ES2135417T3 - Composicion dental resinosa basada en polisiloxanos polimerizables. - Google Patents
Composicion dental resinosa basada en polisiloxanos polimerizables.Info
- Publication number
- ES2135417T3 ES2135417T3 ES92922122T ES92922122T ES2135417T3 ES 2135417 T3 ES2135417 T3 ES 2135417T3 ES 92922122 T ES92922122 T ES 92922122T ES 92922122 T ES92922122 T ES 92922122T ES 2135417 T3 ES2135417 T3 ES 2135417T3
- Authority
- ES
- Spain
- Prior art keywords
- nhc
- photochemically
- aryl
- curing
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001296 polysiloxane Polymers 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- -1 polysiloxanes Polymers 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000000732 arylene group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 239000005548 dental material Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 235000011837 pasties Nutrition 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/896—Polyorganosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/92—Polymers useful for replacing hard animal tissues, e.g. dentures, bones
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dental Preparations (AREA)
- Polyethers (AREA)
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
LA INVENCION SE REFIERE A UNA COMPOSICION DENTAL RESINOSA, ENDURECIBLE, TERMICA O FOTOQUIMICAMENTE BASADA EN POLISILOXANOS POLIMERIZABLES, A UN PROCESO PARA SU PREPARACION Y A SU EMPLEO PARA LA PREPARACION DE UNA PASTA PARA MATERIALES DENTALES ENDURECIBLES TERMICA O FOTOQUIMICAMENTE. DICHA COMPOSICION SE PUEDE OBTENER POR CONDENSACION HIDROLITICA DE UNO O MAS COMPUESTOS DE SILICIO CONDENSABLES HIDROLITICAMENTE, DE 1 A 100 MOL %, BASADOS EN COMPUESTOS MONOMERICOS, DE SILANOS DE LA FORMULA GENERAL: SIENDO SELECCIONADO DE YM KSI [R2 (A) 1] 4 Y R SON IDENTICOS O DIFERENTES Y TIENEN EL SIGUIENTE SIGNIFICADO: A = O, S, PR'', POR'', NHC(O)O O NHC(O)ONR'', B = UN RADICAL ORGANICO RAMIFICADO O DE CADENA LINEAL QUE ES DERIVADO DE UN COMPUESTO P'' QUE TIENE AL MENOS UN ENLACE C = C (PARA L = 1 Y A = NHC(O)O O NHC(O)NR'') O AL MENOS DOS ENLACES DOBLES C = C Y DE 5 A 50 ATOMOS DE CARBONO, R = ALQUILO, ALQUENILO, ARILO, ALQUILARILO O ARILALQUILO, R'' = H, ALQUILO O ARILO, R2 = ALQUILENO, ARILENO O ALQUILENOARILENO, X = H, HALOGENO, HIDROXILO, ALCOXI, ACILOXI, ALQUILCARBONILO, ALCOXILCARBONILO O NR''2, Y = UN SUSTITUYENTE QUE CONTIENE UN RADICAL NONANO [4.4] TRIOXASPIRO 1, 4, 6 SUSTITUDO O INSUSTITUIDO, N = 1, 2 O 3, M = 1, 2 O 3 EN DONDE N + M ES MENOR O IGUAL QUE 4, K = 0, 1 O 2, L = 0 O 1, X = UN NUMERO ENTERO CUYO VALOR SE HA MOSTRADO EN LA DESCRIPCION.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4133494A DE4133494C2 (de) | 1991-10-09 | 1991-10-09 | Dentalharzmasse, Verfahren zu deren Herstellung und deren Verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2135417T3 true ES2135417T3 (es) | 1999-11-01 |
Family
ID=6442372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92922122T Expired - Lifetime ES2135417T3 (es) | 1991-10-09 | 1992-10-07 | Composicion dental resinosa basada en polisiloxanos polimerizables. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5877232A (es) |
EP (1) | EP0643752B1 (es) |
AT (1) | ATE184627T1 (es) |
AU (1) | AU2767492A (es) |
CA (1) | CA2120490C (es) |
DE (2) | DE4133494C2 (es) |
DK (1) | DK0643752T3 (es) |
ES (1) | ES2135417T3 (es) |
GR (1) | GR3031475T3 (es) |
PT (1) | PT100951B (es) |
WO (1) | WO1993007230A1 (es) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4310733A1 (de) * | 1993-04-01 | 1994-10-06 | Fraunhofer Ges Forschung | Selbsthärtende Systeme |
DE19617876A1 (de) * | 1996-04-24 | 1997-11-06 | Ivoclar Ag | Polymerisierbares Dentalmaterial |
DE19619046A1 (de) * | 1996-05-02 | 1997-11-06 | Ivoclar Ag | Verwendung einer Zusammensetzung als Dentalmaterial und Dentalmaterial |
DE19648283A1 (de) * | 1996-11-21 | 1998-05-28 | Thera Ges Fuer Patente | Polymerisierbare Massen auf der Basis von Epoxiden |
DE19714324B4 (de) * | 1997-03-25 | 2004-09-02 | Ivoclar Vivadent Ag | Hydrolysierbare und polymerisierbare Oxetansilane |
US6096903A (en) * | 1997-03-25 | 2000-08-01 | Ivoclar Ag | Hydrolysable and polymerizable oxetane silanes |
DE19807631A1 (de) * | 1998-02-23 | 1999-08-26 | Agfa Gevaert Ag | Härtbare Dentalmassen |
DE19846556A1 (de) | 1998-10-09 | 2000-04-13 | Degussa | Dentalwerkstoff aufweisend poröse Glaskeramiken, poröse Glaskeramiken, Verfahren und Verwendung |
US6458865B2 (en) | 1999-01-15 | 2002-10-01 | Curators Of The University Of Missouri | Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates |
US6569917B1 (en) | 1999-01-21 | 2003-05-27 | Ivoclar Ag | Dental materials based on polysiloxanes |
DE19903177C5 (de) * | 1999-01-21 | 2010-09-16 | Ivoclar Vivadent Ag | Verwendung von Materialien auf der Basis von Polysiloxanen als Dentalmaterialien |
JP2003507499A (ja) * | 1999-08-13 | 2003-02-25 | デルタメド・メディツィーンプロドュクテ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 可視光を用いて架橋する組成物およびその使用 |
TR200200570T2 (tr) | 1999-09-10 | 2002-06-21 | Nargacard S.A. | Veri tabanları için mesaj iletim prosesi ve sistemi |
US6610759B1 (en) | 2000-03-06 | 2003-08-26 | Curators Of The University Of Missouri | Cationically polymerizable adhesive composition containing an acidic component and methods and materials employing same |
DE10016324A1 (de) * | 2000-03-31 | 2001-10-11 | Roehm Gmbh | Ormocere, Verfahren zu deren Herstellung sowie Verwendung |
DE10021605A1 (de) * | 2000-05-04 | 2001-11-08 | Upmeyer Hans Juergen | Füllmaterial für Zähne |
DE60120416T2 (de) * | 2000-08-11 | 2006-12-14 | Dentsply International Inc. | Polyaminoester und ihre verwendung in dentalmassen |
US7101942B2 (en) | 2001-01-19 | 2006-09-05 | Ivoclar Vivadent Ag | Dental materials based on metal oxide clusters |
WO2002088222A1 (de) | 2001-03-13 | 2002-11-07 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. | Phosphorhaltige, organisch polymerisierbare silane und damit hergestellte kieselsäure-polykondensate |
DE10114290B4 (de) | 2001-03-23 | 2004-08-12 | Ivoclar Vivadent Ag | Desktop-Verfahren zur Herstellung von Dentalprodukten unter Verwendung des 3D-Plottings |
US6812266B2 (en) | 2001-08-10 | 2004-11-02 | Dentsply Detrey Gmbh | Hydrolysis stable one-part self-etching, self-priming dental adhesive |
US20030199605A1 (en) * | 2002-04-23 | 2003-10-23 | Fischer Dan E. | Hydrophilic endodontic sealing compositions and methods for using such compositions |
US20050059752A1 (en) * | 2002-07-12 | 2005-03-17 | Rhodia Chimie | Stable, cationically polymerizable/crosslinkable dental compositions having high filler contents |
DE10339912B4 (de) | 2003-08-29 | 2016-07-21 | Ivoclar Vivadent Ag | Dentale Beschichtungsmaterialien, deren Verwendung sowie Verfahren zur Beschichtung einer Substratoberfläche |
DE10349766A1 (de) | 2003-10-24 | 2005-06-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Kieselsäurepolykondensate mit verzweigtkettigen, urethan-, säureamid- und/oder carbonsäureestergruppenhaltigen Resten |
DE102005018059A1 (de) | 2003-10-24 | 2006-10-26 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Verbrücken von Hydroxy- oder Carbonsäuregruppen enthaltenden, organisch polymerisierbaren Silanen oder Silanharzeinheiten, sowie Produkte dieses Verfahrens |
US7173075B2 (en) * | 2004-08-30 | 2007-02-06 | Ultradent Products, Inc. | Gas releasing sealing and filling compositions |
DE102005018351B4 (de) | 2005-04-20 | 2008-05-29 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung widerstandsfähiger, langlebiger Komposite im Dentalbereich |
US7828550B2 (en) | 2005-09-21 | 2010-11-09 | Ultradent Products, Inc. | Activating endodontic points and dental tools for initiating polymerization of dental compositions |
DE102007035734A1 (de) | 2006-08-29 | 2008-03-20 | Ivoclar Vivadent Ag | Dentalmaterialien mit geringem Polymerisationsschrumpf |
EP1905415B1 (de) | 2006-09-27 | 2009-07-01 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzungen mit Acylgermanium-Verbindungen als Initiatoren |
US20090075235A1 (en) * | 2006-10-27 | 2009-03-19 | Letcher William F | Fixed, Implant-Supported, Full Arch Dental Prosthetics and Methods of Seating Thereof |
US20090017421A1 (en) * | 2006-10-27 | 2009-01-15 | Letcher William F | Method of Preparing an Artificial Dental Prosthetic and Seating Thereof |
US7758346B1 (en) | 2006-10-27 | 2010-07-20 | Letcher William F | Implant prosthodontics and methods of preparing and seating the same |
EP2103297B1 (de) | 2008-03-20 | 2012-05-16 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzung mit mehrere Germanium-Atome enthaltenden Initiatoren |
EP2151214B1 (de) * | 2008-07-30 | 2013-01-23 | Ivoclar Vivadent AG | Lichthärtende Schlicker für die stereolithographische Herstellung von Dentalkeramiken |
JP5269734B2 (ja) * | 2008-10-16 | 2013-08-21 | 株式会社デンソー | 重合硬化性組成物、その重合硬化方法、および重合硬化樹脂組成物 |
DE102009035970A1 (de) | 2009-08-04 | 2011-02-17 | Heraeus Kulzer Gmbh | Antimikrobiell ausgestattete Dentalmaterialien, insbesondere zur Verhinderung von Plaqueanlagerungen |
JP5055397B2 (ja) * | 2010-03-10 | 2012-10-24 | 株式会社ユニックスジャパン | 歯科用成形体、及び歯科用樹脂材料 |
KR101071554B1 (ko) * | 2010-04-06 | 2011-10-10 | 주식회사 하스 | 세라믹 유치관 제조방법 및 이에 의해 제조된 세라믹 유치관 |
US20140080082A1 (en) * | 2012-09-14 | 2014-03-20 | Orthoaccel Technologies Inc. | Light cure bite plate for orthodontic remodeling devices |
DE102013008176A1 (de) | 2012-10-05 | 2014-04-10 | Voco Gmbh | Kit und Verfahren zur indirekten chairside Herstellung von Kompositinlays |
DE102014116402A1 (de) | 2014-11-11 | 2016-05-12 | Voco Gmbh | Verwendung radikalisch härtbarer Zusammensetzungen in generativen Fertigungsverfahren |
DE102014116389A1 (de) | 2014-11-11 | 2016-05-12 | Voco Gmbh | Radikalisch härtbare dentale Zusammensetzungen |
DE102015112800A1 (de) | 2015-04-09 | 2016-10-13 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Mehrteilig aufgebaute Dentalprothese sowie Verfahren und Vorrichtung zu ihrer Herstellung |
DE102015114397A1 (de) | 2015-08-28 | 2017-03-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Misch- und Formverfahren für gefüllte Duromere aus organisch vernetzbaren Kompositmassen, insbesondere für dentale Zwecke |
KR102470542B1 (ko) * | 2017-04-28 | 2022-11-24 | (주) 개마텍 | 광경화 코팅용 조성물 및 코팅막 |
EP3660085A1 (de) | 2018-11-29 | 2020-06-03 | Ivoclar Vivadent AG | Stützmaterial für den energieimpuls-induzierten transferdruck |
EP3660087B1 (de) | 2018-11-29 | 2024-05-29 | Ivoclar Vivadent AG | Verfahren und werkstoff zur herstellung von 3d objekten durch energieimpuls-induzierten transferdruck |
DE102019122174A1 (de) | 2019-08-19 | 2021-02-25 | Voco Gmbh | Dentale polymerisierbare Zusammensetzung auf der Basis kondensierter Silane |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3127363A (en) * | 1955-08-05 | 1964-03-31 | Process for the manufacture of elasto- | |
US4387240A (en) * | 1978-06-02 | 1983-06-07 | Minnesota Mining And Manufacturing Company | Oligomeric methacryl substituted alkylsiloxanes |
JPS55137178A (en) * | 1979-04-11 | 1980-10-25 | Kanebo Ltd | Adhesive material for rigid living tissue |
DE3031894A1 (de) * | 1980-08-23 | 1982-09-16 | Bayer Ag, 5090 Leverkusen | Vinylsilikon-pasten fuer die zahnabformung |
US4368314A (en) * | 1980-08-29 | 1983-01-11 | Toagoesi Chemical Industry Co., Ltd. | Curable composition comprising spiro-orthoester compound |
US4504231A (en) * | 1981-02-17 | 1985-03-12 | Dentsply Research & Development Corp. | Process for filling teeth |
JPS6067531A (ja) * | 1983-09-22 | 1985-04-17 | Toshiba Corp | 樹脂組成物 |
JPS61227509A (ja) * | 1985-04-02 | 1986-10-09 | G C Dental Ind Corp | 歯科用修復材 |
US4673354A (en) * | 1985-10-01 | 1987-06-16 | Minnesota Mining And Manufacturing Company | Stable silanol priming solution for use in dentistry |
US4843136A (en) * | 1986-09-26 | 1989-06-27 | Bayer Aktiengesellschaft | (Meth)-acrylates of siloxanes containing tricyclodecane groups |
DE3903407A1 (de) * | 1989-02-06 | 1990-08-09 | Blendax Werke Schneider Co | Dentales fuellungsmaterial |
DE3913250A1 (de) * | 1989-04-22 | 1990-10-25 | Degussa | Dentalmaterial (ii) |
DE3913252A1 (de) * | 1989-04-22 | 1990-10-25 | Degussa | Dentalmaterial (i) |
DE4011044A1 (de) * | 1990-04-05 | 1991-10-10 | Fraunhofer Ges Forschung | Silane, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polymerisaten und polykondensaten |
DE4125201C1 (es) * | 1991-07-30 | 1992-10-01 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De |
-
1991
- 1991-10-09 DE DE4133494A patent/DE4133494C2/de not_active Expired - Lifetime
-
1992
- 1992-10-07 ES ES92922122T patent/ES2135417T3/es not_active Expired - Lifetime
- 1992-10-07 DK DK92922122T patent/DK0643752T3/da active
- 1992-10-07 AU AU27674/92A patent/AU2767492A/en not_active Abandoned
- 1992-10-07 WO PCT/US1992/008530 patent/WO1993007230A1/en active IP Right Grant
- 1992-10-07 AT AT92922122T patent/ATE184627T1/de active
- 1992-10-07 EP EP92922122A patent/EP0643752B1/en not_active Expired - Lifetime
- 1992-10-07 CA CA002120490A patent/CA2120490C/en not_active Expired - Lifetime
- 1992-10-07 DE DE69230006T patent/DE69230006T2/de not_active Expired - Lifetime
- 1992-10-09 PT PT100951A patent/PT100951B/pt not_active IP Right Cessation
-
1996
- 1996-09-13 US US08/712,653 patent/US5877232A/en not_active Expired - Lifetime
-
1999
- 1999-10-08 GR GR990402566T patent/GR3031475T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
CA2120490A1 (en) | 1993-04-15 |
DE4133494A1 (de) | 1993-04-15 |
CA2120490C (en) | 1998-01-27 |
EP0643752A1 (en) | 1995-03-22 |
WO1993007230A1 (en) | 1993-04-15 |
ATE184627T1 (de) | 1999-10-15 |
JP3606325B2 (ja) | 2005-01-05 |
JPH07504157A (ja) | 1995-05-11 |
DE69230006T2 (de) | 2000-04-20 |
PT100951A (pt) | 1993-11-30 |
EP0643752B1 (en) | 1999-09-15 |
DK0643752T3 (da) | 1999-12-20 |
DE4133494C2 (de) | 1996-03-28 |
GR3031475T3 (en) | 2000-01-31 |
EP0643752A4 (en) | 1994-06-03 |
DE69230006D1 (de) | 1999-10-21 |
US5877232A (en) | 1999-03-02 |
AU2767492A (en) | 1993-05-03 |
PT100951B (pt) | 1999-07-30 |
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