EP0066164A2 - Procédé pour le chauffage d'une surface d'un substrat au moyen d'un jet de gaz chaud, particulièrement avec application simultanée d'un matériau de revêtement en utilisant la méthode de pulvérisation par flamme, et brûleur pour la réalisation de ce procédé - Google Patents
Procédé pour le chauffage d'une surface d'un substrat au moyen d'un jet de gaz chaud, particulièrement avec application simultanée d'un matériau de revêtement en utilisant la méthode de pulvérisation par flamme, et brûleur pour la réalisation de ce procédé Download PDFInfo
- Publication number
- EP0066164A2 EP0066164A2 EP82104279A EP82104279A EP0066164A2 EP 0066164 A2 EP0066164 A2 EP 0066164A2 EP 82104279 A EP82104279 A EP 82104279A EP 82104279 A EP82104279 A EP 82104279A EP 0066164 A2 EP0066164 A2 EP 0066164A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- nozzle
- burner
- ring guide
- air
- guide plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 title claims abstract description 12
- 239000000758 substrate Substances 0.000 title claims abstract description 12
- 238000010438 heat treatment Methods 0.000 title claims abstract description 9
- 238000010285 flame spraying Methods 0.000 title claims abstract description 7
- 239000011248 coating agent Substances 0.000 title claims description 20
- 238000000576 coating method Methods 0.000 title claims description 20
- 239000007789 gas Substances 0.000 claims abstract description 18
- 239000007921 spray Substances 0.000 claims abstract description 11
- 238000002485 combustion reaction Methods 0.000 claims abstract description 6
- 239000002737 fuel gas Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 4
- 239000013505 freshwater Substances 0.000 claims description 2
- 238000013021 overheating Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 4
- 230000001133 acceleration Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000010349 pulsation Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920006300 shrink film Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 241001156002 Anthonomus pomorum Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004323 axial length Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
- B05B7/20—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion
- B05B7/201—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion downstream of the nozzle
- B05B7/205—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed by flame or combustion downstream of the nozzle the material to be sprayed being originally a particulate material
Definitions
- the invention relates to a method for heating the surface of a substrate by means of a hot gas jet, in particular with simultaneous supply of a substance used for surface treatment or coating by the flame spraying method, in which the ring-shaped fuel gas to be mixed with combustion air is supplied by supplying compressed air in the form of a pump jet is accelerated towards the surface to be heated.
- the invention further relates to a burner for heating the surface of a substrate, in particular in combination with a spray nozzle for flame spraying for a surface treatment or coating substance, consisting in particular of a coaxial nozzle for compressed air with an axial flow component and one with a spacing between the nozzle surrounding ring guide plate, which forms an annular channel with rear openings for the supply of air, and from a concentrically arranged fuel gas nozzle.
- the compressed air supplied via the axial nozzle simultaneously transports the coating material in particle form.
- the pump jet sucks in the compressed air via the ring duct, which is open at the rear.
- the sucked-in air mixes in the annular duct with the fuel gases supplied via an annular nozzle on the outer edge of the annular duct, so that a ring of flame arises which, like a jacket, surrounds the central, conical compressed air jet loaded with laminate particles, whereby between this jacket and the conical compressed air jet forms a coat from the air drawn in.
- the hot gas flame jacket heats the surface to be coated and dries it off.
- the advantages of a method carried out with such a burner are that the coating takes place in a zone of very low air humidity.
- the heat energy required to dry the surface can be generated and transported sufficiently quickly without the temperature on the transport route becoming too high. Flammable and low-boiling solvents can also be added to the coating material without igniting them when sprayed.
- the invention has for its object to improve a method and a burner of the type mentioned in performance and flame stability.
- the improvement in performance and flame stability is based on the multiple acceleration of the hot combustion gases and the cascade-shaped cross-sectional expansion with simultaneous air supply. Measurements have shown that there is a combustion with a content below 0.1 CO vol.%.
- the measures according to the invention convert the high combustion gas temperature to a low temperature of the hot gases at a high flow rate of these gases in a depressurized, concentric system. This is a prerequisite for favorable heat transfer coefficients on the surface to be heated.
- the low temperature drop of the emerging hot gases in the direction of flow is also advantageous. That's why can also be heated with the method according to the invention bodies that are very sensitive to excessive temperatures.
- shrink films for packaging objects can also be heated without the shrink film overheating even with small changes in distance.
- surface heating, drying and coating e.g. carry out a pipe or coil coating in one pass.
- the object can be achieved in that the one ring baffle is surrounded by at least one further ring baffle of larger diameter with rear openings for the supply of air or in that at least one further, in particular coaxial nozzle for the supply of compressed air is provided with an axial flow component, or finally by combining both of the aforementioned measures.
- next larger cascade protrudes beyond the front end of the smaller ring guide plate. It is also advantageous if the associated, further nozzle for compressed air is arranged within the larger cross section, in particular the protruding section of the larger ring guide plate.
- throttle elements can be assigned to the f rear openings of the ring channel for the air.
- the throttle elements can be formed by a perforated disc.
- the throttle elements can also be inclined blades, which then give the air supplied a swirl favoring the swirl. Both the perforated disc and the inclined blades can serve as spacer and support elements between the ring guide plates.
- Both the burner and the spray gun can be used in an oxygen-free atmosphere if each ring channel is closed on the back except for the openings for the supply of air and the openings are connected to a supply line for compressed air.
- the end of the burner is closed by a ring plate except for a central opening.
- a nozzle for a flushing medium with jet direction should be provided through the central opening, in particular a ring guide plate being connected to the opening. The rinsing medium then cleans the surface to be coated from residues arising during drying, e.g. Salt.
- a further nozzle for a gaseous or liquid medium with jet direction can be arranged on the area of the substrate which is exposed to the hot gases outside the burner head.
- the burner and the spray gun have a concentric structure.
- first ring guide plate 1 consists of a first ring guide plate 1 and a second ring guide plate 2 of larger diameter, which is arranged concentrically to the first ring guide plate 1 and is supported by spacers 3 from the first ring guide plate 1.
- the spacers 3 are preferably designed as inclined blades.
- a channel 4 is provided for the supply of compressed air which is maintained by appropriate spacers. 3 Approximately half the axial length of the ring guide plate 1, openings 5 formed as nozzles with a main flow component in the axial direction are formed in the channel 4. The end of the channel 4 has a nozzle 6, which is already outside the ring guide plate 1 and emerges from the compressed air with a main flow component in the axial direction.
- the nozzle 6 can also be designed as a slot die, wherein the slot can also be formed by a row of holes.
- the ring channels formed by the ring guide plates 1, 2 and the compressed air channel 4 are open at the rear so that outside air can be announced via these openings 7, 8.
- the suction power is through
- holes can also be provided in the walls of the ring guide plate 1 in the rear region.
- annular nozzle 9 which has a row of holes on the side facing the ring guide plate 2 for the escape of fuel gas.
- the escaping fuel gas mixes with the air sucked in through the rear openings 7, so that a combustible gas-air mixture is formed for an annular flame.
- a spray gun can also be constructed according to the principle of the burner described.
- compressed air loaded with coating particles is supplied via the central channel 4 or, if the coating material is supplied separately, the coating material is supplied to the compressed air in the exit plane and atomized there.
- further compressed air can then be supplied either centrally or in a ring for further acceleration of the flow.
- a further nozzle 10 is arranged on the side of the burner head for the supply of compressed air or a liquid medium, which is either blown or sprayed onto the surface of the substrate acted upon by the hot gases or into the hot gas jet.
- compressed air dust particles and dirt particles released during drying can be blown away.
- a liquid medium e.g. of an activating agent
- the surface for the coating medium can be activated.
- the nozzle 10 itself can be designed as a single nozzle or as a slot die. Instead of the slot, a row of holes can also be provided.
- the coating medium is fed to a central high-pressure nozzle 11 with a cone jet.
- the high-pressure nozzle 11 is arranged within a ring guide plate 12 which has openings 13 on the rear for the supply of air.
- an annular channel 14 fed with compressed air is arranged on the outside of the ring guide plate 12. Compressed air with axial main flow components emerges from the annular channel 14 via a plurality of annularly arranged nozzles 15 into the annular channel formed by the annular guide plate 12 and the high-pressure nozzle 11, so that air is sucked in from the atmosphere via the openings 13.
- Compressed air also passes from the ring channel 14 via ring-shaped, axial nozzles 16 into the ring channel, which is formed by the ring guide plate 12 and a ring guide plate 17 of larger diameter.
- the compressed air emerging from the nozzles 16 acts as a pump jet and sucks in air via the rear openings 18.
- An annular nozzle 19 for supplying fuel gas to the annular channel is arranged in the outer annular channel on the inside of the annular guide plate 17.
- coating material is supplied via a nozzle 20, which can be closed by a central hollow needle 21. Compressed air can be supplied via the hollow needle 21.
- the nozzle 20 is surrounded by an annular nozzle 22, the annular channel 23 of which is fed via an axial channel 24 and a branch 25 from a main channel 26, compressed air, which atomizes the emerging coating material in the mouth plane of the nozzle 20.
- the nozzle arrangement 20 to 22 is surrounded by an inner ring guide plate 27, which forms an annular channel with an outer ring guide plate 28, in which an annular nozzle 29 for fuel gas is arranged.
- the rear of the ring channel is closed by a plate 30 except for openings 31, via which, with the interposition of an annular distribution channel 32, compressed air is supplied from the main supply channel 26.
- the end face of the burner is closed except for a central opening 33 by an annular plate 34, to the inner edge of which an inwardly projecting, funnel-shaped ring baffle 35 is connected.
- the ring of the hot gases is directed through the ring guide plate 35 and on the other hand causes the hot gases to swirl in the annular space formed by the ring guide plates 28, 35.
- the cross section is initially gradually increased in the direction of flow, kinetic energy being supplied to the flow in axially offset planes with the compressed air supplied, and the cross section is reduced only when it exits in the area of the ring guide plate 34.
- the burner described is suitable for use under water except for the front, central opening 33. Because of the central, additional compressed air jet through the hollow needle 21, a strong pump jet results which withstands the pressure from the outside.
- a detergent in particular fresh water, can be supplied via the central opening 33 and additionally via a nozzle 36.
- the beam direction should be slightly inclined to create a swirl.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Nozzles (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Gas Burners (AREA)
- Resistance Heating (AREA)
- Drying Of Solid Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82104279T ATE29113T1 (de) | 1981-05-29 | 1982-05-15 | Verfahren zum erwaermen der oberflaeche eines substrates mittels eines heissgasstrahls, insbesondere unter gleichzeitiger zufuhr von beschichtungsstoff nach dem flammspritzverfahren und brenner zur durchfuehrung des verfahrens. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3121370 | 1981-05-29 | ||
DE19813121370 DE3121370A1 (de) | 1981-05-29 | 1981-05-29 | Pressluft-gasbrenner zum betrieb von flammspritzpistolen und als trockner |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0066164A2 true EP0066164A2 (fr) | 1982-12-08 |
EP0066164A3 EP0066164A3 (en) | 1983-07-20 |
EP0066164B1 EP0066164B1 (fr) | 1987-08-26 |
Family
ID=6133493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82104279A Expired EP0066164B1 (fr) | 1981-05-29 | 1982-05-15 | Procédé pour le chauffage d'une surface d'un substrat au moyen d'un jet de gaz chaud, particulièrement avec application simultanée d'un matériau de revêtement en utilisant la méthode de pulvérisation par flamme, et brûleur pour la réalisation de ce procédé |
Country Status (11)
Country | Link |
---|---|
US (1) | US4579280A (fr) |
EP (1) | EP0066164B1 (fr) |
JP (1) | JPS5824713A (fr) |
AR (1) | AR228902A1 (fr) |
AT (1) | ATE29113T1 (fr) |
BR (1) | BR8203170A (fr) |
CA (1) | CA1180548A (fr) |
DE (2) | DE3121370A1 (fr) |
ES (1) | ES512652A0 (fr) |
NO (2) | NO155676C (fr) |
ZA (1) | ZA823832B (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0240751A2 (fr) * | 1986-04-07 | 1987-10-14 | Rothenberger Werkzeuge-Maschinen Gmbh | Brûleur à main à basse pression |
CN107597462A (zh) * | 2017-09-30 | 2018-01-19 | 京华派克邯郸机械科技有限公司 | 一种发泡胶使用工艺 |
DE102017223113A1 (de) * | 2017-12-18 | 2019-06-19 | Sms Group Gmbh | Brenner |
CN112856491A (zh) * | 2021-01-15 | 2021-05-28 | 宁波方太厨具有限公司 | 防干烧燃烧器及包含其的防干烧灶具 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8721481D0 (en) * | 1987-09-11 | 1987-10-21 | Volstatic Ltd | Powder delivery apparatus |
US4874310A (en) * | 1988-02-25 | 1989-10-17 | Selas Corporation Of America | Low NOX burner |
US5405085A (en) * | 1993-01-21 | 1995-04-11 | White; Randall R. | Tuneable high velocity thermal spray gun |
US5445325A (en) * | 1993-01-21 | 1995-08-29 | White; Randall R. | Tuneable high velocity thermal spray gun |
US5520334A (en) * | 1993-01-21 | 1996-05-28 | White; Randall R. | Air and fuel mixing chamber for a tuneable high velocity thermal spray gun |
US7051743B2 (en) * | 2002-10-29 | 2006-05-30 | Yong Bae Kim | Apparatus and method for cleaning surfaces of semiconductor wafers using ozone |
DE10332339A1 (de) * | 2003-07-16 | 2005-02-03 | BSH Bosch und Siemens Hausgeräte GmbH | Heizungsanordnung für einen Trockner |
US20090014558A1 (en) * | 2007-07-12 | 2009-01-15 | Itt Manufacturing Enterprises, Inc. | Portable sprayer/mister/fogging system for dispersing media in a uniform and controlled manner |
WO2012034018A1 (fr) * | 2010-09-09 | 2012-03-15 | Integrated Green Technogies Llc | Système et dispositif de pulvérisation thermique de poudre |
KR101692347B1 (ko) * | 2015-04-17 | 2017-01-03 | 주식회사 에스엠뿌레 | 분무기 및 분무조절장치 |
JP7319821B2 (ja) * | 2019-05-09 | 2023-08-02 | 株式会社Nippo | 路面乾燥装置及び路面乾燥方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR493478A (fr) * | 1918-12-02 | 1919-08-09 | Thomas Stansfield Worthington | Perfectionnements aux appareils à métalliser |
US1421844A (en) * | 1914-09-14 | 1922-07-04 | Westinghouse Electric & Mfg Co | Fluid-translating device |
GB675503A (en) * | 1949-07-27 | 1952-07-09 | Christian Semenitz | Improvements relating to welding and like processes |
DE1055409B (de) * | 1952-03-29 | 1959-04-16 | Colarit Korrosionsschutz Ges M | Flammspritzpistole |
DE1097327B (de) * | 1959-04-29 | 1961-01-12 | Hermine Wolf Geb Freudenthaler | Flammspritzpistole |
DE2838500A1 (de) * | 1978-09-04 | 1980-03-06 | Helmut Gruen | Brenner fuer gasfoermige brennstoffe, insbesondere fluessiggas, wie propan, butan o.dgl. |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US364101A (en) * | 1887-05-31 | Gas-burner | ||
US586066A (en) * | 1897-07-06 | Burner for compound blowpipes or brazers | ||
GB189501857A (en) * | 1895-01-26 | 1895-03-23 | Fletcher Russell & Co Ltd | Improvements in Air-blast Gas Burners. |
US992181A (en) * | 1909-07-03 | 1911-05-16 | Foss Gas Burner And Heating Company | Gas-burner. |
GB191507338A (en) * | 1914-05-23 | 1915-10-07 | Ernst Reinhard | Improvements in Injectors for Ventilating Purposes. |
US1824397A (en) * | 1927-12-20 | 1931-09-22 | Ellsberg Edward | Underwater torch and method therefor |
NL21010C (fr) * | 1928-02-08 | 1929-12-16 | ||
US1995934A (en) * | 1933-09-18 | 1935-03-26 | Trust Company | Gas burner |
US2544259A (en) * | 1944-11-25 | 1951-03-06 | Duccini Gaetano | Metallizing spray gun |
US2466100A (en) * | 1946-01-19 | 1949-04-05 | Charles J Harrah | Oil burner |
BE495126A (fr) * | 1949-06-13 | |||
GB1245393A (en) * | 1967-09-06 | 1971-09-08 | Colebrand Ltd | Improvements relating to under-water painting |
US3620454A (en) * | 1968-01-31 | 1971-11-16 | Eutectic Corp | Flame spray torch |
US3929291A (en) * | 1973-05-24 | 1975-12-30 | Pfrengle Otto | Spray mixing nozzle |
SU748089A1 (ru) * | 1977-07-04 | 1980-07-15 | Восточный научно-исследовательский и проектный институт огнеупорной промышленности | Газова горелка |
US4313721A (en) * | 1979-03-15 | 1982-02-02 | Joseph Henriques | Oil burner diffuser |
DE2952038C2 (de) * | 1979-12-22 | 1982-03-11 | Heraeus Quarzschmelze Gmbh, 6450 Hanau | Schmelzvorrichtung aus Quarzglas zum Herstellen von massivem Quarzglas |
US4411935A (en) * | 1981-11-02 | 1983-10-25 | Anderson James Y | Powder flame spraying apparatus and method |
-
1981
- 1981-05-29 DE DE19813121370 patent/DE3121370A1/de not_active Withdrawn
-
1982
- 1982-05-15 AT AT82104279T patent/ATE29113T1/de not_active IP Right Cessation
- 1982-05-15 EP EP82104279A patent/EP0066164B1/fr not_active Expired
- 1982-05-15 DE DE8282104279T patent/DE3277064D1/de not_active Expired
- 1982-05-26 AR AR289515A patent/AR228902A1/es active
- 1982-05-28 ES ES512652A patent/ES512652A0/es active Granted
- 1982-05-28 CA CA000403961A patent/CA1180548A/fr not_active Expired
- 1982-05-28 BR BR8203170A patent/BR8203170A/pt unknown
- 1982-05-28 NO NO821795A patent/NO155676C/no unknown
- 1982-05-29 JP JP57090532A patent/JPS5824713A/ja active Pending
- 1982-06-01 ZA ZA823832A patent/ZA823832B/xx unknown
-
1985
- 1985-02-12 US US06/701,436 patent/US4579280A/en not_active Expired - Fee Related
-
1986
- 1986-01-21 NO NO860194A patent/NO860194L/no unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1421844A (en) * | 1914-09-14 | 1922-07-04 | Westinghouse Electric & Mfg Co | Fluid-translating device |
FR493478A (fr) * | 1918-12-02 | 1919-08-09 | Thomas Stansfield Worthington | Perfectionnements aux appareils à métalliser |
GB675503A (en) * | 1949-07-27 | 1952-07-09 | Christian Semenitz | Improvements relating to welding and like processes |
DE1055409B (de) * | 1952-03-29 | 1959-04-16 | Colarit Korrosionsschutz Ges M | Flammspritzpistole |
DE1097327B (de) * | 1959-04-29 | 1961-01-12 | Hermine Wolf Geb Freudenthaler | Flammspritzpistole |
DE2838500A1 (de) * | 1978-09-04 | 1980-03-06 | Helmut Gruen | Brenner fuer gasfoermige brennstoffe, insbesondere fluessiggas, wie propan, butan o.dgl. |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0240751A2 (fr) * | 1986-04-07 | 1987-10-14 | Rothenberger Werkzeuge-Maschinen Gmbh | Brûleur à main à basse pression |
EP0240751A3 (en) * | 1986-04-07 | 1988-09-21 | Rothenberger Gmbh & Co. Werkzeuge-Maschinen Kg | Low-pressure hand burner |
CN107597462A (zh) * | 2017-09-30 | 2018-01-19 | 京华派克邯郸机械科技有限公司 | 一种发泡胶使用工艺 |
DE102017223113A1 (de) * | 2017-12-18 | 2019-06-19 | Sms Group Gmbh | Brenner |
CN112856491A (zh) * | 2021-01-15 | 2021-05-28 | 宁波方太厨具有限公司 | 防干烧燃烧器及包含其的防干烧灶具 |
Also Published As
Publication number | Publication date |
---|---|
EP0066164B1 (fr) | 1987-08-26 |
NO860194L (no) | 1982-11-30 |
DE3277064D1 (en) | 1987-10-01 |
JPS5824713A (ja) | 1983-02-14 |
ZA823832B (en) | 1983-09-28 |
BR8203170A (pt) | 1983-05-17 |
AR228902A1 (es) | 1983-04-29 |
NO155676B (no) | 1987-01-26 |
ES8306526A1 (es) | 1983-06-16 |
NO155676C (no) | 1987-05-06 |
ES512652A0 (es) | 1983-06-16 |
US4579280A (en) | 1986-04-01 |
EP0066164A3 (en) | 1983-07-20 |
ATE29113T1 (de) | 1987-09-15 |
DE3121370A1 (de) | 1983-05-19 |
CA1180548A (fr) | 1985-01-08 |
NO821795L (no) | 1982-11-30 |
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