DK0959990T3 - Fremgangsmåde til hindring af korrosion af metalplader under anvendelse af vinylsilaner - Google Patents
Fremgangsmåde til hindring af korrosion af metalplader under anvendelse af vinylsilanerInfo
- Publication number
- DK0959990T3 DK0959990T3 DK97951134T DK97951134T DK0959990T3 DK 0959990 T3 DK0959990 T3 DK 0959990T3 DK 97951134 T DK97951134 T DK 97951134T DK 97951134 T DK97951134 T DK 97951134T DK 0959990 T3 DK0959990 T3 DK 0959990T3
- Authority
- DK
- Denmark
- Prior art keywords
- preventing corrosion
- sheet metal
- sheet
- vinyl silanes
- metal sheet
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Laminated Bodies (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/743,864 US5759629A (en) | 1996-11-05 | 1996-11-05 | Method of preventing corrosion of metal sheet using vinyl silanes |
PCT/EP1997/006090 WO1998019798A2 (en) | 1996-11-05 | 1997-11-04 | Method of preventing corrosion of metal sheet using vinyl silanes |
Publications (1)
Publication Number | Publication Date |
---|---|
DK0959990T3 true DK0959990T3 (da) | 2002-10-07 |
Family
ID=24990509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK97951134T DK0959990T3 (da) | 1996-11-05 | 1997-11-04 | Fremgangsmåde til hindring af korrosion af metalplader under anvendelse af vinylsilaner |
Country Status (21)
Country | Link |
---|---|
US (1) | US5759629A (de) |
EP (1) | EP0959990B1 (de) |
JP (1) | JP3993244B2 (de) |
KR (1) | KR20000053055A (de) |
CN (1) | CN1072531C (de) |
AT (1) | ATE220576T1 (de) |
AU (1) | AU724454B2 (de) |
BR (1) | BR9712744A (de) |
CA (1) | CA2270879C (de) |
DE (1) | DE69714080T2 (de) |
DK (1) | DK0959990T3 (de) |
EA (1) | EA199900444A1 (de) |
ES (1) | ES2180074T3 (de) |
HU (1) | HUP0000458A3 (de) |
IL (1) | IL129673A0 (de) |
NZ (1) | NZ335605A (de) |
PL (1) | PL333326A1 (de) |
TR (1) | TR199901538T2 (de) |
TW (1) | TW422894B (de) |
WO (1) | WO1998019798A2 (de) |
ZA (1) | ZA979948B (de) |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5750197A (en) | 1997-01-09 | 1998-05-12 | The University Of Cincinnati | Method of preventing corrosion of metals using silanes |
AU1198799A (en) | 1997-10-23 | 1999-05-10 | Cornelis P. J. Van Der Aar | Rubber to metal bonding by silane coupling agents |
JP4165943B2 (ja) * | 1998-11-18 | 2008-10-15 | 日本ペイント株式会社 | 亜鉛被覆鋼および無被覆鋼の防錆コーティング剤 |
US6416869B1 (en) | 1999-07-19 | 2002-07-09 | University Of Cincinnati | Silane coatings for bonding rubber to metals |
US6071566A (en) * | 1999-02-05 | 2000-06-06 | Brent International Plc | Method of treating metals using vinyl silanes and multi-silyl-functional silanes in admixture |
US6106901A (en) * | 1999-02-05 | 2000-08-22 | Brent International Plc | Method of treating metals using ureido silanes and multi-silyl-functional silanes in admixture |
US6132808A (en) | 1999-02-05 | 2000-10-17 | Brent International Plc | Method of treating metals using amino silanes and multi-silyl-functional silanes in admixture |
WO2001006036A1 (en) * | 1999-07-19 | 2001-01-25 | University Of Cincinnati | Acyloxy silane treatments for metals |
US6827981B2 (en) | 1999-07-19 | 2004-12-07 | The University Of Cincinnati | Silane coatings for metal |
FR2796655B1 (fr) * | 1999-07-22 | 2001-10-19 | Dacral Sa | Procede et composition de traitement anti-corrosion d'un substrat metallique prealablement protege par une couche de revetement a base de zinc |
US6270884B1 (en) * | 1999-08-02 | 2001-08-07 | Metal Coatings International Inc. | Water-reducible coating composition for providing corrosion protection |
US6710123B1 (en) | 1999-11-12 | 2004-03-23 | Atofina Chemicals, Inc. | Fluoropolymers containing organo-silanes and methods of making the same |
US6461682B1 (en) | 2001-03-08 | 2002-10-08 | David Crotty | Composition and method for inhibiting corrosion of aluminum and aluminum alloys using mercapto substituted silanes |
DE60236006D1 (de) * | 2001-06-28 | 2010-05-27 | Alonim Holding Agricultural Co | Verfahren zum anodisieren von magnesium und magnesiumlegierungen und zur herstellung von leitfähigen schichten auf einer anodisierten oberfläche |
KR20040030925A (ko) * | 2001-08-03 | 2004-04-09 | 엘리사 홀딩 엘엘씨 | 금속 표면 처리용 무전해 방법 및 이로부터 형성된 물품 |
US20040188262A1 (en) * | 2002-02-05 | 2004-09-30 | Heimann Robert L. | Method for treating metallic surfaces and products formed thereby |
US6833414B2 (en) | 2002-02-12 | 2004-12-21 | Arkema Inc. | Cross-linkable aqueous fluoropolymer based dispersions containing silanes |
US6770419B2 (en) * | 2002-09-11 | 2004-08-03 | International Business Machines Corporation | Low silicon-outgassing resist for bilayer lithography |
FR2845390B1 (fr) * | 2002-10-03 | 2006-02-24 | Centre Nat Rech Scient | Compositions pigmentaires de particules d'aluminium metallique |
US6887308B2 (en) * | 2003-01-21 | 2005-05-03 | Johnsondiversey, Inc. | Metal coating coupling composition |
DE10320779A1 (de) | 2003-05-09 | 2004-11-18 | Degussa Ag | Korrosionsschutz auf Metallen |
EP1504891A1 (de) * | 2003-08-06 | 2005-02-09 | Elisha Holding LLC | Mehrschichtig-beschichteter korrosionsbeständiger Gegenstand und Verfahren zu seiner Herstellung |
US7524535B2 (en) * | 2004-02-25 | 2009-04-28 | Posco | Method of protecting metals from corrosion using thiol compounds |
JP5021479B2 (ja) * | 2004-10-01 | 2012-09-05 | フェノメネクス インコーポレイテッド | テンプレーティッド多層有機/無機グラフィティングを用いたpH安定クロマトグラフィー媒体 |
US10041176B2 (en) * | 2005-04-07 | 2018-08-07 | Momentive Performance Materials Inc. | No-rinse pretreatment methods and compositions |
US7994249B2 (en) * | 2005-09-09 | 2011-08-09 | The University Of Cincinnati | Silane coating compositions and methods of use thereof |
US7704563B2 (en) * | 2005-09-09 | 2010-04-27 | The University Of Cincinnati | Method of applying silane coating to metal composition |
DE102005045034A1 (de) * | 2005-09-21 | 2007-03-29 | Rasselstein Gmbh | Verfahren zur Passivierung der Oberfläche von beschichteten Metallbändern und Vorrichtung für das Aufbringen der Passivschicht auf ein metallisch beschichtetes Stahlband |
US7527872B2 (en) * | 2005-10-25 | 2009-05-05 | Goodrich Corporation | Treated aluminum article and method for making same |
ATE554917T1 (de) * | 2006-05-26 | 2012-05-15 | Borealis Tech Oy | Beschichtete röhre mit einer polyolefinschicht mit verbesserter haftung |
US20080026151A1 (en) * | 2006-07-31 | 2008-01-31 | Danqing Zhu | Addition of silanes to coating compositions |
US8383204B2 (en) * | 2006-11-17 | 2013-02-26 | Ecosil Technologies, Llc | Siloxane oligomer treatment for metals |
US7875318B2 (en) * | 2007-04-24 | 2011-01-25 | Momentive Performance Materials Inc. | Method of applying an anti-corrosion and/or adhesion promoting coating to a metal and resulting coated metal |
US8575292B2 (en) * | 2007-04-24 | 2013-11-05 | Momentive Performance Materials Inc. | Hydroxyl-functional carbamoyl organosilicon compounds of low VOC and HAP generating potential, anti-corrosion and/or adhesion promoting coating composition containing same, environmentally benign method of coating metal therewith and resulting coated metal |
US20090092760A1 (en) * | 2007-10-03 | 2009-04-09 | Adam Brager | Metal protectant and method of application |
US7972659B2 (en) * | 2008-03-14 | 2011-07-05 | Ecosil Technologies Llc | Method of applying silanes to metal in an oil bath containing a controlled amount of water |
EP2103713A1 (de) * | 2008-03-20 | 2009-09-23 | Münch Chemie International GmbH | Korrosionsschutzgrundierung |
US8597482B2 (en) | 2010-09-14 | 2013-12-03 | Ecosil Technologies Llc | Process for depositing rinsable silsesquioxane films on metals |
CN102560490A (zh) * | 2010-12-28 | 2012-07-11 | 鸿富锦精密工业(深圳)有限公司 | 铝及铝合金表面防腐处理方法及其制品 |
CN102337530A (zh) * | 2011-07-11 | 2012-02-01 | 武汉迪赛高科技研究发展有限公司 | 一种用于金属涂装前表面处理的硅烷复合材料 |
CN102304704A (zh) * | 2011-09-09 | 2012-01-04 | 重庆大学 | 一种提高金属表面防护性能的水性硅烷处理剂 |
CN102653861A (zh) * | 2012-05-14 | 2012-09-05 | 合肥华清金属表面处理有限责任公司 | 一种专用于海上钻井隔水套管的表面处理剂及其制备方法 |
CN103757619A (zh) * | 2013-12-26 | 2014-04-30 | 常熟市美尔特金属制品有限公司 | 金属表面处理剂 |
US9739168B2 (en) * | 2014-06-05 | 2017-08-22 | General Electric Company | Off-line wash systems and methods for a gas turbine engine |
CN104532255A (zh) * | 2014-12-05 | 2015-04-22 | 重庆兰芳金属表面处理有限公司 | 一种铝合金水基防护液 |
CN104630782A (zh) * | 2015-03-13 | 2015-05-20 | 上海浦央新材料科技有限公司 | 一种用于钢铁的耐腐蚀防锈液及其制备方法和使用方法 |
CN109112547A (zh) * | 2018-08-30 | 2019-01-01 | 白强 | 一种碱性铝材表面抛光液及其制备和抛光方法 |
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JPS57159865A (en) * | 1981-03-27 | 1982-10-02 | Toray Silicone Co Ltd | Primer composition for bonding |
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JPS60208480A (ja) * | 1984-03-30 | 1985-10-21 | Sumitomo Metal Ind Ltd | 表面処理めつき鋼板 |
JPS61237636A (ja) * | 1985-04-15 | 1986-10-22 | 大同鋼板株式会社 | 塗装鋼板 |
JPS61278582A (ja) * | 1985-06-03 | 1986-12-09 | Toray Silicone Co Ltd | 接着用プライマ−組成物 |
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US5108793A (en) * | 1990-12-24 | 1992-04-28 | Armco Steel Company, L.P. | Steel sheet with enhanced corrosion resistance having a silane treated silicate coating |
US5200275A (en) * | 1990-12-24 | 1993-04-06 | Armco Steel Company, L.P. | Steel sheet with enhanced corrosion resistance having a silane treated silicate coating |
JP2943364B2 (ja) * | 1991-01-28 | 1999-08-30 | ぺんてる株式会社 | アルミニウム又はアルミニウム合金の無電解着色法 |
US5221371A (en) * | 1991-09-03 | 1993-06-22 | Lockheed Corporation | Non-toxic corrosion resistant conversion coating for aluminum and aluminum alloys and the process for making the same |
FR2681334A1 (fr) * | 1991-09-18 | 1993-03-19 | Siderurgie Fse Inst Rech | Procede et dispositif de revetement d'un produit metallurgique par des couches de polymere et produit obtenu par ce procede. |
JP3184614B2 (ja) * | 1992-07-16 | 2001-07-09 | 三菱重工業株式会社 | 鋼材の防食塗装方法 |
US5455080A (en) * | 1992-08-26 | 1995-10-03 | Armco Inc. | Metal substrate with enhanced corrosion resistance and improved paint adhesion |
US5292549A (en) * | 1992-10-23 | 1994-03-08 | Armco Inc. | Metallic coated steel having a siloxane film providing temporary corrosion protection and method therefor |
US5326594A (en) * | 1992-12-02 | 1994-07-05 | Armco Inc. | Metal pretreated with an inorganic/organic composite coating with enhanced paint adhesion |
CA2110461A1 (en) * | 1993-01-25 | 1994-07-26 | Suzanne M. Zefferi | Composition and methods for inhibiting the corrosion of low carbon steel in aqueous systems |
JPH06279732A (ja) * | 1993-01-29 | 1994-10-04 | Asahi Glass Co Ltd | フッ素ゴム接着用プライマー組成物 |
US5322713A (en) * | 1993-03-24 | 1994-06-21 | Armco Inc. | Metal sheet with enhanced corrosion resistance having a silane treated aluminate coating |
JPH06334793A (ja) * | 1993-05-21 | 1994-12-02 | Roland Corp | 画像情報システム |
US5412011A (en) * | 1993-10-15 | 1995-05-02 | Betz Laboratories, Inc. | Composition and process for coating metals |
US5389405A (en) * | 1993-11-16 | 1995-02-14 | Betz Laboratories, Inc. | Composition and process for treating metal surfaces |
US5433976A (en) * | 1994-03-07 | 1995-07-18 | Armco, Inc. | Metal pretreated with an aqueous solution containing a dissolved inorganic silicate or aluminate, an organofuctional silane and a non-functional silane for enhanced corrosion resistance |
JP2878967B2 (ja) * | 1994-06-08 | 1999-04-05 | ポリプラスチックス株式会社 | 金属をインサートした樹脂成形部品及びその製造法 |
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-
1996
- 1996-11-05 US US08/743,864 patent/US5759629A/en not_active Expired - Lifetime
-
1997
- 1997-11-04 NZ NZ335605A patent/NZ335605A/xx unknown
- 1997-11-04 AT AT97951134T patent/ATE220576T1/de active
- 1997-11-04 BR BR9712744-2A patent/BR9712744A/pt unknown
- 1997-11-04 PL PL97333326A patent/PL333326A1/xx unknown
- 1997-11-04 TR TR1999/01538T patent/TR199901538T2/xx unknown
- 1997-11-04 JP JP52104998A patent/JP3993244B2/ja not_active Expired - Lifetime
- 1997-11-04 WO PCT/EP1997/006090 patent/WO1998019798A2/en not_active Application Discontinuation
- 1997-11-04 EP EP97951134A patent/EP0959990B1/de not_active Expired - Lifetime
- 1997-11-04 EA EA199900444A patent/EA199900444A1/ru unknown
- 1997-11-04 TW TW086116372A patent/TW422894B/zh not_active IP Right Cessation
- 1997-11-04 DK DK97951134T patent/DK0959990T3/da active
- 1997-11-04 IL IL12967397A patent/IL129673A0/xx unknown
- 1997-11-04 DE DE69714080T patent/DE69714080T2/de not_active Expired - Lifetime
- 1997-11-04 ES ES97951134T patent/ES2180074T3/es not_active Expired - Lifetime
- 1997-11-04 KR KR1019990703962A patent/KR20000053055A/ko not_active Application Discontinuation
- 1997-11-04 CA CA002270879A patent/CA2270879C/en not_active Expired - Lifetime
- 1997-11-04 AU AU54791/98A patent/AU724454B2/en not_active Expired
- 1997-11-04 CN CN97180415A patent/CN1072531C/zh not_active Expired - Lifetime
- 1997-11-04 HU HU0000458A patent/HUP0000458A3/hu unknown
- 1997-11-05 ZA ZA979948A patent/ZA979948B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
WO1998019798A3 (en) | 1998-08-06 |
HUP0000458A3 (en) | 2003-07-28 |
DE69714080T2 (de) | 2003-03-20 |
ZA979948B (en) | 1998-11-05 |
AU724454B2 (en) | 2000-09-21 |
EA199900444A1 (ru) | 1999-12-29 |
PL333326A1 (en) | 1999-12-06 |
BR9712744A (pt) | 1999-12-21 |
CN1239908A (zh) | 1999-12-29 |
EP0959990B1 (de) | 2002-07-17 |
WO1998019798A2 (en) | 1998-05-14 |
HUP0000458A2 (hu) | 2000-06-28 |
DE69714080D1 (de) | 2002-08-22 |
JP2001504146A (ja) | 2001-03-27 |
EP0959990A2 (de) | 1999-12-01 |
JP3993244B2 (ja) | 2007-10-17 |
KR20000053055A (ko) | 2000-08-25 |
IL129673A0 (en) | 2000-02-29 |
CA2270879C (en) | 2007-03-13 |
NZ335605A (en) | 2000-04-28 |
US5759629A (en) | 1998-06-02 |
CN1072531C (zh) | 2001-10-10 |
TW422894B (en) | 2001-02-21 |
ATE220576T1 (de) | 2002-08-15 |
TR199901538T2 (xx) | 1999-09-21 |
CA2270879A1 (en) | 1998-05-14 |
AU5479198A (en) | 1998-05-29 |
ES2180074T3 (es) | 2003-02-01 |
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