mortar having high waterproofness when mixed with a concrete or mortar composition, including a water repellency imparting material, an inorganic particle filling material, hydrogel particles and the like. These liquid-filled concrete waterproofing agents must be mixed into the concrete or mortar composition prior to casting, and may be mixed into the concrete or mortar composition by in-situ mixing or plant mixing. Field mixing is a method of mixing directly into a mix truck and mixing the liquid spheres with a water repellent agent into the mix truck and mixing them uniformly at high speed for 3 minutes or more. Factory mixing is a method of mixing liquid concrete waterproofing agent in a batcher plant which is a facility for manufacturing a large amount of concrete or mortar composition, and it is a method of mixing 3 to 3.5 kg May be added to the mixed water.
Hereinafter, the present invention will be described in more detail with reference to examples and evaluation examples.
Example 1 (Preparation of water-repellent agent for liquid spheres)
As the first step for the preparation of the liquid spherical water repellent agent, 175 g of N, N'-methylenebisstearic acid amide, 175 g of oleic acid, 450 g of sulfonated naphthalene formaldehyde condensate, 15 g of sodium naphthonate, 70 g of aqueous ammonia, Benzenesulfonate were mixed. The mixed solution was stirred at a temperature of 85 캜 for 15 minutes to prepare a water-repellent mixed solution.
In the second step, 25 g of silica fume, 250 g of active silica, 40 g of diatomaceous earth and 120 g of water-soluble latex were mixed with 1 L of water and stirred at 80 캜 for 15 minutes to prepare an inorganic particle-filled dispersion solution.
Then, in the third step, the water repellency-imparting mixed solution and the inorganic particle-filled dispersion solution were mixed at a weight ratio of 1: 0.65 and stirred at a temperature of 70 to 80 캜 for 10 minutes to prepare a base water-repellent base solution.
Then, in a fourth step, 15 g of sodium lauryl sulfate and 15 g of sodium benzoate were mixed with 1000 g of the base water-repellent base solution and stirred at 75 캜 for 10 minutes to prepare a concrete waterproof solution.
Example 2 (Preparation of water-repellent agent for liquid spheres)
After the fourth step in Example 1, 7.5 g of poly-2-hydroxyethylmethacrylate particles (average particle size: 10 microns) were mixed with 1000 g of the concrete waterproofing liquid and stirred at room temperature for 10 minutes while applying ultrasonic waves In addition, a liquid-filled concrete waterproofing agent was prepared.
Example 1-1 (Preparation of concrete composition)
In order to measure the strength, absorption ratio and permeability ratio of the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.2% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Example 1-2 (Preparation of concrete composition)
In order to measure the strength, the absorption ratio, and the permeability ratio with respect to the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.5% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Example 1-3 (Preparation of concrete composition)
In order to measure the strength, absorption ratio and permeability ratio of the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.7% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Example 2-1 (Preparation of concrete composition)
In order to measure the strength, absorption ratio and permeability ratio of the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.2% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Example 2-2 (Preparation of concrete composition)
In order to measure the strength, absorption ratio and permeability ratio of the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.5% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Example 2-3 (Preparation of concrete composition)
In order to measure the strength, absorption ratio and permeability ratio of the concrete composition, the mortar mixed with 1000 parts by weight of Portland cement, 2450 parts by weight of sand and 500 parts by weight of water, 0.7% by weight, and the mixture was stirred at room temperature for 5 minutes to prepare a mortar composition.
Comparative Example (Preparation of concrete composition)
A mortar composition was prepared in the same manner as in Example 2-1, except that the liquid concrete waterproofing liquid was not added to measure the strength, the absorption ratio, and the permeability ratio with respect to the concrete composition.
The composition ratios of the concrete compositions prepared according to Examples 1-1 to Comparative Examples are summarized in Table 1 below.
[Table 1]
Evaluation example (compression strength and waterproof performance evaluation)
The compressive strength ratio, the absorption ratio, and the permeability ratio were measured according to the evaluation methods specified in KS F 2405 and KS F 4926 by using the mortar compositions of the examples and comparative examples.
The evaluation results are summarized in Table 2 below. It was confirmed that the results of the examples were superior to those of the comparative example in the absorption ratio and the permeability ratio. In particular, the absorption ratio and permeability ratio of Examples 2-1 to 2-3 were excellent.
[Table 2]
While the present invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. Therefore, the embodiments described in the present invention are not intended to limit the scope of the present invention but to limit the scope of the present invention. The scope of protection of the present invention should be construed according to the claims, and all technical ideas within the scope of equivalents should be construed as falling within the scope of the present invention.
Claims (3)
100 parts by weight of water (dispersion medium), 2.5 parts by weight of silica fume having a particle size of 50 to 300 microns, 25 parts by weight of active silica having a particle size of 10 to 50 microns, 4 parts by weight of diatomaceous earth having a particle size of 10 to 50 micron and 12 parts by weight of water- , And stirred at a temperature of 80 캜 for 15 minutes to prepare an inorganic particle-filled dispersion solution;
A third step of mixing the water repellency-imparting mixed solution and the inorganic particle-filled dispersion solution at a weight ratio of 1: 0.65 and stirring the mixture at a temperature of 70 to 80 캜 for 10 minutes;
A fourth step of mixing 1.5 parts by weight of sodium lauryl sulfate and 1.5 parts by weight of sodium benzoate into 100 parts by weight of the concrete waterproof base solution and stirring the mixture at 75 DEG C for 10 minutes to prepare a concrete waterproofing solution; And
And a fifth step of mixing 0.75 part by weight of particles of poly-2-hydroxyethyl methacrylate having a particle size of 5 to 20 microns into 100 parts by weight of the spherical waterproofing liquid and stirring at room temperature for 10 minutes while applying ultrasonic waves. A method for producing a waterproofing agent.
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| PCT/KR2016/000761 WO2016167451A1 (en) | 2015-04-16 | 2016-01-25 | Method for preparing liquid waterproofing admixture, waterproofing admixture composition prepared thereby, and construction method using same |
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Cited By (4)
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| CN105645838A (en) * | 2016-03-09 | 2016-06-08 | 文登蓝岛建筑工程有限公司 | Composite silicon concrete waterproofer and preparation method thereof |
| CN111233370A (en) * | 2020-01-19 | 2020-06-05 | 广西大胡子防水科技有限公司 | Self-compacting waterproof agent for concrete structure and preparation method and application thereof |
| KR102220462B1 (en) | 2020-07-22 | 2021-02-25 | 박영진 | Alkali metal liquid nano-composite-silicate-based permeable waterproofing agent and concrete structure penetration waterproofing method |
| KR102222895B1 (en) | 2020-07-22 | 2021-03-04 | 박영진 | Floor finishing method by concrete polishing using concrete permeable surface strengthening agent and penetration prevention agent |
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| CN116477864B (en) * | 2023-03-23 | 2024-02-23 | 万舟伟业(北京)科技集团有限公司 | Anti-cracking waterproof compacting agent, preparation method and use method |
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| CN105645838A (en) * | 2016-03-09 | 2016-06-08 | 文登蓝岛建筑工程有限公司 | Composite silicon concrete waterproofer and preparation method thereof |
| CN111233370A (en) * | 2020-01-19 | 2020-06-05 | 广西大胡子防水科技有限公司 | Self-compacting waterproof agent for concrete structure and preparation method and application thereof |
| CN111233370B (en) * | 2020-01-19 | 2022-11-29 | 广西大胡子防水科技有限公司 | Self-compacting waterproof agent for concrete structure and preparation method and application thereof |
| KR102220462B1 (en) | 2020-07-22 | 2021-02-25 | 박영진 | Alkali metal liquid nano-composite-silicate-based permeable waterproofing agent and concrete structure penetration waterproofing method |
| KR102222895B1 (en) | 2020-07-22 | 2021-03-04 | 박영진 | Floor finishing method by concrete polishing using concrete permeable surface strengthening agent and penetration prevention agent |
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| WO2016167451A1 (en) | 2016-10-20 |
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