EP2963100A1 - Flüssige Klarspülmittel - Google Patents

Flüssige Klarspülmittel Download PDF

Info

Publication number: EP2963100A1
Authority: EP; European Patent Office
Prior art keywords: stands; integer; composition; surfactants; surfactant
Prior art date: 2014-07-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP14175880.5A

Other languages

English (en)

French (fr)

Other versions

EP2963100B1 (de

Inventor

Christoph Kolano

Karsten Holtin

Kaoru Tachikawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Kolb Distribution Ltd

Original Assignee

Kolb Distribution Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-07-04

Filing date

2014-07-04

Publication date

2016-01-06

2014-07-04 Application filed by Kolb Distribution Ltd filed Critical Kolb Distribution Ltd

2014-07-04 Priority to EP14175880.5A priority Critical patent/EP2963100B1/de

2014-09-30 Priority to EP14187013.9A priority patent/EP2963101B1/de

2016-01-06 Publication of EP2963100A1 publication Critical patent/EP2963100A1/de

2018-09-19 Application granted granted Critical

2018-09-19 Publication of EP2963100B1 publication Critical patent/EP2963100B1/de

Status Active legal-status Critical Current

2034-07-04 Anticipated expiration legal-status Critical

Links

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230000006750 UV protection Effects 0.000 description 1
ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 1
AQKOHYMKBUOXEB-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-(16-methylheptadecanoyloxy)oxolan-2-yl]-2-(16-methylheptadecanoyloxy)ethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCC(C)C)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC(C)C AQKOHYMKBUOXEB-RYNSOKOISA-N 0.000 description 1
FRGAIZLZPOROJH-BKIJVIAGSA-N [(2R,3S,4S,5R,6S)-3,4,5-trihydroxy-6-[2-hydroxy-3-[2-hydroxy-3-(2-hydroxy-3-octadecanoyloxypropoxy)propoxy]propoxy]oxan-2-yl]methyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COCC(O)CO[C@H]1O[C@H](COC(=O)CCCCCCCCCCCCCCCCC)[C@@H](O)[C@H](O)[C@H]1O FRGAIZLZPOROJH-BKIJVIAGSA-N 0.000 description 1
TTZKGYULRVDFJJ-GIVMLJSASA-N [(2r)-2-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-[(z)-octadec-9-enoyl]oxyethyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1O TTZKGYULRVDFJJ-GIVMLJSASA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
KTYVHLCLTPLSGC-UHFFFAOYSA-N amino propanoate Chemical compound CCC(=O)ON KTYVHLCLTPLSGC-UHFFFAOYSA-N 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
235000013871 bee wax Nutrition 0.000 description 1
239000012166 beeswax Substances 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
150000008366 benzophenones Chemical class 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
229940073507 cocamidopropyl betaine Drugs 0.000 description 1
230000001427 coherent effect Effects 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
239000000645 desinfectant Substances 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000010794 food waste Substances 0.000 description 1
229930182478 glucoside Natural products 0.000 description 1
229960005150 glycerol Drugs 0.000 description 1
150000002333 glycines Chemical class 0.000 description 1
239000008187 granular material Substances 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000010409 ironing Methods 0.000 description 1
PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
229940048848 lauryl glucoside Drugs 0.000 description 1
239000005355 lead glass Substances 0.000 description 1
235000020778 linoleic acid Nutrition 0.000 description 1
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
150000002632 lipids Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
238000002156 mixing Methods 0.000 description 1
RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229940049964 oleate Drugs 0.000 description 1
235000021313 oleic acid Nutrition 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920001515 polyalkylene glycol Polymers 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920000570 polyether Polymers 0.000 description 1
239000008389 polyethoxylated castor oil Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000003996 polyglycerol polyricinoleate Substances 0.000 description 1
235000010958 polyglycerol polyricinoleate Nutrition 0.000 description 1
229940048845 polyglyceryl-3 diisostearate Drugs 0.000 description 1
229940100518 polyglyceryl-4 isostearate Drugs 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
229940043230 sarcosine Drugs 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000005361 soda-lime glass Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
235000011008 sodium phosphates Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000001593 sorbitan monooleate Substances 0.000 description 1
235000011069 sorbitan monooleate Nutrition 0.000 description 1
229940035049 sorbitan monooleate Drugs 0.000 description 1
229960005078 sorbitan sesquioleate Drugs 0.000 description 1
235000019337 sorbitan trioleate Nutrition 0.000 description 1
229960000391 sorbitan trioleate Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000005846 sugar alcohols Chemical class 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000003826 tablet Substances 0.000 description 1
239000003760 tallow Substances 0.000 description 1
238000005494 tarnishing Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
239000001226 triphosphate Substances 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
229940071104 xylenesulfonate Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

compositions of the present invention may encompass co-surfactants (component c) different from components (a) and (b).
co-surfactants -or emulsifiers - are of non-ionic nature, however also anionic or amphoteric surfactants are suitable.
Amphoteric surfactants are amphoteric or zwitterionic surfactants.
Zwitterionic surfactants are surface-active compounds which contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
Typical formulations of such compositions for machine dishwashing comprise pentasodium triphosphate (s. sodium phosphates) in amounts of 0, or 1 to 50 percent by weight.
Sodium citrate in amounts of from 30 to 45 percent by weight
sodium polycarboxylate in amounts of from 5 to 8 percent by weight
sodium metasilicate in amounts of from 10 to 60 percent by weight
sodium hydrogen carbonate in amounts of from 10 to 25 percent by weight
sodium disilicate in amounts of from 10 to 30 percent by weight
sodium perborate in amounts of from 5 to 10 percent by weight
bleach activators in amounts of from 2 to 4 percent by weight
enzymes preferably protease and amylase, in amounts of from 1 to 6 percent by weight
low-foam non-ionic surfactants in amounts of from 1 to 20 percent by weight
silver/glass protection and fragrances in amounts up to 5 percent by weight.

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

EP14175880.5A 2014-07-04 2014-07-04 Flüssige Klarspülmittel Active EP2963100B1 (de)

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EP14175880.5A EP2963100B1 (de)	2014-07-04	2014-07-04	Flüssige Klarspülmittel
EP14187013.9A EP2963101B1 (de)	2014-07-04	2014-09-30	Reinigungsmittel für harte Oberflächen

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Application Number	Priority Date	Filing Date	Title
EP14175880.5A EP2963100B1 (de)	2014-07-04	2014-07-04	Flüssige Klarspülmittel

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EP2963100B1 EP2963100B1 (de)	2018-09-19

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EP14187013.9A Active EP2963101B1 (de)	2014-07-04	2014-09-30	Reinigungsmittel für harte Oberflächen

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WO2018114508A1 (de) *	2016-12-21	2018-06-28	Henkel Ag & Co. Kgaa	Klarspülformulierung
WO2023247309A1 (en)	2022-06-20	2023-12-28	Reckitt Benckiser Finish B.V.	Concentrated liquid rinse aid suitable for dilution and repeated use

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CN114774942A (zh) *	2021-12-29	2022-07-22	苏州盈得化学科技有限公司	一种不锈钢管表面处理剂及其制备方法与应用
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Also Published As

Publication number	Publication date
EP2963101B1 (de)	2018-03-07
EP2963100B1 (de)	2018-09-19
EP2963101A1 (de)	2016-01-06

Publication	Publication Date	Title
EP2963100B1 (de)	2018-09-19	Flüssige Klarspülmittel
EP1856039B1 (de)	2014-01-01	Ionische Flüssigkeiten basierend auf Persäure-Anionen
US7786064B1 (en)	2010-08-31	Ionic liquids derived from functionalized anionic surfactants
US20100099314A1 (en)	2010-04-22	Ionic liquids derived from surfactants
KR102467665B1 (ko)	2022-11-16	액체 세정제
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US20120035090A1 (en)	2012-02-09	Isosorbide Monoesters And Their Use In Household Applications
EP3039008B1 (de)	2018-08-08	Etheramine auf basis von alkoxyliertem glycerin oder trimethylolpropan
EP2841548B1 (de)	2016-10-26	Formulierungen, ihre verwendung als oder zur herstellung von geschirrspülmitteln und ihre herstellung
GB2145726A (en)	1985-04-03	Surface active agents
KR102002656B1 (ko)	2019-07-23	세제 및 섬유 제품용의 액체 세정제
WO2016007293A1 (en)	2016-01-14	Dishwashing detergent and methods of making and using the same
EP3122717B1 (de)	2019-02-06	Etheramine basierend auf 1,2-dialkoholen
JP6659843B2 (ja)	2020-03-04	アルコキシル化ポリアルカノールアミンを有する洗浄組成物
EP3390611B1 (de)	2022-11-16	Verfahren zur reinigung einer harten oberfläche mit einer reinigungszusammensetzung, die ein polyalkanolamin enthält
JP2009155594A (ja)	2009-07-16	液体洗浄剤組成物
JP7190823B2 (ja)	2022-12-16	衣料用液体洗浄剤組成物
KR101903977B1 (ko)	2018-10-04	디알코올 기반 에테르아민
JP5292606B2 (ja)	2013-09-18	衣料用液体洗浄剤組成物
US20110247657A1 (en)	2011-10-13	Rinse Aid, Comprising Fatty Acid Alkanolamide Polyalkylene Glycol Ethers
JP6105360B2 (ja)	2017-03-29	プラスチック食器用乾燥仕上げ剤組成物
CN107849494B (zh)	2021-03-23	衣物用液体洗涤剂组合物
WO2024115118A1 (en)	2024-06-06	Substrate treatment compositions
WO2024115130A1 (en)	2024-06-06	Substrate treatment compositions
JP2016006172A (ja)	2016-01-14	液体洗浄剤

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