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CN102295912A - Multifunctional spray glue formula and process - Google Patents

Multifunctional spray glue formula and process Download PDF

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Publication number
CN102295912A
CN102295912A CN2010102117045A CN201010211704A CN102295912A CN 102295912 A CN102295912 A CN 102295912A CN 2010102117045 A CN2010102117045 A CN 2010102117045A CN 201010211704 A CN201010211704 A CN 201010211704A CN 102295912 A CN102295912 A CN 102295912A
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China
Prior art keywords
resin
rubber
few
percent
spray glue
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Granted
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CN2010102117045A
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Chinese (zh)
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CN102295912B (en
Inventor
吕大洋
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DONGGUAN DAYANG CHEMICAL TECHNOLOGY Co.,Ltd.
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DONGGUAN DAYANG CHEMICAL CO LTD
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Priority to CN 201010211704 priority Critical patent/CN102295912B/en
Publication of CN102295912A publication Critical patent/CN102295912A/en
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Abstract

The invention relates to the technical field of chemical detergents, in particular to a multifunctional spray glue formula and process. The spray glue formula comprises the following components in percentage by weight: 1-12 percent of rubber, 1.0-15 percent of synthetic resin, 10-40 percent of tackifying resin, 10-60 percent of hydrocarbon solvent, 30-75 percent of propellent, 10-40 percent of chlorine solvent, 3-30 percent of cosolvent, 2-8 percent of plasticizer and 0.05-1 percent of essence. The spray glue is prepared by the following steps of: adding the hydrocarbon solvent, the chlorine solvent and a part of cosolvent such as acetone and the like into a stirring kettle according to formula metering, opening and stirring; adding rubber such as SBS (Styrene-Butadiene-Styrene) thermoplastic elastomer and the like and synthetic resin such as acrylate resin and the like in a stirring state and stirring until the rubber and the synthetic resin are fully dissolved; adding the tackifying resin such as rosin and the like and stirring until the rosin is fully dissolved; adding remaining cosolvent such as the acetone and the like and the plasticizer and stirring until glue liquid is fully dispersed; and filtering and canning, sealing, and inflating a can. The spray glue formula has the advantages of no toxin, no pollution, super-strong viscosity and adaptation to gluing of various materials, and is white and non-yellowing.

Description

Multi-functional spray glue prescription and technology
Technical field:
The present invention relates to chemical industry spray glue technical field, refer in particular to multi-functional spray glue prescription and technology.
Background technology:
Present solvent-borne type spray glue, all different ratios contain the carcinogenic toxicity solvent, the tackiness agent that can not be used as the clothes cloth uses; Simultaneously, be fit to the stickup of single material, bonding effect is also undesirable, easily oxidation and flavescence.
Summary of the invention:
The objective of the invention is at the deficiencies in the prior art, and multi-functional spray glue prescription and technology are provided, its no toxin, pollution-free, superstrong adhesive is fit to the stickup of various material, and colloid is a white, anti-xanthochromia.
For achieving the above object, the present invention adopts following technical scheme, it comprises rubber, synthetic resins, tackifying resin, varsol, propellent, it is characterized in that: the weight percent that its content accounts for total formulation material is respectively: rubber is 1%~12%, synthetic resins is 1.0%~15%, tackifying resin is 10%~40%, and varsol is 10%~60%, and propellent is 30%~75%.
Described prescription also is added with chlorine kind solvent, solubility promoter, softening agent, essence, and the weight percent that its content accounts for total formulation material is respectively: chlorine kind solvent 10%~40%, solubility promoter are 3%~30%, and softening agent is 2%~8%, and essence is 0.5 ‰~10 ‰.
Described rubber is that any one or a few is used in SBS thermoplastic elastomer, SIS thermoplastic elastomer, SEBS thermoplastic elastomer, styrene-butadiene rubber(SBR), chloroprene rubber, polyisobutene, the chlorosulfonated polyethylene; Synthetic resins is that any one or a few is used in acrylate resin, polyamide resin, vibrin, urethane resin, vinyl chloride-vinyl acetate resin, ethylene-vinyl acetate copolymer resins, the ethylene-acrylate copolymer resins; Tackifying resin is that any one or a few is used in rosin, polymerized rosin, ester gum, pentalyn, petroleum resin, the terpine resin; Varsol is that any one or a few is used in normal hexane, hexanaphthene, 6# white spirit, the 120# white spirit; Propellent is that any one or a few is used in liquefied petroleum gas (LPG) (LPG), the dme (DME); The chlorine kind solvent is that any one or a few is used in methylene dichloride, ethylene dichloride, trichloroethane, the trichloropropane; Solubility promoter is that any one or a few is used in acetone, butanone, methyl alcohol, the dehydrated alcohol; Softening agent is that any one or a few is used in white mineral oil, clorafin, Viscotrol C, epoxy soybean oil, the dioctyl phthalate (DOP) etc.
Multi-functional spray glue prescription, the processing method step of making spray glue is:
(1), solubility promoters such as varsol, chlorine kind solvent and part acetone are added stirring tank, open stirring by prescription metering;
(2), the restir state adds down synthetic resins such as rubber such as SBS thermoplastic elastomer and acrylate resin, being stirred to rubber and synthetic resins dissolves fully;
(3), then add tackifying resins such as rosin, after being stirred to rosin and dissolving fully;
(4), again add solubility promoter and softening agent such as residue acetone, being stirred to glue disperses fully;
(5), filter laggard luggage jar, after sealing, toward carrying out the jar inflation.
Beneficial effect of the present invention is: rubber is 1%~12%, synthetic resins is 1.0%~15%, tackifying resin is 10%~40%, varsol is 10%~60%, propellent is 30%~75%, also be added with the chlorine kind solvent, solubility promoter, softening agent, essence, the weight percent that its content accounts for total formulation material is respectively: chlorine kind solvent 10%~40%, solubility promoter is 3%~30%, and softening agent is 2%~8%, and essence is 0.5 ‰~10 ‰, its superstrong adhesive: be fit to the stickup of various material, colloid is a white, anti-xanthochromia, and the material that is specially adapted to the glue color is had relatively high expectations is pasted, as white paper, the stickup of cloth etc., environment-protecting asepsis does not contain formaldehyde, fluorine Lyons, aromatic hydrocarbons.
Embodiment:
The present invention adopts following technical scheme, it comprises rubber, synthetic resins, tackifying resin, varsol, propellent, it is characterized in that: the weight percent that its content accounts for total formulation material is respectively: rubber is 1%~12%, synthetic resins is 1.0%~15%, tackifying resin is 10%~40%, varsol is 10%~60%, and propellent is 30%~75%.
Described prescription also is added with chlorine kind solvent, solubility promoter, softening agent, essence, and the weight percent that its content accounts for total formulation material is respectively: chlorine kind solvent 10%~40%, solubility promoter are 3%~30%, and softening agent is 2%~8%, and essence is 0.5 ‰~10 ‰.
Described rubber is that any one or a few is used in SBS thermoplastic elastomer, SIS thermoplastic elastomer, SEBS thermoplastic elastomer, styrene-butadiene rubber(SBR), chloroprene rubber, polyisobutene, the chlorosulfonated polyethylene; Synthetic resins is that any one or a few is used in acrylate resin, polyamide resin, vibrin, urethane resin, vinyl chloride-vinyl acetate resin, ethylene-vinyl acetate copolymer resins, the ethylene-acrylate copolymer resins; Tackifying resin is that any one or a few is used in rosin, polymerized rosin, ester gum, pentalyn, petroleum resin, the terpine resin; Varsol is that any one or a few is used in normal hexane, hexanaphthene, 6# white spirit, the 120# white spirit; Propellent is that any one or a few is used in liquefied petroleum gas (LPG) (LPG), the dme (DME); The chlorine kind solvent is that any one or a few is used in methylene dichloride, ethylene dichloride, trichloroethane, the trichloropropane; Solubility promoter is that any one or a few is used in acetone, butanone, methyl alcohol, the dehydrated alcohol; Softening agent is that any one or a few is used in white mineral oil, clorafin, Viscotrol C, epoxy soybean oil, the dioctyl phthalate (DOP) etc.
Multi-functional spray glue prescription, the processing method step of making spray glue is:
(1), solubility promoters such as varsol, chlorine kind solvent and part acetone are added stirring tank, open stirring by prescription metering;
(2), the restir state adds down synthetic resins such as rubber such as SBS thermoplastic elastomer and acrylate resin, being stirred to rubber and synthetic resins dissolves fully;
(3), then add tackifying resins such as rosin, after being stirred to rosin and dissolving fully;
(4), again add solubility promoter and softening agent such as residue acetone, being stirred to glue disperses fully;
(5), filter laggard luggage jar, after sealing, toward carrying out the jar inflation.
Viscosity of the present invention is superpower, simple operation, the colloid look is widely used in multiple industry in vain, as upholstery, and computer embroidery (children's garment. underwear, nylon cloth or other are difficult to paste cloth), advertisement, packing is applicable to paper, tinsel, cloth, paperboard, quiver goods cork glued membrane, foamed glue, glass fibre and polystyrene, above material can be bonded at dress material. on the materials such as metal, timber, glass.
Performance characteristics of the present invention: superstrong adhesive: be fit to the stickup of various material; Easy to use: as only to need to press shower nozzle with hand gently and spray, can replace the trouble of brushing glue; The colloid look white: anti-xanthochromia, and the material that is specially adapted to the glue color is had relatively high expectations is pasted, as white paper, the stickup of cloth etc.; Environmentfriendly products: do not contain formaldehyde. fluorine Lyons. aromatic hydrocarbons.
The above only is preferred embodiment of the present invention, so all equivalences of doing according to the described structure of patent claim of the present invention, feature and principle change or modify, is included in the patent claim of the present invention.

Claims (4)

1. multi-functional spray glue prescription, it comprises rubber, synthetic resins, tackifying resin, varsol, propellent, it is characterized in that: the weight percent that its content accounts for total formulation material is respectively: rubber is 1%~12%, synthetic resins is 1.0%~15%, tackifying resin is 10%~40%, varsol is 10%~60%, and propellent is 30%~75%.
2. multi-functional spray glue prescription according to claim 1, it is characterized in that: described prescription also is added with chlorine kind solvent, solubility promoter, softening agent, essence, the weight percent that its content accounts for total formulation material is respectively: chlorine kind solvent 10%~40%, solubility promoter is 3%~30%, softening agent is 2%~8%, and essence is 0.5 ‰~10 ‰.
3. multi-functional spray glue prescription according to claim 1, it is characterized in that: described rubber is that any one or a few is used in SBS thermoplastic elastomer, SIS thermoplastic elastomer, SEBS thermoplastic elastomer, styrene-butadiene rubber(SBR), chloroprene rubber, polyisobutene, the chlorosulfonated polyethylene; Synthetic resins is that any one or a few is used in acrylate resin, polyamide resin, vibrin, urethane resin, vinyl chloride-vinyl acetate resin, ethylene-vinyl acetate copolymer resins, the ethylene-acrylate copolymer resins; Tackifying resin is that any one or a few is used in rosin, polymerized rosin, ester gum, pentalyn, petroleum resin, the terpine resin; Varsol is that any one or a few is used in normal hexane, hexanaphthene, 6# white spirit, the 120# white spirit; Propellent is that any one or a few is used in liquefied petroleum gas (LPG) (LPG), the dme (DME); The chlorine kind solvent is that any one or a few is used in methylene dichloride, ethylene dichloride, trichloroethane, the trichloropropane; Solubility promoter is that any one or a few is used in acetone, butanone, methyl alcohol, the dehydrated alcohol; Softening agent is that any one or a few is used in white mineral oil, clorafin, Viscotrol C, epoxy soybean oil, the dioctyl phthalate (DOP) etc.
4. utilize the described multi-functional spray glue prescription of claim 1, the processing method step of making spray glue is:
(1), solubility promoters such as varsol, chlorine kind solvent and part acetone are added stirring tank, open stirring by prescription metering;
(2), the restir state adds down synthetic resins such as rubber such as SBS thermoplastic elastomer and acrylate resin, being stirred to rubber and synthetic resins dissolves fully;
(3), then add tackifying resins such as rosin, after being stirred to rosin and dissolving fully;
(4), again add solubility promoter and softening agent such as residue acetone, being stirred to glue disperses fully;
(5), filter laggard luggage jar, after sealing, toward carrying out the jar inflation.
CN 201010211704 2010-06-25 2010-06-25 Multifunctional spray glue formula and process Active CN102295912B (en)

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Application Number Priority Date Filing Date Title
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CN102295912B CN102295912B (en) 2013-08-28

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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254852A (en) * 2013-05-08 2013-08-21 安徽艳阳电气集团有限公司 Chlorosulfonated polyethylene rubber waterproof daub for underwater fluorescent lamp and preparation method of chlorosulfonated polyethylene rubber waterproof daub
CN103555267A (en) * 2013-11-07 2014-02-05 湖南神力铃胶粘剂制造有限公司 Laminated paper sealing adhesive used in fireworks and packaging industries and preparation method thereof
CN103805112A (en) * 2012-11-14 2014-05-21 深圳市顾康力化工有限公司 Environment-friendly hot-melt pressure-sensitive adhesive capable of being sprayed and preparation method thereof
CN104745124A (en) * 2013-12-27 2015-07-01 比亚迪股份有限公司 A sprayable glue solution, a preparing method thereof and a preparing method of injection moulding products with inserts
CN105017975A (en) * 2015-06-26 2015-11-04 蚌埠市鸿安精密机械有限公司 Micro-foamed wood adhesive
CN105131876A (en) * 2015-10-19 2015-12-09 深圳市惠尔特实业有限公司 Low-flammability aerosol adhesive
CN105295786A (en) * 2015-11-26 2016-02-03 北京海斯迪克新材料有限公司 Aerosol canned environment-friendly quick-drying acrylic laminated adhesive
CN106047286A (en) * 2016-05-30 2016-10-26 广东泰强化工实业有限公司 Spray adhesive with stable performance and preparation method thereof
CN106189940A (en) * 2016-08-28 2016-12-07 仇颖超 A kind of preparation method of environment friendly heat resistant foamed glue
CN106281127A (en) * 2016-08-10 2017-01-04 东至县洋湖镇希望皮具厂 A kind of PU leatherware metal tag alite paste
CN106318278A (en) * 2016-08-29 2017-01-11 无锡万能胶粘剂有限公司 Quick drying glue spray
CN106520067A (en) * 2016-10-27 2017-03-22 温州国仕邦高分子材料有限公司 Special water-based all-purpose adhesive and preparation method thereof
CN106753050A (en) * 2017-01-11 2017-05-31 合肥英索莱特新材料科技有限公司 Water-soluble environment protective glue spraying
CN107573870A (en) * 2017-09-26 2018-01-12 康菲胶粘剂技术(广东)有限公司 A kind of aqueous, environmental protective pastes box glue
CN108659743A (en) * 2018-06-05 2018-10-16 王锦云 A kind of environment-friendly type glue spraying and preparation method thereof
CN109679538A (en) * 2018-12-31 2019-04-26 广东泰强科技实业有限公司 A kind of low VOC mixed type glue spraying and preparation method thereof
CN110003800A (en) * 2019-04-10 2019-07-12 广东绿洲化工有限公司 A kind of modified butadiene-styrene latex environmental protection glue spraying and preparation method thereof
CN110041883A (en) * 2019-05-08 2019-07-23 王锦云 A kind of pipe protection aerosol photopolymer coating and preparation method thereof
CN110734721A (en) * 2019-09-16 2020-01-31 深圳市力洁化工科技有限公司 aerosol spray glue and preparation method thereof
CN111139032A (en) * 2020-01-13 2020-05-12 广东多正树脂科技有限公司 Refined spraying glue and preparation method thereof
CN111139031A (en) * 2020-01-07 2020-05-12 广东东方一哥新材料股份有限公司 High-elasticity chlorine-free environment-friendly spray adhesive and preparation method thereof
CN112226202A (en) * 2020-11-19 2021-01-15 江苏惠沣环保科技有限公司 Glue directly sprayed for pasting spring festival scrolls and pressure aerosol can for spraying glue
CN113072898A (en) * 2021-03-09 2021-07-06 宁波恩派新材料科技有限公司 Environment-friendly aqueous spray adhesive and preparation method thereof
CN113603976A (en) * 2021-08-17 2021-11-05 广州北极光生物科技有限公司 Preparation method of macromolecular rheological slip reducer
CN116694164A (en) * 2023-07-06 2023-09-05 东易日盛智能家居科技(枣庄)有限公司 Aerosol paint and preparation method thereof
CN116694264A (en) * 2023-06-15 2023-09-05 刘丽 Acrylic resin spray adhesive

Citations (4)

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CN1388197A (en) * 2002-05-27 2003-01-01 黄楚填 Environment protecting sprayed glue and its prepn and use
US20030173023A1 (en) * 2001-07-03 2003-09-18 Northern Elastomeric, Inc. Fire-resistant, self-adhesive rolled roofing membrane and method of making same
CN101294049A (en) * 2008-06-20 2008-10-29 中山市三和气雾有限公司 Aerosol photopolymer coating
CN101624504A (en) * 2008-07-07 2010-01-13 刘水平 Chlorobutyl-butyronitrile glue-spraying adhesive for inside decorative material for vehicle and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030173023A1 (en) * 2001-07-03 2003-09-18 Northern Elastomeric, Inc. Fire-resistant, self-adhesive rolled roofing membrane and method of making same
CN1388197A (en) * 2002-05-27 2003-01-01 黄楚填 Environment protecting sprayed glue and its prepn and use
CN101294049A (en) * 2008-06-20 2008-10-29 中山市三和气雾有限公司 Aerosol photopolymer coating
CN101624504A (en) * 2008-07-07 2010-01-13 刘水平 Chlorobutyl-butyronitrile glue-spraying adhesive for inside decorative material for vehicle and preparation method thereof

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103805112A (en) * 2012-11-14 2014-05-21 深圳市顾康力化工有限公司 Environment-friendly hot-melt pressure-sensitive adhesive capable of being sprayed and preparation method thereof
CN103805112B (en) * 2012-11-14 2015-09-09 深圳市顾康力化工有限公司 Environment-friendly hot-melt pressure sensitive adhesive that can spray and preparation method thereof
CN103254852A (en) * 2013-05-08 2013-08-21 安徽艳阳电气集团有限公司 Chlorosulfonated polyethylene rubber waterproof daub for underwater fluorescent lamp and preparation method of chlorosulfonated polyethylene rubber waterproof daub
CN103555267A (en) * 2013-11-07 2014-02-05 湖南神力铃胶粘剂制造有限公司 Laminated paper sealing adhesive used in fireworks and packaging industries and preparation method thereof
CN103555267B (en) * 2013-11-07 2015-10-28 湖南神力铃胶粘剂制造有限公司 Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof
CN104745124B (en) * 2013-12-27 2016-10-26 比亚迪股份有限公司 Sprayable glue and preparation method thereof and the preparation method of the injecting products with inserts
CN104745124A (en) * 2013-12-27 2015-07-01 比亚迪股份有限公司 A sprayable glue solution, a preparing method thereof and a preparing method of injection moulding products with inserts
CN105017975A (en) * 2015-06-26 2015-11-04 蚌埠市鸿安精密机械有限公司 Micro-foamed wood adhesive
CN105131876A (en) * 2015-10-19 2015-12-09 深圳市惠尔特实业有限公司 Low-flammability aerosol adhesive
CN105295786A (en) * 2015-11-26 2016-02-03 北京海斯迪克新材料有限公司 Aerosol canned environment-friendly quick-drying acrylic laminated adhesive
CN105295786B (en) * 2015-11-26 2018-02-02 北京天山新材料技术有限公司 The canned type ring of one kind spraying protects quick-drying acrylic acid laminated adhesive
CN106047286A (en) * 2016-05-30 2016-10-26 广东泰强化工实业有限公司 Spray adhesive with stable performance and preparation method thereof
CN106281127A (en) * 2016-08-10 2017-01-04 东至县洋湖镇希望皮具厂 A kind of PU leatherware metal tag alite paste
CN106189940A (en) * 2016-08-28 2016-12-07 仇颖超 A kind of preparation method of environment friendly heat resistant foamed glue
CN106318278A (en) * 2016-08-29 2017-01-11 无锡万能胶粘剂有限公司 Quick drying glue spray
CN106520067A (en) * 2016-10-27 2017-03-22 温州国仕邦高分子材料有限公司 Special water-based all-purpose adhesive and preparation method thereof
CN106753050A (en) * 2017-01-11 2017-05-31 合肥英索莱特新材料科技有限公司 Water-soluble environment protective glue spraying
CN107573870A (en) * 2017-09-26 2018-01-12 康菲胶粘剂技术(广东)有限公司 A kind of aqueous, environmental protective pastes box glue
CN108659743A (en) * 2018-06-05 2018-10-16 王锦云 A kind of environment-friendly type glue spraying and preparation method thereof
CN109679538B (en) * 2018-12-31 2022-03-08 广东泰强科技实业有限公司 Low-VOC (volatile organic compound) mixed spray adhesive and preparation method thereof
CN109679538A (en) * 2018-12-31 2019-04-26 广东泰强科技实业有限公司 A kind of low VOC mixed type glue spraying and preparation method thereof
CN110003800A (en) * 2019-04-10 2019-07-12 广东绿洲化工有限公司 A kind of modified butadiene-styrene latex environmental protection glue spraying and preparation method thereof
CN110041883A (en) * 2019-05-08 2019-07-23 王锦云 A kind of pipe protection aerosol photopolymer coating and preparation method thereof
CN110041883B (en) * 2019-05-08 2020-07-28 王锦云 Aerosol spray for pipeline protection and preparation method thereof
CN110734721A (en) * 2019-09-16 2020-01-31 深圳市力洁化工科技有限公司 aerosol spray glue and preparation method thereof
CN110734721B (en) * 2019-09-16 2022-06-28 深圳市力洁化工科技有限公司 Aerosol spray glue and preparation method thereof
CN111139031A (en) * 2020-01-07 2020-05-12 广东东方一哥新材料股份有限公司 High-elasticity chlorine-free environment-friendly spray adhesive and preparation method thereof
CN111139032A (en) * 2020-01-13 2020-05-12 广东多正树脂科技有限公司 Refined spraying glue and preparation method thereof
CN112226202A (en) * 2020-11-19 2021-01-15 江苏惠沣环保科技有限公司 Glue directly sprayed for pasting spring festival scrolls and pressure aerosol can for spraying glue
CN113072898B (en) * 2021-03-09 2022-05-10 宁波恩派新材料科技有限公司 Environment-friendly aqueous spray adhesive and preparation method thereof
CN113072898A (en) * 2021-03-09 2021-07-06 宁波恩派新材料科技有限公司 Environment-friendly aqueous spray adhesive and preparation method thereof
CN113603976A (en) * 2021-08-17 2021-11-05 广州北极光生物科技有限公司 Preparation method of macromolecular rheological slip reducer
CN116694264A (en) * 2023-06-15 2023-09-05 刘丽 Acrylic resin spray adhesive
CN116694164A (en) * 2023-07-06 2023-09-05 东易日盛智能家居科技(枣庄)有限公司 Aerosol paint and preparation method thereof

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