CN1331395C - Insecticidal mixture containing gamma-cyhalothrin - Google Patents
Insecticidal mixture containing gamma-cyhalothrin Download PDFInfo
- Publication number
- CN1331395C CN1331395C CNB2005100976700A CN200510097670A CN1331395C CN 1331395 C CN1331395 C CN 1331395C CN B2005100976700 A CNB2005100976700 A CN B2005100976700A CN 200510097670 A CN200510097670 A CN 200510097670A CN 1331395 C CN1331395 C CN 1331395C
- Authority
- CN
- China
- Prior art keywords
- active ingredient
- cyhalothrin
- gamma
- ester
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Food Science & Technology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An insecticidal mixture of gamma-cyhalothrin [(S)- alpha -cyano-3-phenoxybenzyl (Z)-(1R,3R)-3-(2-chloro-3,3,3-tzifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate] and one or more further active ingredients; compositions containing them and their use.
Description
The application is that application number is 02814616.6, denomination of invention is divided an application for the patent application of " insecticide mixtures that contains gamma-cyhalothrin ".
The present invention relates to contain 2 kinds or multiple mixing active ingredients thing, contain their composition, and use these mixtures or composition to prevent and kill off the method for pest not with insecticidal activity.More specifically say, the present invention relates to contain gamma-cyhalothrin ((S)-alpha-cyano-3-benzyloxy phenoxy base (Z)-(1R, 3R)-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester) and other concrete desinsection, nematicide, kill mite, kill the mixture of mollusk, sterilization, plant growth regulating or weeding active compound, contain the composition of these mixtures, and the method for using these mixtures or composition desinsection.
At this, concrete desinsection, nematicide, kill mite, kill the compound of mollusk, sterilization, plant growth regulating or activity of weeding as active ingredient.
((S)-alpha-cyano-3-benzyloxy phenoxy base (Z)-(1R, 3R)-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl cyclopropane carboxylic acid ester) and insecticidal activity by people such as Bentley at Pestic.Sci. (1980) 11 (2), did introduction on the 156-64.
Gamma-cyhalothrin can want pest such as tobacco budworm, Spodoptera littoralis and black peach aphid to produce the biological agent of synergy by counterweight with combining of a kind or plurality of active ingredients.
Therefore, a kind of gamma-cyhalothrin and a kind or multiple other mixing active ingredients thing are provided at this.
Preferably the active ingredient of other except that gamma-cyhalothrin is the active ingredient with desinsection, nematicide or acaricidal activity.
The suitable insecticide example that can be used as other active ingredient in mixture of the present invention can be to be selected from following arbitrary compound:
A) pyrethroid, as permethrin, cypermethrin, sumicidin, esfenvalerate, decis, cyhalothrin, Biphenthrin, fenpropathrin, cyfloxylate, tefluthrin, to pyrethroid (as ether chrysanthemum ester), pyrethrum, tetramethrin, S-EXTHIN, fenfluthrin, prallethrin or the 5-benzyl-3-furfuryl of fish safety-(E)-(1R, 3S)-2,2-dimethyl-3-(2-oxo tiacyclopentane-3-ylidenylmethyl) cyclopropanecarboxylcompound or any their insecticidal activity isomer;
B) organophosphorus compounds is as methidathion, chlorpyrifos-methyl, Profenofos, second Toyodan, orthene, parathion-methyl, gusathion m, demeton-methyl, heptan worm phosphorus, thiometon, Nemacur, nuvacron, Hostathion, acephatemet, Rogor, phosphamidon, malathion.Chlopyrifos, chlorpyrifos-methyl, Phosalone, Terbufos, fensulfothion, Dyfonate, thimet, phoxim, Actellic, pirimiphos ethyl, sumithion, thiazolone phosphorus or diazinon;
C) carbamate (comprising aryl-carbamate) class is as ABG-6215, alanycarb, Aphox, triaguron, cloethocarb, carbofuran, furathiocarb, benzene worm prestige, Aldicarb, thiofurox, carbosulfan, worm prestige, Osbac, unden, Methomyl or methomyl;
D) benzoyl area kind,, fluorine bell urea grand, flufenoxuron or UC 62644 as the fluorine third oxygen urea, Rimon, polyfluoro worm uride, Teflubenzuron, TH-6040, desinsection;
E) organo-tin compound is as plictran, fenbutatin oxide or azoles ring tin;
F) pyrazoles is as azoles insect amide, pyridaben, tebufenpyrad and azoles mite ester;
G) macrolides is as Avermectins or milbemycin class, as Avermectin, methoxyl group abamectin benzoate (emamectin benzoate), ivermectin, milbemycin, pleocidin or Ai Zhading;
H) hormone or pheromone;
I) organochlorine compound is as 5a,6,9,9a-hexahydro-6,9-methano-2,4, hexachloro-benzene, dichlorodiphenyl trichloroethane, Niran or dieldrin;
J) amidine class is as galecron or amitraz;
K) fumigant is as chloropicrin, dichloropropane, Celfume or metham-sodium;
1) chloro nicotine compound is as thiophene worm amine, thiophene worm quinoline, Imidacloprid, Acetamiprid, nitenpyram or thiophene worm amine;
M) two hydrazides classes are as Benzoic acid N-tert-butyl-N-(4-chlorobenzoyl)hydrazide, RH-5992, ring worm hydrazides or Runner;
N) diphenyl ether is as luxuriant ether of or pyriproxyfen;
O) indenes worm prestige;
P) fluorine azoles worm is clear;
Q) pymetrozine;
R) methamidophos;
S) microbial source toxin is as in the Bt or exotoxin;
T) phenyl pyrazoles is as sharp strength spy, fluorine pyrazoles worm, etiprole or acetyl worm nitrile; Or
U) pyridalyl.
Except top listed main chemical pesticide kind, if be fit to the purposes of this mixture of imagination, other agricultural chemicals with extraordinary target also can adopt in mixture.The selective insecticide of special crop for example, as be used for snout moth's larva insecticide (as cartap) or the leafhopper insecticide (as Buprofezin) of paddy rice, also can use.Also can be included in the mixture at other insecticide in extraordinary insect strain/stage or miticide and (for example, to kill the ovicide of mite, dead clean, the thiazole mite of mite, Hexythiazox or tetradiphon; Multi-functional miticide dicofol or propargite; Miticide go out mite quinone, fenazaquin, spiral shell mite ester, special benzene azoles, fenisobromolate or chlorobenzilate; Or growth regulator such as amdro, fly eradication amine, Entocon ZR 515, UC 62644 or TH-6040).
The suitable insecticidal synergist example that can be used as other active ingredient in mixture of the present invention comprises Butacide, sesoxane, Safroxan and dodecyl imidazoles.
Preferred other active ingredient is one and a plurality of following compounds: thiophene worm piperazine, Avermectin, methoxyl group abamectin benzoate (emamectin benzoate), pleocidin, chlopyrifos, chlorpyrifos-methyl, Profenofos, the fluorine third oxygen urea, indenes worm prestige, cyhalothrin, pymetrozine, Aphox, methidathion, Imidacloprid, Acetamiprid, thiophene worm quinoline, sharp strength spy, Runner, fluorine azoles worm clearly, pyridaben, Rimon, pyridalyl, propargite and Butacide.
Preferred other one or more active ingredients are that thiophene worm quinoline, sharp strength spy, Runner, pleocidin, Profenofos, fluorine azoles worm are clear, pyridaben, methoxyl group abamectin benzoate (emamectin benzoate) and indenes worm prestige; Or thiophene worm piperazine, Avermectin, methoxyl group abamectin benzoate (emamectin benzoate), pleocidin, chlopyrifos, Profenofos, the fluorine third oxygen urea, indenes worm prestige and cyhalothrin.
The suitable bactericide example that can be used as other active ingredient in mixture of the present invention can be to be selected from following arbitrary compound:
(E)-N-methyl-2-[2-(2; 5-dimethyl Phenoxymethyl) phenyl]-2-methoxyl group-imino group acetamide (SSF-129); 4-bromo-2-cyano group-N; N-dimethyl-6-trifluoro methyl benzimidazole-1-sulfonamide; α-[N-(3-chloro-2; The 6-xylyl)-2-methoxyl acetamide base]-the r-butyrolactone; 4-chloro-2-cyano group-N; N-dimethyl-5-p-tolyl imidazoles-1-sulfonamide (IKF-916; Cyanogen azoles flusulfamide); 3; 5-two chloro-N-(3-chloro-1-ethyl-1-methyl-2-oxygen propyl group)-4-methyl benzamide (RH-7281; Zoxamide); N-acrylic-4; 5-dimethyl-2-TMS thiophene-3-formamide (MON 65500); N-(1-cyano group-1; The 2-dimethyl propyl)-2-(2; The 4-dichlorophenoxy) propionamide (AC382042); N-(2-methoxyl group-5-pyridine radicals)-cyclopropane carboxamide; The thiadiazoles element; Alanycarb; Aldimorph; Anilazine; Penta ring azoles; Fluoxastrobin; M 9834; Benomyl; Bitertanol; Blasticidin-S; Bromuconazole; The phonetic bacterium spirit of sulphur; Difoltan; Captan; Carbendazim; Chlorhydrate; Carboxin; Carpropamide; Carvone; CGA41396; CGA41397; Chinomethionat; Bravo; Chlorozolinate; Clozylacon; Copper-containing compound; Such as Cupravit; Copperoxyquinolate; Copper sulphate; Copper resinate and Bordeaux mixture; Cymoxanil; Cyproconazole; Encircle the third pyrimidine; Two ethoxy imidazoles prestige; Two-2-pyridine radicals disulphide 1; The 1-dioxide; Euparen; Diclomezine; Botran; The mould prestige of second; ether azoles; Difenzoquat; The fluorine mepanipyrim; O, O-diisopropyl-S-dibenzylsulfide substituted phosphate; Dimefluazole; Dimetconazole; Dimethomorph; Milcurb; Alkene azoles alcohol; Dinocap; The Delan; Dodecyl dimethyl ammonium chloride; Dodemorfe; Dodine; Hinosan; Oxole bacterium; Milstem; Ethyl (Z)-N-benzyl-N-([methyl (methyl-sulphur ethyleneimino-oxygen carbonyl) amino] sulphur)-the Beta-alanine ester; Kobam; The famoxadone; Fenamidone (RPA407213); Different miaow mykol; RH-7592; Methuroxam; Fenhexamid (KBR2738); Fenpiclonil; Fenpropidin; Butadiene morpholine; Fentinacetate; Fentin hydroxide; Fervam; Ferimzone; Fluazinam; Fluorine bacterium; Fluorine biphenyl bacterium; Fluorine bacterium peace; Fluquinconazole; Flusilazole; Flutolanil; Flutriafol; Folpet; Furidazol; Furalaxyl; The spirit of furan pyrazoles; Guanoctine; Own azoles alcohol; Hydroxyisoxazole; IMAZALIL; The acid amides azoles; Biguanide spicy acid salt; Cycltebuconazole; IBP; Isopropyl is fixed; Iprovalicarb; The isopropyl butyl carbamate; Isoprothiolane; Kasugarnycin; The imines bacterium; LY168054; LY211795; LY248908; Mancozeb; Maneb; Mefenoxam; Mepanipyrim; The third oxygen mebenil; Metalaxyl; Encircle penta azoles bacterium; Carbatene; Fork phenalgin acid amides; Nitrile bacterium azoles; Methylamine iron ammonium; Dimethyldithiocarbamate; Isopropyl disappears; Nuarimol; Fenfuram; Organomercurial compound; The spirit of frost; It is grand to encircle the third oxygen sulphur; Oxolinic acide; The imidazoles; Oxycarboxin; Pefurazoate; Penconazole; Pencycuron; Phenazine oxide; Aliette; Phosphoric acid; Rabcide; ZEN 90160 (ZA19631); Polyoxin; Two sulphur Carbatenes; Probenazole; Prochloraz; Procymidone; Hundred dimension spirits; Propiconazole; Propineb; Propionic acid; Ppyrazophos; Pyrifenox; Pyrimethanil; Pyroquilon; Chlorine pyrrole furan ether; Pyrrolnitrin; Quaternary ammonium compound; Chinomethionat; Quinoxyfen; Pentachloronitrobenzene; Flusilazole (F-155); Penta sodium pentachlorophenate; The luxuriant amine of spiral shell ; Streptomysin; Sulphur; Tebuconazole; Tecloftalam; Tecnazene; Fluorine ether azoles; Apl-Luster; Thifluzamide; 2-(thiocyanogen methyl mercapto) benzothiazole; Thiophanate methyl; Thiram; Timibenconazole; Tolelofos-methyl; Triazolone; Triadimenol; Butrizol; Tricyclazole; Tridemorph; Oxime bacterium ester (CGA279202); Triforine; Fluorine bacterium azoles; Triticonazole; Jinggangmeisu; Metham-sodium; Vinclozolin; Zineb and ziram.
The suitable weed killer herbicide example that can be used as other active ingredient in mixture of the present invention can be to be selected from following arbitrary compound:
A.1,2,4-triazine-5-ketone is as Sai Ke and metribuzin;
B. dimethyl pyrazoles is as benzofenap, pyrazolate and pyrazoxyfen;
C. anilid class is as Stam F-34;
D. acetamide-group herbicides are as benfluamid, bromobutide, carbetamide, flufenacet, different grass amine, naproanilide, proproanmide, alanap, pronamide and the third penta careless amine;
E. amino acid and salt thereof, ester class are as bilanafos and salt thereof, ester, careless ammonium phosphine and salt thereof, ester, glyphosate and salt thereof, ester and sulphosate;
F. fragrant oxygen propionic acid ester, the three-dimensional active isomer that comprises it, as alkynes grass ester, cyhalofop-butyl, chloroformate grass and ester class thereof, as methyl esters, fluazifop, the standing grain spirit of pyrrole fluorine chlorine and ester class, propaquizafop, quizalofop-ethyl and ester class thereof and Quizalotop-ethyl (tetrahydro furfuryl ester);
G. aryl aniline is as Diflufenican, FLAMPROP, strong FLAMPROP and ester class thereof;
H. aryl urea is as bromax, chlortoluron, vanilla is grand, fourth is grand, diuron, fenuron, fluometuron, isoproturon, different are grand, lorox, methabenz thiazuron, phenylpropyl alcohol are grand, metobromuron, metoxuron, afesin, neburea and Metribuzin;
I. benzo-2,1,3-thiadiazine-4-ketone-dioxide class is as Bentazon;
J. benzoic acids, as 2,3,6-trichlorobenzoic acid, Amiben and dicamba;
K. bipyridyliums is as diquat and salt and paraquat and salt thereof;
L. carbamates is as chlorpropham and propham; Phenyl amino methanoyl carbanilate class is as different phenmedipham and phenmedipham;
M. ethanamide is as Acetochlor, alachlor, butachlor, kecaoan, P DimethenamidP and isomer thereof, metazachlor, isopropyl methoxalamine and isomer thereof, the third careless amine, propachlor, propisochlor and thiophene ether grass amine;
N. cyclohexyl diketone reaches and salt, fourth oxygen cyclic ketones, clethodim, cycloxydim, sethoxydim, quinone oximes grass and tralkoxydim extremely as withered;
O. two halobenzene nitriles are as dichlobenil;
P. dinitro phenols is as dinoseb acetate phenol and dnoc;
Q. diphenyl ether, as acifluorfen and salt and ester, aclonifen, bifenox, chlomethoxynil, Mo 9 granular, fluroglycofen or its salt or ester, fomesafen, lactofen and Oxyfluorfen;
R. dinitrobenzene amine is as dinitramine, fourth fluchloralin, fluchloralin, oryzalin, Pendimethalin, prodiamine and trefanocide;
S. haloalkyl acid herbicide is as dalapon and trichloroacetic acid and salt thereof;
T. 4-hydroxy-benzonitrile (HBN) class such as Brominal and ioxynil, HBN precursor such as Faneron;
U. hormone herbicide, as 2,4,5-trichlorophenoxyacetic acid, 2,4-dichlorphenoxyacetic acid, 2,4-Dichlorophenoxybutanoic, morpholine acid dichloride picoline, 2,4-drip propionic acid and high by 2, and 4-drips propionic acid, fluroxypyr, 2 first, 4 chlorine, 2 first, 4 chloro-sulphur ethyls, Thistrol, Vi par and mecopropP, picloram, thiophene halozydine and triclopyr;
V. imidazolone type is as imazapic, imazamox, miaow grass ester, weed eradication cigarette and isopropyl amine salt, weed eradication quinoline and Imazethapyr;
W. methyl isocyanate precursor is as dazomet;
X. various weed killer herbicides are as Amcide Ammate, asulam, azoles pyridine alkynes grass, benazolin, benzobicylon, cinmethylin, different humulone, difenzoquat and salt thereof such as Methylsulfate, the difluoro pyrrole is grand, dimethipin, dimexyflam, enide, epoprodan, ethofumesate, diphenyl, fluazolate, fentrazamide, fluorine ketone grass is grand, acid imide phenoxy acetic acid pentyl ester, fluorine piperazine ketone, amine grass azoles, Florencol, flurochloridone, flurtamone, reach careless fluorine, six piperazines together, mefenacet, Lonster, chlorine piperazine grass, penta azoles grass, the fluorine carfentrazone, pyridatol, reaching grass ends, isoxachlortole, different fluorine grass and sodium chlorate;
Y. organic arsine weed killer herbicide is as Ansar and monsodium acid methanearsonate (MSMA);
Z. organophosphorus herbicide is as anilofos and phosphine ammonium element;
AA. group thiophosphate is as cremart, bensulide and piperophos;
BB. pyridazinone is as pyrazone and monometflurazone;
CC. pyridinone is together careless as fluorine;
DD. pyrimidyl oxy benzoic acid and salt thereof and ester are as phonetic sulphur benzoic acid, two phonetic benzoic acid, oxime pyridine grass and phonetic benzene grass oxime;
EE. quinoline carboxylic acid is as quimerac and dichloro quinolinic acid;
FF. weed killer herbicide antipoison, as benoxacor, cloquintocet, press down evil amine, fenchlorazole, fenclorim, oxime grass amine, separate careless furan, naphthalene dimethyl anhydride, oxabentrinil, pyrroles's two diethyl phthalates, N-(dichloro-acetyl)-1-oxygen-4-nitrogen spiral shell dicyclo-(4,5)-decane (AD-67), 3-dichloro-acetyl-2,2,5-trimethyl azoles alkane (R-29148) and 2-dichloromethyl-2-methyl isophthalic acid, 3-two alkane (MG-191);
GG. sulfonylurea, as it is grand to encircle third sulphur;
HH. sulfonanilide is as chloransulam-methyl, the phonetic sulfanilamide (SN) of azoles, florasulam, fluorine ethofumesate and azoles grass sulfanilamide (SN);
II. sulfonylurea, grand as sulphur ammonia sulphur, tetrazolium sulphur grand, bensulfuron-methyl and ester, chlorimuronethyl and ester thereof,, cinosulfuron, flazasulfuron grand as ethyl ester, chlorine sulphur, fluorine pyridine sulphur is grand and salt, pyrrole chlorine sulphur are grand, ethoxysulfuron, pyridine miaow sulphur are grand, iodine metsulfuron-methyl, metsulfuron-methyl and ester thereof, the ring third oxygen sulphur are grand, primisulfuronmethyl and ester thereof, and, pyrazosulfuron grand as methyl esters, fluorine third sulphur, rimsulfuron 25, Sulfometuron Methyl, second sulphur sulphur are grand, thifensulfuron methyl, triasulfuron, tribenuron-methyl and triflusulfuronmethyl;
JJ. thiocarbamates is as sutan, cycloate, dimepiperate, Eptam (EPTC), esprocarb, ordram, orbencarb, tillam, prosulfocarb, benthiocarb, fourth grass prestige, triallate and vernolate;
KK. triazine herbicide is as ametryn, atrazine, bladex, penta Kusatsu, prometryn, prometryn, propazine, Simanex, symetryne, Garagard, terbutryn and trietazine;
LL. triazole weed killer herbicide is as Amrol;
MM. triazolidine ketone is as fluorine ketazolam grass and sulfentrazone;
NN. three ketones is as sulphur humulone and mesotrione;
OO. ureas is as bromacil, lenacil and terbacil.
The suitable plant growth regulator example that can be used as other active ingredient in mixture of the present invention can be to be selected from following arbitrary compound:
Ancymidol, chlormequat, ethrel, flumetralim, flurprimidol, gibberellin, Gibberellin A4/A7, come hydrazides, help strong element, paclobutrazol, accent naphthenic acid, Thidiazuron, anti-ester and uniconazole P.
In order active ingredient to be applied to insect or to be subject to the plant of pest damage, perhaps as bactericide, be applied to seed, plant or the seed of plant, plant the place, be applied to soil or any other somatomedin, usually to be processed into composition to active ingredient, wherein except that active ingredient, also comprise suitable inert diluent or carrier, and optional surfactant (SFA).SFA is a chemicals, it can by reduce surface tension improve the interface (Gu as liquid/, liquid/gas or liquid/liquid interface) characteristic and change other characteristic (as dispersiveness, emulsibility and wettability).
Therefore, a particular aspects, the present invention also provides novel Pesticidal combination, it contains gamma-cyhalothrin and one or more and has desinsection, nematicide, kill mite, kill the compound of mollusk, sterilization, plant growth regulating or activity of weeding, a kind of desinsection inert carrier or thinner and optional one or more surfactants.
Preferred gamma-cyhalothrin: the ratio of other active ingredient between 1: 100 to 100: 1 (as 1: 10 to 10: 1), w/w.
Preferred said composition contains a kind of compound that has desinsection, kills mite or eelworm-killing activity at least except gamma-cyhalothrin.
Preferred all compositions (solid with formulation liquid) contain 0.0001 to 95%, and more preferably 1 to 85%, the active ingredient as 5 to 60% (weight meter).Said composition generally is used for pest control or fungi, so the amount of application of active ingredient is from 0.1g to 10kg/ha, preferably from 1g to 6kg/ha, more preferably from 1g to 1kg/ha.
The seed soaking time spent, effective ingredient consumption 0.0001g to 10g (as 0.001g or 0.05g), preferred 0.005g to 10g, more preferably 0.005g to 4g/kg seed.
Composition processed can be selected multiple formulation, comprise pulvis (DP), soluble powder (SP), water-soluble granular formulation (SG), water-dispersible granules (WG), wetting powder (WP), granule (GR) (slow release is put or discharged soon), soluble liquid (SL), finish (OL), ultralow amount liquor (UL), missible oil (EC), dispersed liquor (DC), emulsion (oil-in-water (EW) and Water-In-Oil (EO)), microemulsion (ME), suspending agent (SC), aerosol, mist agent/fumicants, micro-capsule suspension (CS) and seed treatment.Contemplated specific purpose and the physics of active ingredient, chemistry and biological nature are all depended in being chosen in of formulation in any case.
DP can grind to form fine powder with mixture and prepare then by mixing active ingredient and one or more solid diluents (as natural clay, kaolin, alumina silicate, bentonite, bauxite, montmorillonite, diatomite, chalk, calcium sulphate, calcium carbonate and magnesium carbonate, sulphur, lime, flour, talcum powder and other organic and inorganic solid carrier).
SP can be by mixing active ingredient and one or more water-soluble inorganic salts (as sodium bicarbonate, sodium carbonate or magnesium sulfate), or one or more water-soluble organic solids (as polysaccharide), and in order to improve water dispersible/dissolubility, optional one or more wetting agents, the mixture of one or more dispersants or said reagent prepares.Then this mixture is ground to form fine powder.Similar compositions also can be generated SG by granulating.
WP can be by mixing active ingredient and one or more solid diluents or carrier, one or more wetting agents and preferred one or more dispersants, and disperse in liquid in order to help, select one or more suspending agents to prepare arbitrarily.Then this mixture is ground to form fine powder.Similar compositions also can be generated WG by granulating.
GR can prepare by the solid diluent of granulating active ingredient and one or more powderies or the mixture of carrier; perhaps prepare by the granular materials (as the corncob of float stone, Attagel, Emathlite, diatomite or grinding) of porous, absorbing active ingredient (perhaps its solution in suitable reagent) from previously prepared blank particle; perhaps prepare by go up absorption active ingredient (perhaps its solution in suitable reagent) at hard-core material (as sand, silicate, carbonate, sulphate or phosphate); if desired, drying.In order to help to absorb or absorption, the reagent that adopts comprises solvent (as fat and aromatic hydrocarbon solvent, alcohol, ether, ketone and ester class) and thickener (as acetic acid polyvinyl ester, polyvinyl alcohol, dextrin, sugar and rape oil) usually.In granule, also can comprise one or more other additives (as emulsifier, wetting agent or dispersant).
DC can prepare by active ingredient is dissolved in water or organic solvent such as ketone, alcohol or the glycol ether.These solution can contain a kind of surfactant (for example for the dilution that improves water or prevent crystallization in spray tank).
EC or EW can prepare (selecting arbitrarily to contain one or more wetting agents, one or more emulsifier, or their mixture) by active ingredient is dissolved in the organic solvent.The organic solvent that is suitable for EC comprises that aromatic hydrocarbons is (as alkylbenzene or Fluhyzon, the registration mark example has SOLVESSO100, SOLVESSO150 and SOLVESSO200), ketone (as cyclohexanone or methyl cyclohexanone) and alcohol (as benzylalcohol, the pure and mild butanols of furans), N-alkyl pyrrolones (as N-N-methyl 2-pyrrolidone N-or N-octyl group pyrrolones), dimethylformamide of fatty acid (as C8-C10 fatty acid dimethylformamide) and chlorohydrocarbon.In a single day missible oil product adds can be automatic emulsified in the entry, produces the emulsion with enough stability, allows by suitable apparatus spray application.The preparation of EW comprises and obtaining as liquid (if it is not a liquid in room temperature, can under rational temperature, melt, generally be lower than 70 ℃) or the active ingredient that in solution, (is dissolved in the appropriate solvent), then, liquid or emulsifying soln with gained under high shear enter in the water that contains one or more surfactants, produce a kind of emulsion.The solvent that is suitable in EW comprises the suitable organic solvent of rape oil, chlorohydrocarbon (as chlorobenzene), aromatic solvent (as alkylbenzene or Fluhyzon) and other low-solubility in water.
ME can contain the water of one or more solvents and one or more surfactants prepare by mixing, produces the stable isotropic liquid dosage form of a kind of thermokinetics thus automatically.Active ingredient is initial just mixes in water or in solvent.The appropriate solvent that is used for ME comprises the top said solvent that uses at EC or EW.ME can be an oil-in-water, also can be water in oil system (this system can be determined by conductivity measurement), in identical formulation, is fit to mix with water soluble pesticide and oil-soluble pesticide.ME is adapted at diluting in the water, both can keep microemulsion, also can form oil in water emulsion easily.
SC can be made up of the moisture or non-aqueous suspension of the insoluble active ingredient solid particle that segments.SC can prepare by active ingredient and optional one or more dispersants in suitable medium by ball milling or pearl mill, produces a kind of fine grain compound suspending agent.In composition, one or more wetting agents can be comprised,, also suspension reagent can be comprised in order to reduce the speed of particles settling.In addition, active ingredient can be dry grinded, and is added to then in the water that contains mentioned reagent, produces desired final products.
Aerosol is made up of active ingredient and a kind of suitable propellant (as normal butane).In order to be provided for non-pressure, the composition of manual sprayer,, active ingredient also can be dissolved and be dispersed in the suitable medium (for example water or water-soluble liquid such as n-butanol).
Active ingredient can discharge compound with pyrotechnics and be mixed together under drying regime, form and be adapted at the composition that confined space produces the smog that contains this compound.
CS can prepare according to the preparation method who is similar to the EW formulation, but has a polymerization procedure that adds in addition, therefore obtains a kind of aqueous dispersions of oil droplet, and wherein oil droplet is aggregated the thing film and wraps up, and contains active ingredient and optional carrier or thinner.Polymer film can produce by interfacial polycondensation reaction or coacervation process.Said composition can provide the sustained release of active ingredient, and they also can be used for seed treatment.Active ingredient also can be processed in biodegradable polymer film, and the slow sustained release of compound is provided.
For the biological property that improves composition (as improving wettability, delay and dispersiveness on the surface; Drench with rain in that treatment surface is anti-; The perhaps absorption of active ingredient or mobility), composition can comprise one or more additives.These additives comprise surfactant, spray additives, they are with oil, and as some mineral oil or crude vegetal (as soybean oil and rapeseed oil), and the mixture of they and other biological reinforcing aids (can help or improve the composition of the effect of active ingredient) is the basis.
Active ingredient also can be processed into seed treatment, powder composition for example, comprise and be used for the pulvis (DS) that dry seeds is handled, water solube powder (SS), or be used for the water-dispersible powder (WS) that pulpous state is handled, perhaps liquid composition comprises flowable (FS), a kind of solution (LS), or micro-capsule suspension (CS).DS, SS, WS, the preparation of FS and LS respectively with above-mentioned DP, SP, WP, SC and DC preparation of compositions are very similar.The composition of handling seed can comprise that a kind of composition that helps is adhered to reagent on the seed (as mineral oil or become membrane carrier).
Wetting agent, dispersant and emulsifier can be cation, anion, both sexes or nonionic surface active agent.
Suitable anion surfactant comprises quaternary ammonium compound (as softex kw), imidazolidine and amine salt.
Suitable anion surfactant comprises the alkali metal salt of fatty acid, sulfuric acid list fat-based ester salt (as sulfuric acid lauryl sodium), the salt of the aryl compound of sulfonation is (as neopelex, calcium dodecyl benzene sulfonate, the mixture of naphthalene sulfonic acids butyl ester and sulfonic acid diisopropyl sodium and sulfonic acid triisopropyl ester), sulfuric ester ether, sulfuric acid alcohol ether (as bay-3-sodium sulphate), carboxylate ether (as bay-3-carboxylic acid sodium), (product of reaction between one or more fatty alcohols and phosphoric acid (mainly being an ester) or five phosphorous oxide (mainly being diester) is as the reaction of laruyl alcohol and four phosphoric acid for phosphate; These products can be ethoxylations in addition), succinate, sulfonation paraffin wax or alkene, taurine ester and lignosulfonates.
Suitable amphoteric surfactant comprises betain, propionic ester and glycinate.
Suitable ionic surfactant pack is drawn together alkylene oxide, as ethylene oxide, propylene oxide, the condensation product of butene oxide or its mixture and fatty alcohol (as oil base alcohol or cetyl alcohol) or alkyl phenol (as octyl phenol, nonyl phenol or octyl cresol); Part ester from long-chain fatty acid or hexitan; The condensation product of said part ester and ethylene oxide; Block polymer (containing ethylene oxide and propylene oxide); Alkane chain alcohol; Single ester (as the fatty acid polyethylene glycol ester); Amine oxide (as lauryl dimethyl amine oxide); And lecithin.
Suitable suspending agent comprises hydrophilic colloid (as polysaccharose, polyvinylpyrrolidone or sodium carboxymethylcellulose) and expanded clay (as bentonite or Emathlite).
Active ingredient can be used by any known applying pesticides or the method for bactericide.For example, can will process or the active ingredient of undressed mistake is applied to the place of insect or insect (as the habitat of insect, or be subject to the plantation plant of pest damage, or be applied to any part of plant, comprise leaf, stem, branch or root, be applied to the preceding seed of plantation, or other medium that plant is growing or quilt is planted is (as the soil around the root, normal soil, the planting system that paddy field water or water are planted), or directly spraying, dust, use by dipping, use, use or by composition (as particulate composition or wrap in composition in the water-soluble bag) being disperseed or sneaking in the soil or in the water environment and use as steam as butterfat or paste.
Active ingredient also can be sneaked into and is used for luring the bait formulation that draws with pest control.
Active ingredient also can be sneaked in building and the material used of agricultural engineering.For example they can be sneaked into for pest control such as termite, in the plastic film of using in the structure of building and Polypropylence Sheet.
Active ingredient also can be injected plant, or is sprayed onto on the plant with electronic spray technique or other low capacity method, or uses by ground or aerial irrigation system.
The composition that is used for aqueous compositions (aqueous solution or dispersion liquid) generally provides with the liquor form that contains high concentration active ingredient, and this liquor will add water before use.This liquor can comprise DC/SC/EC/EW/ME/SG/SP/WP/WG and CS, usually require them to stand long-term storage, they can be added to behind the storage and form the aqueous compositions that can keep enough time homogeneous states in the water, so that can be used by conventional sprayer.Depend on application target, this aqueous compositions can contain different active ingredient amount (as 0.0001-10%, the weight meter).
Active ingredient can be used in the mixture with fertilizer (as the fertilizer of nitrogenous, potassium or phosphorus).Suitable formulation comprises the granule of fertilizer.These mixtures are fit to contain high to 25% active ingredient (weight meter).Therefore, the present invention also provides the Ru 2006101161 that contains fertilizer and active ingredient.
The present composition amount that is used for pest control provides the ratio of an active ingredient, from 0.01-10kg/ha, preferably from 0.1-6kg/ha.
Mixture of the present invention preferably exists with single composition., each composition can leave in separately the container, and one contains gamma-cyhalothrin and optional solid and liquid diluent and mixes, and second contains other active ingredient and optional solid and liquid diluent and mix.These compositions can be placed in the container of one two lattice in addition, and lattice contain gamma-cyhalothrin and optional solid and liquid diluent, and second lattice contain other active ingredient and optional solid and liquid diluent.
Then, can be together with the mixing of materials of two containers or two lattice, for example, before use that both are mixed with water.
On the other hand, the invention provides pest control, the method of mite or nematode, insect that comprises such as Lepidoptera, diptera, Homoptera and coleoptera (comprising the chrysomelid genus of bar, i.e. corn root leaf A) are with agricultural (comprising the plantation as the conduct of food and fiber product), gardening and animal feeding, forest, the insect that the storage of plant resource product such as fruit, cereal and timber is relevant, and the insect relevant with the transmission of humans and animals.The example of insect and mite comprises black peach aphid, cotten aphid, beans winged euonymus aphid, Aedes aegypti, Anopheles, Culex, band line red cotton bug, housefly, Pieris brassicae, diamond-back moth, the horseradish ape is chrysomelid, the kidney Aspidiotus belongs to, Aleyrodes, cassava aleyrodid, Groton bug, American cockroach, oriental cockroach, Spodoptera littoralis, tobacco budworm, Australia epidemic disease locust, the chrysomelid genus of bar, Agrotis, spot dogstail snout moth's larva, brown planthopper, rice leafhopper, panonychus ulmi, citrus red mite (crm), Tetranychus urticae, Tetranychus cinnabarinus, the tangerine rust mite, Polyphagotarsonemus latus Banks and short whisker Acarapis.
The insect example of available present composition control comprises: black peach aphid, cotten aphid, beans winged euonymus aphid, lygus bug belongs to, diamond-back moth, brown planthopper, rice leafhopper, Bemisia spp, cotton stinkbug belongs to, Leptocorisa spp belongs to, Frankliniella occidentalis, Thrips, colorado potato beetles, cotton boll resembles, the kidney Aspidiotus belongs to, Aleyrodes, cassava aleyrodid, European corn borer, Spodoptera littoralis, tobacco budworm, cotton bollworm, the real noctuid of paddy, the wild snout moth's larva of lap leaf, Pieris brassicae, diamond-back moth, the ground Noctua, striped rice borer, migratory locusts, Australia epidemic disease locust, the chrysomelid genus of bar, panonychus ulmi, citrus red mite (crm), Tetranychus urticae, Tetranychus cinnabarinus, the tangerine rust mite, Polyphagotarsonemus latus Banks and short whisker Acarapis, boophilus microplus, Dermacentor variabilis, cat flea, liriomyza bryoniae belongs to, housefly, Aedes aegypti, Anopheles, Culex, Lucilia, Groton bug, American cockroach, oriental cockroach, the termite of Mastotermitidae (as Australia's Cryptotermes), Kalotermitidae (as new termite), Rhinotermitidae is (as the Taiwan formosanes, American-European reticulitermes flavipe, eastern subterranean termite, Reticulitermes virginicus, U.S. reticulitermes flavipe and Termitidae (as yellow ball termite), the fire ant, MonomoriumMayr, Damalinia, Linognathus, Meloidogyne, the ball Heterodera, Heterodera, Pratylenchidae belongs to, Rhodopholus spp. pulvinulus sword Turbatrix, Haemonchus contortus.Caenorhabditiselegans.Trichostrongylus spp. and Deroceras reticulatum.
Therefore, the invention provides a kind of elimination, pest control, mite, nematode or molluscan method, comprise desinsection, nematicide, kill mite, kill the mollusk effective dose contain gamma-cyhalothrin and one or more have desinsection, nematicide, kill mite, the mixture that kills mollusk, sterilization, plant growth regulating or weeding active compound is applied to pest, the place of pest, or be subject to the plant of pest harm, the seed of plant, the place of plant or seed.Soil or any other somatomedin (as nutrient solution).
" plant " speech comprises seedling, shrub and tree as used herein.Method for disinfection of the present invention comprises prevention, treatment, interior suction, radical cure and the processing of anti-gemma.
By following example explanation the present invention.
Embodiment 1
Except that pleocidin, subject composition for pleocidin, adopts the Tracer480SC (pleocidin) that dilutes from the industrial active ingredient preparation among 0.05%Synperonic NP8 in water.For tobacco budworm and greedy noctuid, the cotton leaf of spray testing in Berkhard Potter tower makes its dry 1 hour, puts the tobacco budworm and the greedy exigua larvae in 21 ages then on the basin top.In 25 ℃ laboratory, placed 3 days the lethality of evaluation test strain.For aphid, cut out test leaf dish from the Chinese cabbage leaf that excises, be placed on the agar in the test basin.The black peach aphid that transfer is cultivated on the radish cotyledon, and place and spend the night.Remove dried cotyledon, on each leaf basin, stay about 20-25 aphid.In Berkhard Potter tower, basin is sprayed.In case done, put the top cover of ventilation atop.In 20 ℃ Weiss chamber, placed 3 days, the lethality of evaluation test strain then, all tests all comprise a Synperonic NP8 contrast.Adjust the lethality evaluation result with the arbitrary lethality seen in the check experiment, adopt the analysis of Colby equation, relatively adopt the lethality that the mixture of each ratio obtains and under same amount, use the desired lethality of each active ingredient separately.Any increase of the lethality quantity of expection can be owing to synergistic effect.Computational methods are as follows:
Lethality %+ (the lethality % of 100%-A) * (the lethality % of component of mixture B) from the lethality=component of mixture A of mixture expection.The results are shown in Table I-III.
Table I
The result of the test of tobacco budworm
| Component of mixture | Ratio (γ: ai) | Applicating ratio (ppm) | The lethality of observation, % | The lethality % of expection | Observation-expection | |||
| γ | Its ai of base | γ | Other ai | Mixture | ||||
| Avermectin | 1∶1 | 0.25 | 0.25 | 28 | 0 | 36 | 28 | 8 |
| 1∶1 | 0.50 | 0.50 | 28 | 0 | 25 | 28 | -3 | |
| 1∶1 | 1.00 | 1.00 | 32 | 0 | 43 | 30 | 13 | |
| 1∶2 | 0.25 | 0.50 | 32 | 0 | 29 | 32 | -3 | |
| 1∶2 | 0.50 | 1.00 | 32 | 0 | 43 | 32 | 11 | |
| 2∶1 | 0.50 | 0.25 | 46 | 0 | 43 | 46 | -3 | |
| 2∶1 | 1.00 | 0.50 | 46 | 0 | 64 | 46 | 18 | |
| Emamectin benzoate | 1∶1 | 0.25 | 0.25 | 28 | 97 | 100 | 98 | 2 |
| 1∶1 | 0.50 | 0.50 | 28 | 96 | 99 | 97 | 2 | |
| 2∶1 | 0.25 | 0.13 | 32 | 97 | 100 | 98 | 2 | |
| 2∶1 | 0.50 | 0.25 | 32 | 96 | 100 | 97 | 3 | |
| 2∶1 | 1.00 | 0.50 | 32 | 99 | 100 | 99 | 1 | |
| 4∶1 | 0.50 | 0.13 | 46 | 96 | 100 | 98 | 2 | |
| 4∶1 | 1.00 | 0.25 | 46 | 99 | 100 | 99 | 1 | |
| Pleocidin | 2∶1 | 0.25 | 0.13 | 28 | 33 | 67 | 52 | 14 |
| 2∶1 | 0.50 | 0.25 | 32 | 42 | 89 | 60 | 29 | |
| 4∶1 | 0.25 | 0.06 | 28 | 44 | 79 | 60 | 19 | |
| 4∶1 | 0.50 | 0.13 | 32 | 33 | 65 | 55 | 11 | |
| 4∶1 | 1.00 | 0.25 | 46 | 42 | 93 | 68 | 25 | |
| 8∶1 | 0.50 | 0.0625 | 32 | 44 | 72 | 62 | 10 | |
| 8∶1 | 1.00 | 0.13 | 46 | 33 | 65 | 64 | 1 | |
| Component of mixture | Ratio (γ: ai) | Applicating ratio (ppm) | The lethality of observation, % | The lethality % of expection | Observation-expection | |||
| γ | Its ai of base | γ | Other ai | Mixture | ||||
| Poison roach with poison | 1∶05 | 0.50 | 2.50 | 28 | 36 | 42 | 54 | -13 |
| 1∶05 | 1.00 | 5.00 | 28 | 29 | 49 | 49 | -1 | |
| 1∶10 | 0.25 | 2.50 | 32 | 36 | 29 | 57 | -27 | |
| 1∶10 | 0.50 | 5.00 | 32 | 29 | 49 | 52 | -3 | |
| 1∶10 | 1.00 | 10.00 | 32 | 44 | 71 | 62 | 9 | |
| 1∶20 | 0.25 | 5.00 | 46 | 29 | 56 | 62 | -6 | |
| 1∶20 | 0.50 | 10.00 | 46 | 44 | 63 | 70 | -7 | |
| Indenes worm prestige | 1.25∶1 | 0.25 | 0.20 | 28 | 26 | 40 | 47 | -7 |
| 1.25∶1 | 0.50 | 0.40 | 28 | 22 | 40 | 44 | -4 | |
| 1.25∶1 | 1.00 | 0.80 | 32 | 26 | 40 | 50 | -10 | |
| 1∶1.6 | 0.25 | 0.40 | 32 | 22 | 44 | 47 | -3 | |
| 1∶1.6 | 0.50 | 0.80 | 32 | 46 | 60 | 63 | -3 | |
| 2.5∶1 | 0.50 | 0.20 | 46 | 22 | 46 | 58 | -12 | |
| 2.5∶1 | 1.00 | 0.40 | 46 | 46 | 71 | 71 | 0 | |
| Cyhalothrin | 1∶1 | 0.25 | 0.25 | 28 | 46 | 43 | 61 | -18 |
| 1∶1 | 0.50 | 0.50 | 28 | 50 | 41 | 64 | -23 | |
| 1∶1 | 1.00 | 1.00 | 32 | 46 | 35 | 63 | -28 | |
| 1∶2 | 0.25 | 0.50 | 32 | 50 | 39 | 66 | -27 | |
| 1∶2 | 0.50 | 1.00 | 32 | 52 | 38 | 67 | -30 | |
| 2∶1 | 0.50 | 0.25 | 46 | 50 | 32 | 73 | -41 | |
| 2∶1 | 1.00 | 0.50 | 46 | 52 | 46 | 74 | -28 | |
Table II
The result of the test of Spodoptera littoralis
| Component of mixture | Ratio (γ: ai) | Applicating ratio (ppm) | The lethality of observation, % | The lethality % of expection | Observation-expection | |||
| γ | Its ai of base | γ | Other ai | Mixture | ||||
| Emamectin benzoate | 10∶1 | 0.025 | 0.0025 | 0 | 0 | 22 | 0 | 22 |
| 10∶1 | 0.05 | 0.005 | 25 | 6 | 51 | 29 | 22 | |
| 10∶1 | 0.1 | 0.01 | 90 | 0 | 82 | 90 | -8 | |
| 20∶1 | 0.05 | 0.0025 | 25 | 0 | 32 | 25 | 7 | |
| 20∶1 | 0.1 | 0.005 | 90 | 6 | 66 | 90 | -24 | |
| 5∶1 | 0.025 | 0.005 | 0 | 6 | 46 | 6 | 40 | |
| 5∶1 | 0.05 | 0.01 | 25 | 0 | 76 | 25 | 51 | |
| Pleocidin | 1∶10 | 0.025 | 0.25 | 0 | 0 | 79 | 0 | 79 |
| 1∶10 | 0.05 | 0.5 | 25 | 29 | 96 | 47 | 49 | |
| 1∶2.5 | 0.05 | 0.125 | 25 | 0 | 59 | 25 | 34 | |
| 1∶2.5 | 0.1 | 0.25 | 90 | 0 | 99 | 90 | 9 | |
| 1∶5 | 0.025 | 0.125 | 0 | 0 | 34 | 0 | 34 | |
| 1∶5 | 0.05 | 0.25 | 25 | 0 | 82 | 25 | 57 | |
| 1∶5 | 0.1 | 0.5 | 90 | 29 | 100 | 93 | 7 | |
Table III
The result of the test of black peach aphid
| Component of mixture | Ratio (γ: ai) | Applicating ratio (ppm) | The lethality of observation, % | The lethality % of expection | Observation-expection | |||
| γ | Its ai of base | γ | Other ai | Mixture | ||||
| Thiophene worm piperazine | 1∶10 | 0.25 | 2.5 | 70 | 92 | 100 | 97 | 3 |
| 1∶10 | 0.5 | 5 | 69 | 94 | 100 | 98 | 2 | |
| 1∶2.5 | 0.5 | 1.25 | 69 | 70 | 100 | 91 | 9 | |
| 1∶2.5 | 1.0 | 2.5 | 98 | 92 | 100 | 100 | 0 | |
| 1.5 | 0.25 | 1.25 | 70 | 70 | 100 | 91 | 9 | |
| 1∶5 | 0.5 | 2.5 | 69 | 92 | 100 | 97 | 3 | |
| 1∶5 | 1.0 | 5 | 98 | 94 | 100 | 100 | 0 | |
| Cyhalothrin | 1∶1 | 0.25 | 0.25 | 70 | 4 | 92 | 71 | 21 |
| 1∶1 | 0.5 | 0.5 | 69 | 14 | 96 | 73 | 23 | |
| 1∶2 | 0.25 | 0.125 | 70 | 10 | 66 | 73 | -7 | |
| 1∶2 | 1.0 | 0.5 | 98 | 14 | 100 | 98 | 2 | |
| 2∶1 | 0.5 | 0.25 | 69 | 4 | 100 | 70 | 30 | |
| 4∶1 | 0.5 | 0.125 | 69 | 10 | 98 | 72 | 26 | |
| 4∶1 | 1.0 | 0.25 | 98 | 4 | 100 | 98 | 2 | |
Claims (4)
1. gamma-cyhalothrin and a kind of other mixing active ingredients thing with desinsection, nematicide or acaricidal activity, wherein other active ingredient is a kind of in the middle of Avermectin, methoxyl group abamectin benzoate and the pleocidin, and the weight ratio of gamma-cyhalothrin and a kind of described other active ingredient is 1: 10-10: 1.
2. Pesticidal combination, described composition contains gamma-cyhalothrin and a kind of other active ingredient with desinsection, nematicide or acaricidal activity, desinsection inert carrier or thinner and choose any one kind of them or the kinds of surface activating agent, wherein other active ingredient is a kind of in the middle of Avermectin, methoxyl group abamectin benzoate and the pleocidin, and the weight ratio of gamma-cyhalothrin and a kind of described other active ingredient is 1: 10-10: 1.
One kind use effective dose comprise gamma-cyhalothrin and a kind of other mixing active ingredients thing with desinsection, nematicide or acaricidal activity, in the pest of handling or the place of pest, the method of elimination and pest control, mite or nematode, wherein other active ingredient is a kind of in the middle of Avermectin, methoxyl group abamectin benzoate and the pleocidin, and the weight ratio of gamma-cyhalothrin and a kind of described other active ingredient is 1: 10-10: 1.
4. the method for claim 3, wherein pest is the insect of plantation plant.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0118137.9 | 2001-07-25 | ||
| GBGB0118137.9A GB0118137D0 (en) | 2001-07-25 | 2001-07-25 | Insecticidal mixture |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB028146166A Division CN100401893C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture contg. gamma-cyhalothrin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1736201A CN1736201A (en) | 2006-02-22 |
| CN1331395C true CN1331395C (en) | 2007-08-15 |
Family
ID=9919164
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200610100338XA Pending CN101099472A (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
| CNB2005100976700A Expired - Lifetime CN1331395C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
| CNA2008100991371A Pending CN101268782A (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
| CNB028146166A Expired - Lifetime CN100401893C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture contg. gamma-cyhalothrin |
| CNB2005100994200A Expired - Lifetime CN100349519C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200610100338XA Pending CN101099472A (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100991371A Pending CN101268782A (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
| CNB028146166A Expired - Lifetime CN100401893C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture contg. gamma-cyhalothrin |
| CNB2005100994200A Expired - Lifetime CN100349519C (en) | 2001-07-25 | 2002-07-10 | Insecticidal mixture containing gamma-cyhalothrin |
Country Status (22)
| Country | Link |
|---|---|
| US (2) | US7906127B2 (en) |
| EP (3) | EP1414304A1 (en) |
| JP (1) | JP4427322B2 (en) |
| KR (2) | KR20040018509A (en) |
| CN (5) | CN101099472A (en) |
| AP (1) | AP1669A (en) |
| AR (1) | AR034881A1 (en) |
| AU (1) | AU2002345228B2 (en) |
| BR (1) | BR0211298B1 (en) |
| CA (2) | CA2452515C (en) |
| CO (1) | CO5560519A2 (en) |
| EA (1) | EA005502B1 (en) |
| GB (1) | GB0118137D0 (en) |
| IL (3) | IL159825A0 (en) |
| MA (1) | MA26129A1 (en) |
| MX (2) | MX337223B (en) |
| MY (1) | MY135255A (en) |
| OA (1) | OA12644A (en) |
| PL (1) | PL366828A1 (en) |
| TW (1) | TWI321037B (en) |
| WO (1) | WO2003011031A1 (en) |
| ZA (1) | ZA200400490B (en) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1585392B1 (en) * | 2003-01-06 | 2009-03-18 | Yissum Research Development Company Of The Hebrew University Of Jerusalem | Herbicides inhibiting the action of plant acetyl-coa carboxylase for use as pesticides. |
| US7144583B2 (en) | 2003-03-05 | 2006-12-05 | Sumitomo Chemical Company, Limited | Pesticidal composition |
| US7973083B2 (en) * | 2003-12-01 | 2011-07-05 | Syngenta Crop Protection Llc | Pesticidally active compounds |
| DE102004001271A1 (en) * | 2004-01-08 | 2005-08-04 | Bayer Cropscience Ag | Drug combinations with insecticidal properties |
| EP2474227B1 (en) | 2004-02-24 | 2015-04-15 | Sumitomo Chemical Company, Limited | Insecticide compositions |
| IL160858A (en) * | 2004-03-14 | 2015-09-24 | Adama Makhteshim Ltd | Nanoparticulate pesticidal composition and a process for its preparation |
| MXPA06010912A (en) * | 2004-03-25 | 2007-03-08 | Fmc Corp | Liquid termiticide compositions of pyrethroids and a neonicitinoids. |
| KR100736176B1 (en) * | 2004-09-24 | 2007-07-09 | 대한민국 | Nematicidal Compositions Containing Tartaric Acid |
| DE102006008691A1 (en) * | 2006-02-24 | 2007-08-30 | Bayer Cropscience Ag | Agent, useful e.g. to combat animal parasites, to protect wood against insects and to protect plants against animal and microbial parasites, comprises a mixture of spiromesifen and gamma-cyhalothrine |
| CN1330240C (en) * | 2006-03-23 | 2007-08-08 | 浙江新安化工集团股份有限公司 | Pest killing composition |
| DE102006014482A1 (en) * | 2006-03-29 | 2007-10-04 | Bayer Cropscience Ag | Active agent combination, useful e.g. to treat transgenic plants or its seeds, and to combat animal pest, comprises a chloropyridine-furanone compound and an active agent e.g. benzoic acid dicarboxylic acid derivative and/or macrolides |
| TW200833245A (en) * | 2006-10-09 | 2008-08-16 | Syngenta Participations Ag | Pesticidal combinations |
| CL2007003747A1 (en) * | 2006-12-22 | 2008-07-18 | Bayer Cropscience Ag | PESTICIDE COMPOSITION INCLUDING FOSETIL-AL AND AN INSECTICIDE COMPOUND; AND METHOD FOR CONTROLLING FITOPATOGEN FUNDS OR DANIN INSECTICIDES OF THE PLANTS, CROPS OR SEEDS THAT INCLUDE APPLYING SUCH COMPOSITION. |
| EP2070415A1 (en) * | 2007-12-11 | 2009-06-17 | Bayer CropScience AG | Active compound combinations |
| EP2230914B1 (en) * | 2007-12-20 | 2014-01-15 | Syngenta Participations AG | Ant control |
| WO2009086740A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of indoxacarb and its preparation |
| EP2098119A1 (en) | 2008-02-15 | 2009-09-09 | Sara Lee/DE N.V. | Sustained release insecticide composition |
| US8404260B2 (en) * | 2008-04-02 | 2013-03-26 | Bayer Cropscience Lp | Synergistic pesticide compositions |
| US8110608B2 (en) | 2008-06-05 | 2012-02-07 | Ecolab Usa Inc. | Solid form sodium lauryl sulfate (SLS) pesticide composition |
| CN101380021B (en) * | 2008-07-17 | 2012-08-29 | 张少武 | Insecticidal composition containing efficient lambda-cyhalothrin and chlorfluazuron |
| KR101648596B1 (en) * | 2008-09-12 | 2016-08-16 | 다우 아그로사이언시즈 엘엘씨 | Stabilized pesticidal compositions |
| CN102017948B (en) * | 2009-09-22 | 2013-09-18 | 南京华洲药业有限公司 | Synergistic pesticide combination containing nitenpyram and pyridalyl and application of combination |
| US8796231B2 (en) * | 2010-02-19 | 2014-08-05 | Sumitomo Chemical Company, Limited | Pest control composition |
| JP2011246436A (en) * | 2010-04-28 | 2011-12-08 | Sumitomo Chemical Co Ltd | Pest control composition |
| CN101874486B (en) * | 2010-07-30 | 2014-02-12 | 湖南大方农化有限公司 | Insecticide composition containing spinosad and etofenprox |
| US8968757B2 (en) | 2010-10-12 | 2015-03-03 | Ecolab Usa Inc. | Highly wettable, water dispersible, granules including two pesticides |
| ES2387711B8 (en) * | 2011-03-03 | 2013-09-27 | Química De Munguía, S.A. (Quimunsa) | PRODUCT FOR TREATMENT OF PLANTS. |
| JP5947894B2 (en) * | 2011-08-22 | 2016-07-06 | ロマーノ ナチュール ゲーエムベーハーＲｏｍａｎｏ Ｎａｔｕｒ Ｇｍｂｈ | Highly active antiparasitic composition against Rhynchophorus ferruginus |
| CN102396508A (en) * | 2011-11-24 | 2012-04-04 | 陕西美邦农药有限公司 | Novel pesticide composition containing thiamethoxam |
| CN103314988A (en) * | 2012-03-24 | 2013-09-25 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing pyridalyl and synthetic pyrethroids |
| CN102630697A (en) * | 2012-04-03 | 2012-08-15 | 浙江威尔达化工有限公司 | Insecticidal composition containing pyridalyl and efficient cyhalothrin and application thereof |
| CN103371168B (en) * | 2012-04-28 | 2017-02-22 | 马国丰 | High-efficiency insecticide composition |
| GB2513859B (en) * | 2013-05-07 | 2018-01-17 | Rotam Agrochem Int Co Ltd | Agrochemical composition, method for its preparation and the use thereof |
| CN103704252B (en) * | 2013-12-10 | 2015-06-17 | 徐茂航 | Cyhalothrin-containing missible oil and its application |
| CN104738043A (en) * | 2013-12-26 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and fufenozide and application thereof |
| CN104430485B (en) * | 2014-11-13 | 2017-01-18 | 山东潍坊润丰化工股份有限公司 | Insecticide composition containing acetamiprid and efficient cyhalothrin and application of insecticide composition |
| CN105794831B (en) * | 2014-12-30 | 2018-12-18 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination and application thereof |
| EP3081086B1 (en) * | 2015-04-16 | 2018-09-12 | Rotam Agrochem International Company Limited | Synergistic insecticidal composition comprising imidacloprid, bifenthrin and abamectin |
| WO2018037094A1 (en) * | 2016-08-24 | 2018-03-01 | Vestergaard Sa | Fenazaquin and indoxacarb in a product for killing insects, especially mosquitoes |
| CN107821414A (en) * | 2017-12-05 | 2018-03-23 | 徐州农丰生物化工有限公司 | A kind of abamectin insecticide and preparation method thereof |
| CN108522535A (en) * | 2018-05-07 | 2018-09-14 | 福建省农业科学院植物保护研究所 | A kind of bucket for field control agricultural pests mixes pesticide |
| BR112020025690A2 (en) * | 2018-06-18 | 2021-03-16 | Upl Ltd | STABLE COFORMULATION OF BENZOYLUREA WITH PIRETROIDS |
| CN109526976A (en) * | 2018-11-19 | 2019-03-29 | 江苏明德立达作物科技有限公司 | A kind of method and its microcapsule suspension-suspendinagent agent preparing the microcapsule suspension-suspendinagent agent containing thiacloprid and gamma cyhalothrin |
| WO2020198185A1 (en) * | 2019-03-25 | 2020-10-01 | Valent Biosciences Llc | Mixtures of terpendoles and pesticides and uses thereof |
| CN115768263A (en) | 2020-06-10 | 2023-03-07 | 瓦伦特生物科学有限责任公司 | Mixtures of pyrethroids and rhzomorphs and use thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0237227A1 (en) * | 1986-03-13 | 1987-09-16 | Imperial Chemical Industries Plc | Insecticidal compositions |
| WO1993003618A2 (en) * | 1991-08-27 | 1993-03-04 | Uniroyal Chemical Company, Inc. | Insecticide compounds for agricultural and horticultural use |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4183948A (en) * | 1977-01-24 | 1980-01-15 | Imperial Chemical Industries Limited | Halogenated esters |
| AU531541B2 (en) | 1979-05-11 | 1983-08-25 | Pitman-Moore Australia Limited | Tickicidal composition |
| DE3372480D1 (en) * | 1982-10-18 | 1987-08-20 | Ici Plc | Insecticidal product and preparation thereof |
| GB8515459D0 (en) | 1985-06-19 | 1985-07-24 | Young Robert Co Ltd | Parasitical compositions |
| DE3784520D1 (en) * | 1986-01-25 | 1993-04-08 | Hoechst Ag | PEST CONTROL. |
| JPH0784365B2 (en) | 1986-11-14 | 1995-09-13 | 日本バイエルアグロケム株式会社 | Insecticidal composition for agriculture and horticulture |
| CN1096632A (en) | 1993-06-24 | 1994-12-28 | 潘尧方 | Kill the compound liquor of the mite pesticidal ternary mite king of going out |
| CN1096633A (en) * | 1993-06-24 | 1994-12-28 | 潘尧方 | The ternary complex preparation Meilingwang of control cotton bollworm |
| ATE181206T1 (en) | 1994-02-27 | 1999-07-15 | Rhone Poulenc Agrochimie | SYNERGETIC TERMITICIDE COMPOSITION OF PYRETHROID AND N-PHENYL-PYRAZOLE |
| CH688216A5 (en) | 1994-05-30 | 1997-06-30 | Ciba Geigy Ag | Synergistic composition. |
| ES2250970T3 (en) * | 1994-06-08 | 2006-04-16 | Syngenta Participations Ag | SYNERGIC COMPOSITIONS THAT INCLUDE LUFENURON AND PROFENOFOS. |
| JP3493476B2 (en) * | 1994-09-30 | 2004-02-03 | バイエルクロップサイエンス株式会社 | Termite control composition |
| IL116148A (en) | 1994-11-30 | 2001-03-19 | Rhone Poulenc Agrochimie | Emulsifiable composition for the control of insects |
| CH689326A5 (en) | 1995-04-10 | 1999-02-26 | Novartis Ag | Synergistic pesticidal composition containing pymetrozine |
| EP0845944B2 (en) | 1995-08-16 | 2003-08-13 | S.C.Johnson & Son, Inc. | Active substance combinations comprising pyrethroids and insect-development inhibitors |
| AU722204B2 (en) | 1995-10-31 | 2000-07-27 | Sumitomo Chemical Company, Limited | Pesticidal composition |
| CN101077072B (en) | 1996-04-29 | 2012-08-08 | 先正达参股股份有限公司 | Pesticide composition |
| JP4243727B2 (en) | 1996-10-02 | 2009-03-25 | 日本農薬株式会社 | Insecticides and acaricides |
| IL129757A (en) | 1998-06-02 | 2003-07-31 | Sumitomo Chemical Co | Arthropod-controlling agent comprising a substituted dichloropropenyloxybenzene and a pyrethroid |
| FR2780857B1 (en) * | 1998-07-07 | 2006-09-22 | Novartis Ag | PESTICIDE AGENT |
| US6838473B2 (en) | 2000-10-06 | 2005-01-04 | Monsanto Technology Llc | Seed treatment with combinations of pyrethrins/pyrethroids and clothiandin |
| US6660690B2 (en) | 2000-10-06 | 2003-12-09 | Monsanto Technology, L.L.C. | Seed treatment with combinations of insecticides |
| US6903093B2 (en) * | 2000-10-06 | 2005-06-07 | Monsanto Technology Llc | Seed treatment with combinations of pyrethrins/pyrethroids and thiamethoxam |
| US20020103233A1 (en) | 2000-11-30 | 2002-08-01 | Arther Robert G. | Compositions for enhanced acaricidal activity |
| US6919464B1 (en) * | 2001-03-21 | 2005-07-19 | Dow Agrosciences Llc | Synthetic derivatives of 21-butenyl and related spinosyns |
| US6727228B2 (en) * | 2001-04-25 | 2004-04-27 | Johnson & Johnson Consumer Companies, Inc. | Pediculicidal and ovacidal treatment compositions and methods for killing head lice and their eggs |
| US20030108585A1 (en) * | 2001-05-04 | 2003-06-12 | Roe R. Michael | Polymer conjugates of insecticidal peptides or nucleic acids or insecticides and methods of use thereof |
| MXPA04002649A (en) * | 2001-09-21 | 2004-06-07 | Du Pont | Insecticidal diamides. |
-
2001
- 2001-07-25 GB GBGB0118137.9A patent/GB0118137D0/en not_active Ceased
-
2002
- 2002-07-10 JP JP2003516275A patent/JP4427322B2/en not_active Expired - Fee Related
- 2002-07-10 CA CA2452515A patent/CA2452515C/en not_active Expired - Fee Related
- 2002-07-10 US US10/484,745 patent/US7906127B2/en not_active Expired - Fee Related
- 2002-07-10 EP EP02743440A patent/EP1414304A1/en not_active Ceased
- 2002-07-10 WO PCT/GB2002/003181 patent/WO2003011031A1/en active Application Filing
- 2002-07-10 BR BRPI0211298-1B1A patent/BR0211298B1/en active IP Right Grant
- 2002-07-10 MX MX2013001959A patent/MX337223B/en unknown
- 2002-07-10 AU AU2002345228A patent/AU2002345228B2/en not_active Ceased
- 2002-07-10 CN CNA200610100338XA patent/CN101099472A/en active Pending
- 2002-07-10 EA EA200400221A patent/EA005502B1/en not_active IP Right Cessation
- 2002-07-10 CN CNB2005100976700A patent/CN1331395C/en not_active Expired - Lifetime
- 2002-07-10 AP APAP/P/2004/002964A patent/AP1669A/en active
- 2002-07-10 PL PL02366828A patent/PL366828A1/en unknown
- 2002-07-10 KR KR10-2004-7001085A patent/KR20040018509A/en not_active Application Discontinuation
- 2002-07-10 OA OA1200400008A patent/OA12644A/en unknown
- 2002-07-10 KR KR1020097004493A patent/KR20090031794A/en not_active Application Discontinuation
- 2002-07-10 MX MXPA04000661A patent/MXPA04000661A/en not_active Application Discontinuation
- 2002-07-10 CN CNA2008100991371A patent/CN101268782A/en active Pending
- 2002-07-10 CN CNB028146166A patent/CN100401893C/en not_active Expired - Lifetime
- 2002-07-10 CA CA2758173A patent/CA2758173C/en not_active Expired - Fee Related
- 2002-07-10 IL IL15982502A patent/IL159825A0/en unknown
- 2002-07-10 EP EP09005759A patent/EP2087791A3/en not_active Ceased
- 2002-07-10 CN CNB2005100994200A patent/CN100349519C/en not_active Expired - Lifetime
- 2002-07-10 EP EP10172169.4A patent/EP2260708A3/en not_active Withdrawn
- 2002-07-22 MY MYPI20022763A patent/MY135255A/en unknown
- 2002-07-23 AR ARP020102770A patent/AR034881A1/en not_active Application Discontinuation
- 2002-07-25 TW TW091116581A patent/TWI321037B/en not_active IP Right Cessation
-
2004
- 2004-01-12 IL IL159825A patent/IL159825A/en not_active IP Right Cessation
- 2004-01-22 ZA ZA200400490A patent/ZA200400490B/en unknown
- 2004-01-23 MA MA27498A patent/MA26129A1/en unknown
- 2004-02-24 CO CO04016166A patent/CO5560519A2/en active IP Right Grant
-
2008
- 2008-08-21 IL IL193603A patent/IL193603A/en not_active IP Right Cessation
-
2009
- 2009-12-08 US US12/633,063 patent/US8852618B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0237227A1 (en) * | 1986-03-13 | 1987-09-16 | Imperial Chemical Industries Plc | Insecticidal compositions |
| WO1993003618A2 (en) * | 1991-08-27 | 1993-03-04 | Uniroyal Chemical Company, Inc. | Insecticide compounds for agricultural and horticultural use |
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1331395C (en) | Insecticidal mixture containing gamma-cyhalothrin | |
| US10555520B2 (en) | Pesticide composition potentiated in efficacy and method for potentiating efficacy of pesticidal active ingredients | |
| JP5188974B2 (en) | Use of lactate esters to improve the effectiveness of pesticides | |
| AU2002345228A1 (en) | Insecticidal mixture containing gamma-cyhalothrin | |
| DE60203299T2 (en) | FUNGICIDAL COMPOSITION AND USE OF THIS COMPOSITION TO COMBAT PLANT DISEASES | |
| AU2012365434A1 (en) | Variable release water dispersible granule composition | |
| US8415273B2 (en) | Broadleaf perennial weed control agent for grass, and method for controlling broadleaf perennial weeds in grass | |
| DE60007165T2 (en) | PESTICIDES AND / OR PLANT GROWTH REGULATING COMPOSITIONS WITH NON-IONIC SURFACES | |
| CN102088844B (en) | Method for producing extended-release preparation composition | |
| AU2008200430B2 (en) | Insecticidal mixture containing gamma-cyhalothrin | |
| JPH10139604A (en) | Hygienic noxious insect expellent having no repellent effect | |
| JP2009531362A (en) | Penetration enhancers for pesticides | |
| TWI494060B (en) | Poaceous perennial weed control agent for grass, and poaceous perennial weed control method in grass | |
| JPH06192011A (en) | Composition for controlling soil disease damage | |
| JPH10101507A (en) | Composition for controlling blight by microorganisms | |
| KR20120115236A (en) | Stabilized aqueous suspended agricultural chemical composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20070815 |