CN1977417B - 含有低聚醚硫酸盐的离子导电材料 - Google Patents
含有低聚醚硫酸盐的离子导电材料 Download PDFInfo
- Publication number
- CN1977417B CN1977417B CN2005800215854A CN200580021585A CN1977417B CN 1977417 B CN1977417 B CN 1977417B CN 2005800215854 A CN2005800215854 A CN 2005800215854A CN 200580021585 A CN200580021585 A CN 200580021585A CN 1977417 B CN1977417 B CN 1977417B
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- Prior art keywords
- conductive material
- ion conductive
- material according
- oligo
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000004020 conductor Substances 0.000 title claims abstract description 34
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title claims abstract description 10
- 229910021653 sulphate ion Inorganic materials 0.000 title abstract 4
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 claims abstract description 45
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229920000642 polymer Polymers 0.000 claims abstract description 30
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 150000008040 ionic compounds Chemical class 0.000 claims abstract description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 13
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 39
- 150000002500 ions Chemical class 0.000 claims description 33
- 239000010408 film Substances 0.000 claims description 26
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 22
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 15
- 239000003792 electrolyte Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 239000005518 polymer electrolyte Substances 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
- 210000000031 electric organ Anatomy 0.000 claims description 8
- 229920001519 homopolymer Polymers 0.000 claims description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims description 8
- 159000000002 lithium salts Chemical class 0.000 claims description 8
- 150000002641 lithium Chemical group 0.000 claims description 7
- BQODPTQLXVVEJG-UHFFFAOYSA-N [O].C=C Chemical compound [O].C=C BQODPTQLXVVEJG-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 239000012766 organic filler Substances 0.000 claims description 3
- 150000004862 dioxolanes Chemical class 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 229940075933 dithionate Drugs 0.000 claims 1
- 229920001451 polypropylene glycol Polymers 0.000 claims 1
- 229910003870 O—Li Inorganic materials 0.000 abstract 1
- VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical class OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 abstract 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 21
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 14
- 239000002202 Polyethylene glycol Substances 0.000 description 14
- 150000001768 cations Chemical class 0.000 description 14
- 229920001223 polyethylene glycol Polymers 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910052786 argon Inorganic materials 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 230000000875 corresponding effect Effects 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 5
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
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- 239000007788 liquid Substances 0.000 description 4
- 210000003739 neck Anatomy 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007872 degassing Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229920000554 ionomer Polymers 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
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- 238000001704 evaporation Methods 0.000 description 2
- 238000002270 exclusion chromatography Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 150000002466 imines Chemical class 0.000 description 2
- 238000001453 impedance spectrum Methods 0.000 description 2
- 229940006487 lithium cation Drugs 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- -1 perfluoromethanesulfonyl Chemical group 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000007614 solvation Methods 0.000 description 2
- 238000000935 solvent evaporation Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N trifluoromethane acid Natural products FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
- 238000000970 chrono-amperometry Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 description 1
- 238000005822 methylenation reaction Methods 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/166—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solute
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/188—Processes of manufacture
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
- G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
- G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Secondary Cells (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Polyethers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
样品 | MPEGx(mol) | MPEGM(g/mol) | HCISO<sub>3</sub>Hv(cm<sup>3</sup>) | POEMSn |
POEMS120 | 0.17 | 120 | 11.6 | 2 |
POEMS164 | 0.12 | 164 | 8.5 | 3 |
POEMS350 | 0.057 | 350 | 4 | 7.2 |
POEMS550 | 0.0364 | 550 | 2.5 | 11.8 |
样品 | MPEGx(mol) | MPEGM(g/mol) | HCISO<sub>3</sub>Hv(cm<sup>3</sup>) | POEMSn |
POEMS750 | 0.266 | 750 | 1.9 | 16.3 |
聚合物 | M理论 | Mw(PEG当量) | Mn(PEG当量) | I | ΔM理论 | ΔM测量 | t(min) |
MPEG | 164 | 129 | 112 | 1.16 | 22.6 | ||
POEMS 164 | 250.2 | 282 | 254 | 1.11 | 86.2 | 153 | 19.4 |
MPEG | 350 | 357 | 346 | 1.03 | 19.2 | ||
POEMS350 | 436.2 | 408 | 373 | 1.09 | 86.2 | 51 | 17.8 |
MPEG | 550 | 530 | 439 | 1.21 | 17.4 | ||
POEMS550 | 636.2 | 533 | 463 | 1.15 | 86.2 | 3 | 16.6 |
MPEG | 750 | 637 | 566 | 1.13 | 17.0 | ||
POEMS750 | 836.2 | 683 | 551 | 1.24 | 86.2 | 46 | 16.3 |
样品 | Tg(℃) | Tm(℃) | ΔH<sub>f</sub>(J/g) | 在80℃下的σ(S/cm) |
POEMS164 | -31 | 57 | 62 | 4×10<sup>-5</sup> |
POEMS350 | -48 | 9×10<sup>-5</sup> |
样品 | Tg(℃) | Tm(℃) | ΔH<sub>f</sub>(J/g) | 在80℃下的σ(S/cm) |
POEMS550 | -59 | 34 | 100 | 9×10<sup>-5</sup> |
POEMS750 | -60 | 40 | 120 | 9×10<sup>-5</sup> |
样品 | PEGx’(mol) | PEGM’(g/mol) | HCISO<sub>3</sub>Hv’(cm<sup>3</sup>) | POEDSn |
POEDS200 | 0.2 | 200 | 14 | 3.1 |
POEDS400 | 0.05 | 400 | 3.5 | 7.7 |
POEDS600 | 0.088 | 600 | 5.8 | 12.2 |
POEDS1000 | 0.03 | 1000 | 2.1 | 21.4 |
POEDS2000 | 0.01 | 2000 | 0.7 | 44 |
样品 | Tg(℃) | Tm(℃) | ΔH<sub>f</sub>(J/g) | 在80℃的σ(S/cm) |
POEDS200 | -24 | 27 | 1.2 | |
POEDS400 | -26 | 25 | 44 | 3.0×10<sup>-6</sup> |
POEDS600 | -41 | 25 | 21 | 8.0×10<sup>-6</sup> |
POEDS1000 | -58 | 42 | 85 | 1×10<sup>-4</sup> |
POEDS2000 | -53 | 50 | 120 | 5.0×10<sup>-5</sup> |
薄膜 | LiTFSIy(mg) | 低聚醚(性质) | 低聚醚z(mg) | O<sub>t</sub>/Li<sub>TFSI</sub> | O<sub>t</sub>/Li<sub>P</sub>OEMS | O<sub>t</sub>/Li<sub>t</sub> | 在70℃下的t<sup>+</sup> |
164a | 130.5 | POEMS164 | 126.4 | 33.3 | 30 | 15.2 | 0.21 |
164b | 130.5 | POEMS164 | 92.21 | 32.4 | 40 | 17.9 | 0.27 |
164c | 130.5 | POEMS164 | 72.59 | 31.9 | 50 | 19.5 | 0.30 |
164d | 130.5 | POEMS164 | 59.86 | 31.6 | 60 | 20.7 | 0.20 |
164e | 65.23 | POEMS164 | 126.4 | 66.7 | 30 | 20.7 | 0.21 |
164f | 65.23 | POEMS164 | 92.21 | 64.9 | 40 | 24.7 | 0.25 |
薄膜 | LiTFSIy(mg) | 低聚醚(性质) | 低聚醚z(mg) | O<sub>t</sub>/Li<sub>TFSI</sub> | O<sub>t</sub>/Li<sub>P</sub>OEMS | O<sub>t</sub>/Li<sub>t</sub> | 在70℃下的t<sup>+</sup> |
164g | 65.23 | POEMS164 | 72.59 | 63.8 | 50 | 28 | 0.23 |
164h | 65.23 | POEMS164 | 59.86 | 63.2 | 60 | 30.8 | 0.21 |
164i | 65.23 | POEMS164 | 126.4 | 100 | 30 | 23.1 | 0.27 |
164j | 43.48 | POEMS164 | 92.21 | 97.3 | 40 | 28.3 | 0.30 |
164k | 43.48 | POEMS164 | 72.59 | 95.8 | 50 | 32.8 | 0.26 |
164l | 43.48 | POEMS164 | 59.86 | 94.7 | 60 | 36.7 | 0.27 |
350a | 130.5 | POEMS350 | 261.12 | 39.5 | 30 | 17.1 | 0.24 |
350b | 130.5 | POEMS350 | 181.5 | 36.6 | 40 | 19.1 | 0.24 |
350c | 65.23 | POEMS350 | 261.12 | 79 | 30 | 21.7 | 0.30 |
350d | 65.23 | POEMS350 | 181.5 | 73.2 | 40 | 25.9 | 0.27 |
350e | 43.48 | POEMS350 | 261.12 | 118.6 | 30 | 23.9 | 0.30 |
350f | 43.48 | POEMS350 | 181.5 | 109.9 | 40 | 29.3 | 0.27 |
550a | 130.5 | POEMS550 | 476.0 | 49.4 | 30 | 18.7 | 0.25 |
550b | 130.5 | POEMS550 | 307.3 | 42.5 | 40 | 20.6 | 0.28 |
550c | 65.23 | POEMS550 | 476.0 | 98.7 | 30 | 23 | 0.26 |
550d | 65.23 | POEMS550 | 307.3 | 85 | 40 | 27.2 | 0.29 |
550e | 43.48 | POEMS550 | 476.0 | 148.1 | 30 | 24.9 | 0.33 |
550f | 43.48 | POEMS550 | 307.3 | 127.6 | 40 | 30.5 | 0.32 |
750a | 130.5 | POEMS750 | 833.4 | 65.8 | 30 | 20.6 | 0.27 |
薄膜 | LiTFSIy(mg) | 低聚醚(性质) | 低聚醚z(mg) | O<sub>t</sub>/Li<sub>TFSI</sub> | O<sub>t</sub>/Li<sub>P</sub>OEMS | O<sub>t</sub>/Li<sub>t</sub> | 在70℃下的t<sup>+</sup> |
750b | 130.5 | POEMS 750 | 481.5 | 50.7 | 40 | 22.4 | 0.29 |
750c | 65.23 | POEMS750 | 833.4 | 131.6 | 30 | 24.4 | 0.31 |
750d | 65.23 | POEMS750 | 481.5 | 101.3 | 40 | 28.7 | 0.31 |
20TFS | 197.7 | - | 20 | 0.13 | |||
30TFS | 130.5 | - | 30 | 0.13 | |||
40TFS | 97.84 | - | 40 | 0.14 |
薄膜 | LiTFSIy(mg) | 低聚醚(性质) | 低聚醚z(mg) | O<sub>t</sub>/Li<sub>TFSI</sub> | O<sub>t</sub>/Li<sub>P</sub>OEMS | O<sub>t</sub>/Li<sub>t</sub> | 在70℃下的t<sup>+</sup> |
200a | 130.5 | POEDS200 | 89.30 | 31.7 | 30 | 15.4 | 0.21 |
200b | 130.5 | POEDS200 | 66.07 | 31.2 | 40 | 17.5 | 0.26 |
200d | 65.23 | POEDS200 | 66.07 | 62.4 | 40 | 24.4 | 0.22 |
薄膜 | LiTFSIy(mg) | 低聚醚(性质) | 低聚醚z(mg) | O<sub>t</sub>/Li<sub>TFSI</sub> | O<sub>t</sub>/Li<sub>P</sub>OEMS | O<sub>t</sub>/Li<sub>t</sub> | 在70℃下的t<sup>+</sup> |
400b | 130.5 | POEDS400 | 107.9 | 33.2 | 40 | 18.1 | 0.21 |
400c | 65.23 | POEDS400 | 149.2 | 68.8 | 30 | 20.9 | 0.24 |
400d | 65.23 | POEDS400 | 107.9 | 66.4 | 40 | 25 | 0.28 |
600a | 130.5 | POEDS600 | 220.5 | 37.7 | 30 | 16.7 | 0.20 |
600b | 130.5 | POEDS600 | 155.4 | 35.4 | 40 | 18.8 | 0.22 |
600d | 65.23 | POEDS600 | 155.4 | 70.8 | 40 | 25.6 | 0.24 |
1000e | 43.48 | POEDS1000 | 413.3 | 139.6 | 30 | 24.7 | 0.28 |
1000f | 43.48 | POEDS1000 | 155.4 | 122.7 | 40 | 30.2 | 0.31 |
2000b | 130.5 | POEDS2000 | 823.9 | 66.8 | 40 | 25 | 0.25 |
2000d | 65.23 | POEDS2000 | 823.9 | 133.5 | 40 | 30.8 | 0.26 |
20TFS | 195.7 | 20 | 0.13 | ||||
30TFS | 130.5 | - | 30 | 0.13 | |||
40TFS | 97.84 | - | 40 | 0.14 |
Claims (17)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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FR0407061 | 2004-06-28 | ||
FR0407061A FR2872349B1 (fr) | 2004-06-28 | 2004-06-28 | Materiau a conduction ionique contenant un oligoether sulfate |
PCT/FR2005/001623 WO2006010843A1 (fr) | 2004-06-28 | 2005-06-27 | Materiau a conduction ionique contenant un oligoether sulfate |
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CN1977417A CN1977417A (zh) | 2007-06-06 |
CN1977417B true CN1977417B (zh) | 2010-06-02 |
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CN2005800215854A Expired - Fee Related CN1977417B (zh) | 2004-06-28 | 2005-06-27 | 含有低聚醚硫酸盐的离子导电材料 |
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US (1) | US7960060B2 (zh) |
EP (1) | EP1790030B1 (zh) |
JP (1) | JP5208503B2 (zh) |
KR (1) | KR101222093B1 (zh) |
CN (1) | CN1977417B (zh) |
AT (1) | ATE424045T1 (zh) |
CA (1) | CA2571208C (zh) |
DE (1) | DE602005012970D1 (zh) |
ES (1) | ES2321317T3 (zh) |
FR (1) | FR2872349B1 (zh) |
HK (1) | HK1103576A1 (zh) |
WO (1) | WO2006010843A1 (zh) |
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US10211461B2 (en) * | 2014-04-02 | 2019-02-19 | Zeon Corporation | Binder composition for secondary battery electrode-use, slurry composition for secondary battery electrode-use, electrode for secondary battery-use, and secondary battery |
CN106459392A (zh) * | 2014-06-04 | 2017-02-22 | 陶氏环球技术有限责任公司 | 固体聚合物电解质和用于其的化合物 |
EP3151327B1 (en) * | 2014-07-16 | 2019-05-08 | Daikin Industries, Ltd. | Electrolyte solution |
CN109428112B (zh) * | 2017-08-23 | 2020-12-18 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其电解液 |
CN109428119B (zh) * | 2017-08-23 | 2020-12-22 | 宁德时代新能源科技股份有限公司 | 锂离子电池及其非水电解液 |
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WO2003075373A2 (en) * | 2002-02-28 | 2003-09-12 | The Gillette Company | Non-aqueous electrochemical cell |
WO2004001877A2 (en) * | 2002-06-21 | 2003-12-31 | The Regents Of The University Of California | Electrolytes for electrooptic devices comprising ionic liquids |
CN1497765A (zh) * | 2002-10-23 | 2004-05-19 | 松下电器产业株式会社 | 非水电解质二次电池及该电池中使用的电解质 |
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US5196484A (en) * | 1986-10-27 | 1993-03-23 | The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland | Polymeric ion conductors |
FR2713646B1 (fr) * | 1993-12-09 | 1996-02-23 | Centre Nat Rech Scient | Procédé de préparation d'un terpolymère du type poly(oxyalkylène) par hydrogénation. |
FR2742437B1 (fr) * | 1995-12-14 | 1998-01-09 | Electricite De France | Bis(phenylsulfonyl)imidures, leur procede de preparation et materiaux a conduction ionique les comprenant |
DE69829955T2 (de) * | 1997-12-01 | 2006-03-02 | Acep Inc., Montreal | Salze von perfluorierten sulfonen und ihre verwendung als ionisch leitfähige materialien |
JP2003040885A (ja) | 2001-07-27 | 2003-02-13 | Toyota Motor Corp | グリセリンジカーボネート誘導体、それを用いた非水電解液、高分子電解質および電池 |
FR2866154B1 (fr) * | 2004-02-10 | 2014-02-21 | Batscap Sa | Procede d'elaboration d'un dispositif electrochimique. |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2003075373A2 (en) * | 2002-02-28 | 2003-09-12 | The Gillette Company | Non-aqueous electrochemical cell |
WO2004001877A2 (en) * | 2002-06-21 | 2003-12-31 | The Regents Of The University Of California | Electrolytes for electrooptic devices comprising ionic liquids |
CN1497765A (zh) * | 2002-10-23 | 2004-05-19 | 松下电器产业株式会社 | 非水电解质二次电池及该电池中使用的电解质 |
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KR20070039085A (ko) | 2007-04-11 |
US7960060B2 (en) | 2011-06-14 |
CN1977417A (zh) | 2007-06-06 |
HK1103576A1 (en) | 2007-12-21 |
KR101222093B1 (ko) | 2013-01-14 |
DE602005012970D1 (de) | 2009-04-09 |
FR2872349A1 (fr) | 2005-12-30 |
ES2321317T3 (es) | 2009-06-04 |
US20070190428A1 (en) | 2007-08-16 |
FR2872349B1 (fr) | 2006-10-06 |
EP1790030A1 (fr) | 2007-05-30 |
WO2006010843A1 (fr) | 2006-02-02 |
JP2008504661A (ja) | 2008-02-14 |
CA2571208A1 (fr) | 2006-02-02 |
CA2571208C (fr) | 2012-12-18 |
JP5208503B2 (ja) | 2013-06-12 |
ATE424045T1 (de) | 2009-03-15 |
EP1790030B1 (fr) | 2009-02-25 |
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