JP2016058601A - 半導体装置 - Google Patents
半導体装置 Download PDFInfo
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- JP2016058601A JP2016058601A JP2014184893A JP2014184893A JP2016058601A JP 2016058601 A JP2016058601 A JP 2016058601A JP 2014184893 A JP2014184893 A JP 2014184893A JP 2014184893 A JP2014184893 A JP 2014184893A JP 2016058601 A JP2016058601 A JP 2016058601A
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 39
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 71
- 239000010410 layer Substances 0.000 claims abstract description 39
- 238000009792 diffusion process Methods 0.000 claims abstract description 34
- 230000002093 peripheral effect Effects 0.000 claims abstract description 27
- 239000011229 interlayer Substances 0.000 claims abstract description 13
- 230000006870 function Effects 0.000 claims description 8
- 238000002955 isolation Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 37
- 239000001257 hydrogen Substances 0.000 abstract description 37
- 238000000034 method Methods 0.000 abstract description 21
- 230000006866 deterioration Effects 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000010408 film Substances 0.000 description 168
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 229910052814 silicon oxide Inorganic materials 0.000 description 15
- 229910052581 Si3N4 Inorganic materials 0.000 description 13
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 12
- 150000002431 hydrogen Chemical class 0.000 description 12
- 229910052710 silicon Inorganic materials 0.000 description 12
- 239000010703 silicon Substances 0.000 description 12
- 239000000758 substrate Substances 0.000 description 12
- 238000002161 passivation Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000005468 ion implantation Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/423—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
- H01L29/42312—Gate electrodes for field effect devices
- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
- H01L29/42324—Gate electrodes for transistors with a floating gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4916—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen
- H01L29/4925—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/401—Multistep manufacturing processes
- H01L29/4011—Multistep manufacturing processes for data storage electrodes
- H01L29/40114—Multistep manufacturing processes for data storage electrodes the electrodes comprising a conductor-insulator-conductor-insulator-semiconductor structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
- H01L29/7881—Programmable transistors with only two possible levels of programmation
- H01L29/7884—Programmable transistors with only two possible levels of programmation charging by hot carrier injection
- H01L29/7885—Hot carrier injection from the channel
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/40—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the peripheral circuit region
- H10B41/42—Simultaneous manufacture of periphery and memory cells
- H10B41/43—Simultaneous manufacture of periphery and memory cells comprising only one type of peripheral transistor
- H10B41/47—Simultaneous manufacture of periphery and memory cells comprising only one type of peripheral transistor with a floating-gate layer also being used as part of the peripheral transistor
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/482—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of lead-in layers inseparably applied to the semiconductor body
- H01L23/485—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of lead-in layers inseparably applied to the semiconductor body consisting of layered constructions comprising conductive layers and insulating layers, e.g. planar contacts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
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- Condensed Matter Physics & Semiconductors (AREA)
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- Computer Hardware Design (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Semiconductor Memories (AREA)
- Non-Volatile Memory (AREA)
- Geometry (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
Abstract
Description
このP型ウエル11aの表面には、ゲート電極18aを挟むようにして、メモリトランジスタMCのソース又はドレインとしてのN型拡散層12a、12a’が形成されている。拡散層12aは、例えばリン(P)などの不純物を自己整合的にイオン注入することにより形成される。
更に図9に示すように、このゲート電極18a及び18bの側壁に、例えばシリコン酸化膜などの絶縁膜からなる側壁膜19a、及び19bを成膜させる。その後、図10に示すようにこの側壁膜19a、19b及びゲート電極18a、18bに対し自己整合的にリン(P)等のイオン注入を行って、P型ウエル11a及びシリコン基板11の表層中に、拡散層12a、12a’、12b及び12b’を形成する。
続いて、図12に示すように、多結晶シリコン膜22の上方に、ゲート電極18a及び18bの構造を埋め込むよう、シリコン酸化膜からなる層間絶縁膜23を堆積させる。
以上説明したように、本実施の形態の半導体装置は、ゲート電極を覆うように、多結晶シリコン膜を備えている。これにより、例えば層間絶縁膜の上層に水素を多く含む膜が形成され、水素が拡散されたとしても、その水素は多結晶シリコン膜の表面のダングリングボンドにおいて移動を抑制され、ゲート絶縁膜には到達しない。したがって、ゲート絶縁膜の信頼性が低下することを防止することができる。また、このような多結晶シリコン膜は、複雑な工程の追加を必要とせず形成することができ、製造コストの増大を招かない。また、多結晶シリコン膜は例えば8nm程度の小さい膜厚で形成すれば十分であり、装置の大型化させるものではない。この多結晶シリコン膜は、最終製品においても残存しているため、出荷後の、製品使用中における水素の拡散も効果的に防止することができる。このように、本実施の形態によれば、水素の拡散に伴う信頼性の劣化を、僅かな工程の追加により、しかも装置の大型化を招くことなく効果的に抑制することができる。
Claims (7)
- チャネル層の表面上に形成されたゲート絶縁膜と、
前記ゲート絶縁膜の上面に形成されたゲート電極と、
前記チャネル層に形成された拡散層と、
前記ゲート電極及び前記拡散層の表面を覆うように形成された多結晶シリコン膜と、
前記ゲート電極及び前記多結晶シリコン膜を覆うように形成された層間絶縁膜と
を備えたことを特徴とする半導体装置。 - 前記多結晶シリコン膜と前記ゲート電極又は前記拡散層との間に挟まれるように形成され絶縁膜からなるライナ膜を更に備えた請求項1記載の半導体装置。
- 前記ゲート電極の側面に形成され絶縁膜からなる側壁膜を更に備え、
前記多結晶シリコン膜は前記側壁膜を介して形成される、請求項1又は2記載の半導体装置。 - 前記層間絶縁膜及び前記多結晶シリコン膜を貫通して前記ゲート電極又は前記拡散層に到達するコンタクト配線と、
前記コンタクト配線と前記層間絶縁膜又は前記多結晶シリコン膜との間に形成される分離絶縁膜と
を更に備えた請求項1〜3のいずれか1項に記載の半導体装置。 - 前記多結晶シリコン膜の膜厚が8nm以上であることを特徴とする請求項1〜4のいずれか1項に記載の半導体装置。
- 前記多結晶シリコンの平均粒径が30nm以下であることを特徴とする請求項1〜5のいずれか1項に記載の半導体装置。
- データを不揮発に記憶するメモリセルとして機能するメモリトランジスタ、及び前記メモリトランジスタを制御する周辺回路に含まれる周辺トランジスタとを備え、
前記メモリトランジスタ及び前記周辺トランジスタはそれぞれ前記ゲート電極を備え、前記メモリトランジスタ中の前記ゲート電極と、前記周辺トランジスタ中の前記ゲート電極とは、共通の前記多結晶シリコン膜により覆われる
ことを特徴とする請求項1記載の半導体装置。
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JP2014184893A JP2016058601A (ja) | 2014-09-11 | 2014-09-11 | 半導体装置 |
US14/792,879 US9530855B2 (en) | 2014-09-11 | 2015-07-07 | Semiconductor device with polycrystalline silicon film |
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JP2014184893A JP2016058601A (ja) | 2014-09-11 | 2014-09-11 | 半導体装置 |
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JP2014184893A Pending JP2016058601A (ja) | 2014-09-11 | 2014-09-11 | 半導体装置 |
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JP2016105880A (ja) * | 2016-03-14 | 2016-06-16 | 株式会社大一商会 | 遊技機 |
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US10147875B1 (en) * | 2017-08-31 | 2018-12-04 | Micron Technology, Inc. | Semiconductor devices and electronic systems having memory structures |
JP2020035802A (ja) | 2018-08-27 | 2020-03-05 | キオクシア株式会社 | 半導体記憶装置 |
KR20210070417A (ko) * | 2019-12-04 | 2021-06-15 | 삼성디스플레이 주식회사 | 표시 장치 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04102367A (ja) * | 1990-08-21 | 1992-04-03 | Seiko Epson Corp | 半導体装置、半導体メモリ及び半導体装置の製造方法 |
JPH04212471A (ja) * | 1990-07-12 | 1992-08-04 | Hitachi Ltd | 半導体集積回路装置 |
JP2000353757A (ja) * | 1999-06-10 | 2000-12-19 | Mitsubishi Electric Corp | 不揮発性半導体記憶装置およびその製造方法 |
JP2001217247A (ja) * | 2000-02-04 | 2001-08-10 | Nec Corp | 半導体装置およびその製造方法 |
JP2009016462A (ja) * | 2007-07-03 | 2009-01-22 | Renesas Technology Corp | 半導体装置およびその製造方法 |
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US5422504A (en) * | 1994-05-02 | 1995-06-06 | Motorola Inc. | EEPROM memory device having a sidewall spacer floating gate electrode and process |
JP3445660B2 (ja) * | 1994-07-08 | 2003-09-08 | 新日本製鐵株式会社 | 不揮発性半導体記憶装置及びその製造方法 |
JP3397903B2 (ja) * | 1994-08-23 | 2003-04-21 | 新日本製鐵株式会社 | 不揮発性半導体記憶装置の製造方法 |
US5972765A (en) | 1997-07-16 | 1999-10-26 | International Business Machines Corporation | Use of deuterated materials in semiconductor processing |
JP3152215B2 (ja) | 1998-09-07 | 2001-04-03 | 日本電気株式会社 | 半導体装置の製造方法 |
JP5416936B2 (ja) | 2008-09-02 | 2014-02-12 | 株式会社東芝 | 半導体装置およびその製造方法 |
JP2011210999A (ja) | 2010-03-30 | 2011-10-20 | Renesas Electronics Corp | 半導体装置及びその製造方法 |
JP5823353B2 (ja) | 2012-06-20 | 2015-11-25 | 株式会社東芝 | 不揮発性半導体記憶装置の製造方法 |
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Patent Citations (5)
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JPH04212471A (ja) * | 1990-07-12 | 1992-08-04 | Hitachi Ltd | 半導体集積回路装置 |
JPH04102367A (ja) * | 1990-08-21 | 1992-04-03 | Seiko Epson Corp | 半導体装置、半導体メモリ及び半導体装置の製造方法 |
JP2000353757A (ja) * | 1999-06-10 | 2000-12-19 | Mitsubishi Electric Corp | 不揮発性半導体記憶装置およびその製造方法 |
JP2001217247A (ja) * | 2000-02-04 | 2001-08-10 | Nec Corp | 半導体装置およびその製造方法 |
JP2009016462A (ja) * | 2007-07-03 | 2009-01-22 | Renesas Technology Corp | 半導体装置およびその製造方法 |
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JP2016105880A (ja) * | 2016-03-14 | 2016-06-16 | 株式会社大一商会 | 遊技機 |
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