JP5823353B2 - 不揮発性半導体記憶装置の製造方法 - Google Patents
不揮発性半導体記憶装置の製造方法 Download PDFInfo
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- JP5823353B2 JP5823353B2 JP2012139021A JP2012139021A JP5823353B2 JP 5823353 B2 JP5823353 B2 JP 5823353B2 JP 2012139021 A JP2012139021 A JP 2012139021A JP 2012139021 A JP2012139021 A JP 2012139021A JP 5823353 B2 JP5823353 B2 JP 5823353B2
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- 239000004065 semiconductor Substances 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 15
- 238000003860 storage Methods 0.000 claims description 28
- 239000010410 layer Substances 0.000 description 235
- 239000000463 material Substances 0.000 description 23
- 238000002955 isolation Methods 0.000 description 20
- 230000014759 maintenance of location Effects 0.000 description 16
- 239000007789 gas Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 11
- 230000008859 change Effects 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 229910052747 lanthanoid Inorganic materials 0.000 description 5
- 150000002602 lanthanoids Chemical class 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 238000009751 slip forming Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005036 potential barrier Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229910004129 HfSiO Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910006501 ZrSiO Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/401—Multistep manufacturing processes
- H01L29/4011—Multistep manufacturing processes for data storage electrodes
- H01L29/40114—Multistep manufacturing processes for data storage electrodes the electrodes comprising a conductor-insulator-conductor-insulator-semiconductor structure
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C16/00—Erasable programmable read-only memories
- G11C16/02—Erasable programmable read-only memories electrically programmable
- G11C16/04—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS
- G11C16/0408—Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells containing floating gate transistors
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
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- H01L29/423—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
- H01L29/42312—Gate electrodes for field effect devices
- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
- H01L29/42324—Gate electrodes for transistors with a floating gate
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/423—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
- H01L29/42312—Gate electrodes for field effect devices
- H01L29/42316—Gate electrodes for field effect devices for field-effect transistors
- H01L29/4232—Gate electrodes for field effect devices for field-effect transistors with insulated gate
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
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- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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- H01L29/772—Field effect transistors
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- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
Description
図1は、不揮発性半導体記憶装置を構成するメモリセルアレイ内のメモリセルを示している。図2は、図1のII−II線に沿う断面図である。図3は、図1のIII−III線に沿う断面図である。
・ 伝導帯下端がチャージトラップ層の伝導帯下端よりも低い
・ 電荷トラップ性を有しない
これについては、エネルギーバンドの説明で詳述する。
HfO2、HfSiO、ZrO2、ZrSiOなど
・ 界面絶縁層
[チャージトラップ層を構成する材料にMg(アルカリ金属)を添加した材料]
HfMgO、HfMgSiO、ZrMgO、ZrMgSiOなど
[チャージトラップ層を構成する材料にLa又はY(ランタノイド系材料)を添加した材料]
HfLaO、HfLaSiO、ZrLaO、ZrLaSiO、HfYO、HfYSiO、ZrYO、ZrYSiOなど
但し、チャージトラップ層及び界面絶縁層を構成する材料の組成比は、上述の例に限られない。例えば、チャージトラップ層及び界面絶縁層が安定な状態を維持することを条件に、それらの組成比を適宜変更することは可能である。
図1乃至図3の不揮発性半導体記憶装置の製造方法を説明する。
Claims (1)
- 半導体層と、前記半導体層上の第1の絶縁層と、前記第1の絶縁層上の電荷蓄積層と、前記電荷蓄積層上の第2の絶縁層と、前記第2の絶縁層上のコントロールゲート電極とを具備し、前記電荷蓄積層は、前記第1の絶縁層上のフローティングゲート層と、前記フローティングゲート層上の界面絶縁層と、前記界面絶縁層上のチャージトラップ層とを備え、前記界面絶縁層の伝導帯下端は、前記チャージトラップ層のトラップ準位よりも高く、前記チャージトラップ層の伝導帯下端よりも低い不揮発性半導体記憶装置の製造方法において、
前記界面絶縁層は、第1の条件として、第1及び第2のガスを含む雰囲気中で形成され、前記チャージトラップ層は、第2の条件として、前記第1のガスを含み、前記第2のガスを含まない雰囲気中で形成され、
前記界面絶縁層及び前記チャージトラップ層は、同一チャンバー内で前記第1及び第2の条件の切替を行うことにより連続して形成される
不揮発性半導体記憶装置の製造方法。
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JP2012139021A JP5823353B2 (ja) | 2012-06-20 | 2012-06-20 | 不揮発性半導体記憶装置の製造方法 |
US13/748,101 US8803219B2 (en) | 2012-06-20 | 2013-01-23 | Nonvolatile semiconductor memory device and method of manufacturing |
US14/325,762 US20140315378A1 (en) | 2012-06-20 | 2014-07-08 | Nonvolatile semiconductor memory device and method of manufacturing |
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JP2012139021A JP5823353B2 (ja) | 2012-06-20 | 2012-06-20 | 不揮発性半導体記憶装置の製造方法 |
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JP2014003235A JP2014003235A (ja) | 2014-01-09 |
JP5823353B2 true JP5823353B2 (ja) | 2015-11-25 |
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JP (1) | JP5823353B2 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016058601A (ja) | 2014-09-11 | 2016-04-21 | 株式会社東芝 | 半導体装置 |
JP2017163044A (ja) | 2016-03-10 | 2017-09-14 | 東芝メモリ株式会社 | 半導体装置およびその製造方法 |
US9859446B2 (en) | 2016-03-11 | 2018-01-02 | Toshiba Memory Corporation | Non-volatile semiconductor memory device |
WO2018048713A1 (en) | 2016-09-06 | 2018-03-15 | Becsis, Llc | Electrostatic catalysis |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6528858B1 (en) * | 2002-01-11 | 2003-03-04 | Advanced Micro Devices, Inc. | MOSFETs with differing gate dielectrics and method of formation |
US6693321B1 (en) * | 2002-05-15 | 2004-02-17 | Advanced Micro Devices, Inc. | Replacing layers of an intergate dielectric layer with high-K material for improved scalability |
EP1372160B1 (en) * | 2002-06-10 | 2008-05-28 | Interuniversitair Microelektronica Centrum (IMEC) | Transistors or memory capacitors comprising a composition of HfO2 with enhanced dielectric constant |
JP3987418B2 (ja) * | 2002-11-15 | 2007-10-10 | 株式会社東芝 | 半導体記憶装置 |
US7235501B2 (en) * | 2004-12-13 | 2007-06-26 | Micron Technology, Inc. | Lanthanum hafnium oxide dielectrics |
US7508648B2 (en) * | 2005-02-08 | 2009-03-24 | Micron Technology, Inc. | Atomic layer deposition of Dy doped HfO2 films as gate dielectrics |
US7429767B2 (en) * | 2005-09-01 | 2008-09-30 | Micron Technology, Inc. | High performance multi-level non-volatile memory device |
JP4374037B2 (ja) * | 2007-03-28 | 2009-12-02 | 株式会社東芝 | 不揮発性半導体メモリ及びその製造方法 |
FR2915623B1 (fr) * | 2007-04-27 | 2009-09-18 | St Microelectronics Crolles 2 | Circuit electronique integre comprenant une portion de couche mince a base d'oxyde d'hafnium. |
JP2009076764A (ja) * | 2007-09-21 | 2009-04-09 | Toshiba Corp | 不揮発性半導体メモリおよびその書き込み方法ならびにその消去方法 |
JP2009081203A (ja) * | 2007-09-25 | 2009-04-16 | Toshiba Corp | 不揮発性半導体記憶装置およびその製造方法 |
US8068370B2 (en) | 2008-04-18 | 2011-11-29 | Macronix International Co., Ltd. | Floating gate memory device with interpoly charge trapping structure |
JP2010034233A (ja) * | 2008-07-28 | 2010-02-12 | Toshiba Corp | 不揮発性半導体記憶装置およびその製造方法 |
JP5314964B2 (ja) * | 2008-08-13 | 2013-10-16 | ルネサスエレクトロニクス株式会社 | 半導体装置の製造方法 |
JP5537130B2 (ja) | 2009-11-25 | 2014-07-02 | 株式会社東芝 | 半導体記憶装置 |
JP2011142227A (ja) | 2010-01-07 | 2011-07-21 | Toshiba Corp | 半導体記憶装置 |
JP2011142246A (ja) | 2010-01-08 | 2011-07-21 | Toshiba Corp | 半導体記憶装置 |
JP2012009700A (ja) * | 2010-06-25 | 2012-01-12 | Toshiba Corp | 半導体記憶装置及びその製造方法 |
-
2012
- 2012-06-20 JP JP2012139021A patent/JP5823353B2/ja active Active
-
2013
- 2013-01-23 US US13/748,101 patent/US8803219B2/en active Active
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2014
- 2014-07-08 US US14/325,762 patent/US20140315378A1/en not_active Abandoned
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Publication number | Publication date |
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US20130341698A1 (en) | 2013-12-26 |
US8803219B2 (en) | 2014-08-12 |
US20140315378A1 (en) | 2014-10-23 |
JP2014003235A (ja) | 2014-01-09 |
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