JP2008281988A - 発光装置とその作製方法 - Google Patents
発光装置とその作製方法 Download PDFInfo
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- JP2008281988A JP2008281988A JP2008036044A JP2008036044A JP2008281988A JP 2008281988 A JP2008281988 A JP 2008281988A JP 2008036044 A JP2008036044 A JP 2008036044A JP 2008036044 A JP2008036044 A JP 2008036044A JP 2008281988 A JP2008281988 A JP 2008281988A
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Abstract
【解決手段】有機EL素子を駆動するための電界効果型トランジスタを有する発光装置の作製方法において、基板1上に電界効果型トランジスタを形成する工程と、絶縁層7を形成する工程と、絶縁層7の上に下部電極8を形成する工程と、下部電極8の上に有機EL素子を構成するための有機層10を形成する工程と、有機層10の上に上部電極11を形成する工程と、を含み、電界効果型トランジスタの半導体層を形成する工程の後、有機層10を形成する工程の前に、電界効果型トランジスタからH2Oとして脱離し得る成分量が10−5g/m2未満となる熱処理を行う熱処理工程を含む。
【選択図】図1
Description
P.Gorrnら,Advanced Materials,Vol.18,pp.738−741(2006) Applied Physics Letters,Vol.82,pp.733−735(2003) Nature,Vol.432,pp.488−492(2004)
本実施の形態では、非晶質In−Ga−Zn−O系のTOS−TFTをスイッチング素子とし、本発明の典型的な構成である、同一基板上に有機EL素子を積層して有機EL表示パネルを作製する場合について説明する。本発明において、In−Ga−Zn−O系とは、少なくともInとGaとZnとを含む酸化物系材料を意味する。
一般的に発光素子にはガラス基板が用いられているが、本実施形態で用いる基板としては、Ra(算術平均粗さ)が数nm以内の平坦性を有する基板が好適に用いることができる。
本実施の形態においては、電界効果型トランジスタの半導体層に関してはIn−Zn−O系又はこれにGaを加えた系の半導体を用いることが好ましい。
本実施形態で用いる有機層10は、一般的には以下の複数層の構成となっている。
ホール輸送層/発光層/電子輸送層の3層構造
ホール注入層/ホール輸送層/発光層/電子輸送層の4層構造
ホール注入層/ホール輸送層/発光層/電子輸送層/電子注入層の5層構造
この他電子障壁層や付着改善層なども挿入する場合がある。
上部及び下部電極は両面発光タイプ及びトップエミッションタイプかボトムエミッションタイプか、及び陰極や陽極かで好ましい材料が異なってくる。
両面発光タイプ及びトップエミッションタイプでは上部電極が透明であることが必要である。有機EL素子の場合、その構成により好ましい電極がある。
下部電極は両面発光タイプ及びボトムエミッションタイプでは透明であることが必要である。
以下に、図5に基づいて、有機EL素子とTOS−TFTを同一基板上に実装する際の作製例を説明する。有機EL素子の形成プロセス中の最高到達温度は150℃である。
被成膜基板としてガラス基板1(コーニング社製1737)を選択する。成膜前処理としてはこの基板の超音波脱脂洗浄をアセトン、IPA、超純水により各5分ずつ行った後、空気中150℃にて10分間、脱水のための熱処理を施す。この時に脱水が不充分な場合は、ガラス基板の表面平坦性等に悪影響を及ぼさない範囲で、雰囲気や温度及び時間を変えることができる。
次にITOをスパッタリング法により350nm形成して下部電極8とする。
下部電極8の形成後の熱処理が終わった試料の一部を、トランスファーベッセルを用い、大気にさらさない状態で昇温脱離分析装置に移動し測定を行う。
必要に応じて素子分離膜9を形成する。
次に抵抗蒸発法により、電子輸送層としてトリス(8−キノリノール)アルミニウム膜を25nm成膜し、その上に発光層として4,4’−ビス(2,2)−ジフェニルビニル膜を45nm形成する。
2元蒸着法によりAlとAgの合金を50nm、Alを50nm成膜して上部電極11とする。
必要に応じてパッシベーション膜12を形成する。
実施例において、In−Ga−Zn−O系アモルファス酸化物半導体薄膜4に水分脱離処理を施さない場合、有機層の形成前に、昇温脱離分析を行うと次のような結果になる。150℃までにH2Oとして脱離し得る成分量は9×10−4g/m2以上であり、10−5g/m2を大幅に上回る。
2 ゲート電極
3 ゲート絶縁層
4 酸化物半導体層
5 ドレイン電極
6 ソース電極
7 絶縁層
8 下部電極(透明陽極)
9 素子分離膜
10 有機層
11 上部電極(金属陰極)
12 絶縁層(パッシベーション膜)
Claims (8)
- 有機EL素子を駆動するための電界効果型トランジスタを有する発光装置の作製方法において、
前記電界効果型トランジスタはIn又はZnから選択される少なくとも一つの元素を含む酸化物半導体を有し、
基板上に前記電界効果型トランジスタを形成する工程と、
絶縁層を形成する工程と、
前記絶縁層の上に下部電極を形成する工程と、
前記下部電極の上に前記有機EL素子を構成するための有機層を形成する工程と、
前記有機層の上に上部電極を形成する工程と、を含み、
前記電界効果型トランジスタの半導体層を形成する工程の後、前記有機層を形成する工程の前に、該電界効果型トランジスタから前記有機層を形成する工程中にH2Oとして脱離し得る成分量が10−5g/m2未満となる熱処理工程を含むことを特徴とする発光装置の作製方法。 - 前記熱処理工程が、前記電界効果型トランジスタの半導体層を形成する工程の後、連続して行われることを特徴とする請求項1記載の発光装置の作製方法。
- 前記熱処理工程が、前記電界効果型トランジスタを形成する工程の後、連続して行われることを特徴とする請求項1記載の発光装置の作製方法。
- 前記熱処理工程が、前記絶縁層を形成した後、有機EL素子を構成するための有機層を形成する工程の前までに行われることを特徴とする請求項1記載の発光装置の作製方法。
- 前記電界効果型トランジスタが、ソース電極と、ドレイン電極と、半導体層と、ゲート電極と、ゲート絶縁膜と、を含み、
前記ソース電極、前記ドレイン電極、前記半導体層、前記ゲート絶縁膜及び前記ゲート電極を300℃以下の温度で形成することを特徴とする請求項1から4のいずれか1項記載の発光装置の作製方法。 - 請求項1から5のいずれか1項に記載される発光装置の作製方法で作製される発光装置であって、
前記半導体層が、In又はZnのうちの少なくとも一つを含む酸化物であることを特徴とする発光装置。 - 前記半導体層がInとZnとを含む酸化物であって、少なくとも一部が非晶質であることを特徴とする請求項6記載の発光装置。
- 前記熱処理工程の後の前記半導体層中に、600℃まで熱処理する際にH2Oとして脱離し得る成分が、3.0×10−3g/m2未満であることを特徴とする請求項6又は7記載の発光装置。
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