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HUP0101157A2 - Új, áthidalt bisztetrahidroindenil-metallocének és ligandumaik, ilyen metallocénekből előállított katalizátorok, valamint eljárás olefinek polimerizálására - Google Patents

Új, áthidalt bisztetrahidroindenil-metallocének és ligandumaik, ilyen metallocénekből előállított katalizátorok, valamint eljárás olefinek polimerizálására

Info

Publication number
HUP0101157A2
HUP0101157A2 HU0101157A HUP0101157A HUP0101157A2 HU P0101157 A2 HUP0101157 A2 HU P0101157A2 HU 0101157 A HU0101157 A HU 0101157A HU P0101157 A HUP0101157 A HU P0101157A HU P0101157 A2 HUP0101157 A2 HU P0101157A2
Authority
HU
Hungary
Prior art keywords
atom
integer
aryl
alkyl
atoms
Prior art date
Application number
HU0101157A
Other languages
English (en)
Inventor
Luigi Resconi
Original Assignee
Montell Technology Company B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Company B.V. filed Critical Montell Technology Company B.V.
Publication of HUP0101157A2 publication Critical patent/HUP0101157A2/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A találmány szerinti áthidalt bisztetrahidroindenil-metallocének (I)általános képletében - M jelentése átmenetifém; - az X jelentésehidrogénatom, halogénatom, -R, -OR, -OSO2CF3, -OCOR, -SR, -NR2 vagy -PR2 általános képletű csoport, amely adott esetben egy vagy több másatomot is tartalmazhat; - (ZR1i)j jelentése a kéttetrahidroindenilgyököt hídként összekötő kétértékű csoport, amelyben- - Z jelentése szénatom, szilíciumatom, germániumatom, nitrogénatomvagy foszforatom; - - az R1 szubsztituensek jelentése hidrogénatom,adott esetben egy vagy több más atomot tartalmazó C1-C20-alkil-, C3-C20-cikloalkil-, C7-C20-aril-, C7-C20-alkil-aril- vagy C7-C20-ari1-alki1-csoport; - R2 és R3 jelentése halogénatom, adott esetben egyvagy több más atomot is tartalmazó C1-C20-alkil-, C3-C20-cikloalkil-,C7-C20-aril-, C7-C20-alkil-aril- vagy C7-C20-aril-alkil-csoport, N-pirrolil-csoport, N-indolil-csoport -OR, -SR, -NR2, -PR2, -BR2 vagy -SiR3 általános képletű csoport; - p jelentése 0 és 3 közötti egészszám; - i jelentése 1 vagy 2; - j jelentése 1 és 4 közötti egész szám; -m jelentése 0 és 2 közötti egész szám és n jelentése 0 és 8 közöttiegész szám. Ó
HU0101157A 1998-11-18 1999-11-10 Új, áthidalt bisztetrahidroindenil-metallocének és ligandumaik, ilyen metallocénekből előállított katalizátorok, valamint eljárás olefinek polimerizálására HUP0101157A2 (hu)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98203905 1998-11-18
PCT/EP1999/008647 WO2000029416A1 (en) 1998-11-18 1999-11-10 Bis(tetrahydro-indenyl) metallocenes as olefin-polymerisation-catalyst

Publications (1)

Publication Number Publication Date
HUP0101157A2 true HUP0101157A2 (hu) 2001-07-30

Family

ID=8234357

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0101157A HUP0101157A2 (hu) 1998-11-18 1999-11-10 Új, áthidalt bisztetrahidroindenil-metallocének és ligandumaik, ilyen metallocénekből előállított katalizátorok, valamint eljárás olefinek polimerizálására

Country Status (14)

Country Link
US (1) US6541584B1 (hu)
EP (1) EP1047702B1 (hu)
JP (1) JP2002530286A (hu)
KR (1) KR20010034211A (hu)
CN (1) CN1291986A (hu)
AR (1) AR021311A1 (hu)
AU (1) AU1270500A (hu)
BR (1) BR9910192A (hu)
CA (1) CA2317588A1 (hu)
DE (1) DE69905011T2 (hu)
ES (1) ES2189516T3 (hu)
HU (1) HUP0101157A2 (hu)
IL (1) IL137036A0 (hu)
WO (1) WO2000029416A1 (hu)

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IT1318436B1 (it) * 2000-03-31 2003-08-25 Enichem Spa Ciclopentadieni sostituiti policiclici e metodo per la loropreparazione.
AU2001275462A1 (en) * 2000-06-30 2002-01-14 Dow Global Technology Inc. Polycyclic, fused ring compounds, metal complexes and polymerization process
JP4315808B2 (ja) * 2001-11-16 2009-08-19 シーディーティー オックスフォード リミテッド 発光装置及びそれに使用される装置
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
US6958377B2 (en) * 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
EP1674523A1 (en) * 2004-12-22 2006-06-28 Total Petrochemicals Research Feluy Caps and closures
EP1721913A1 (en) * 2005-05-09 2006-11-15 Total Petrochemicals Research Feluy Microwave-promoted creation of catalytic species
AU2006270436B2 (en) 2005-07-19 2011-12-15 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US7592395B2 (en) * 2006-08-01 2009-09-22 Exxonmobil Chemical Patents Inc. Multimodal polyethylene for use in single piece beverage bottle caps and closures
EP2199078A1 (en) * 2008-12-22 2010-06-23 Total Petrochemicals Research Feluy Polyethylene and poly(hydroxy carboxylic acid) multilayer films
CN102464748B (zh) * 2010-11-16 2013-07-03 中国石油化工股份有限公司 一种丙烯共聚物大分子单体及其制备方法
AU2012321290B2 (en) * 2011-10-10 2016-07-07 Exxonmobil Chemical Patents Inc. Poly alpha olefin compositions and process to produce poly alpha olefin compositions
US9000200B2 (en) * 2011-12-19 2015-04-07 Saudi Basic Industries Corporation Process for the preparation of metallocene complexes
CN107721797A (zh) * 2011-12-19 2018-02-23 沙特基础工业公司 用于制备茂金属络合物的方法
CN103509060B (zh) * 2012-06-27 2016-08-10 大林产业株式会社 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
US11040995B2 (en) 2016-01-05 2021-06-22 Sabic Global Technologies B.V. Catalyst comprising a metallocene complex and co-catalyst
US10669356B2 (en) 2016-01-27 2020-06-02 Lg Chem, Ltd. Supported hybrid catalyst and method for preparing olefin polymer using the same

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DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
ES2071888T3 (es) 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
EP0485821B1 (de) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE4121368A1 (de) * 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
NL9201970A (nl) 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
IT1276084B1 (it) * 1995-11-07 1997-10-24 Enichem Spa Ciclopentadienil derivati pontati e procedimento per la loro preparazione
IT1290856B1 (it) * 1996-12-19 1998-12-14 Enichem Spa Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine

Also Published As

Publication number Publication date
DE69905011T2 (de) 2003-11-06
EP1047702B1 (en) 2003-01-22
AU1270500A (en) 2000-06-05
US6541584B1 (en) 2003-04-01
CA2317588A1 (en) 2000-05-25
AR021311A1 (es) 2002-07-17
DE69905011D1 (de) 2003-02-27
EP1047702A1 (en) 2000-11-02
WO2000029416A1 (en) 2000-05-25
IL137036A0 (en) 2001-06-14
BR9910192A (pt) 2001-05-22
CN1291986A (zh) 2001-04-18
JP2002530286A (ja) 2002-09-17
KR20010034211A (ko) 2001-04-25
ES2189516T3 (es) 2003-07-01

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