CN1858142A - Environment friendly adhesive without tribenzene - Google Patents
Environment friendly adhesive without tribenzene Download PDFInfo
- Publication number
- CN1858142A CN1858142A CN 200610035862 CN200610035862A CN1858142A CN 1858142 A CN1858142 A CN 1858142A CN 200610035862 CN200610035862 CN 200610035862 CN 200610035862 A CN200610035862 A CN 200610035862A CN 1858142 A CN1858142 A CN 1858142A
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- tribenzene
- environment friendly
- friendly adhesive
- adhesive
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Abstract
The present invention discloses the recipe of no-benzene environment friendly adhesive. The adhesive consists of dimethyl carbonate 10-30 wt%, butanone 10-25 wt%, acetaone 1-15 wt%, ethyl acetate 1-15 wt%, 3L natural rubber 10- 15 wt%, and rosin 10-20 wt% The present invention has good use effect, environment friendship and other advantages.
Description
Technical field
The present invention relates to a kind of tackiness agent.
Background technology
Tackiness agent uses quite extensive in life, as footwear, tire etc.Existing tackiness agent mainly adopts chloroprene rubber, tackifying resin etc. to make solvent, be used for the tackiness agent (being tackiness agent (promptly yellow the paste)) in the shoemaking, as application number be 88105902, the applying date is that May 18, denomination of invention in 1988 are multifunctional adhesive for shoes, the patent application in open/December 6 1989 day for announcing, it is that graft reaction mixture with vinyl acetate and methyl methacrylate and chloroprene rubber is a base-material, cooperates specific tackifying resin to make.The formula constituent of this tackiness agent (by weight) is: the graft reaction mixture that adhesive purpose chloroprene rubber and vinyl acetate and methyl methacrylate generate, 100 parts of tackifying resins, 3-10 part optimum formula component is: the graft reaction mixture that adhesive purpose chloroprene rubber and vinyl acetate and methyl methacrylate generate, 100 parts of tackifying resins, 4-6 part.And existing oil price is constantly soaring, and the raw materials cost of producing organic solvent also increases much, and very strong moment corrodibility is much arranged, and also has pollution hidden trouble.
Summary of the invention
The objective of the invention is in order to solve above-mentioned deficiency, and provide a kind of environmental protection that has, the environment friendly adhesive without tribenzene that bonding force is strong.
The technical solution that the present invention adopts in order to reach above-mentioned effect is as follows:
The production formula of this environment friendly adhesive without tribenzene (promptly yellow the paste), it is characterized in that, it constitutes (weight ratio) by following set of dispense ratio, methylcarbonate 10-30%, butanone 10-25%, acetone 1-15%, vinyl acetic monomer 1-15%, 3L natural rubber 10-15%, rosin 10-20%.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The solvent body that product of the present invention uses belongs to real no triphen environmental protection system, and use range is wide, uses natural rubber and natural rosin resins, and production cost is low, and excellent generalization values is arranged.
Embodiment
This environment friendly adhesive without tribenzene (promptly yellow the paste) constitutes (weight ratio) by following set of dispense ratio, methylcarbonate-30%, butanone-2 0%, acetone-15%, vinyl acetic monomer-15%, 3L natural rubber-12%, rosin-18%.
Of the present invention dose is to use natural rubber to replace general chloroprene rubber, use natural rosin resins to prepare the tackiness agent (promptly yellow the paste) that is mainly used in shoemaking, solved a difficult problem because of the high production organic solvent adhesive starting material aspect in short supply that causes of crude oil price as tackifying resin.
Product of the present invention often by the footwear industry be used for EVA/EVA, the end, foam compound, climb group etc., probably about 4500cps/30 ℃, solid content is near 30% for viscosity.
Product of the present invention is having in essence difference with traditions of the past product cryogenic vulcanization tyre patching rubber material, glue for repairing tyre etc. aspect the collocation of organic solvent and the environment protection, and the scope of application is more extensive.
Claims (1)
1, a kind of environment friendly adhesive without tribenzene is characterized in that, it is made of following set of dispense ratio, methylcarbonate 10-30%, butanone 10-25%, acetone 1-15%, vinyl acetic monomer 1-15%, 3L natural rubber 10-15%, rosin 10-20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100358623A CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100358623A CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1858142A true CN1858142A (en) | 2006-11-08 |
| CN1858142B CN1858142B (en) | 2012-04-25 |
Family
ID=37297100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100358623A Expired - Fee Related CN1858142B (en) | 2006-06-09 | 2006-06-09 | Environment-friendly adhesive without triphenyl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1858142B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850975A (en) * | 2012-09-28 | 2013-01-02 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4431914C2 (en) * | 1994-09-08 | 1996-10-17 | Beiersdorf Ag | Strip of an adhesive film for a residue-free, removable adhesive and its use |
| CN1232605C (en) * | 2002-09-05 | 2005-12-21 | 株洲硬质合金集团有限公司 | Preparation method of adhesive |
-
2006
- 2006-06-09 CN CN2006100358623A patent/CN1858142B/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850975A (en) * | 2012-09-28 | 2013-01-02 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
| CN102850975B (en) * | 2012-09-28 | 2015-02-18 | 广东多正化工科技有限公司 | Aliphatic carbonate modified multivariant copolymerization grafted neoprene adhesive and preparation method of neoprene adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1858142B (en) | 2012-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171010 Address after: 528139 Guangdong province Foshan Sanshui Lubao Town Industrial Development Zone (duozheng chemical adhesive resin Research Institute) Patentee after: Guangdong multi Resin Technology Co., Ltd. Address before: 528139 Guangdong province Foshan Sanshui Lubao Industrial Development Zone multi way Patentee before: Duozheng Chemical Science and Technology Co., Ltd., Guangdong |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120425 Termination date: 20180609 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |