CN1858142B - Environment-friendly adhesive without triphenyl - Google Patents
Environment-friendly adhesive without triphenyl Download PDFInfo
- Publication number
- CN1858142B CN1858142B CN2006100358623A CN200610035862A CN1858142B CN 1858142 B CN1858142 B CN 1858142B CN 2006100358623 A CN2006100358623 A CN 2006100358623A CN 200610035862 A CN200610035862 A CN 200610035862A CN 1858142 B CN1858142 B CN 1858142B
- Authority
- CN
- China
- Prior art keywords
- friendly adhesive
- environment
- triphenyl
- adhesive
- rosin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 11
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 title abstract 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 239000000806 elastomer Substances 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- CXHHBNMLPJOKQD-UHFFFAOYSA-M methyl carbonate Chemical compound COC([O-])=O CXHHBNMLPJOKQD-UHFFFAOYSA-M 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- 244000043261 Hevea brasiliensis Species 0.000 abstract 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 abstract 1
- 229920003052 natural elastomer Polymers 0.000 abstract 1
- 229920001194 natural rubber Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a production formula of a non-triphenyl environment-friendly adhesive (namely yellow paste), which is characterized by comprising the following components in percentage by weight, 10-30% of dimethyl carbonate, 10-25% of butanone, 1-15% of acetone, 1-15% of ethyl acetate, 10-15% of 3L natural rubber and 10-20% of rosin. The invention has the advantages of practicality, good effect, environmental protection compliance and the like.
Description
Technical field
The present invention relates to a kind of tackiness agent.
Background technology
Tackiness agent uses quite extensive in life, like footwear, tire etc.Existing tackiness agent mainly adopts X 050, tackifying resin etc. to process solvent; Be used for the tackiness agent (being tackiness agent (promptly yellow the paste)) in the shoemaking; As application number be 88105902, the applying date is that May 18, denomination of invention in 1988 are multifunctional adhesive for shoes, the patented claim in open/December 6 1989 day for announcing; It is that graft reaction mixture with vinyl acetate and TEB 3K and X 050 is a base-material, cooperates specific tackifying resin to process.The formula constituent of this tackiness agent (by weight) is: the graft reaction mixture that adhesive purpose chloroprene rubber and vinyl acetate and TEB 3K generate; 100 parts of tackifying resins; 3-10 parts of optimum formula components are: the graft reaction mixture that adhesive purpose chloroprene rubber and vinyl acetate and TEB 3K generate; 100 parts of tackifying resins, 4-6 parts.And existing oil price is constantly soaring, and the raw materials cost of producing organic solvent also increases much, and very strong moment corrodibility is much arranged, and also has pollution hidden trouble.
Summary of the invention
The objective of the invention is in order to solve above-mentioned deficiency, and a kind of environmental protection that has is provided, the environment friendly adhesive without tribenzene that bonding force is strong.
The technical solution that the present invention adopts in order to reach above-mentioned effect is following:
The production formula of this environment friendly adhesive without tribenzene (promptly yellow the paste); It is characterized in that; It constitutes (weight ratio) by following set of dispense ratio, methylcarbonate 10-30%, butanone 10-25%, acetone 1-15%, vinyl acetic monomer 1-15%, 3L tree elastomer 10-15%, rosin 10-20%.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The solvent body that product of the present invention uses belongs to real no triphen environmental protection system, and use range is wide, uses tree elastomer and natural rosin resins, and production cost is low, and excellent generalization values is arranged.
Embodiment
This environment friendly adhesive without tribenzene (promptly yellow the paste) constitutes (weight ratio) by following set of dispense ratio, methylcarbonate-30%, butanone-20%, acetone-15%, vinyl acetic monomer-15%, 3L tree elastomer-12%, rosin-18%.
Of the present invention dose is to use tree elastomer to replace general X 050; Use natural rosin resins to prepare the tackiness agent (promptly yellow the paste) that is mainly used in shoemaking, solved a difficult problem because of the high production organic solvent adhesive starting material aspect in short supply that causes of crude oil price as tackifying resin.
Product of the present invention often by the footwear industry be used for EVA/EVA, the end, foam compound, climb group etc., probably about 4500cps/30 ℃, solid content is near 30% for viscosity.
Product of the present invention is having difference in essence with traditions of the past product cryogenic vulcanization tyre patching rubber material, glue for repairing tyre etc. aspect the collocation of organic solvent and the environment protection, and the scope of application is more extensive.
Claims (1)
1. an environment friendly adhesive without tribenzene is characterized in that, it is made up of by weight proportioning following component: methylcarbonate 10-30%, butanone 10-25%, acetone 1-15%, vinyl acetic monomer 1-15%, 3L tree elastomer 10-15%, rosin 10-20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100358623A CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100358623A CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1858142A CN1858142A (en) | 2006-11-08 |
| CN1858142B true CN1858142B (en) | 2012-04-25 |
Family
ID=37297100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100358623A Expired - Fee Related CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1858142B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850975B (en) * | 2012-09-28 | 2015-02-18 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5626932A (en) * | 1994-09-08 | 1997-05-06 | Beiersdorf Aktiengesellschaft | Adhesive film strip |
| CN1427057A (en) * | 2002-09-05 | 2003-07-02 | 株洲硬质合金集团有限公司 | Preparation method of adhesive |
-
2006
- 2006-06-09 CN CN2006100358623A patent/CN1858142B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5626932A (en) * | 1994-09-08 | 1997-05-06 | Beiersdorf Aktiengesellschaft | Adhesive film strip |
| CN1427057A (en) * | 2002-09-05 | 2003-07-02 | 株洲硬质合金集团有限公司 | Preparation method of adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1858142A (en) | 2006-11-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171010 Address after: 528139 Guangdong province Foshan Sanshui Lubao Town Industrial Development Zone (duozheng chemical adhesive resin Research Institute) Patentee after: Guangdong multi Resin Technology Co., Ltd. Address before: 528139 Guangdong province Foshan Sanshui Lubao Industrial Development Zone multi way Patentee before: Duozheng Chemical Science and Technology Co., Ltd., Guangdong |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120425 Termination date: 20180609 |