JP5834801B2 - 半導体装置の製造方法および半導体装置 - Google Patents
半導体装置の製造方法および半導体装置 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 72
- 238000004519 manufacturing process Methods 0.000 title claims description 58
- 239000000758 substrate Substances 0.000 claims description 81
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 47
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 20
- 238000005530 etching Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 238000001312 dry etching Methods 0.000 claims description 2
- 210000000746 body region Anatomy 0.000 description 20
- 239000012535 impurity Substances 0.000 description 18
- 239000010410 layer Substances 0.000 description 18
- 239000011229 interlayer Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 230000005684 electric field Effects 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000004020 conductor Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 230000002040 relaxant effect Effects 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 230000001747 exhibiting effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000001020 plasma etching Methods 0.000 description 3
- 239000002344 surface layer Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- LKTZODAHLMBGLG-UHFFFAOYSA-N alumanylidynesilicon;$l^{2}-alumanylidenesilylidenealuminum Chemical compound [Si]#[Al].[Si]#[Al].[Al]=[Si]=[Al] LKTZODAHLMBGLG-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021334 nickel silicide Inorganic materials 0.000 description 1
- RUFLMLWJRZAWLJ-UHFFFAOYSA-N nickel silicide Chemical compound [Ni]=[Si]=[Ni] RUFLMLWJRZAWLJ-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RLOWWWKZYUNIDI-UHFFFAOYSA-N phosphinic chloride Chemical compound ClP=O RLOWWWKZYUNIDI-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910021341 titanium silicide Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/7801—DMOS transistors, i.e. MISFETs with a channel accommodating body or base region adjoining a drain drift region
- H01L29/7802—Vertical DMOS transistors, i.e. VDMOS transistors
- H01L29/7813—Vertical DMOS transistors, i.e. VDMOS transistors with trench gate electrode, e.g. UMOS transistors
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- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/02227—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process
- H01L21/0223—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate
- H01L21/02233—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a process other than a deposition process formation by oxidation, e.g. oxidation of the substrate of the semiconductor substrate or a semiconductor layer
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- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02296—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
- H01L21/02318—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
- H01L21/02321—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer
- H01L21/02329—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer introduction of nitrogen
- H01L21/02332—Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer introduction of nitrogen into an oxide layer, e.g. changing SiO to SiON
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- H01L21/0445—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
- H01L21/048—Making electrodes
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/3065—Plasma etching; Reactive-ion etching
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- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
- H01L29/42356—Disposition, e.g. buried gate electrode
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- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66674—DMOS transistors, i.e. MISFETs with a channel accommodating body or base region adjoining a drain drift region
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- H01L29/72—Transistor-type devices, i.e. able to continuously respond to applied control signals
- H01L29/739—Transistor-type devices, i.e. able to continuously respond to applied control signals controlled by field-effect, e.g. bipolar static induction transistors [BSIT]
- H01L29/7393—Insulated gate bipolar mode transistors, i.e. IGBT; IGT; COMFET
- H01L29/7395—Vertical transistors, e.g. vertical IGBT
- H01L29/7396—Vertical transistors, e.g. vertical IGBT with a non planar surface, e.g. with a non planar gate or with a trench or recess or pillar in the surface of the emitter, base or collector region for improving current density or short circuiting the emitter and base regions
- H01L29/7397—Vertical transistors, e.g. vertical IGBT with a non planar surface, e.g. with a non planar gate or with a trench or recess or pillar in the surface of the emitter, base or collector region for improving current density or short circuiting the emitter and base regions and a gate structure lying on a slanted or vertical surface or formed in a groove, e.g. trench gate IGBT
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- Electrodes Of Semiconductors (AREA)
- Formation Of Insulating Films (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Description
上記半導体装置の製造方法および上記半導体において、基板は第1導電型の第1層と第2導電型の第2層とを含み、酸化膜は、トレンチの壁面上において、第1層および第2層に直接接するように形成されてもよい。
Claims (6)
- 炭化珪素からなる基板を準備する工程と、
前記基板の一方の主表面側に開口し、{0001}面と平行な底面および{0001}面とのなす角が40°以上70°以下である壁面を含むトレンチをドライエッチングによる予備エッチングを実施した後、熱エッチングを実施することによって前記基板に形成する工程と、
前記トレンチの前記底面と前記壁面とを含む領域に酸化膜を形成する工程とを備え、
前記酸化膜を形成する工程では、酸素を含む雰囲気中において、前記熱エッチングにより形成された前記壁面を露出させた状態で1250℃以上の温度で前記基板が加熱され、
前記底面を含む領域に形成された酸化膜の膜厚に対する前記壁面を含む領域に形成された酸化膜の膜厚の比率が60パーセント以上となるように前記酸化膜が形成される、半導体装置の製造方法。 - 前記酸化膜を形成する工程では、1300℃以上の温度で前記基板が加熱される、請求項1に記載の半導体装置の製造方法。
- 前記酸化膜を形成する工程では、1400℃以下の温度で前記基板が加熱される、請求項1または2に記載の半導体装置の製造方法。
- 窒素原子を含むガスを含有する雰囲気中において前記基板を加熱することにより、前記酸化膜と前記基板を構成する炭化珪素との界面を含む領域に窒素原子を導入する工程をさらに備える、請求項1〜3のいずれか1項に記載の半導体装置の製造方法。
- 前記基板の前記主表面は、{0001}面である、請求項1〜4のいずれか1項に記載の半導体装置の製造方法。
- 前記基板は第1導電型の第1層と第2導電型の第2層とを含み、
前記酸化膜は、前記トレンチの前記壁面上において、前記第1層および前記第2層に直接接するように形成される、請求項1〜5のいずれか1項に記載の半導体装置の製造方法。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011250256A JP5834801B2 (ja) | 2011-11-16 | 2011-11-16 | 半導体装置の製造方法および半導体装置 |
CN201280049775.7A CN103890951B (zh) | 2011-11-16 | 2012-09-26 | 用于制造半导体器件的方法和半导体器件 |
EP12849942.3A EP2782137A4 (en) | 2011-11-16 | 2012-09-26 | METHOD FOR PRODUCING A SEMICONDUCTOR COMPONENT AND SEMICONDUCTOR COMPONENT |
KR1020147004423A KR20140041863A (ko) | 2011-11-16 | 2012-09-26 | 반도체 장치의 제조 방법 및 반도체 장치 |
PCT/JP2012/074661 WO2013073293A1 (ja) | 2011-11-16 | 2012-09-26 | 半導体装置の製造方法および半導体装置 |
US13/676,931 US20130119407A1 (en) | 2011-11-16 | 2012-11-14 | Method for manufacturing semiconductor device, and semiconductor device |
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JP2011250256A JP5834801B2 (ja) | 2011-11-16 | 2011-11-16 | 半導体装置の製造方法および半導体装置 |
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JP2015161088A Division JP6070790B2 (ja) | 2015-08-18 | 2015-08-18 | 半導体装置の製造方法および半導体装置 |
Publications (3)
Publication Number | Publication Date |
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JP2013105966A JP2013105966A (ja) | 2013-05-30 |
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JP5806600B2 (ja) * | 2011-11-21 | 2015-11-10 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
JP5751146B2 (ja) * | 2011-11-24 | 2015-07-22 | 住友電気工業株式会社 | 半導体装置およびその製造方法 |
JP2015015352A (ja) | 2013-07-04 | 2015-01-22 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
US9570570B2 (en) | 2013-07-17 | 2017-02-14 | Cree, Inc. | Enhanced gate dielectric for a field effect device with a trenched gate |
JP6357869B2 (ja) * | 2014-05-20 | 2018-07-18 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
CN104465440A (zh) * | 2014-11-26 | 2015-03-25 | 上海华力微电子有限公司 | 一种监测原位水汽生长栅氧化膜的生长缺陷的方法 |
CN109037060A (zh) * | 2018-07-19 | 2018-12-18 | 厦门芯代集成电路有限公司 | 一种能抑制沟道迁移率低下的igbt新结构的制备方法 |
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JP3551909B2 (ja) * | 1999-11-18 | 2004-08-11 | 株式会社デンソー | 炭化珪素半導体装置の製造方法 |
JP4843854B2 (ja) * | 2001-03-05 | 2011-12-21 | 住友電気工業株式会社 | Mosデバイス |
US20060214268A1 (en) * | 2005-03-25 | 2006-09-28 | Shindengen Electric Manufacturing Co., Ltd. | SiC semiconductor device |
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JP5017823B2 (ja) * | 2005-09-12 | 2012-09-05 | 富士電機株式会社 | 半導体素子の製造方法 |
US20070096107A1 (en) * | 2005-11-03 | 2007-05-03 | Brown Dale M | Semiconductor devices with dielectric layers and methods of fabricating same |
JP4923543B2 (ja) * | 2005-11-30 | 2012-04-25 | トヨタ自動車株式会社 | 炭化珪素半導体装置及びその製造方法 |
JP2008226997A (ja) * | 2007-03-09 | 2008-09-25 | Sumitomo Electric Ind Ltd | 半導体装置およびその製造方法 |
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US8709897B2 (en) * | 2010-11-30 | 2014-04-29 | Taiwan Semiconductor Manufacturing Company, Ltd. | High performance strained source-drain structure and method of fabricating the same |
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CN103890951B (zh) | 2017-07-21 |
JP2013105966A (ja) | 2013-05-30 |
WO2013073293A1 (ja) | 2013-05-23 |
EP2782137A4 (en) | 2015-08-12 |
EP2782137A1 (en) | 2014-09-24 |
CN103890951A (zh) | 2014-06-25 |
US20130119407A1 (en) | 2013-05-16 |
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