CH689326A5 - Synergistic pesticidal composition containing pymetrozine - Google Patents

Abstract

A pesticidal composition contains: (a) pymetrozine of formula (I) or one of its salts; (b) a thiourea, benzoylurea, carbamoyl oxime, halocarboxylic acid, organophosphate, organochlorine derivative, nitroenamine, nitroguanidine, cyanoguanidine, carbamate, thiocarbamate, carbodiimide, formamidine, benzilic acid, dioxolane, thiadiazine, triazine, pyridazinone, pyrrole, phenoxyphenyl ether, sulphonamide, Bacillus thuringiensis preparation, milbemycin, avermectin or pyrethroid; and (c) adjuvant. (I) is known from EP 314615.

Description

The present invention relates to a pest control agent according to claim 1, a method for producing this agent according to claim 5 and the use of this agent in a method for controlling pests according to claim 6.

In the literature, certain mixtures of active ingredients for pest control are suggested. However, the biological properties of these known mixtures are not entirely satisfactory in the field of pest control, which is why there is a need to provide further mixtures with pest control properties, in particular for controlling insects and representatives of the Acarina order. This object is achieved according to the invention by providing the present agent.

The invention relates to a pesticide which is characterized in that it is a pesticidal combination of the compound of the formula

in free form or in the form of an agrochemically acceptable salt, and of one or more pesticidally active compound (s) which is (are) selected from the group of active substances consisting of the substance classes of thioureas, benzoylureas, carbamoyloximes, halogenated carboxylic acids, organophosphates , Organochlorine derivatives, nitroenamines, nitroguanidines, cyanoguanidines, carbamates, thiocarbamates, carbodiimides, formamidines, benzilic acid derivatives, dioxolanes, thiadiazine derivatives, asymmetrical triazines, symmetrical triazines, pyridazinones, pyrroles, phenoxyphenyl ethers, pyrroles-amides as active ingredients, baconermectic acid amides, phenoxyphenyl ethers, pyrroles-amides, phenoxyphenyl ethers, baconamides, and phenoxyphenyl ethers. and contains at least one excipient.

The pesticidally active compound 2,3,4,5-tetrahydro-3-oxo-4 - [(pyridin-3-yl) -methyleneamino] -6-methyl-1,2,4-triazine (pymetrozine) of the formula (A. ) and their production are known from EP-A 0 314 615, for example.

The agrochemically acceptable salts of the compound of the formula (A) are, for example, acid addition salts of inorganic and organic acids, in particular of hydrochloric acid, hydrobromic acid, sulfuric acid, nitric acid, perchloric acid, phosphoric acid, formic acid, acetic acid, trifluoroacetic acid, oxalic acid, malolonic acid, toluene sulfonic acid . In the context of the present invention, preference is given to agents which contain the compound of the formula (A) in free form.

Preference is given to an agent which, in addition to the compound of the formula (A), contains only one further pesticidally active compound as active ingredient.

Particularly preferred is an agent which, together with the compound of the formula (A) as a further pesticidally active compound either as an active ingredient

(I) 2-methyl-2- (methylthio) propionaldehyde O-methylcarbamoyloxime (Aldicarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 16; or

(II) S-6-chloro-2,3-dihydro-2-oxo-1,3-oxazolo [4,5-b] pyridin-3-ylmethyl O, O-dimethyl phosphorothioate (Azamethiphos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 44; or

(III) S-3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl O, O-Dimethyl Phophorodithioate (Azinphos-methyl), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 46; or

(IV) Ethyl N- [2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl (methyl) aminothio] -N-isopropyl-beta -alaninate (Benfuracarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 57; or

(V) 2-Methylbiphenyl-3-ylmethyl (Z) - (1RS) -cis -3- (2-chloro-3,3,3-trifluoroprop-1-enyl) -2,2-dimethylpropanecarboxylate (bifendrin) are known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, 73; or

(VI) 2-tert-Butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazian-4-one (buprofezin), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 105; or

(VII) 2,3-Dihydro-2,2-dimethylbenzofuran-7-yl methyl carbamate (carbofuran), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 126; or

(VIII) 2,3-Dihydro-2,2-dimethylbenzofuran-7-yl (Dibutylaminothio) methylcarbamate (Carbosulfan), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, 129; or

(IX) S, S min - (2-dimethylaminotrimethylene) bis (thiocarbamate) (Cartap), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 132; or

(X) 2-chloro-1- (2,4-dichlorophenyl) vinyl diethyl phosphate (chlorfenvinphos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 141; or

(XI) 1- [3,5-Dichloro-4- (3-chloro-5-trifluoromethyl-2-pyridyloxy) phenyl] -3- (2,6-difluorobenzoyl) urea (Chlorfluazuron), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, 143; or

(XII) O, O-Diethyl O-3,5,6-Trichloro-2-pyridyl Phosphorothioate (Chlorpyrifos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 166; or

(XIII) (RS) - alpha -Cyano-4-fluoro-3-phenoxybenzyl (1RS) -cis-trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (cyfluthrin), known from The Pesticide Manual , 9th Ed. (1991) The British Crop Protection Council, London, 198; or

(XIV) Lambda-Cyhalothrin, known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 203; or

(XV) (RS) - alpha -Cyano-3-phenoxybenzyl-cis-trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (cypermethrin, cypermethrin high-cis), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 208; or

(XVI) Racemate consisting of (S) - alpha -Cyano-3-phenoxybenzyl (1R) -cis-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxyla and (R) - alpha -Cyano-3phenoxybenzyl- ( 1S) -cis-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (alpha-cypermethrin), known from The Pesticide Manual, 9th Ed. (199 1) The British Crop Protection Council, London, p. 210; or

(XVII) N-Cyclopropyl-1,3,5-triazine-2,4,6-triamine (cyromazine), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 217; or

(XVIII) (S) - alpha -Cyano-3-phenoxybenzyl- (1R) -cis-3- (2,2-dibromovinyl) -2,2-dimethylcyclopropanecarboxylate (Deltamethrin), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 232; or

(XIX) 1-tert-butyl-3- (2,6-di-isopropyl-4-phenoxyphenyl) thiourea (diafenthiuron), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 240; or

(XX) O, O-Diethyl O-2-Isopropyl-6-methylpyrimidin-4-yl-phosphorothioate (Diazinon), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 243; or

(XXI) 2,2-dichlorovinyl dimethyl phosphate (dichlorvos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 259; or

(XXII) 1- (4-Chlorophenyl) -3- (2,6-difluorobenzoyl) urea (diflubenzuron), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 281; or

(XXIII) (1,4,5,6,7,7-Hexachloro-8,9,10-trinorborn-5-en-2,3-ylenebismethylene) sulfite (Endosulfan), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 332; or

(XXIV) alpha-ethylthio-o-tolyl methyl carbamate (Ethiofencarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 343; or

(XXV) O, O-dimethyl O-4-nitro-m-tolyl phosphorothioate (fenitrothion), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 369; or

(XXVI) 2-sec-Butylphenyl Methylcarbamate (Fenobucarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 371; or

(XXVII) Ethyl 2- (4-phenoxyphenoxy) ethylcarbamate (fenoxycarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 375; or

(XXVIII) (RS) - alpha -Cyano-3-phenoxybenzyl (RS) -2- (4-chlorophenyl) -3-methylbutyrate (fenvalerate), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 388; or

(XXIX) (RS) - alpha -Cyano-3-phenoxybenzyl N- (2-chloro- (alpha, alpha, alpha -trifluoro-p-tolyl) -D-valinate (tau-fluvalinate), known from The Pesticide Manual, 9th Ed. (1991), The British Crop Protection Council, London, p. 428; or

(XXX) S- [Formyl (methyl) carbamoylmethyl] O, O-Dimethyl Phosphorodithioate (Formothion), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 440; or

(XXXI) Butyl 2,3-dihydro-2,2-dimethylbenzofuran-7-yl N, N min -Dimethyl-N, N min -dithiocarbamate (furathiocarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 448; or

(XXXII) 7-chlorobicyclo [3.2.0] hepta-2,6-dien-6-yl dimethylphosphate (Heptenophos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 467; or

(XXXIIII) 1- (6-chloro-3-pyridylmethyl) -N-nitroimidazolidin-2-ylidenamine (Imidacloprid), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 491; or

(XXXIV) O-5-chloro-1-isopropyl-1H-1,2,4-triazol-3-yl O, O-diethyl phosphorothioate (Isazophos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 502; or

(XXXV) 2-Isopropylphenyl Methylcarbamate (Isoprocarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 504; or

(XXXVI) 1- (2,5-dichloro-4- [1,1,2,3,3,3-hexafluoroprop-1-oxy] phenyl) -3- (2,6-difluorobenzoyl) urea (Lufenuron), known from Med. Fac. Landbouww. Ghent, 57 / 3a (1992),

(XXXVII) Methyl (E) -3- (Dimethoxyphosphinothiolyloxy) -2-methylacrylate (Methacriphos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 562; or

(XXXVIII) O, S-Dimethyl Phosphoramidothioate (Methamidophos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 563; or

(XXXIX) S-2,3-Dihydro-5-methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl O, O-dimethyl phosphorodithioate (methidathione), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 567; or

(XXXX) S-Methyl N- (Methylcarbamoyloxy) thioacetimidate (Methomyl), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 570; or

(XXXXI) Methyl 3- (Dimethoxyphosphinoyloxy) but-2-enoate (Mevinphos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 592; or

(XXXXII) Dimethyl (E) -1-methyl-2- (methylcarbamoyl) vinyl phosphate (Monocrotophos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 597; or

(XXXXIII) O, O-Diethyl O-4-Nitrophenyl Phosphorothioate (Parathion), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 648; or

(XXXXIV) O, O-Dimethyl O-4-Nitrophenyl Phosphorothioate (Parathion-methyl), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 650; or

(XXXXV) S-6-Chloro-2,3-dihydro-2-oxo-1,3-benzoxazol-3-ylmethyl O, O-Diethyl Phosphorodithioate (Phosalone), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 674; or

(XXXXVI) 2-Chloro-2-diethylcarbamoyl-1-methylvinyl Dimethyl Phosphate (Phosphamidon), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 679; or

(XXXXVII) 2-Dimethylamino-5,6-dimethylpyrimidin-4-yl Dimethylcarbamate (Pirimicarb), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 690; or

(XXXXVIII) O-4-Bromo-2-chlorophenyl O-Ethyl S-Propyl Phosphorothioate (Profenofos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 705; or

(IL) 2-Isopropoxyphenyl Methylcarbamate (Propoxur), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, 727; or

(L) 1- (3,5-Dichloro-2,4-difluorophenyl) -3- (2,6-difluorobenzoyl) urea (Teflubenzuron), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 790; or

(LI) S-tert-Butylthiomethyl O, O-Diethyl Phosphorodithioate (Terbufos), known from The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, p. 795; or

(LII) ethyl (3-tert-butyl-1-dimethyl carbamoyl-1-H-1,2,4-triazol-5-yl-thio) acetate (RH-7988, triazamate), known from Proc. 1988 Br. Crop Prot. Conf.-Pest Dis. (1988), 2, 73; or

(LIII) a substance obtainable from a Bacillus thuringiensis strain, for example from strain GC 91 (NCTC 11821), known from EP-B 0 178 151; or

(LIV) a mixture of compounds known under the name Abamectin and described in The Pesticide Manual, 9th Ed. (1991) The British Crop Protection Council, London, page 5, or

(LV) Isopropyl 4,4 min -Dibromobenzilate (Bromopropylate), known from The Pesticide Manual 9th Ed. (1991) The British Crop Protection Council, London, p. 99; or

(LVI) a mixture of (S) - alpha -Cyano-3-phenoxybenzyl (1RS) 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate and (S) - alpha -Cyano-3-phenoxybenzyl (3RS) 3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (zeta-cypermethrin), known from The Pesticide Manual, 10th Ed. (1994), The British Crop Protection Council, London, p. 265 contains.

The active ingredient combination according to the invention contains the active ingredient of the formula (A) and one of the active ingredients I to LVI, preferably in a mixing ratio (weight ratio) of 1:50 to 50: 1, in particular in a ratio between 1 : 20 and 20: 1, especially between 10: 1 and 1:10, very especially between 5: 1 and 1: 5, especially preferably between 2: 1 and 1: 2, especially in a ratio of 1: 1, or 5: 1, or 5: 2, or 5: 3, or 5: 4, or 4: 1, or 4: 3, or 3: 1, or 3: 2, or 2: 1, or 1: 5, or 2: 5, or 3: 5, or 4: 5, or 1: 4, or 3: 4, or 1: 3, or 2: 3, or 1: 2.

It has now been found, surprisingly, that the combination of the active ingredient of the formula (A) with one or more of the active ingredients I to LVI not only causes an additive addition to the spectrum of activity to be expected on the pests to be controlled, but rather achieves a synergistic effect that extends the limits of action of both mixing partners under two aspects:

On the one hand, the application rates of the individual compounds (A) and I to LVI are reduced while maintaining the same good effect. On the other hand, the combined mixture also achieves a high degree of pest control where both individual substances have become completely ineffective in the range of too low application rates. This enables, on the one hand, a broadening of the spectrum of pests that can be controlled and, on the other hand, an increase in application security.

The agents according to the invention are preventively and / or curatively valuable in the field of pest control when they are favorably tolerated by warm-blooded animals, fish and plants even at low application concentrations and have a very favorable biocide Spectrum on. The agents according to the invention are effective against all or individual developmental stages of normally sensitive, but also resistant, animal pests such as insects and representatives of the Acarina order. The insecticidal and / or acaricidal effect of the agents according to the invention can be directly, i.e. in a mortification of the pests, which occurs immediately or only after some time, for example during hatching, or indirectly, e.g. in a reduced oviposition and / or hatching rate, show, the good effect corresponding to a mortality rate (mortality) of at least 50 to 60%.

The animal pests mentioned include, for example: from the order Lepidoptera, for example Acleris spp., Adoxophyes spp., Aegeria spp., Agrotis spp., Alabama argillaceae, Amylois spp., Anticarsia gemmatalis, Archips spp., Argyrotaenia spp., Autographa spp., Busseola fusca, Cadra cautella, Carposina nipponensis,. , Choristoneura spp., Clysia ambiguella, Cnaphalocrocis spp., Cnephasia spp., Cochylis spp., Coleophora spp., Crocidolomia binotalis, Cryptophlebia leucotreta, Cydia spp., Diatraea spp., Ephasis spp., Ephasis spp., Diparopsis spp spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Grapholita spp., Hedya nubiferana, Heliothis spp., Hellula undalis, Hyphantria cunea, Keiferia lycopersicella, Leucoptera scitella, Lithocollethis spp., Lobesia botetria spp., Lobesia botetrana ., Malacosoma spp., Mamestra brassicae, Manduca sexta, Operophtera spp., Ostrinia nubilalis, Pammene spp., Pandemis spp., Panolis flammea, Pectinophora gossypiella, Phthorimaea operculella, Pieris xy rapae, Pieris sppayslop., Plutella xy rapaestell Scirpophaga spp., Sesamia spp., Sparganothis spp., Spodoptera spp., Synanthedon spp., Thaumetopoea spp., Tortrix spp., Trichoplusia ni and Yponomeuta spp .; from the order Coleoptera, for example Agriotes spp., Anthonomus spp., Atomaria linearis, Chaetocnema tibialis, Cosmopolites spp., Curculio spp., Dermestes spp., Diabrotica spp., Epilachna spp., Eremnus spp., Leptinotarsa decemlineata. Melolontha spp., Lissorhoptrus spp spp., Otiorhynchus spp., Phlyctinus spp., Popillia spp., Psylliodes spp., Rhizopertha spp., Scarabeidae, Sitophilus spp., Sitotroga spp., Tenebrio spp., Tribolium spp. and Trogoderma spp .; from the order Orthoptera, for example Blatta spp., Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Periplaneta spp. and Schistocerca spp .; from the order Isoptera, for example Reticulitennes spp .; from the order Psocoptera, for example Liposcelis spp .; from the order Anoplura, for example Haematopinus spp., Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp .; from the order Mallophaga, for example Damalinea spp. and Trichodectes spp .; from the order Thysanoptera, for example Frankliniella spp., Hercinothrips spp., Taeniothrips spp., Thrips palmi, Thrips tabaci and Scirtothrips aurantii; from the order Heteroptera, for example Cimex spp., Distantiella theobroma, Dysdercus spp., Euchistus spp. Eurygaster spp. Leptocorisa spp., Nezara spp., Piesma spp., Rhodnius spp., Sahlbergella singularis, Scotinophara spp. and Triatoma spp .; from the order Homoptera, for example Aleurothrixus floccosus, Aleyrodes brassicae, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Bemisia tabaci, Ceroplaster spp., Chrysomphalus aonidium, Chrysomphalus dictyospermi, Coccus hesperytum. Erascardia sp., Erascardia sp. , Laodelphax spp., Lecanium corni, Lepidosaphes spp., Macrosiphus spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Paratoria spp .; Pemphigus spp., Planococcus spp., Pseudaulacaspis spp., Pseudococcus spp., Psylla spp., Pulvinaria aethiopica, Quadraspidiotus spp., Rhopalosiphum spp., Saissetia spp., Scaphoideus spp., Trials spp. Trioza erytreae and Unaspis citri; from the order Hymenoptera, for example Acromyrmex, Atta spp., Cephus spp., Diprion spp., Diprionidae, Gilpinia polytoma, Hoplocampa spp., Lasius spp., Monomorium pharaonis, Neodiprion spp., Solenopsis spp. and Vespa spp .; from the order Diptera, for example Aedes spp., Antherigona soccata, Bibio hortulanus, Calliphora erythrocephala, Ceratitis spp., Chrysomyia spp., Culex spp., Cuterebra spp., Dacus spp., Drosophila melanogaster, Fannia spp., Gastrophilus spp., Glossina spp ., Hyppobosca spp., Liriomyza spp., Lucilia spp., Melanagromyza spp., Musca spp., Oestrus spp., Orseolia spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Rhagoletis pomonella, Sciara spp., Stomoxys spp. , Tabanus spp., Tannia spp. and Tipula spp .; from the order Siphonaptera, for example Ceratophyllus spp. and Xenopsylla cheopis; from the order Thysanura, for example Lepisma saccharina and from the order Acarina, for example Acarus siro, Aceria sheldoni, Aculus badendali, Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Calipitrimerus spp., Chorioptes spp., Dermanyssus gallinae, Eotetranychus carpinip., Eriophalyes spp., Eriophalyes spp. Ixodes spp., Olygonychus pratensis, Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Tarsonemus. and Tetranychus spp.

However, within the scope of the subject matter of the invention, pests of the order Homoptera, in particular (1) insects of the family Aleyrodidae, in particular of the genera Bomisia and Trialeurodes; (2) insects of the family Cicadellidae, in particular of the genera Empoasca and Erythroneura; (3) insects of the Delphacidae family, in particular of the genera Laodelphax and Nilaparvata, in particular of the species Laodelphax striatellus and Nilaparvata lugens; (4) Insects of the Aphididae family, especially of the genera Aphis, Mycus, Acyrthosiphon, Brachycaudus, Brevicoryne, Dysaphis, Hyalopterus, Macrosiphum, Phorodon, Rhopalosiphum, Sappaphis, Schizaphis and Toxoptera, especially of the genera Aphis, Mycus, Macrosiphum, Phorodon, Sappaphis, Schizaphis and Toxoptera, preferably of the genera Aphis, Mycus, Brevicoryne, Hyalopterus, Macrosiphum, Phorodon and Toxoptera, in particular of the species Brevicoryne brassicae, Hyalopterus amygdali, Macrosiphum euphorbiae, Phorodon humuli, Toxoptera aurantii, Toxoptera citricida, Mycus persicae, Aphis craccivora, Aphis fabae and Aphis gossypii; (5) insects of the species Aphis craccivora, Aphis fabae and Aphis gossypii; or (6) insects selected from the group of insects consisting of (a) Acyrthosiphon pisum; (b) Aphis gossypii; (c) Aphis craccivora; (d) Bemisia tabaci; (e) Brachycaudus persicaecola; (f) Brevicoryne brassicae; (g) Dysaphis devecta; (h) Dysaphis plantaginea; (i) Empoasca flavescens; (j) Erythroneura apicalis; (k) Hyalopterus amygdali; (l) Laodelphax striatellus; (m) Macrosiphum avenae; (n) Macrosiphum euphorbiae; (o) Macrosiphum rosae; (p) Nilaparvata lugens; (q) Phorodon humuli; (r) Rhopalosiphum insertum; (s) Rhopalosiphum padi; (t) Rhopalosiphum pseudobrassicae; (u) Sappaphis piricola; (v) Schizaphis graminum; (w) Toxoptera aurantii; (x) Toxoptera citricida; (y) Trialeurodes vaporariorum, (z) Mycus persicae and (aa) Aphis fabae are combated.

The active ingredient mixtures according to the invention can be used, in particular, on plants, especially useful and ornamental plants in agriculture, horticulture and forestry, or on parts such as fruits, flowers, foliage, stems, tubers or roots, fighting pests of the type mentioned occurring in such plants, ie contain or destroy, whereby plant parts that grow later are also protected against these pests.

The active ingredient mixture according to the invention can advantageously be used for pest control in cereals, such as wheat, barley, rye, oats, rice, maize or sorghum; in beets, such as sugar beets or fodder beets; in fruit, e.g. Pome, stone and soft fruit, such as apples, pears, plums, peaches, almonds, cherries or berries, e.g. Strawberries, raspberries and blackberries; in legumes such as beans, lentils, peas or soy; in fruits such as rapeseed, mustard, poppy seeds, olives, sunflowers, coconut, castor, cocoa or peanuts; in cucumber plants such as kebabs, cucumbers or melons; in fibers such as cotton, flax, hemp or jute; in citrus fruits, such as oranges, lemons, grapefruits or mandarins; in vegetables such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes or peppers; in laurel plants such as avocado, cinnamonium or camphor; or in tobacco, nuts, coffee, eggplant, sugar cane, tea, pepper, grapevines, hops, banana plants, natural rubber plants or ornamental plants, especially in cereals, fruit, legumes, cucumber plants , Cotton, citrus fruits, vegetables, egg fruits, vines, hops or ornamental plants, especially in peaches, beans, peas, cucumbers, citrus fruits, cabbage types, tomatoes, potatoes or egg fruits, especially in peaches, Cucumbers, tomatoes or potatoes.

Further fields of application of the active ingredient mixtures according to the invention are the protection of supplies and stores and of material and, in the hygiene sector, in particular the protection of domestic animals and farm animals from pests of the type mentioned.

The pest control agents according to the invention are emulsifiable concentrates, suspension concentrates, directly sprayable or dilutable solutions, spreadable pastes, diluted emulsions, wettable powders, depending on the desired goals and given conditions Soluble powders, dispersible powders, wettable powders, dusts, granulates or encapsulations in polymeric substances which contain the compound of the formula (A) and one or more active ingredients I to LVI.

The active ingredients are in pure form in these agents, the solid active ingredients e.g. in a special particle size, or preferably together with - at least - one of the auxiliaries customary in formulation technology, such as extenders, e.g. Solvents or solid carriers, or such as surface-active compounds (surfactants), are used.

As a solvent, e.g. Possible are: Optionally partially hydrogenated aromatic hydrocarbons, preferably the fractions C8 to C12 of alkylbenzenes, such as xylene mixtures, alkylated naphthalenes or tetrahydronaphthalene, aliphatic or cycloaliphatic hydrocarbons, such as paraffins or cyclohexane, alcohols such as ethanol, propanol or butanol, glycols, and glycols and esters, such as propylene glycol, dipropylene glycol ether, ethylene glycol or ethylene glycol monomethyl or ethyl ether, ketones such as cyclohexanone, isophorone or diacetone alcohol, strongly polar solvents such as N-methylpyrrolid-2-one, dimethyl sulfoxide or N, N-dimethylformamide , Water, optionally epoxidized vegetable oils, such as optionally epoxidized rapeseed, castor, coconut or soybean oil, and silicone oils.

As solid carriers, e.g. For dusts and dispersible powders, natural rock flour is usually used, such as calcite, talc, kaolin, montmorillonite or attapulgite. To improve the physical properties, highly dispersed silicic acids or highly dispersed absorbent polymers can also be added. Porous types such as pumice stone, broken bricks, sepiolite or bentonite are possible as crowned, adsorptive granulate carriers, and calcite or sand as non-sorptive carrier materials. In addition, a large number of granulated materials of inorganic or organic nature can be used, in particular dolomite or comminuted plant residues.

Suitable surface-active compounds, depending on the type of active ingredient to be formulated, are nonionic, cationic and / or anionic surfactants or surfactant mixtures with good emulsifying, dispersing and wetting properties. The surfactants listed below are only to be regarded as examples; In the relevant literature, many other surfactants customary in formulation technology and suitable according to the invention are described.

Suitable nonionic surfactants are primarily polyglycol ether derivatives of aliphatic or cycloaliphatic alcohols, saturated or unsaturated fatty acids and alkylphenols, which have 3 to 30 glycol ether groups and 8 to 20 carbon atoms in the (aliphatic) hydrocarbon radical and 6 to 18 carbon atoms in the May contain alkyl radicals of the alkylphenols. Also suitable are water-soluble polyethylene oxide adducts containing 20 to 250 ethylene glycol ether groups and 10 to 100 propylene glycol ether groups with polypropylene glycol, ethylene diamino polypropylene glycol and alkyl polypropylene glycol with 1 to 10 carbon atoms in the alkyl chain. The compounds mentioned usually contain 1 to 5 ethylene glycol units per propylene glycol unit. Examples are nonylphenol polyethoxyethanols, castor oil polyglycol ethers, polypropylene-polyethylene oxide adducts, tributylphenoxypolyethoxyethanol, polyethylene glycol and octylphenoxypolyethoxyethanol. Fatty acid esters of polyoxyethylene sorbitan, such as polyoxyethylene sorbitan trioleate, are also suitable.

The cationic surfactants are primarily quaternary ammonium salts which have at least one alkyl radical with 8 to 22 carbon atoms as substituents and lower, optionally halogenated, alkyl, benzyl or lower hydroxyalkyl radicals as further substituents. The salts are preferably in the form of halides, methyl sulfates or ethyl sulfates. Examples are stearyl trimethyl ammonium chloride and benzyl di (2-chloroethyl) lauryl ammonium bromide.

Suitable anionic surfactants can be both water-soluble soaps and water-soluble synthetic surface-active compounds. Suitable soaps are the alkali, alkaline earth and optionally substituted ammonium salts of higher fatty acids (C10-C22), such as the sodium or potassium salts of l- or stearic acid, or of natural fatty acid mixtures, for example from coconut or tall oil can be won; the fatty acid methyl taurine salts should also be mentioned. However, synthetic surfactants are used more frequently, in particular fatty sulfonates, fatty sulfates, sulfonated benzimidazole derivatives or alkylarylsulfonates. The fatty sulfonates and sulfates are generally in the form of alkali, alkaline earth or optionally substituted ammonium salts and generally have an alkyl radical having 8 to 22 carbon atoms, alkyl also including the alkyl part of acyl radicals; Examples include the sodium or calcium salt of ligninsulphonic acid, dodecylsulphuric acid ester or a fatty alcohol sulphate mixture produced from natural fatty acids. This subheading also includes the salts of sulfuric acid esters and sulphonic acids of fatty alcohol-ethylene oxide adducts. The sulfonated benzimidazole derivatives preferably contain 2 sulfonic acid groups and one fatty acid residue with about 8 to 22 carbon atoms. Examples of alkylarylsulfonates are the sodium, calcium or triethanolammonium salts of dodecylbenzenesulfonic acid, dibutylnaphthalenesulfonic acid or a naphthalenesulfonic acid-formaldehyde condensation product. Corresponding phosphates, such as salts of the phosphoric acid ester of a p-nonylphenol- (4-14) -ethylene oxide adduct or phospholipids, are also suitable.

The agents generally contain 0.1 to 99%, in particular 0.1 to 95%, of a mixture of the active ingredient of the formula (A) with one or more of the active ingredients I to LVI, and 1 to 99.9%, in particular 5 up to 99.9%, - at least - of a solid or liquid auxiliary substance, where as a rule 0 to 25%, in particular 0.1 to 20%, of the agents can be surfactants (% in each case means percent by weight). While concentrated agents are preferred as commercial goods, the end user generally uses dilute agents which have significantly lower concentrations of active ingredient. Preferred agents are composed as follows (% = percent by weight): <TABLE> Columns = 2 Emulsifiable concentrates Active ingredient mixture: 1 to 90%, preferably 5 to 20% Surfactant: 1 to 30%, preferably 10 to 20% Solvent: 5 to 98 %, preferably 70 to 85% </TABLE> <TABLE> Columns = 2 dusts: Mixture of active ingredients: 0.1 to 10%, preferably 0.1 to 1% solid carrier: <CEL AL = L> 99.9 to 90% , preferably 99.9 to 99% </TABLE> <TABLE> Columns = 2 suspension concentrates: Mixture of active ingredients: 5 to 75%, preferably 10 to 50% Water: <CEL AL = L> 94 to 24%, preferably 88 to 30% Surfactant: 1 to 40%, preferably 2 to 30% </TABLE> <TABLE> Columns = 2 Wettable powders: Active ingredient mixture: 0.5 to 90%, preferably 1 to 80% Surfactant: 0.5 to 20%, preferably 1 Up to 15% solid carrier: 5 to 99%, preferably 15 to 98% Columns = 2 granules: Active ingredient mixture: 0.5 to 30%, preferably 3 to 15% solid carrier: <CEL AL = L > 99.5 to 70%, preferably se 97 to 85% </TABLE>

The agents according to the invention can also contain other solid or liquid auxiliaries, such as stabilizers, e.g. optionally epoxidized vegetable oils (e.g. epoxidized coconut oil, rapeseed oil or soybean oil), defoamers, e.g. Silicone oil, preservatives, viscosity regulators, binders and / or adhesives, as well as fertilizers or other active ingredients to achieve special effects, e.g. Bactericides, fungicides, nematicides, molluscicides or herbicides.

The agents according to the invention are prepared in a known manner, in the absence of auxiliaries e.g. by grinding, sieving and / or pressing a solid active ingredient or active ingredient mixture, e.g. to a certain grain size, and in the presence of at least one auxiliary e.g. by intimately mixing and / or grinding the active ingredient or active ingredient mixture with the auxiliary substance (s). The process for producing the agents is therefore a further subject of the invention.

The methods of application for the agents, that is to say the methods of combating pests of the type mentioned, such as spraying, misting, dusting, brushing, pickling, scattering or pouring, and the use of the agents for combating, depending on the desired goals and given circumstances Pests of the type mentioned are further objects of the invention. Typical use concentrations are between 0.1 and 1000 ppm, preferably between 0.1 and 500 ppm, of active ingredient. The application rate can vary within wide ranges and depends on the nature of the soil, the type of application (foliar application; seed dressing; application in the seed furrow), the cultivated plant, the pest to be controlled, the prevailing climatic conditions and others through the type of application, application time and Target culture depends on certain factors. The application rates per hectare are in general from 1 to 2000 g of active ingredient per hectare, in particular from 10 to 1000 g / ha, preferably from 20 to 600 g / ha.

A preferred method of application in the field of crop protection is application to the foliage of the plants (foliar application), the frequency and rate of application being able to be tailored to the pressure of the pest in question. The active ingredients can also get into the plants through the root system (systemic effect) by soaking the location of the plants with a liquid agent or by soaking the active ingredients in solid form in the location of the plants, e.g. into the soil, e.g. in the form of granules (floor application). In the case of water rice cultures, such granules can be added to the flooded rice field.

The agents according to the invention are also suitable for protecting plant propagation material, e.g. Seeds, such as fruits, tubers or grains, or plant cuttings, against animal pests. The reproductive material can be treated with the agent prior to application, seeds e.g. must be dressed before sowing. The active ingredients according to the invention can also be applied to seeds (coating) by either soaking the seeds in a liquid agent or coating them with a solid agent. The agent can also be used when applying the propagation material to the place of application, e.g. when sowing in the seed furrow. These treatment methods for plant reproductive material and the plant reproductive material treated in this way are further objects of the invention.

The following examples serve to illustrate the invention. They do not limit the invention.

Formulation examples (% = Weight percent, active ingredient ratios = weight ratios)

<TABLE> Columns = 4 Head Col 1: Example F1: Emulsion concentrates Head Col 2: a) Head Col 3: b) Head Col 4: c) Mixture of active substances (ratio of the compound of the formula (A) to a compound I to LVI = 1: 1) 25% 40% 50% calcium dodecylbenzenesulfonate 5% <CEL AL = L> 8% 6% castor oil polyethylene glycol ether (36 mol EO) 5% - (SEP) <-> (TB> <CEL AL = L> Tributylphenol polyethylene glycol ether (30 mol EO) - 12% 4% cyclohexanone - <CEL AL = L> 15% 20% xylene mixture 65% 25% 20% </TABLE>

Emulsions of any desired concentration can be prepared from such concentrates by dilution with water. <TABLE> Columns = 5 Head Col 1: Example F2: Solutions Head Col 2: a) Head Col 3: b) Head Col 4: c) Head Col 5: d) Mixture of active ingredients (1: 2) 80% 10% 5% 95% <CEL AL = L> ethylene glycol monomethyl ether 20% - - (SEP) <-> (TB> polyethylene glycol MG 400 <CEL AL = L> - 70% - (SEP) <-> (TB> N-methyl-2- pyrrolidon - 20% - <CEL AL = L> - <CEL AL = L> Epoxidized coconut oil - - 1% 5% petrol (boiling point 160-190 DEG C) <CEL AL = L> - - 94% - </TABLE>

The solutions are suitable for use in the form of tiny drops. <TABLE> Columns = 5 Head Col 1: Example F3: Granules Head Col 2: a) Head Col 3: b) Head Col 4: c) Head Col 5: d) Mixture of active ingredients (2: 1) 2% 10% 8% 21% <CEL AL = L> Kaolin <CEL AL = L> 94% - 79% 54% Highly dispersed silica 3% - 13% <CEL AL = L> 7% Attapulgite 1 90% - 18% </TABLE>

The active ingredients are dissolved together in dichloromethane, sprayed onto the carrier and the solvent is then evaporated off in vacuo. <TABLE> Columns = 3 Head Col 1: Example F4: Dust Head Col 2: a) Head Col 3: b) Active ingredient mixture (1: 1) 2% 5% Highly disperse silica <CEL AL = L> 1% <CEL AL = L> 5% talc 97% (SEP) <-> (TB> kaolin - 90% </TABLE>

By intimately mixing the carrier substances with the active ingredients, ready-to-use dusts are obtained. <TABLE> Columns = 4 Head Col 1: Example F5: Wettable powder Head Col 2: a) Head Col 3: b) Head Col 4: c) Active ingredient mixture (1: 3) 25% 50% 75% <CEL AL = L> Na lignin sulfonate <CEL AL = L> 5% 5% (SEP) <-> (TB> Na lauryl sulfate 3% - 5% <CEL AL = L> Na diisobutylnaphthalene sulfonate - 6% 10% octylphenol polyethylene glycol ether (7-8 mol EO) - 2% (SEP) <-> (TB> Highly disperse silica 5% 10% 10% <CEL AL = L> Kaolin 62% 27% - </TABLE>

The active ingredients are mixed with the additives and ground well in a suitable mill. Wettable powders are obtained which can be diluted with water to form suspensions of any desired concentration. <TABLE> Columns = 2 Head Col 1: Example F6: Emulsion concentrate active ingredient mixture (1: 4) 10% <CEL AL = L> Octylphenol polyethylene glycol ether (4-5 mol EO) 3% Ca-dodecylbenzenesulfonate 3% <CEL AL = L > Castor oil polyglycol ether (36 mol EO) 4% cyclohexanone 30% xylene mixture <CEL AL = L> 50% </TABLE>

This concentrate can be diluted with water to produce emulsions of any desired concentration. <TABLE> Columns = 3 Head Col 1: Example F7: Dust Head Col 2: a) Head Col 3: b) Active ingredient mixture (1: 1) 5% (SEP) <-> (TB> Talc 95% <CEL AL = L> 92% <CEL AL = L> Kaolin - 92% </TABLE>

Ready-to-use dusts are obtained by mixing the active ingredients with the carrier and grinding them in a suitable mill. <TABLE> Columns = 2 Head Col 1: Example F8: Extruder granulate mixture of active ingredients (3: 1) 10% <CEL AL = L> Na lignin sulfonate <CEL AL = L> 2% carboxymethyl cellulose 1% kaolin 87% </ TABLE >

The active ingredients are mixed with the additives, ground and moistened with water. This mixture is extruded, granulated and then dried in a stream of air. <TABLE> Columns = 2 Head Col 1: Example F9: Coating granulate, active ingredient mixture (4: 1) 3% <CEL AL = L> Polyethylene glycol (MG 200) 3% Kaolin 94% </TABLE>

The finely ground active ingredients are evenly applied in a mixer to the kaolin moistened with polyethylene glycol. In this way, dust-free coating granules are obtained. <TABLE> Columns = 2 Head Col 1: Example F10: Suspension concentrate mixture of active ingredients (1: 1) 40% <CEL AL = L> ethylene glycol <CEL AL = L> 10% nonylphenol polyethylene glycol ether (15 mol EO) 6% sodium lignin sulfonate 10% carboxymethyl cellulose 1% 37% aqueous formaldehyde solution 0.2% silicone oil in the form of a 75% aqueous emulsion 0.8% <CEL AL = L> water 32% </TABLE>

The finely ground active ingredients are intimately mixed with the additives. This gives a suspension concentrate from which suspensions of any desired concentration can be prepared by diluting with water.

It is often more practical to formulate the active ingredient of the formula (A) and one or more of the mixing partners I to LVI individually and then bring them together in the desired mixing ratio as a "tank mix" in the water shortly before application in the applicator.

Biological examples (% = Percent by weight, unless otherwise stated)

A synergistic effect is always present when the effect of the combination of the active substance of the formula (A) with one or more of the active substances I to LVI is greater than the sum of the effect of the active substances applied individually.

For example, the expected pesticidal effect We can be calculated for a given combination of two pesticides as follows (cf. COLBY, S.R., "Calculating synergistic and antagonistic response of herbicide combinations", Weeds 15, pages 20-22, 1967):

Mean:

X = percent mortality on treatment with the compound of the formula (A) with p kg application rate per hectare compared to the untreated control (= 0%). Y = percent mortality after treatment with a compound up to LVI with q kg application rate per hectare compared to the untreated control. We = expected pesticidal effect (percent mortality compared to the untreated control) after treatment with the compound of the formula (A) and a compound 1 to LVI at an application rate of p + q kg of active ingredient per hectare.

If the actually observed effect is greater than the expected value We, then there is synergism.

The synergistic effect of the combinations of the active ingredient of the formula (A) with one of the active ingredients I to LVI is demonstrated in the following examples.

Example B1: Action against Bemisia tabaci

Bush bean plants are placed in gauze cages and colonized with adults of Bemisia tabaci. After oviposition, all adults are removed. 10 days later, the plants with the nymphs on them are sprayed with an aqueous suspension spray mixture which contains 50 ppm of active ingredient. After a further 14 days, the hatching percentage of the eggs is evaluated in comparison to untreated control batches. In this experiment, the combinations of the active ingredient of the formula (A) with one of the active ingredients 1 to LVI show a synergistic effect.

Example B2: Action against Nilaparvata lugens

Rice plants two weeks old are treated with an aqueous suspension spray liquor containing 50 ppm of the active ingredient mixture. After the spray coating has dried on, the plants are populated with nymphs of Nilaparvata lugens and then left to stand at 28 ° for 14 days. The evaluation then takes place. By comparing the number of freshly hatched nymphs of the next generation on the treated and on untreated plants, the percentage reduction in the next generation (% activity) is determined.

In this experiment, the combinations of the active ingredient of the formula (A) with one of the active ingredients I to LVI show a synergistic effect.

Example B3: Pickling effect against Nilaparvata lugens

A glass bottle or a plastic container is filled with 100 g of rice seeds and enough of a formulation of the active ingredient mixture that a ratio of 0.1, 1 or 10 g of active ingredient mixture per kg of seeds is achieved. By rotating and / or shaking the container, the active ingredient is distributed evenly on the surface of the seeds. The seeds dressed in this way are sown in flower pots. After emergence, the young plants are cultivated in a greenhouse for 2 weeks and then populated in Plexiglas cylinders with 20 nymphs (N-3) each by Nilaparvata lugens. The cylinders are closed with a net. Evaluation takes place 5 days after colonization. The percentage reduction in population (% activity) is determined from the comparison of the number of surviving individuals on the plants grown from the dressed seeds and on plants grown from non-dressed seeds. In this experiment, the combinations of the active ingredient of the formula (A) with one of the active ingredients 1 to LVI show a synergistic effect.

Example B4: Pickling effect against Aphis fabae

A glass bottle or a plastic container is filled with 100 g of bean seeds and enough of a formulation of the active ingredient mixture that a ratio of 0.1, 1 or 10 g of active ingredient mixture per kg of seeds is achieved. By rotating and / or shaking the container, the active ingredients are distributed evenly on the surface of the seeds. The seeds dressed in this way are sown in flower pots (3 seeds per pot). The young plants are cultivated in a greenhouse at 25 to 30 ° to the 2-leaf stage and then colonized with Aphis fabae. The evaluation takes place 6 days after the colonization. The percentage reduction in population (% activity) is determined from the comparison of the number of surviving individuals on the plants grown from the dressed seeds and on plants grown from non-dressed seeds. In this experiment, the combinations of the active ingredient of the formula (A) with one of the active ingredients I to LVI show a synergistic effect.

Example B5: Pickling effect against Myzus persicae

A glass bottle or a plastic container is filled with 100 g of sugar beet seeds and enough of a paste formulation of the active ingredient mixture made from a wettable powder and a little water that a ratio of 0.1, 1 or 10 g of active ingredient mixture per kg of seeds is achieved. The sealed dressing vessel is moved on a roller bench until the paste has spread evenly over the surface of the seeds. The seeds so dressed (coated) are dried and sown in loess soil in plastic pots. The seedlings are cultivated in a greenhouse at 24 to 26 °, a relative humidity of 50 to 60% and an illumination period of 14 hours a day. 4 weeks after germination, the 10 cm high plants are colonized with a mixed population of Myzus persicae. Evaluation is carried out 2 and 7 days after colonization. The percentage reduction in population (% activity) is determined from the comparison of the number of surviving individuals on the plants grown from the dressed seeds and on plants grown from non-dressed seeds. In this experiment, the combinations of the active ingredient of the formula (A) with one of the active ingredients I to LVI show a synergistic effect.

Claims (7)

1. Pesticide, characterized in that it is a pesticidal combination of the compound of the formula in free form or in the form of an agrochemically acceptable salt, and of one or more pesticidally active compound (s), which is (are) selected from the group of active substances consisting of the substance classes of thioureas, benzoylureas, carbamoyloximes, halogenated Carboxylic acids, organophosphates, organochlorine derivatives, nitroenamines, nitroguanidines, cyanoguantdines, carbamates, thiocarbamates, carbodiimides, formamidines, benzilic acid derivatives, dioxolanes, thiadiazine derivatives, unsymmetrical triazines, symmetrical triazines, milidazinis-sulfonic acids, pyrrolesic ethers, bacamethro-phenylethers, bacamethro-phenyl ethers, bacamshenyl ethers, bacamethroids, bacamethroids, pyrrole, phenroles, baconamethroids, bacams, pyrrole, phenolic ethers as an active ingredient, as well as at least one excipient. 2. Agent according to claim 1, characterized in that it contains the compound of the formula (A) in free form. 3. Agent according to claim 2, characterized in that it contains only one further pesticidally active compound as an active ingredient in addition to the compound of the formula (A). 4. Agent according to claim 3, characterized in that it is either as an active ingredient together with the compound of the formula (A) as a further pesticidally active compound (I) 2-methyl-2- (methylthio) propionaldehyde, O-methylcarbamoyloxime (aldicarb); or (II) S-6-chloro-2,3-dihydro-2-oxo-1,3-oxazolo [4,5-b] pyridin-3-ylmethyl O, O-dimethyl phosphorothioate (Azamethiphos); or (III) S-3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl O, O-dimethyl phosphorodithioate (azinphos-methyl); or (IV) ethyl N- [2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl (methyl) aminothio] N-isopropyl-beta-alaninate (benfuracarb); or (V) 2-methylbiphenyl-3-ylmethyl (Z) - (1RS) -cis -3- (2-chloro-3,3,3-trifluoroprop-1-enyl) -2,2-dimethylpropanecarboxylate (bifenthrin); or (VI) 2-tert-butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazian-4-one (buprofezin); or (VII) 2,3-dihydro-2,2-dimethylbenzofuran-7-yl methyl carbamate (carbofuran); or (VIII) 2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylaminothio) methylcarbamate (carbosulfan); or (IX) S, S min - (2-dimethylaminotrimethylene) bis (thiocarbamate) (Cartap); or (X) 2-chloro-1- (2,4-dichlorophenyl) vinyl diethyl phosphate (chlorfenvinphos); or (XI) 1- [3,5-dichloro-4- (3-chloro-5-trifluoromethyl-2-pyridyloxy) phenyl] -3- (2,6-difluorobenzoyl) urea (chlorfluazuron); or (XII) O, O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos); or (XIII) (RS) -alpha-cyano-4-fluoro-3-phenoxybenzyl (1RS) -cis-trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (cyfluthrin); or (XIV) lambda cyhalothrin; or (XV) (RS) -alpha-cyano-3-phenoxybenzyl-cis-trans-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (cypermethrin, cypermethrin high-cis); or (XVI) Racemate consisting of (S) - alpha -Cyano-3-phenoxybenzyl- (1R) -cis-3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxy and (R) - alpha -Cyano-3- phenoxybenzyl- (1S) -cis -3- (2,2-dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate (alpha-cypermethrin); or (XVII) N-Cyclopropyl-1,3,5-triazine-2,4,6-triamine (cyromazine); or (XVIII) (S) -alpha-cyano-3-phenoxybenzyl- (1R) -cis -3- (2,2-dibromovinyl) -2,2-dimethylcyclopropanecarboxylate (deltamethrin); or (XIX) 1-tert-butyl-3- (2,6-di-isopropyl-4-phenoxyphenyl) thiourea (diafenthiuron); or (XX) O, O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl-phosphorothioate (diazinon); or (XXI) 2,2-dichlorovinyl dimethyl phosphate (dichlorphos); or (XXII) 1- (4-chlorophenyl) -3- (2,6-difluorobenzoyl) urea (diflubenzuron); or (XXIII) (1,4,5,6,7,7-hexachloro-8,9,10-trinorborn-5-en-2,3-ylenebismethylene) sulfite (endosulfan); or (XXIV) alpha -ethylthio-o-tolyl methyl carbamate (Ethiofencarb); or (XXV) O, O-dimethyl O-4-nitro-m-tolyl phosphorothioate (fenitrothion); or (XXVI) 2-sec-butylphenyl methylcarbamate (fenobucarb); or (XXVII) ethyl 2- (4-phenoxyphenoxy) ethyl carbamate (fenoxycarb); or (XXVIII) (RS) -alpha-cyano-3-phenoxybenzyl (RS) -2- (4-chlorophenyl) -3-methylbutyrate (fenvalerate); or (XXIX) (RS) -alpha-cyano-3-phenoxybenzyl N- (2-chloro-alpha, alpha, alpha-trifluoro-p-tolyl) -D-valinate (tau-fluvalinate); or (XXX) S- [formyl (methyl) carbamoylmethyl] O, O-dimethyl phosphorodithioate (formothione); or (XXXI) butyl 2,3-dihydro-2,2-dimethylbenzofuran-7-yl N, N min = dimethyl-N, N min -dithiocarbamate (furathiocarb); or (XXXII) 7-chlorobicyclo [3.2.0] hepta-2,6-dien-6-yl dimethylphosphate (Heptenophos); or (XXXIII) 1- (6-chloro-3-pyridylmethyl) -N-nitroimidazolidin-2-ylidenamine (imidacloprid); or (XXXIV) O-5-chloro-1-isopropyl-1H-1,2,4-triazol-3-yl O, O-diethyl phosphorothioate (Isazophos); or (XXXV) 2-isopropylphenyl methylcarbamate (Isoprocarb); or (XXXVI) 1- (2,5-dichloro-4- [1,1,2,3,3,3-hexafluoroprop-1-oxy] phenyl) -3- (2,6-difluorobenzoyl) urea (Lufenuron); or (XXXVII) methyl (E) -3- (dimethoxyphosphinothiolyloxy) -2-methyl acrylate (Methacriphos); or (XXXVIII) O, S-dimethyl phosphoramidothioate (methamidophos); or (XXXIX) S-2,3-Dihydro-5-methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl O, O-dimethyl phosphorodithioate (methidathione); or (XXXX) S-methyl N- (methylcarbamoyloxy) thioacetimidate (methomyl); or (XXXXI) methyl 3- (dimethoxyphosphinoyloxy) but-2-enoate (Mevinphos); or (XXXXII) Dimethyl (E) -1-methyl-2- (methylcarbamoyl) vinyl phosphate (Monocrotophos); or (XXXXIII) O, O-Diethyl O-4-Nitrophenyl Phosphorothioate (Parathion); or (XXXXIV) O, O-dimethyl O-4-nitrophenyl phosphorothioate (parathion-methyl); or (XXXXV) S-6-chloro-2,3-dihydro-2-oxo-1,3-benzoxazol-3-ylmethyl O, O-diethyl phosphorodithioate (Phosalone); or (XXXXVI) 2-chloro-2-diethylcarbamoyl-1-methylvinyl dimethyl phosphate (phosphamidon); or (XXXXVII) 2-dimethylamino-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (pirimicarb); or (XXXXVIII) O-4-bromo-2-chlorophenyl O-ethyl S-propyl phosphorothioate (Profenofos); or (IL) 2-isopropoxyphenyl methyl carbamate (Propoxur); or (L) 1- (3,5-dichloro-2,4-difluorophenyl) -3- (2,6-difluorobenzoyl) urea (teflubenzuron); or (LI) S-tert-Butylthiomethyl O, O-Diethyl Phosphorodithioate (Terbufos); or (LII) ethyl (3-tert-butyl-1-dimethyl carbamoyl-1H-1,2,4-triazol-5-yl-thio) acetate (triazamate); or (LIII) a substance obtainable from a Bacillus thuringiensis strain, for example GC 91 (NCTC 11821); or (LIV) a mixture of compounds known under the name Abamectin; or (LV) isopropyl 4.4 min -dibromobenzilate (bromopropylate); or (LVI) contains zeta-cypermethrin. 5. A process for the preparation of an agent as described in one of claims 1 to 4, characterized in that the active ingredients are intimately mixed with the auxiliary substance (s). 6. Use of an agent according to any one of claims 1 to 4 in a method for controlling pests, characterized in that the pests or their habitat are treated with said agent. 7. Use of an agent according to claim 6 for the protection of plant reproductive material, characterized in that the reproductive material or the place of application of the reproductive material is treated with an agent according to claim 1.